File name: Pandora257s1_AustinTX_20240322_L2Fit_fout2c2d20230110p1-8.txt File generation date: 20240323T064527.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 257 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora257_OF_v2d20221216.txt Instrument calibration file used: Pandora257s1_CF_v2d20230110.txt Level 1 file used: Pandora257s1_AustinTX_20240322_L1_smca1c2d20230110p1-8.txt Full location name: St. Edward's University Short location name: AustinTX Country of location: United States Location latitude [deg]: 30.2285 Location longitude [deg]: -97.7544 Location altitude [m]: 205 Local noon date: 20240322 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 228 370 Nominal wavelengths inside fitting window [nm]: 305.0779 305.2183 305.3587 305.4991 305.6395 305.7799 305.9203 306.0607 306.2010 306.3413 306.4817 306.6220 306.7623 306.9026 307.0429 307.1832 307.3234 307.4637 307.6039 307.7442 307.8844 308.0246 308.1648 308.3050 308.4452 308.5854 308.7255 308.8657 309.0058 309.1459 309.2860 309.4261 309.5662 309.7063 309.8464 309.9865 310.1265 310.2665 310.4066 310.5466 310.6866 310.8266 310.9666 311.1065 311.2465 311.3865 311.5264 311.6663 311.8062 311.9461 312.0860 312.2259 312.3658 312.5057 312.6455 312.7854 312.9252 313.0650 313.2048 313.3446 313.4844 313.6242 313.7639 313.9037 314.0434 314.1832 314.3229 314.4626 314.6023 314.7420 314.8816 315.0213 315.1610 315.3006 315.4402 315.5799 315.7195 315.8591 315.9986 316.1382 316.2778 316.4173 316.5569 316.6964 316.8359 316.9754 317.1149 317.2544 317.3939 317.5334 317.6728 317.8123 317.9517 318.0911 318.2305 318.3699 318.5093 318.6487 318.7880 318.9274 319.0667 319.2061 319.3454 319.4847 319.6240 319.7633 319.9025 320.0418 320.1810 320.3203 320.4595 320.5987 320.7379 320.8771 321.0163 321.1555 321.2946 321.4338 321.5729 321.7121 321.8512 321.9903 322.1294 322.2685 322.4075 322.5466 322.6856 322.8247 322.9637 323.1027 323.2417 323.3807 323.5197 323.6587 323.7976 323.9366 324.0755 324.2144 324.3533 324.4922 324.6311 324.7700 324.9089 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240322T143651.8Z 8847.608933 268 1 4.44 2 64.04 105.17 125.72 317.61 0.00 1 0.00 1 0 17 3.674e-02 7.976e-03 2.213e-02 5.351e-03 3.296381e-01 2.934709e-03 3.543610e-03 -6.000000e+00 2.338858e-02 227.55 -2.00 3.25 -2.00 317.71 0.00e+00 8.951389e-04 5.031279e-04 1.279180e-04 -6.000000e+00 1.067963e-03 285.03 -2.00 20.00 -2.00 316.94 0.00e+00 2.271 0.000 302.00 328.00 3 4.5085e+00 7.8110e-03 2.7111e-02 -6.0000e+00 5.7922e-02 1.3940e-02 8.7992e-03 1.5543e-02 -6.0000e+00 6.2601e-02 8.9354e-03 5.3805e-03 7.6253e-03 -6.0000e+00 3.7377e-02 -8.6309e-03 2.6403e-03 2.3553e-03 -6.0000e+00 1.5519e-02 4.1361e-04 1.6122e-03 1.8893e-04 3.1913e-05 -6.0000e+00 1.3267e-03 1.4205e-02 2.3734e-04 12 9 1 12 1 1 99.98 26.57 0.12 0.01420 0.02632 3 5 2 5 0 1108.810 35.00 20.00 26.57 20.46 0.2 902.80 -15256 -14297 -16394 -8628 -17257 -9764 601 -9764 631 -9087 -1188 -5000 -3662 3229 2360 -3653 -5894 5734 5106 -1630 9495 -1473 4903 914 1270 -1122 -3794 1821 1492 6214 1120 -775 2519 1875 -2243 6215 -2022 -943 308 1353 -277 -286 1414 -3277 -955 -1921 -751 846 -1077 -110 605 1718 1262 2463 -1365 -237 442 108 -4 -502 1335 307 2315 534 -263 -51 1294 572 343 265 849 1275 40 251 -61 35 793 -1916 16 -1768 -928 -1682 -1653 -2064 -336 -115 -298 -103 798 -88 15 16 83 -25 271 822 614 581 -505 -414 -726 -817 476 30 -414 -64 -6 -809 -97 239 -189 85 59 241 -186 83 1369 774 -227 109 -409 293 189 437 -67 -106 840 335 1614 154 -225 -675 174 -93 -134 -573 -84 178 509 110 -488 -331 -502 -1202 -1201 -1429 -675 -1414 -739 43 -851 54 -901 -115 -545 -445 421 352 -639 -1132 1035 970 -343 1828 -293 1041 192 279 -258 -891 433 350 1414 259 -197 658 505 -631 1654 -641 -341 128 581 -133 -145 729 -1799 -515 -1045 -401 442 -577 -60 346 1036 751 1523 -910 -160 301 74 -3 -346 937 232 1704 419 -209 -39 944 422 269 227 778 1129 36 231 -52 27 625 -1519 12 -1504 -873 -1637 -1735 -2172 -371 -134 -344 -121 930 -106 17 17 88 -26 296 918 715 740 -682 -557 -936 -992 582 37 -509 -83 -8 -1109 -140 346 -289 132 90 345 -265 112 1814 1064 -332 166 -606 429 284 633 -93 -148 1136 459 2295 224 -346 -1034 273 -152 -218 -985 -148 319 913 194 -838 -549 -821 SS 20240322T144447.6Z 8847.614440 274 1 3.15 2 62.39 106.40 126.84 319.46 0.00 1 0.00 1 0 25 1.901e-02 6.981e-03 1.053e-02 3.608e-03 3.149686e-01 1.985702e-03 3.484319e-03 -6.000000e+00 1.208449e-02 227.55 -2.00 3.25 -2.00 317.06 0.00e+00 2.769554e-04 2.842201e-04 1.725507e-04 -6.000000e+00 5.523434e-04 285.03 -2.00 20.00 -2.00 316.31 0.00e+00 2.147 0.000 302.00 328.00 3 3.7499e+00 5.2127e-03 2.5788e-02 -6.0000e+00 2.9927e-02 2.3115e-02 5.8367e-03 1.4930e-02 -6.0000e+00 3.2362e-02 3.4963e-05 3.4275e-03 7.3124e-03 -6.0000e+00 1.9320e-02 -1.6026e-03 1.6180e-03 2.0314e-03 -6.0000e+00 8.0092e-03 1.0142e-03 1.6750e-04 1.2648e-04 3.0850e-05 -6.0000e+00 6.8669e-04 1.7010e-02 -4.9230e-05 12 9 1 12 1 1 99.94 26.58 0.46 0.01701 0.01827 5 10 1 5 0 524.720 35.00 20.00 26.58 21.05 0.2 906.88 -3490 -10081 -5800 -2769 -7944 -8651 -368 -7278 -2563 -1719 2882 -1826 -1838 1163 1272 465 -1088 1772 1331 3448 2672 -701 2203 374 50 -1895 -282 338 -792 979 3106 136 -701 -1453 -3052 95 -1254 -1324 653 208 -1134 -1244 601 -358 -874 -103 -1064 150 -160 -38 1075 977 927 1856 542 546 729 1131 -117 1290 682 981 1908 915 -21 -182 982 953 1122 1127 -30 -488 -32 622 -1404 -91 -698 36 -340 -822 -1365 -1882 -2003 -1718 -772 -962 -457 440 631 -379 220 -119 814 -490 637 458 74 571 487 -837 -805 -588 -1119 -16 -197 -664 -684 -194 -110 607 304 304 264 381 131 236 202 360 194 326 -289 -190 462 362 272 889 488 850 889 451 -117 -238 -110 -76 -61 -136 68 41 242 -474 -291 -460 -645 -392 -1291 -718 -322 -931 -1017 -42 -973 -353 -248 417 -272 -307 215 265 107 -271 452 355 930 742 -188 593 107 15 -595 -86 100 -231 284 931 45 -248 -529 -1128 35 -514 -578 325 110 -663 -719 351 -214 -527 -61 -634 87 -94 -23 674 652 616 1284 394 407 549 847 -88 967 533 766 1575 797 -17 -154 794 773 961 994 -29 -464 -31 593 -1275 -79 -568 28 -282 -713 -1324 -1911 -2084 -1897 -856 -1134 -536 524 749 -459 248 -132 839 -504 679 509 92 728 624 -1082 -1039 -712 -1370 -19 -242 -868 -901 -268 -153 894 451 458 389 554 178 320 271 497 271 476 -433 -283 668 503 377 1170 654 1142 1198 649 -172 -363 -166 -120 -97 -226 112 69 407 -786 -484 -742 -1025 SS 20240322T145309.7Z 8847.620251 280 1 44.43 2 60.66 107.74 127.97 321.47 0.00 1 0.00 1 0 17 2.477e-02 7.101e-03 4.671e-03 1.463e-03 2.955544e-01 8.046458e-04 3.244354e-03 -6.000000e+00 1.575174e-02 227.55 -2.00 3.25 -2.00 317.22 0.00e+00 1.881547e-04 1.209279e-04 1.174627e-04 -6.000000e+00 7.195972e-04 285.03 -2.00 20.00 -2.00 316.47 0.00e+00 2.032 0.000 302.00 328.00 3 4.7431e+00 2.1219e-03 2.4330e-02 -6.0000e+00 3.9010e-02 3.0594e-02 2.3806e-03 1.4003e-02 -6.0000e+00 4.2174e-02 7.7111e-03 1.4120e-03 6.8641e-03 -6.0000e+00 2.5179e-02 -6.9749e-03 6.7300e-04 1.9241e-03 -6.0000e+00 1.0445e-02 4.2992e-04 6.6942e-04 5.1869e-05 2.8777e-05 -6.0000e+00 8.9452e-04 1.5715e-02 6.0390e-05 12 9 1 12 1 1 100.00 26.61 0.14 0.01572 0.02075 54 7 1 5 0 807.650 35.00 20.00 26.61 21.44 0.2 910.08 -7766 -5499 -6902 -702 -15937 -9411 -5698 -6514 2674 -3476 -1091 -4225 1599 4759 4692 -1710 -942 6336 2746 588 2935 -889 4284 369 -57 -1197 -3317 1099 -1356 1292 -378 1343 -1327 1011 -4268 2753 -2517 -2310 -26 710 -419 198 791 -1034 -604 -490 -1546 962 -108 -407 944 1759 332 1397 51 -1 886 -27 626 908 832 1421 2333 1384 -129 -515 832 104 342 1164 -187 633 -139 163 -324 -379 -405 -1030 -567 -829 -1521 -1806 -2055 -1549 -598 -830 -526 -24 622 266 -15 60 286 -139 614 1007 847 663 134 -492 -705 -488 -482 108 -214 -609 -701 -459 -92 486 437 286 67 307 -18 122 499 -40 -143 240 -283 -150 343 574 160 497 383 481 1038 340 -131 -366 -173 -189 -47 123 -133 309 367 -232 -521 -449 -460 -817 -603 -773 -71 -1803 -991 -610 -766 310 -451 -145 -621 247 809 895 -380 -221 1449 615 139 691 -222 1045 98 -16 -344 -964 296 -364 340 -106 397 -425 322 -1431 884 -933 -984 -12 355 -231 115 469 -633 -369 -297 -936 562 -64 -246 591 1071 217 948 36 -1 648 -20 456 665 631 1138 1832 1144 -108 -416 686 86 278 1020 -179 582 -129 156 -290 -311 -333 -829 -473 -707 -1450 -1768 -2171 -1731 -661 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