File name: Pandora257s1_AustinTX_20240828_L2Fit_fout2c2d20230110p1-8.txt File generation date: 20240829T063934.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Paul Walter Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 257 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora257_OF_v3d20221216.txt Instrument calibration file used: Pandora257s1_CF_v2d20230110.txt Level 1 file used: Pandora257s1_AustinTX_20240828_L1_smca1c2d20230110p1-8.txt Full location name: St. Edward's University Short location name: AustinTX Country of location: United States Location latitude [deg]: 30.2285 Location longitude [deg]: -97.7544 Location altitude [m]: 205 Local noon date: 20240828 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 228 370 Nominal wavelengths inside fitting window [nm]: 305.0779 305.2183 305.3587 305.4991 305.6395 305.7799 305.9203 306.0607 306.2010 306.3413 306.4817 306.6220 306.7623 306.9026 307.0429 307.1832 307.3234 307.4637 307.6039 307.7442 307.8844 308.0246 308.1648 308.3050 308.4452 308.5854 308.7255 308.8657 309.0058 309.1459 309.2860 309.4261 309.5662 309.7063 309.8464 309.9865 310.1265 310.2665 310.4066 310.5466 310.6866 310.8266 310.9666 311.1065 311.2465 311.3865 311.5264 311.6663 311.8062 311.9461 312.0860 312.2259 312.3658 312.5057 312.6455 312.7854 312.9252 313.0650 313.2048 313.3446 313.4844 313.6242 313.7639 313.9037 314.0434 314.1832 314.3229 314.4626 314.6023 314.7420 314.8816 315.0213 315.1610 315.3006 315.4402 315.5799 315.7195 315.8591 315.9986 316.1382 316.2778 316.4173 316.5569 316.6964 316.8359 316.9754 317.1149 317.2544 317.3939 317.5334 317.6728 317.8123 317.9517 318.0911 318.2305 318.3699 318.5093 318.6487 318.7880 318.9274 319.0667 319.2061 319.3454 319.4847 319.6240 319.7633 319.9025 320.0418 320.1810 320.3203 320.4595 320.5987 320.7379 320.8771 321.0163 321.1555 321.2946 321.4338 321.5729 321.7121 321.8512 321.9903 322.1294 322.2685 322.4075 322.5466 322.6856 322.8247 322.9637 323.1027 323.2417 323.3807 323.5197 323.6587 323.7976 323.9366 324.0755 324.2144 324.3533 324.4922 324.6311 324.7700 324.9089 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240828T141948.5Z 9006.597089 281 1 2.84 2 62.09 95.45 1.89 210.44 0.00 1 0.00 1 0 17 1.899e-02 7.752e-03 1.164e-02 4.743e-03 2.751298e-01 2.624131e-03 3.038735e-03 -6.000000e+00 1.211312e-02 229.07 -2.00 3.25 -2.00 316.71 0.00e+00 4.059034e-04 3.523039e-04 5.432203e-05 -6.000000e+00 5.700175e-04 293.01 -2.00 20.00 -2.00 315.82 0.00e+00 2.125 0.000 302.00 328.00 3 4.0093e+00 6.8761e-03 2.4559e-02 -6.0000e+00 3.0022e-02 2.6140e-02 7.6957e-03 1.3186e-02 -6.0000e+00 3.2400e-02 5.1459e-03 4.4321e-03 6.3954e-03 -6.0000e+00 1.9415e-02 -5.4943e-03 2.0426e-03 1.7867e-03 -6.0000e+00 8.0811e-03 8.5794e-04 3.3723e-04 1.6753e-04 2.7361e-05 -6.0000e+00 6.8613e-04 2.7861e-02 -5.4528e-05 12 9 1 12 1 1 999.00 28.18 0.24 0.02786 0.03039 2 6 1 5 0 943.240 36.00 20.00 28.18 33.50 0.0 991.24 1360 -6436 -2417 -3802 -13335 -6178 666 -1097 -4428 -610 -3770 612 -3132 -2358 3715 -1895 -1460 -1147 1574 -104 4491 1986 3015 2365 -2174 518 -302 457 413 -382 4486 1473 397 203 -2277 -64 -578 -863 -1297 -184 486 -796 449 1052 -153 337 -1808 -581 -836 669 1497 1862 416 1375 -443 642 627 431 102 1082 98 1447 1674 1234 -38 -652 -352 225 796 440 165 -988 -153 -287 -604 850 -251 -1599 -19 -965 -1240 -714 -1536 -2180 -867 -245 -621 -173 -243 831 787 439 -507 -711 701 1410 376 1336 19 -932 -214 -1075 10 310 -409 -1162 -894 -340 -183 516 95 438 -20 -67 188 685 82 -379 761 378 33 -485 7 234 324 1013 1165 317 1281 367 333 284 -592 48 69 -505 -502 145 220 -344 -310 -351 -581 194 -955 -345 -580 -2140 -920 98 -179 -728 -101 -672 112 -664 -560 925 -541 -403 -330 457 -32 1328 612 948 782 -783 184 -107 155 136 -128 1503 542 155 80 -921 -26 -241 -416 -676 -107 305 -497 285 670 -99 215 -1162 -364 -524 422 982 1291 309 992 -336 493 486 334 79 839 80 1162 1425 1093 -34 -558 -288 184 684 414 157 -988 -152 -273 -569 725 -214 -1349 -16 -874 -1179 -739 -1630 -2352 -983 -293 -744 -211 -295 1009 895 488 -535 -740 754 1559 463 1680 24 -1182 -269 -1286 12 379 -505 -1529 -1178 -468 -253 751 139 640 -30 -94 257 889 107 -511 1069 535 48 -705 10 332 436 1357 1511 417 1748 512 488 412 -894 72 108 -799 -821 240 364 -562 -491 -561 -921 SS 20240828T142431.1Z 9006.600360 284 1 54.69 2 61.07 96.10 2.55 230.58 0.00 1 0.00 1 0 17 9.222e-03 5.735e-03 5.405e-04 2.397e-04 2.667213e-01 1.327562e-04 2.932965e-03 -6.000000e+00 5.883133e-03 229.07 -2.00 3.25 -2.00 316.48 0.00e+00 2.669787e-04 1.682516e-05 8.639155e-05 -6.000000e+00 2.768640e-04 293.01 -2.00 20.00 -2.00 315.60 0.00e+00 2.058 0.000 302.00 328.00 3 1.5433e+00 3.4631e-04 2.3752e-02 -6.0000e+00 1.4581e-02 8.2353e-03 3.8694e-04 1.2700e-02 -6.0000e+00 1.5736e-02 -1.4175e-03 2.2156e-04 6.1584e-03 -6.0000e+00 9.4299e-03 -3.7937e-03 1.0076e-04 1.6904e-03 -6.0000e+00 3.9246e-03 1.1061e-02 2.5603e-04 8.5042e-06 2.6577e-05 -6.0000e+00 3.3326e-04 2.8731e-02 -3.9138e-05 10 0 0 10 0 0 99.99 28.20 0.30 0.02873 0.03065 3241 313 1 5 0 16.870 36.25 19.99 28.20 33.77 0.0 994.31 -1303 -2758 -2884 -3498 -3565 -1879 -717 -376 -454 -1832 -2450 -502 -49 173 577 -208 -383 619 633 1151 898 439 1104 1118 614 260 -462 -498 -40 1074 1099 582 679 -1036 -2527 -1188 -773 -476 -65 -376 -1091 -696 -420 -594 -369 -188 -548 -178 -111 210 948 931 756 1040 575 799 894 556 538 889 1228 1460 1307 1199 30 -546 -78 -11 798 887 149 9 -114 61 -74 -329 -245 -539 -230 -503 -1220 -1417 -1900 -1712 -903 -686 -323 -155 130 193 49 294 152 446 814 519 300 437 35 -529 -472 -533 -597 56 -112 -1022 -675 -407 -158 314 352 153 66 42 -36 225 419 352 377 252 -128 -83 371 302 484 635 280 808 1001 324 114 -78 -240 -20 110 5 -241 125 96 -407 -304 -385 -620 -207 -470 -491 -574 -559 -289 -115 -65 -85 -363 -508 -109 -12 43 158 -62 -121 203 215 399 318 147 377 399 229 99 -174 -181 -14 375 402 227 278 -436 -1075 -514 -341 -241 -36 -232 -691 -462 -285 -409 -253 -128 -368 -117 -73 141 659 646 555 795 431 610 689 429 414 689 985 1241 1119 1064 27 -467 -68 -9 684 827 143 9 -114 58 -70 -284 -207 -446 -199 -452 -1161 -1408 -2037 -1859 -1036 -797 -393 -193 160 229 56 315 161 463 881 585 357 539 45 -681 -579 -644 -700 67 -140 -1311 -907 -551 -216 451 506 222 96 58 -48 299 553 481 521 353 -184 -119 516 420 668 837 359 1037 1342 444 164 -112 -357 -30 171 8 -392 207 159 -666 -482 -615 -982 SS 20240828T151033.1Z 9006.632327 315 1 20.11 2 51.27 103.03 11.86 265.34 0.00 1 0.00 1 0 17 8.098e-03 6.050e-03 1.009e-03 6.597e-04 2.073734e-01 3.695322e-04 2.305239e-03 -6.000000e+00 5.166674e-03 229.07 -2.00 3.25 -2.00 315.22 0.00e+00 2.760407e-04 3.575789e-05 3.576364e-05 -6.000000e+00 2.431151e-04 293.01 -2.00 20.00 -2.00 314.45 0.00e+00 1.595 0.000 302.00 328.00 3 3.1442e+00 9.4927e-04 1.8426e-02 -6.0000e+00 1.2806e-02 1.7718e-02 1.0535e-03 9.8612e-03 -6.0000e+00 1.3820e-02 2.7241e-03 5.9997e-04 4.7901e-03 -6.0000e+00 8.2813e-03 -3.8257e-03 2.5814e-04 1.3226e-03 -6.0000e+00 3.4469e-03 3.8212e-03 3.5416e-04 2.3367e-05 2.2705e-05 -6.0000e+00 2.9264e-04 2.8264e-02 -2.7833e-05 12 1 1 12 1 1 99.99 28.40 0.31 0.02826 0.03093 118 31 1 5 0 168.900 36.25 20.01 28.40 36.75 0.0 1015.56 -501 -1691 -1730 -3174 -2663 -474 215 726 398 -1528 -1537 -637 96 430 410 96 7 734 961 895 1016 745 1456 1084 511 219 -223 -356 33 1243 1412 888 838 -975 -2258 -832 -836 -358 -240 -662 -1071 -829 -401 -782 -461 -357 -733 -302 -255 395 920 784 723 932 473 770 1015 501 466 774 1099 1553 1167 893 -216 -716 -47 -75 613 960 62 36 -70 134 -166 -388 -327 -585 -109 -453 -1227 -1475 -1942 -1743 -894 -629 -302 -163 146 135 -6 295 25 376 790 577 324 515 107 -463 -420 -519 -545 74 -117 -948 -635 -394 -158 401 442 281 85 3 -24 223 301 342 368 324 -54 -95 369 358 532 693 331 795 970 200 117 -106 -334 1 32 -17 -213 77 106 -455 -351 -357 -669 -151 -538 -545 -964 -763 -131 62 225 132 -496 -512 -222 36 167 174 41 3 336 451 430 495 368 731 533 261 113 -113 -185 16 605 706 468 430 -512 -1190 -444 -489 -225 -165 -486 -814 -628 -309 -610 -357 -273 -576 -231 -192 299 718 616 596 796 399 659 873 432 401 671 983 1401 1115 844 -203 -667 -43 -68 559 907 64 37 -72 137 -158 -354 -288 -522 -96 -417 -1201 -1513 -2062 -1960 -1023 -737 -369 -197 181 162 -7 325 27 391 849 646 384 634 133 -572 -512 -621 -634 87 -141 -1178 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