File name: Pandora257s1_AustinTX_20250603_L2Fit_fwvt1c2d20230110p1-8.txt File generation date: 20250604T063442.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Paul Walter Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 257 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora257_OF_v3d20221216.txt Instrument calibration file used: Pandora257s1_CF_v2d20230110.txt Level 1 file used: Pandora257s1_AustinTX_20250603_L1_smca1c2d20230110p1-8.txt Full location name: St. Edward's University Short location name: AustinTX Country of location: United States Location latitude [deg]: 30.2285 Location longitude [deg]: -97.7544 Location altitude [m]: 205 Local noon date: 20250603 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 1653 1803 Nominal wavelengths inside fitting window [nm]: 492.0741 492.1946 492.3152 492.4357 492.5562 492.6767 492.7971 492.9176 493.0380 493.1584 493.2788 493.3992 493.5196 493.6399 493.7603 493.8806 494.0009 494.1211 494.2414 494.3617 494.4819 494.6021 494.7223 494.8425 494.9626 495.0828 495.2029 495.3230 495.4431 495.5632 495.6832 495.8033 495.9233 496.0433 496.1633 496.2832 496.4032 496.5231 496.6430 496.7630 496.8828 497.0027 497.1226 497.2424 497.3622 497.4820 497.6018 497.7215 497.8413 497.9610 498.0807 498.2004 498.3201 498.4398 498.5594 498.6790 498.7987 498.9183 499.0378 499.1574 499.2769 499.3964 499.5160 499.6354 499.7549 499.8744 499.9938 500.1132 500.2326 500.3520 500.4714 500.5907 500.7101 500.8294 500.9487 501.0680 501.1872 501.3065 501.4257 501.5449 501.6641 501.7833 501.9024 502.0216 502.1407 502.2598 502.3789 502.4980 502.6170 502.7361 502.8551 502.9741 503.0931 503.2121 503.3310 503.4500 503.5689 503.6878 503.8067 503.9255 504.0444 504.1632 504.2820 504.4008 504.5196 504.6383 504.7571 504.8758 504.9945 505.1132 505.2319 505.3505 505.4692 505.5878 505.7064 505.8250 505.9436 506.0621 506.1806 506.2992 506.4177 506.5361 506.6546 506.7730 506.8915 507.0099 507.1283 507.2467 507.3650 507.4834 507.6017 507.7200 507.8383 507.9565 508.0748 508.1930 508.3113 508.4295 508.5476 508.6658 508.7839 508.9021 509.0202 509.1383 509.2564 509.3744 509.4925 509.6105 509.7285 509.8465 509.9645 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250603T131317.9Z 9285.550902 111 1 6.86 2 69.87 75.18 144.77 6.69 0.00 1 0.00 1 0 29 4.858e-03 4.824e-03 6.642e-04 6.635e-04 6.689235e+03 4.500704e+01 4.612789e+02 -6.000000e+00 2.835828e+02 290.44 -2.00 20.00 -2.00 505.30 0.00e+00 6.307421e-04 1.876705e-05 4.661906e-05 -6.000000e+00 1.396613e-04 290.44 -2.00 20.00 -2.00 500.56 0.00e+00 1.713718e-01 1.313509e-02 4.149076e-02 -6.000000e+00 9.663532e-02 230.96 -2.00 3.25 -2.00 502.14 0.00e+00 2.874 0.000 489.00 513.00 1 5.2889e+00 1.0111e-03 5.4718e-03 -6.0000e+00 7.4429e-03 -1.4721e-03 2.5519e-04 1.0426e-03 -6.0000e+00 1.9047e-03 6.4141e-03 9.4825e-04 6.6879e-05 4.3951e-05 -6.0000e+00 5.1713e-04 2.6516e-02 -8.6820e-05 12 9 9 12 1 1 99.92 28.39 1.71 0.02652 0.03309 16 13 1 4 0 403.340 36.25 20.00 28.39 31.79 0.0 973.56 -887 -535 294 325 289 612 857 821 745 369 191 51 -213 -325 -442 -646 -384 349 508 253 251 127 121 305 509 526 458 404 -181 -809 -1033 -1007 -345 495 676 365 -148 -159 -380 -428 -320 -227 56 129 506 430 319 281 43 -165 -584 -1006 -1352 -967 -404 227 264 206 81 49 80 318 348 609 454 234 -96 -131 -173 -535 -488 -588 -362 141 565 46 -370 -686 -627 -416 -499 -249 -338 -341 -142 -191 -157 -179 -367 -438 -292 55 659 784 469 302 120 1 -298 -821 -1227 -1216 -523 371 485 385 -126 -499 -748 -478 -145 232 251 203 293 351 594 847 797 509 75 -64 -182 109 423 307 311 301 218 640 640 206 -93 -421 -634 -356 12 133 110 210 245 183 313 371 552 462 326 -243 -618 -830 -645 -855 -524 289 330 295 623 883 851 770 378 193 52 -215 -324 -440 -648 -391 354 525 261 259 132 125 317 529 545 472 419 -184 -821 -1035 -1014 -346 509 695 379 -154 -163 -386 -441 -330 -231 57 133 525 448 330 287 44 -165 -582 -986 -1316 -947 -403 228 269 208 82 49 81 323 355 619 458 238 -96 -130 -173 -531 -481 -581 -360 139 556 46 -367 -672 -608 -401 -482 -241 -330 -338 -139 -188 -155 -177 -363 -435 -291 56 653 775 469 295 117 0 -284 -773 -1156 -1164 -503 360 484 381 -125 -491 -733 -469 -144 231 253 206 293 353 599 856 803 508 75 -64 -179 107 415 302 307 296 215 625 633 202 -90 -405 -612 -347 12 131 110 209 245 185 317 376 559 465 325 -239 -610 -814 -636 SQ 20250603T132606.1Z 9285.559793 117 1 54.09 2 67.19 76.53 144.39 11.93 0.00 1 0.00 1 0 22 5.538e-03 5.509e-03 1.009e-03 1.007e-03 6.612763e+03 6.878295e+01 4.629540e+02 -6.000000e+00 3.232392e+02 290.44 -2.00 20.00 -2.00 505.27 0.00e+00 6.526784e-04 2.854067e-05 4.494389e-05 -6.000000e+00 1.591918e-04 290.44 -2.00 20.00 -2.00 500.44 0.00e+00 2.508889e-01 2.004943e-02 3.881846e-02 -6.000000e+00 1.101502e-01 230.96 -2.00 3.25 -2.00 502.03 0.00e+00 2.558 0.000 489.00 513.00 1 8.0796e+00 1.5462e-03 5.0111e-03 -6.0000e+00 8.4838e-03 8.5380e-03 3.8933e-04 9.9203e-04 -6.0000e+00 2.1712e-03 4.0892e-04 1.2497e-03 1.0088e-04 4.5413e-05 -6.0000e+00 5.8945e-04 2.9049e-02 -1.0335e-04 12 8 8 10 0 0 99.99 28.40 1.76 0.02905 0.03772 25 2 1 4 0 2163.100 36.25 20.00 28.40 32.21 0.0 976.37 -1102 -507 239 441 119 719 574 1020 445 73 -151 -469 28 -237 -679 -457 -381 437 752 17 379 91 -151 133 418 779 639 573 -19 -997 -1114 -894 44 651 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-469 205 22 740 151 65 703 621 1070 764 322 -34 -264 176 108 528 425 415 54 498 528 367 116 -153 -750 -703 -493 -8 411 -157 351 283 260 59 814 573 541 361 -474 -687 -1040 -708 SQ 20250603T134438.2Z 9285.572664 128 1 55.40 2 63.28 78.46 143.43 19.28 0.00 1 0.00 1 0 22 4.726e-03 4.696e-03 5.189e-04 5.181e-04 5.675995e+03 3.465278e+01 3.999625e+02 -6.000000e+00 2.758830e+02 290.44 -2.00 20.00 -2.00 505.28 0.00e+00 5.279179e-04 1.463623e-05 3.833417e-05 -6.000000e+00 1.358702e-04 290.44 -2.00 20.00 -2.00 500.51 0.00e+00 1.263317e-01 1.025603e-02 3.432902e-02 -6.000000e+00 9.401381e-02 230.96 -2.00 3.25 -2.00 502.09 0.00e+00 2.211 0.000 489.00 513.00 1 6.9838e+00 7.8925e-04 4.3676e-03 -6.0000e+00 7.2410e-03 7.1699e-03 1.9997e-04 8.7253e-04 -6.0000e+00 1.8531e-03 1.3005e-03 8.4152e-04 5.2412e-05 3.7883e-05 -6.0000e+00 5.0310e-04 2.7678e-02 -9.5855e-05 12 8 8 10 0 0 99.80 28.42 1.69 0.02768 0.03351 39 4 1 4 0 1420.080 36.25 20.00 28.42 32.13 0.0 975.98 -1008 -323 261 331 213 430 732 818 610 278 78 -140 -65 -384 -427 -575 -446 297 555 272 320 129 -29 255 440 468 588 521 -140 -868 -1108 -899 -286 614 713 240 -40 -174 -349 -502 -332 -264 -151 267 556 359 457 164 163 -98 -510 -797 -1184 -1021 -379 251 160 111 -20 113 135 473 394 399 304 110 -33 -181 -113 -535 -484 -501 -174 103 461 163 -399 -511 -476 -435 -620 -275 -381 -304 -70 -214 -45 -210 -424 -301 -447 111 647 720 676 492 210 -71 -269 -819 -1272 -1136 -615 368 561 290 -68 -455 -637 -389 -105 22 313 225 16 329 520 853 717 472 72 -251 72 219 483 487 364 64 295 492 408 265 -269 -442 -703 -290 -3 171 4 318 114 206 272 476 572 491 314 -324 -582 -840 -692 -969 -315 260 341 217 447 771 867 645 292 81 -143 -65 -383 -425 -576 -454 307 585 281 332 134 -30 266 459 487 607 548 -144 -878 -1107 -900 -292 640 735 250 -41 -178 -354 -525 -346 -268 -154 276 576 373 471 167 169 -99 -504 -772 -1179 -990 -375 253 165 112 -21 114 136 477 399 404 305 113 -34 -181 -112 -524 -470 -487 -170 102 457 161 -390 -493 -454 -428 -591 -263 -368 -296 -69 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