File name: Pandora38s1_BayonneNJ_20210404_L2Fit_fout2c6d20210317p1-8.txt File generation date: 20250227T135216.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 38 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora38_OF_v4d20201028.txt Instrument calibration file used: Pandora38s1_CF_v6d20210317.txt Level 1 file used: Pandora38s1_BayonneNJ_20210404_L1_smca1c6d20210317p1-8.txt Full location name: Bayonne NJDEP (USEPA AQS ID 34-017-0006) Short location name: BayonneNJ Country of location: USA Location latitude [deg]: 40.6703 Location longitude [deg]: -74.1261 Location altitude [m]: 3 Local noon date: 20210404 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 259 401 Nominal wavelengths inside fitting window [nm]: 305.1058 305.2465 305.3872 305.5279 305.6685 305.8092 305.9498 306.0904 306.2310 306.3716 306.5122 306.6528 306.7933 306.9339 307.0744 307.2150 307.3555 307.4960 307.6365 307.7770 307.9174 308.0579 308.1983 308.3388 308.4792 308.6196 308.7600 308.9004 309.0408 309.1812 309.3215 309.4619 309.6022 309.7425 309.8828 310.0231 310.1634 310.3037 310.4439 310.5842 310.7244 310.8647 311.0049 311.1451 311.2853 311.4255 311.5656 311.7058 311.8460 311.9861 312.1262 312.2663 312.4064 312.5465 312.6866 312.8267 312.9667 313.1068 313.2468 313.3868 313.5268 313.6668 313.8068 313.9468 314.0868 314.2267 314.3666 314.5066 314.6465 314.7864 314.9263 315.0662 315.2060 315.3459 315.4857 315.6256 315.7654 315.9052 316.0450 316.1848 316.3246 316.4643 316.6041 316.7438 316.8836 317.0233 317.1630 317.3027 317.4424 317.5820 317.7217 317.8613 318.0010 318.1406 318.2802 318.4198 318.5594 318.6990 318.8386 318.9781 319.1177 319.2572 319.3967 319.5362 319.6757 319.8152 319.9547 320.0941 320.2336 320.3730 320.5124 320.6518 320.7912 320.9306 321.0700 321.2094 321.3487 321.4881 321.6274 321.7667 321.9060 322.0453 322.1846 322.3239 322.4631 322.6024 322.7416 322.8808 323.0201 323.1593 323.2984 323.4376 323.5768 323.7159 323.8551 323.9942 324.1333 324.2724 324.4115 324.5506 324.6897 324.8287 324.9678 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210404T131708.7Z 7764.553573 254 1 11.45 2 60.42 109.37 72.38 208.26 0.00 1 0.00 1 0 17 1.757e-02 5.394e-03 9.629e-03 1.654e-03 3.584909e-01 8.495192e-04 4.242383e-03 -6.000000e+00 1.031960e-02 227.76 -2.00 3.51 -2.00 318.34 0.00e+00 3.348814e-04 1.638843e-04 1.156750e-04 -6.000000e+00 4.512746e-04 279.37 -2.00 20.00 -2.00 317.66 0.00e+00 2.017 0.000 302.00 328.00 3 3.0990e+00 2.2897e-03 2.7516e-02 -6.0000e+00 2.5646e-02 1.0163e-02 2.6001e-03 1.8413e-02 -6.0000e+00 2.7862e-02 -4.6835e-03 1.7188e-03 9.0851e-03 -6.0000e+00 1.6570e-02 -2.8777e-03 8.8488e-04 2.5639e-03 -6.0000e+00 6.9313e-03 1.9688e-03 -1.1140e-04 5.0554e-05 3.0572e-05 -6.0000e+00 5.1826e-04 -2.7727e-03 3.6226e-05 12 1 1 12 1 1 99.99 21.81 0.18 -0.00277 -0.00361 61 61 1 5 0 181.750 26.94 20.01 21.81 19.23 12.7 1046.63 642 -5688 -4009 -6984 -7846 -2736 -9394 1153 -4928 -109 -7020 -3234 -1428 -1753 494 -2062 265 -2018 644 131 335 624 -695 361 -246 723 -1107 -296 244 -270 1731 646 1507 -1583 -1350 -2488 -773 -388 -1153 -306 -1242 -488 -816 -80 -484 -545 -508 -986 145 -357 903 687 1625 1386 717 815 141 680 238 1196 925 1789 1561 559 675 -161 291 271 882 274 213 15 -85 25 -342 451 -516 451 -394 -668 -835 -1570 -1224 -1816 -910 -962 -317 23 -185 276 148 527 355 1276 792 836 759 534 112 -591 -564 -199 57 -430 -691 -787 -831 -351 53 151 98 17 86 175 279 184 562 229 195 -389 -193 -285 -210 542 230 741 671 862 350 390 187 -303 71 -100 29 -143 93 -405 -192 -20 -438 131 -129 31 -314 -220 -371 -427 -140 -559 70 -317 -7 -495 -238 -120 -173 55 -261 35 -288 94 20 52 96 -113 62 -45 136 -209 -53 42 -47 325 136 341 -374 -306 -578 -196 -116 -381 -116 -517 -212 -366 -36 -219 -247 -228 -440 64 -164 440 362 906 817 407 475 84 400 138 744 555 1152 1098 421 505 -115 197 184 649 227 178 13 -73 20 -277 327 -348 297 -282 -543 -712 -1488 -1238 -1954 -967 -1089 -374 27 -221 315 157 547 347 1234 827 908 924 672 149 -775 -738 -239 65 -510 -881 -1060 -1102 -488 79 225 154 26 132 269 398 250 764 327 295 -585 -293 -452 -322 793 322 1048 916 1200 494 594 301 -479 115 -169 51 -254 170 -753 -356 -36 -803 230 -223 SS 20210404T132228.9Z 7764.557279 257 1 1.86 2 59.47 110.44 72.84 209.38 0.00 1 0.00 1 0 17 1.423e-02 5.859e-03 1.166e-02 2.869e-03 3.486243e-01 1.479677e-03 4.158040e-03 -6.000000e+00 8.356171e-03 227.76 -2.00 3.51 -2.00 317.65 0.00e+00 1.261459e-04 2.337749e-04 1.026926e-04 -6.000000e+00 3.654963e-04 279.37 -2.00 20.00 -2.00 316.97 0.00e+00 1.961 0.000 302.00 328.00 3 2.5687e+00 3.9240e-03 2.6729e-02 -6.0000e+00 2.0766e-02 4.5106e-03 4.4201e-03 1.7859e-02 -6.0000e+00 2.2562e-02 -7.4141e-03 2.7393e-03 8.8009e-03 -6.0000e+00 1.3418e-02 3.9033e-04 1.3721e-03 2.4574e-03 -6.0000e+00 5.6117e-03 3.6002e-03 -4.9242e-04 8.6979e-05 3.0053e-05 -6.0000e+00 4.1975e-04 -2.1982e-03 8.2815e-06 12 1 1 12 1 1 47.41 21.81 0.21 -0.00220 -0.00590 10 72 1 5 0 153.670 26.94 20.00 21.81 19.34 12.8 1046.97 -7200 -3875 -7328 -4539 -2323 -4574 1139 -2718 1312 -3331 -370 -25 -2582 1701 581 1339 -2745 1194 -335 1497 649 136 125 1409 -430 -209 372 -1442 483 53 -253 1590 -876 -389 -1168 -1454 -2087 -1050 80 -375 -1429 -865 -648 -242 -719 -361 -801 -53 -236 633 449 1029 1485 917 1037 796 862 1000 288 622 1351 1267 1500 834 74 -602 -121 882 848 541 59 -286 102 60 -293 344 4 566 -202 -201 -757 -1117 -1814 -1895 -1202 -1141 -476 -494 -175 -33 664 163 638 686 1022 681 653 560 -126 -407 -438 -140 224 -256 -134 -828 -832 -466 -76 122 -118 67 180 124 -4 157 511 439 62 -623 -150 -417 -258 583 620 818 1162 438 507 447 397 -9 8 236 -160 -78 133 -410 -313 -131 -369 -91 -335 -575 -325 -643 -363 -167 -334 85 -239 122 -339 -37 -3 -332 245 98 226 -513 226 -67 306 136 29 28 327 -108 -54 94 -353 111 12 -65 445 -272 -122 -354 -446 -661 -389 33 -177 -743 -470 -337 -127 -378 -189 -417 -29 -130 332 252 620 950 584 683 540 592 682 194 418 937 952 1153 682 60 -468 -95 687 675 457 55 -273 96 54 -257 271 3 428 -156 -175 -707 -1093 -1914 -2010 -1352 -1301 -566 -602 -211 -38 741 176 644 691 1100 778 794 717 -170 -543 -547 -168 269 -303 -169 -1066 -1125 -632 -109 180 -183 102 274 178 -5 216 703 605 91 -928 -226 -616 -385 828 876 1100 1574 582 722 657 591 -14 13 377 -271 -134 232 -732 -557 -226 -614 -151 -546 SS 20210404T132823.7Z 7764.561385 260 1 49.38 2 58.42 111.64 73.38 210.60 0.00 1 0.00 1 0 17 3.161e-02 5.843e-03 2.452e-02 3.348e-03 3.402528e-01 1.723522e-03 3.999875e-03 -6.000000e+00 1.856407e-02 227.76 -2.00 3.51 -2.00 319.04 0.00e+00 6.256610e-04 3.978788e-04 1.832664e-04 -6.000000e+00 8.117314e-04 279.37 -2.00 20.00 -2.00 318.36 0.00e+00 1.902 0.000 302.00 328.00 3 4.4914e+00 4.7515e-03 2.6057e-02 -6.0000e+00 4.6136e-02 2.1457e-03 5.4623e-03 1.7569e-02 -6.0000e+00 5.0121e-02 2.1867e-02 3.8108e-03 8.6750e-03 -6.0000e+00 2.9808e-02 -1.4599e-02 1.9703e-03 2.5615e-03 -6.0000e+00 1.2469e-02 5.5789e-04 -1.6802e-05 1.0636e-04 3.1298e-05 -6.0000e+00 9.3222e-04 -2.8638e-03 5.1622e-05 10 0 0 10 0 0 99.99 21.80 0.15 -0.00286 -0.00299 356 81 1 5 0 137.140 26.83 20.00 21.80 19.40 12.7 1047.04 -8095 1767 -12378 1424 -9457 -10244 13837 -10436 8166 -13751 4160 -3200 -3167 5238 -3703 5966 -6770 3875 -3783 -1046 -1070 -559 3003 -2630 3133 -2708 -241 -3871 2305 2518 -760 6731 -820 2619 -2120 114 -2588 339 -1509 -1830 66 -2501 468 -1501 -605 -1278 -486 573 -1081 656 -423 1213 26 1295 514 457 1817 309 1274 23 1853 1768 1792 1133 51 304 -441 1236 -323 939 -453 20 190 -846 735 0 923 -342 213 12 -860 -1276 -1697 -1235 -1267 -224 -569 -257 70 232 389 102 1634 697 1723 618 830 584 -337 25 -800 -59 -173 -158 -647 -944 -887 -714 334 -87 92 -97 56 -32 153 288 298 417 -270 -357 -355 -187 -146 466 751 284 1023 398 702 406 143 -57 -59 342 -311 214 -117 -100 -186 -183 -142 -282 -24 -353 76 -621 58 -399 -432 497 -539 385 -845 219 -196 -224 400 -356 575 -724 393 -434 -121 -126 -66 355 -351 418 -395 -34 -536 315 351 -119 1083 -141 480 -392 21 -496 75 -404 -566 22 -893 167 -552 -221 -470 -176 203 -389 239 -167 507 12 608 252 230 913 156 629 11 948 980 1081 727 33 184 -255 707 -204 655 -347 16 148 -633 499 0 521 -192 128 8 -663 -1088 -1555 -1189 -1304 -243 -650 -300 81 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