File name: Pandora38s1_BayonneNJ_20220224_L2Fit_fout2c6d20210317p1-8.txt File generation date: 20250227T135144.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 38 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora38_OF_v4d20201028.txt Instrument calibration file used: Pandora38s1_CF_v6d20210317.txt Level 1 file used: Pandora38s1_BayonneNJ_20220224_L1_smca1c6d20210317p1-8.txt Full location name: Bayonne NJDEP (USEPA AQS ID 34-017-0006) Short location name: BayonneNJ Country of location: USA Location latitude [deg]: 40.6703 Location longitude [deg]: -74.1261 Location altitude [m]: 3 Local noon date: 20220224 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 259 401 Nominal wavelengths inside fitting window [nm]: 305.1058 305.2465 305.3872 305.5279 305.6685 305.8092 305.9498 306.0904 306.2310 306.3716 306.5122 306.6528 306.7933 306.9339 307.0744 307.2150 307.3555 307.4960 307.6365 307.7770 307.9174 308.0579 308.1983 308.3388 308.4792 308.6196 308.7600 308.9004 309.0408 309.1812 309.3215 309.4619 309.6022 309.7425 309.8828 310.0231 310.1634 310.3037 310.4439 310.5842 310.7244 310.8647 311.0049 311.1451 311.2853 311.4255 311.5656 311.7058 311.8460 311.9861 312.1262 312.2663 312.4064 312.5465 312.6866 312.8267 312.9667 313.1068 313.2468 313.3868 313.5268 313.6668 313.8068 313.9468 314.0868 314.2267 314.3666 314.5066 314.6465 314.7864 314.9263 315.0662 315.2060 315.3459 315.4857 315.6256 315.7654 315.9052 316.0450 316.1848 316.3246 316.4643 316.6041 316.7438 316.8836 317.0233 317.1630 317.3027 317.4424 317.5820 317.7217 317.8613 318.0010 318.1406 318.2802 318.4198 318.5594 318.6990 318.8386 318.9781 319.1177 319.2572 319.3967 319.5362 319.6757 319.8152 319.9547 320.0941 320.2336 320.3730 320.5124 320.6518 320.7912 320.9306 321.0700 321.2094 321.3487 321.4881 321.6274 321.7667 321.9060 322.0453 322.1846 322.3239 322.4631 322.6024 322.7416 322.8808 323.0201 323.1593 323.2984 323.4376 323.5768 323.7159 323.8551 323.9942 324.1333 324.2724 324.4115 324.5506 324.6897 324.8287 324.9678 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220224T125135.8Z 8090.535831 235 1 23.16 2 77.53 114.17 68.44 200.84 0.00 1 0.00 1 0 25 2.004e-01 8.546e-03 2.464e-01 8.103e-03 5.221757e-01 4.269123e-03 5.899794e-03 -6.000000e+00 1.165405e-01 225.33 -2.00 3.51 -2.00 320.56 0.00e+00 6.546724e-05 1.615784e-03 4.093616e-04 -6.000000e+00 5.114582e-03 276.08 -2.00 20.00 -2.00 320.00 0.00e+00 4.501 0.002 302.00 328.00 3 3.6990e+00 1.2858e-02 5.2219e-02 -6.0000e+00 2.8829e-01 4.5693e-02 1.6182e-02 2.7316e-02 -6.0000e+00 3.1410e-01 -9.5997e-03 1.5461e-02 1.3941e-02 -6.0000e+00 1.8680e-01 -8.2017e-03 7.7848e-03 4.1373e-03 -6.0000e+00 7.8754e-02 8.4833e-05 -3.6939e-04 2.5183e-04 5.2944e-05 -6.0000e+00 5.9320e-03 3.1853e-03 2.4099e-05 12 9 1 12 1 1 96.62 21.79 0.32 0.00319 0.00041 11 6 1 5 0 1915.500 26.83 19.99 21.79 6.67 25.5 1033.86 900000 -78290 63762 -19606 75900 -116621 -72141 -80270 33518 30214 -32549 -45305 -21281 -18509 -9490 1449 -23113 -10417 662 -22134 -14360 -19086 -2009 -32895 9396 -12478 -947 -4182 -1537 15611 40714 6302 -7333 22615 -834 -15379 12199 4294 -14380 1370 -3915 -2266 5055 -4206 -6064 -1230 2325 4008 -3292 9838 -1137 4998 -1520 3357 3612 1056 1391 1869 1691 1478 5306 1261 137 1371 -1660 643 1396 2873 1801 1933 -308 344 882 -384 1763 -138 -4026 334 -2569 -168 -765 242 -1858 -1756 -1034 -1707 -457 -1036 735 13 2244 163 130 -691 1126 1415 475 458 -141 674 -882 -1542 284 -554 -438 -898 -980 -296 -103 783 -480 713 -870 138 352 1471 -226 537 211 -1095 671 -100 -168 -75 42 1462 522 871 27 106 -441 -70 -122 -85 424 -409 162 -336 -347 56 -197 395 -85 900000 -1031 504 -155 600 -2150 -950 -1321 265 239 -429 -776 -350 -366 -206 32 -730 -315 19 -845 -520 -741 -70 -1711 346 -600 -41 -179 -64 586 1367 344 -512 1206 -55 -1205 819 376 -1846 176 -588 -357 769 -714 -1062 -208 384 665 -609 1703 -242 1102 -389 880 994 310 416 552 491 430 1558 424 52 557 -707 259 548 1154 811 907 -160 184 461 -192 858 -62 -1773 143 -1262 -93 -454 159 -1351 -1357 -848 -1500 -416 -969 669 11 1796 124 96 -528 933 1332 514 553 -168 846 -1050 -1689 290 -584 -493 -1075 -1239 -396 -139 1151 -769 1165 -1423 213 509 2029 -319 791 330 -1798 1080 -158 -257 -110 64 2100 741 1286 41 178 -802 -134 -243 -179 944 -896 362 -765 -787 122 -438 834 -179 SS 20220224T125651.7Z 8090.539487 238 1 48.59 2 76.62 115.12 68.81 202.02 0.00 1 0.00 1 0 17 3.902e-01 2.120e-02 3.219e-01 2.036e-02 4.844049e-01 1.073921e-02 5.678305e-03 -6.000000e+00 2.281955e-01 225.33 -2.00 3.51 -2.00 320.55 0.00e+00 5.661920e-03 3.880092e-03 1.801213e-03 -6.000000e+00 1.039803e-02 276.08 -2.00 20.00 -2.00 319.97 0.00e+00 4.216 0.001 302.00 328.00 3 5.3116e+00 3.2240e-02 4.8805e-02 -6.0000e+00 5.6656e-01 1.9109e-01 3.9243e-02 2.5192e-02 -6.0000e+00 6.1824e-01 -2.0307e-01 3.3731e-02 1.5118e-02 -6.0000e+00 3.6506e-01 9.6688e-02 1.7046e-02 7.1695e-03 -6.0000e+00 1.5352e-01 2.1848e-05 -3.8698e-04 6.4953e-04 9.6383e-05 -6.0000e+00 1.1719e-02 4.1280e-03 -4.1575e-05 12 8 8 10 0 0 99.60 21.79 0.33 0.00413 0.00122 13 3 1 5 0 3737.020 26.83 20.00 21.79 6.68 25.5 1033.98 900000 4409 97342 -80085 41177 -111402 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1206 -1012 3449 109 -99 4049 895 -1245 -557 3730 -962 157 2713 -1018 536 1862 1357 -255 269 532 -266 -585 1650 -265 -1008 2724 720 31 -4259 658 -31 -2431 -2592 1943 -2286 -484 1255 -375 2337 -988 -520 -1348 -5229 561 -1022 1611 -94 2332 -4598 -2030 -1802 -1345 -2647 -686 2193 4600 1619 2793 81 -1242 -206 720 -977 -704 627 640 360 3211 1167 -1263 -2869 -1036 3664 2122 -545 -2686 -1750 2419 -482 435 2557 -2330 -1648 -2183 4838 146 2084 -3495 2186 1184 -4082 SS 20220224T132254.5Z 8090.557575 248 1 48.74 2 72.23 120.00 70.86 207.74 0.00 1 0.00 1 0 25 2.934e-02 4.692e-03 4.458e-02 3.752e-03 3.847669e-01 1.936781e-03 4.489486e-03 -6.000000e+00 1.705299e-02 225.33 -2.00 3.51 -2.00 319.61 0.00e+00 1.344310e-04 5.205348e-04 1.738912e-04 -6.000000e+00 7.434959e-04 276.08 -2.00 20.00 -2.00 318.99 0.00e+00 3.233 0.001 302.00 328.00 3 4.0421e+00 5.4545e-03 3.7693e-02 -6.0000e+00 4.2186e-02 3.4330e-02 6.3688e-03 1.9802e-02 -6.0000e+00 4.5956e-02 -7.4767e-03 4.9371e-03 9.8551e-03 -6.0000e+00 2.7329e-02 -4.4798e-03 2.5718e-03 2.8432e-03 -6.0000e+00 1.1441e-02 2.3715e-04 -5.4082e-04 1.2023e-04 3.6592e-05 -6.0000e+00 8.6485e-04 3.6011e-03 -3.7501e-05 11 1 0 11 8 0 99.92 21.78 0.21 0.00360 -0.00046 63 14 1 5 0 773.490 26.83 19.99 21.78 6.79 25.5 1034.37 7288 4454 -5918 9442 -18384 -4883 -7650 -6744 -4279 -8172 2001 -7856 3099 -10931 657 -338 827 92 1247 6802 -1748 -1314 -6223 -2850 2480 -3681 1665 -4047 2448 -1186 -39 -2870 415 58 278 3070 -2820 -1281 -2227 90 422 -2547 962 -838 -590 463 -84 -395 -869 878 974 1286 669 1532 313 703 169 -134 -153 239 1171 874 2058 99 926 -186 -831 303 642 596 138 612 -256 -110 681 -582 233 -919 -66 -1027 -502 -1708 -1139 -1552 -1105 -224 -3 56 431 362 -188 1049 790 533 1054 -9 1278 901 -37 -563 -450 -665 -312 -548 -755 -569 -459 89 -193 176 254 -88 259 11 293 158 559 13 -160 -354 66 -294 -143 49 180 149 979 682 134 -112 203 -258 -105 -37 -212 -76 347 -162 57 18 -259 50 -56 158 108 -161 207 -495 -115 -204 -202 -138 -288 66 -314 130 -625 39 -23 58 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