File name: Pandora38s1_BayonneNJ_20240313_L2Fit_fwvt1c5d20230101p1-8.txt File generation date: 20240503T161244.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 38 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora38_OF_v4d20201028.txt Instrument calibration file used: Pandora38s1_CF_v5d20230101.txt Level 1 file used: Pandora38s1_BayonneNJ_20240313_L1_smca1c5d20230101p1-8.txt Full location name: Bayonne NJDEP (USEPA AQS ID 34-017-0006) Short location name: BayonneNJ Country of location: USA Location latitude [deg]: 40.6703 Location longitude [deg]: -74.1261 Location altitude [m]: 3 Local noon date: 20240313 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1682 1832 Nominal wavelengths inside fitting window [nm]: 492.0275 492.1481 492.2688 492.3894 492.5101 492.6307 492.7512 492.8718 492.9924 493.1129 493.2334 493.3539 493.4744 493.5949 493.7153 493.8358 493.9562 494.0766 494.1970 494.3173 494.4377 494.5580 494.6783 494.7986 494.9189 495.0392 495.1594 495.2797 495.3999 495.5201 495.6402 495.7604 495.8806 496.0007 496.1208 496.2409 496.3610 496.4810 496.6011 496.7211 496.8411 496.9611 497.0811 497.2010 497.3210 497.4409 497.5608 497.6807 497.8006 497.9204 498.0403 498.1601 498.2799 498.3997 498.5194 498.6392 498.7589 498.8787 498.9984 499.1180 499.2377 499.3574 499.4770 499.5966 499.7162 499.8358 499.9554 500.0749 500.1944 500.3139 500.4334 500.5529 500.6724 500.7918 500.9113 501.0307 501.1501 501.2694 501.3888 501.5081 501.6275 501.7468 501.8661 501.9853 502.1046 502.2238 502.3430 502.4622 502.5814 502.7006 502.8198 502.9389 503.0580 503.1771 503.2962 503.4153 503.5343 503.6533 503.7723 503.8913 504.0103 504.1293 504.2482 504.3672 504.4861 504.6050 504.7238 504.8427 504.9615 505.0804 505.1992 505.3179 505.4367 505.5555 505.6742 505.7929 505.9116 506.0303 506.1490 506.2676 506.3863 506.5049 506.6235 506.7421 506.8606 506.9792 507.0977 507.2162 507.3347 507.4532 507.5716 507.6901 507.8085 507.9269 508.0453 508.1637 508.2820 508.4003 508.5187 508.6370 508.7553 508.8735 508.9918 509.1100 509.2282 509.3464 509.4646 509.5828 509.7009 509.8190 509.9371 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240313T112857.5Z 8838.478444 51 1 48.47 2 87.34 95.76 104.53 55.27 0.00 1 0.00 1 0 22 4.128e-03 4.067e-03 7.080e-04 7.052e-04 9.255270e+03 4.706642e+01 6.328916e+02 -6.000000e+00 2.263905e+02 277.21 -2.00 20.00 -2.00 505.42 0.00e+00 6.790076e-03 1.928418e-05 3.717212e-04 -6.000000e+00 1.144865e-04 277.21 -2.00 20.00 -2.00 500.98 0.00e+00 1.446224e+00 1.374300e-02 8.932647e-02 -6.000000e+00 8.216277e-02 226.16 -2.00 3.51 -2.00 502.49 0.00e+00 14.398 0.055 489.00 513.00 1 5.0968e+00 1.0489e-03 2.4923e-02 -6.0000e+00 6.2917e-03 -3.2903e-02 2.6390e-04 2.1547e-03 -6.0000e+00 1.6271e-03 1.2384e-03 4.9053e-04 7.0723e-05 1.5429e-04 -6.0000e+00 4.3216e-04 5.8214e-03 -5.8527e-05 11 8 0 10 0 0 94.17 21.47 1.69 0.00582 0.00922 37 8 1 4 0 1309.820 26.62 19.99 21.47 15.07 35.6 977.10 -805 -595 -79 256 460 680 840 906 730 591 281 103 -212 -247 -255 -366 -228 -130 289 270 38 280 247 206 521 512 291 354 5 -190 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-439 -221 -54 117 75 487 743 684 935 961 857 521 488 333 200 340 417 323 239 408 281 160 342 86 -93 -174 -255 -291 -95 32 -87 97 200 293 84 443 190 156 110 -112 -400 -537 -595 SQ 20240313T113235.9Z 8838.480971 54 1 49.24 2 86.66 96.36 103.97 55.92 0.00 1 0.00 1 0 22 3.489e-03 3.438e-03 5.154e-04 5.139e-04 8.242556e+03 3.387140e+01 5.694974e+02 -6.000000e+00 1.913837e+02 277.21 -2.00 20.00 -2.00 505.38 0.00e+00 6.092132e-03 1.403415e-05 3.344571e-04 -6.000000e+00 9.677401e-05 277.21 -2.00 20.00 -2.00 500.88 0.00e+00 1.355270e+00 1.005407e-02 7.931936e-02 -6.000000e+00 6.943263e-02 226.16 -2.00 3.51 -2.00 502.40 0.00e+00 12.795 0.038 489.00 513.00 1 4.7966e+00 7.6743e-04 2.1755e-02 -6.0000e+00 5.3172e-03 -2.5823e-02 1.9392e-04 1.8939e-03 -6.0000e+00 1.3744e-03 2.1390e-03 2.6826e-04 5.1709e-05 1.3899e-04 -6.0000e+00 3.6525e-04 -1.6882e-02 1.0553e-04 10 0 0 10 0 0 88.54 21.47 1.22 -0.01688 -0.01502 59 13 1 4 0 834.550 26.62 19.99 21.47 15.35 35.4 977.53 -547 -391 -172 328 393 554 680 769 599 617 278 -3 25 -310 -198 -311 -216 -65 161 198 80 342 185 270 307 516 289 216 122 -332 -435 -480 -262 -123 138 -16 -121 7 -99 -128 -143 -57 -11 102 242 289 303 119 91 -219 -440 -646 -705 -779 -600 -199 -66 12 -31 44 120 266 295 199 307 112 96 -147 -39 -193 -511 -341 -316 -160 -34 49 -377 -318 -316 -472 -437 -483 -303 -409 -326 -279 -332 -184 -288 -134 -143 15 160 406 237 259 281 21 -269 -533 -813 -895 -658 -501 -346 -226 -298 -208 -276 -264 -15 -27 147 355 550 736 740 695 606 443 430 438 229 249 364 229 306 357 198 207 345 146 -17 -131 -212 -315 -31 -29 -114 96 143 263 115 323 129 114 71 -189 -265 -484 -321 -491 -354 -160 298 369 532 665 760 593 605 270 -3 24 -290 -183 -290 -203 -62 158 196 80 342 186 273 312 501 281 220 122 -324 -416 -458 -253 -122 134 -16 -120 7 -96 -124 -139 -56 -11 103 248 299 314 122 92 -219 -431 -618 -666 -739 -580 -197 -67 13 -33 46 125 280 312 211 325 117 99 -150 -39 -192 -506 -336 -314 -160 -34 50 -378 -313 -307 -456 -422 -467 -295 -401 -322 -278 -331 -183 -285 -132 -142 15 163 416 242 260 275 20 -251 -489 -739 -817 -614 -484 -345 -229 -304 -211 -278 -266 -15 -27 147 361 564 760 772 732 641 466 447 448 233 252 371 236 316 370 206 216 357 150 -17 -132 -213 -319 -32 -30 -121 99 149 276 122 342 137 120 74 -196 -269 -510 -339 SQ 20240313T114240.8Z 8838.487972 57 1 48.90 2 84.76 98.01 102.41 57.70 0.00 1 0.00 1 0 15 2.624e-03 2.602e-03 1.823e-04 1.820e-04 5.853866e+03 1.156978e+01 4.146470e+02 -6.000000e+00 1.439564e+02 277.21 -2.00 20.00 -2.00 505.35 0.00e+00 4.203584e-03 5.002168e-06 2.327083e-04 -6.000000e+00 7.279380e-05 277.21 -2.00 20.00 -2.00 500.73 0.00e+00 1.080537e+00 3.584169e-03 5.596818e-02 -6.000000e+00 5.223176e-02 226.16 -2.00 3.51 -2.00 502.28 0.00e+00 9.490 0.016 489.00 513.00 1 3.3354e+00 2.7443e-04 1.5561e-02 -6.0000e+00 3.9999e-03 -1.6974e-02 6.9570e-05 1.3511e-03 -6.0000e+00 1.0340e-03 1.5539e-02 2.0237e-04 1.8457e-05 9.8942e-05 -6.0000e+00 2.7475e-04 -9.8507e-03 5.5181e-05 10 0 0 10 0 0 4.95 21.45 0.84 -0.00985 -0.00845 363 83 1 4 0 134.690 26.62 20.00 21.45 15.82 34.8 979.22 -369 -284 -106 182 264 364 632 574 512 445 215 144 -28 -131 -207 -199 -111 -60 188 155 31 122 183 132 342 380 151 188 66 -271 -374 -218 -255 -82 183 -12 -103 10 -70 -170 -133 -25 29 116 145 219 194 91 27 -147 -366 -546 -525 -623 -399 -236 -143 -68 -26 77 59 213 179 175 180 145 59 -58 -52 -160 -319 -246 -172 -197 -42 4 -199 -238 -240 -241 -382 -321 -337 -332 -174 -197 -218 -230 -119 -131 -75 -13 107 275 219 208 161 -65 -175 -354 -557 -592 -549 -405 -211 -336 -305 -151 -217 -153 -2 38 32 276 371 450 531 562 527 356 324 276 191 254 325 156 206 284 118 246 319 122 -31 26 -119 -148 -4 -63 -99 32 142 102 127 260 127 129 -17 -108 -276 -308 -303 -344 -267 -97 173 258 364 643 564 504 455 217 143 -28 -127 -200 -192 -108 -60 182 153 30 122 182 133 345 385 153 189 65 -260 -369 -214 -254 -81 184 -12 -106 10 -70 -170 -134 -25 29 120 152 231 196 95 27 -149 -362 -529 -501 -596 -388 -236 -147 -71 -26 78 60 215 182 178 182 145 61 -60 -52 -159 -315 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