File name: Pandora38s1_BayonneNJ_20240430_L2Fit_fout2c7d20230101p1-8.txt File generation date: 20250227T135150.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 38 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora38_OF_v4d20201028.txt Instrument calibration file used: Pandora38s1_CF_v7d20230101.txt Level 1 file used: Pandora38s1_BayonneNJ_20240430_L1_smca1c7d20230101p1-8.txt Full location name: Bayonne NJDEP (USEPA AQS ID 34-017-0006) Short location name: BayonneNJ Country of location: USA Location latitude [deg]: 40.6703 Location longitude [deg]: -74.1261 Location altitude [m]: 3 Local noon date: 20240430 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 259 401 Nominal wavelengths inside fitting window [nm]: 305.1040 305.2447 305.3854 305.5261 305.6667 305.8074 305.9480 306.0886 306.2292 306.3698 306.5104 306.6510 306.7916 306.9321 307.0727 307.2132 307.3537 307.4942 307.6347 307.7752 307.9157 308.0561 308.1966 308.3370 308.4775 308.6179 308.7583 308.8987 309.0391 309.1794 309.3198 309.4601 309.6005 309.7408 309.8811 310.0214 310.1617 310.3020 310.4423 310.5825 310.7228 310.8630 311.0032 311.1434 311.2836 311.4238 311.5640 311.7042 311.8443 311.9844 312.1246 312.2647 312.4048 312.5449 312.6850 312.8250 312.9651 313.1052 313.2452 313.3852 313.5252 313.6652 313.8052 313.9452 314.0852 314.2251 314.3651 314.5050 314.6449 314.7848 314.9247 315.0646 315.2045 315.3443 315.4842 315.6240 315.7639 315.9037 316.0435 316.1833 316.3231 316.4628 316.6026 316.7423 316.8821 317.0218 317.1615 317.3012 317.4409 317.5806 317.7202 317.8599 317.9995 318.1391 318.2788 318.4184 318.5580 318.6975 318.8371 318.9767 319.1162 319.2558 319.3953 319.5348 319.6743 319.8138 319.9533 320.0927 320.2322 320.3716 320.5110 320.6505 320.7899 320.9293 321.0686 321.2080 321.3474 321.4867 321.6261 321.7654 321.9047 322.0440 322.1833 322.3226 322.4618 322.6011 322.7403 322.8795 323.0188 323.1580 323.2972 323.4363 323.5755 323.7147 323.8538 323.9930 324.1321 324.2712 324.4103 324.5494 324.6884 324.8275 324.9666 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240430T172327.2Z 8886.724620 439 1 32.82 2 26.40 196.35 114.96 257.18 0.00 1 0.00 1 0 17 9.102e-03 6.338e-03 5.188e-03 2.998e-03 1.657317e-01 1.576297e-03 1.988730e-03 -6.000000e+00 5.390832e-03 229.97 -2.00 3.51 -2.00 315.71 0.00e+00 4.325697e-04 1.545726e-04 2.995370e-05 -6.000000e+00 2.365611e-04 282.30 -2.00 20.00 -2.00 315.04 0.00e+00 1.116 0.000 302.00 328.00 3 6.1937e+00 4.0923e-03 1.4137e-02 -6.0000e+00 1.3455e-02 4.0431e-02 4.5556e-03 8.5268e-03 -6.0000e+00 1.4585e-02 1.0212e-03 2.5990e-03 4.1591e-03 -6.0000e+00 8.6735e-03 -2.2985e-03 1.1492e-03 1.1786e-03 -6.0000e+00 3.6229e-03 2.9883e-04 1.4030e-04 9.2035e-05 1.5783e-05 -6.0000e+00 2.6858e-04 -4.0169e-03 3.2940e-05 12 1 1 12 1 1 99.80 21.87 0.16 -0.00402 -0.00296 8 3 1 5 0 3645.620 26.94 19.99 21.87 26.54 35.8 980.97 -526 -614 -1196 -2831 -171 -2030 2413 -1405 -10 -1082 -2077 1640 -2151 2099 233 745 923 -197 140 802 2049 -116 1130 -973 1844 721 151 -641 -788 1697 244 1563 -592 -25 -2519 -1508 -1484 -1487 -2 -975 -380 -326 -129 -437 -372 63 -92 -1049 -764 -98 277 561 -3 486 1300 -163 670 445 -25 489 1223 1469 1664 1275 -207 32 -562 47 594 157 310 349 968 60 -85 -485 -638 -772 -1379 -186 -1060 -1562 -1561 -1540 -990 -519 191 -245 452 -24 340 -107 -206 -155 128 1122 886 1123 504 333 -555 -583 -433 -621 -214 -1130 -225 -401 566 265 469 94 -219 108 -374 216 42 426 27 -16 135 -155 15 160 847 103 1214 226 46 345 -502 -159 -204 -34 -411 55 285 54 573 -161 -298 -379 -503 -139 -170 -328 -722 -38 -448 541 -362 -3 -306 -583 455 -677 706 88 296 374 -83 60 349 886 -51 499 -457 874 351 72 -287 -330 678 102 682 -276 -12 -1122 -665 -718 -839 -1 -668 -278 -247 -99 -337 -285 47 -67 -745 -524 -66 195 416 -3 391 1060 -137 561 371 -21 403 1039 1329 1600 1271 -203 29 -467 38 510 150 319 372 1020 62 -81 -417 -543 -627 -1172 -159 -1006 -1618 -1712 -1775 -1120 -624 239 -317 577 -30 385 -120 -210 -153 132 1246 1000 1374 644 417 -657 -697 -502 -751 -256 -1439 -296 -550 804 395 721 144 -321 145 -463 272 53 516 35 -23 192 -220 21 210 1048 132 1468 276 59 465 -655 -210 -274 -47 -605 84 448 87 920 -256 -459 -567 -744 SS 20240430T172824.4Z 8886.728060 442 1 7.40 2 26.68 198.95 115.83 257.88 0.00 1 0.00 1 0 17 1.170e-02 8.686e-03 9.452e-03 6.435e-03 1.626809e-01 3.396547e-03 1.987151e-03 -6.000000e+00 6.931471e-03 229.97 -2.00 3.51 -2.00 314.97 0.00e+00 8.478383e-05 2.881617e-04 5.510080e-05 -6.000000e+00 3.042154e-04 282.30 -2.00 20.00 -2.00 314.37 0.00e+00 1.119 0.000 302.00 328.00 3 6.0718e+00 8.7511e-03 1.4087e-02 -6.0000e+00 1.7301e-02 3.3728e-02 9.7180e-03 8.4174e-03 -6.0000e+00 1.8754e-02 5.0101e-03 5.5416e-03 4.1142e-03 -6.0000e+00 1.1153e-02 -4.4825e-03 2.3935e-03 1.1330e-03 -6.0000e+00 4.6579e-03 3.3997e-04 -1.9837e-05 1.9498e-04 1.6931e-05 -6.0000e+00 3.4539e-04 -4.0373e-03 1.6066e-06 12 9 1 12 1 1 999.00 21.88 0.42 -0.00404 -0.00419 1 3 1 5 0 3698.290 26.94 19.98 21.88 26.69 35.8 982.52 -563 1924 -3144 -4603 1092 -727 2346 -1441 -307 1434 987 -3008 -289 -1176 1558 1705 -722 186 268 218 1818 2097 153 1629 282 160 -22 882 -854 884 924 3410 931 518 -2960 -2041 -2314 -1346 -507 -300 -1468 -1076 -310 41 -568 -825 -2477 -1203 -608 -371 1297 218 1109 1250 479 1766 1420 -339 -177 148 685 1254 2139 1343 179 704 -906 -466 -64 351 1312 -137 964 804 19 -1537 -803 -486 -89 -1169 -1957 -1054 -2567 -567 -955 245 -507 -102 359 165 -357 183 -95 128 705 1226 1016 1662 -239 248 -1275 -835 109 -565 115 -1547 -690 -590 459 447 413 740 127 -357 651 99 -905 -32 -79 -421 134 412 379 81 867 671 607 621 528 746 -546 -991 46 -698 229 -49 -607 887 46 0 128 -188 -832 -187 653 -1102 -1498 325 -213 710 -469 -107 500 340 -1105 -113 -514 682 789 -350 91 134 112 926 1060 80 879 161 93 -12 460 -423 419 452 1714 502 278 -1555 -1063 -1327 -840 -349 -233 -1173 -887 -258 34 -471 -676 -2000 -973 -474 -289 1031 175 923 1077 425 1568 1275 -307 -158 132 631 1164 2096 1369 179 674 -814 -407 -60 342 1369 -144 990 835 19 -1439 -713 -410 -78 -1080 -1914 -1110 -2766 -630 -1087 294 -645 -127 442 204 -409 199 -99 129 736 1322 1206 2031 -295 313 -1529 -973 122 -664 138 -1989 -879 -781 627 614 586 1039 178 -465 803 122 -1119 -39 -103 -564 183 558 500 107 1079 831 718 736 656 931 -717 -1328 62 -939 322 -69 -889 1305 68 0 189 -270 -1188 SS 20240430T174645.0Z 8886.740799 448 1 48.80 2 28.07 208.11 119.07 260.48 0.00 1 0.00 1 0 17 6.836e-03 5.474e-03 9.993e-04 5.890e-04 1.595836e-01 3.084813e-04 1.932571e-03 -6.000000e+00 4.048542e-03 229.97 -2.00 3.51 -2.00 315.63 0.00e+00 2.151430e-04 3.007562e-05 2.381472e-05 -6.000000e+00 1.776657e-04 282.30 -2.00 20.00 -2.00 314.97 0.00e+00 1.133 0.000 302.00 328.00 3 3.5063e+00 7.9944e-04 1.4093e-02 -6.0000e+00 1.0105e-02 6.6097e-03 8.8990e-04 8.2622e-03 -6.0000e+00 1.0954e-02 5.8495e-03 5.0937e-04 4.0328e-03 -6.0000e+00 6.5139e-03 -3.8559e-03 2.2538e-04 1.1197e-03 -6.0000e+00 2.7207e-03 4.4320e-03 1.6108e-04 1.8061e-05 1.5468e-05 -6.0000e+00 2.0171e-04 -3.6614e-03 3.6229e-05 10 0 0 10 0 0 99.85 21.87 0.21 -0.00366 -0.00245 254 58 1 5 0 192.080 26.94 19.99 21.87 28.04 35.9 991.16 -169 -1065 -1306 -2212 -1439 -616 669 1206 860 -438 -591 -257 -111 256 237 1 -297 290 623 214 557 556 723 777 810 504 -50 -149 278 742 995 1735 592 -379 -1311 -1589 -1018 -620 -611 -875 -986 -820 -657 -518 -721 -622 -416 -580 -374 -7 450 876 1013 742 552 640 645 546 192 956 1044 1462 1518 674 287 -391 -308 73 588 392 223 201 167 -19 27 54 -239 -116 -230 -323 -726 -1555 -1606 -1508 -1088 -850 -402 -234 -18 39 86 284 411 780 854 782 957 602 186 -402 -508 -300 40 -170 -407 -717 -656 -511 20 141 192 -23 -116 -93 94 168 531 347 342 -189 15 -242 -40 526 437 545 810 691 459 302 65 -135 -104 -27 66 -99 81 -149 -146 -56 -301 -210 -460 -46 -309 -373 -584 -340 -140 159 317 245 -129 -172 -76 -36 92 93 0 -115 114 251 88 232 253 304 340 369 234 -23 -69 121 313 432 787 284 -182 -601 -732 -512 -330 -383 -622 -753 -647 -527 -415 -576 -490 -316 -425 -265 -5 330 673 814 619 472 555 563 473 165 819 927 1265 1399 646 267 -366 -266 61 526 358 220 206 170 -18 25 48 -195 -90 -185 -288 -719 -1546 -1692 -1671 -1284 -1069 -489 -291 -22 50 101 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