File name: Pandora38s1_BayonneNJ_20240630_L2Fit_fout2c5d20230101p1-8.txt File generation date: 20240701T050712.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 38 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora38_OF_v4d20201028.txt Instrument calibration file used: Pandora38s1_CF_v5d20230101.txt Level 1 file used: Pandora38s1_BayonneNJ_20240630_L1_smca1c5d20230101p1-8.txt Full location name: Bayonne NJDEP (USEPA AQS ID 34-017-0006) Short location name: BayonneNJ Country of location: USA Location latitude [deg]: 40.6703 Location longitude [deg]: -74.1261 Location altitude [m]: 3 Local noon date: 20240630 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 259 401 Nominal wavelengths inside fitting window [nm]: 305.1040 305.2447 305.3854 305.5261 305.6667 305.8074 305.9480 306.0886 306.2292 306.3698 306.5104 306.6510 306.7916 306.9321 307.0727 307.2132 307.3537 307.4942 307.6347 307.7752 307.9157 308.0561 308.1966 308.3370 308.4775 308.6179 308.7583 308.8987 309.0391 309.1794 309.3198 309.4601 309.6005 309.7408 309.8811 310.0214 310.1617 310.3020 310.4423 310.5825 310.7228 310.8630 311.0032 311.1434 311.2836 311.4238 311.5640 311.7042 311.8443 311.9844 312.1246 312.2647 312.4048 312.5449 312.6850 312.8250 312.9651 313.1052 313.2452 313.3852 313.5252 313.6652 313.8052 313.9452 314.0852 314.2251 314.3651 314.5050 314.6449 314.7848 314.9247 315.0646 315.2045 315.3443 315.4842 315.6240 315.7639 315.9037 316.0435 316.1833 316.3231 316.4628 316.6026 316.7423 316.8821 317.0218 317.1615 317.3012 317.4409 317.5806 317.7202 317.8599 317.9995 318.1391 318.2788 318.4184 318.5580 318.6975 318.8371 318.9767 319.1162 319.2558 319.3953 319.5348 319.6743 319.8138 319.9533 320.0927 320.2322 320.3716 320.5110 320.6505 320.7899 320.9293 321.0686 321.2080 321.3474 321.4867 321.6261 321.7654 321.9047 322.0440 322.1833 322.3226 322.4618 322.6011 322.7403 322.8795 323.0188 323.1580 323.2972 323.4363 323.5755 323.7147 323.8538 323.9930 324.1321 324.2712 324.4103 324.5494 324.6884 324.8275 324.9666 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240630T111105.1Z 8947.466032 226 1 42.67 2 73.23 73.64 31.10 151.91 0.00 1 0.00 1 0 17 3.101e-01 1.337e-02 1.870e-01 7.492e-03 4.500508e-01 3.982972e-03 5.202955e-03 -6.000000e+00 1.854751e-01 232.91 -2.00 3.51 -2.00 320.10 0.00e+00 4.341012e-03 1.330322e-03 9.335826e-04 -6.000000e+00 8.270480e-03 288.38 -2.00 20.00 -2.00 319.32 0.00e+00 3.410 0.001 302.00 328.00 3 4.8662e+00 1.1984e-02 4.1767e-02 -6.0000e+00 4.6531e-01 9.8588e-02 1.4404e-02 2.3903e-02 -6.0000e+00 5.0291e-01 -7.0504e-02 1.1210e-02 1.2618e-02 -6.0000e+00 2.9943e-01 1.8675e-02 5.7014e-03 5.1449e-03 -6.0000e+00 1.2489e-01 7.6015e-05 -3.6642e-04 2.3415e-04 6.1569e-05 -6.0000e+00 9.1632e-03 3.3170e-03 -1.4673e-05 12 9 9 12 9 1 99.91 21.58 0.08 0.00332 0.00056 13 4 1 5 0 3047.470 26.73 20.00 21.58 32.94 36.8 976.33 45510 -111103 127590 -76244 183681 -65627 190110 -55639 -18357 22758 -74067 38425 -27225 40860 -28615 -3426 -3035 2017 33969 -19168 26129 -15524 8846 -12759 8134 19507 -17140 4284 -26469 13444 -6979 18325 -8471 -1305 1998 -8243 13516 -4119 12874 227 11766 2698 633 2881 452 3960 -6127 8221 -2469 1551 4578 5371 7864 -2827 5614 -5506 3939 -1188 -2491 806 854 4872 2547 3996 -363 3898 -1208 -110 583 -2181 2188 512 3813 -1703 737 1011 -843 -548 -4095 -291 -3097 327 -2248 -1662 -1456 -770 816 -1182 674 -810 1066 -1080 865 435 -260 1866 -433 710 219 -394 -1258 -64 546 -3132 508 -1604 107 -1588 -145 1383 519 445 -105 239 -390 860 -586 48 -186 -455 814 -217 1789 -888 1757 -568 1112 -281 207 1537 -336 41 -470 872 -613 184 205 -656 431 -691 262 -629 -114 443 -5308 932 -2485 1342 -1770 1389 -1626 -436 374 -3080 632 -964 970 -1496 -158 -152 103 1448 -1336 1273 -1064 492 -932 507 1211 -1406 275 -2291 900 -600 1390 -924 -135 193 -899 1322 -570 1794 41 2090 555 138 627 102 875 -1505 1765 -602 382 1186 1503 2307 -979 1855 -2089 1377 -433 -906 285 318 1909 1128 1871 -179 1755 -554 -51 295 -1275 1325 325 2306 -1031 400 495 -393 -256 -2177 -171 -2134 242 -1835 -1429 -1335 -746 817 -1235 685 -800 961 -921 687 353 -232 1844 -495 828 271 -482 -1562 -72 581 -3561 596 -2030 140 -2086 -202 2062 833 732 -169 363 -558 1257 -877 69 -286 -732 1300 -342 2675 -1410 2597 -823 1539 -407 326 2606 -575 74 -875 1685 -1275 397 455 -1490 965 -1515 543 -1258 -223 SS 20240630T111643.0Z 8947.469942 229 1 48.11 2 72.20 74.47 30.61 154.35 0.00 1 0.00 1 0 17 1.825e-01 9.285e-03 1.843e-01 8.043e-03 4.299356e-01 4.256348e-03 4.936632e-03 -6.000000e+00 1.091792e-01 232.91 -2.00 3.51 -2.00 319.91 0.00e+00 1.727981e-03 1.349899e-03 6.061127e-04 -6.000000e+00 4.866641e-03 288.38 -2.00 20.00 -2.00 319.13 0.00e+00 3.226 0.001 302.00 328.00 3 5.1560e+00 1.2629e-02 3.9661e-02 -6.0000e+00 2.7391e-01 5.5268e-02 1.5119e-02 2.2911e-02 -6.0000e+00 2.9601e-01 1.4831e-03 1.1804e-02 1.1354e-02 -6.0000e+00 1.7625e-01 -1.0805e-02 6.0400e-03 3.4343e-03 -6.0000e+00 7.3535e-02 7.0083e-05 -2.8000e-04 2.5264e-04 4.1231e-05 -6.0000e+00 5.3920e-03 2.1390e-03 1.4254e-05 11 8 0 10 0 0 98.54 21.59 0.36 0.00214 0.00003 14 3 1 5 0 3435.640 26.73 20.00 21.59 33.14 36.7 977.63 -5593 -50684 49899 32001 88719 -55007 -65254 122120 10470 5289 -43602 -47355 11769 3892 14824 -9832 -27414 -19293 -10402 -8043 -14693 -6674 16318 28158 -23669 7085 -4856 6328 20049 -2011 14752 3256 6452 252 4663 6087 3944 2319 1893 981 -4274 2825 -3649 -1447 3645 2322 3827 -7081 -1023 1696 2966 -4 -931 1548 2563 3851 -192 1177 739 2156 850 2339 684 6202 409 1747 -2568 -2158 1261 114 -133 524 -1713 -186 -1924 300 -1166 -3835 -2252 2247 355 -2428 -1613 -46 -40 -367 -336 363 44 956 56 1324 60 1118 1277 -1039 1792 -568 139 154 -585 -1766 -484 -409 -1078 -990 -1122 -338 440 576 -88 661 247 -108 801 -905 430 98 363 2 -365 -258 244 511 446 -118 1552 244 -562 288 672 -159 -34 -249 -324 -318 282 138 -4 21 -306 110 -430 -84 -1325 489 356 696 -1366 -1962 958 185 104 -1453 -1826 300 130 523 -501 -1810 -1261 -660 -520 -1037 -441 896 1472 -2212 505 -387 434 1179 -155 1080 302 637 27 463 609 451 321 317 192 -967 630 -899 -355 858 559 908 -1884 -261 441 826 -1 -316 544 930 1422 -75 451 280 808 338 1000 327 3004 211 846 -1254 -1070 664 68 -86 350 -1155 -117 -1134 157 -575 -1940 -1225 1338 245 -1911 -1354 -40 -37 -368 -352 387 47 962 52 1141 50 926 1149 -1077 2035 -676 172 188 -729 -2047 -529 -459 -1304 -1263 -1510 -477 611 865 -141 1078 395 -163 1213 -1337 632 151 592 3 -581 -402 396 795 663 -169 2118 347 -876 485 1201 -276 -61 -470 -651 -669 605 301 -9 45 -618 213 -821 SS 20240630T112155.1Z 8947.473554 232 1 33.18 2 71.25 75.23 30.18 156.67 0.00 1 0.00 1 0 17 8.798e-02 7.279e-03 6.352e-02 4.590e-03 4.101173e-01 2.414991e-03 4.671905e-03 -6.000000e+00 5.260737e-02 232.91 -2.00 3.51 -2.00 319.68 0.00e+00 6.194274e-04 6.989277e-04 2.112059e-04 -6.000000e+00 2.346826e-03 288.38 -2.00 20.00 -2.00 318.86 0.00e+00 3.072 0.000 302.00 328.00 3 4.4106e+00 6.9976e-03 3.7714e-02 -6.0000e+00 1.3198e-01 2.3855e-02 8.2891e-03 2.1686e-02 -6.0000e+00 1.4266e-01 -1.8552e-02 6.2646e-03 1.0532e-02 -6.0000e+00 8.4937e-02 3.7611e-03 3.2218e-03 2.9520e-03 -6.0000e+00 3.5417e-02 1.8075e-04 -4.3600e-04 1.4468e-04 3.3875e-05 -6.0000e+00 2.6002e-03 3.5556e-03 -9.5598e-05 12 9 1 12 1 1 99.96 21.59 0.08 0.00356 0.00028 22 8 1 5 0 1442.210 26.73 19.99 21.59 33.42 36.8 979.42 -18177 8606 990 7997 5033 -51533 35646 -53570 -12412 -27887 4265 22927 -18760 10437 -7137 12374 -9120 7783 -14225 8016 1898 -3651 12693 -2152 7632 -2259 -7210 -7042 -4603 5643 -6220 6650 -4452 2123 -1827 2924 1111 -2653 2195 -4106 3864 -1738 236 -1935 -1119 2332 -880 2201 -989 1617 -775 2287 -1222 221 1513 412 1688 -1318 2544 1132 2078 1122 2023 1180 -205 1409 -2253 2871 -1022 1332 30 -450 1022 473 1352 -579 606 -3081 -1485 506 -1113 -881 -2810 -1314 -2077 -189 -703 780 560 -216 494 -327 1199 249 896 305 1171 604 -372 458 -1059 679 -737 -411 -876 -946 101 -553 532 -171 379 101 38 -22 -2 337 -161 533 391 -289 -17 -177 -194 44 810 -271 864 98 458 23 -40 -287 -437 397 -101 169 -12 71 -271 -63 -369 59 108 -420 167 21 149 98 -1634 566 -2158 -366 -1009 116 625 -840 417 -397 632 -623 479 -1151 541 139 -286 885 -187 641 -217 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