File name: Pandora38s1_BayonneNJ_20240821_L2Fit_fout2c7d20230101p1-8.txt File generation date: 20250227T135209.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 38 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora38_OF_v4d20201028.txt Instrument calibration file used: Pandora38s1_CF_v7d20230101.txt Level 1 file used: Pandora38s1_BayonneNJ_20240821_L1_smca1c7d20230101p1-8.txt Full location name: Bayonne NJDEP (USEPA AQS ID 34-017-0006) Short location name: BayonneNJ Country of location: USA Location latitude [deg]: 40.6703 Location longitude [deg]: -74.1261 Location altitude [m]: 3 Local noon date: 20240821 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 259 401 Nominal wavelengths inside fitting window [nm]: 305.1040 305.2447 305.3854 305.5261 305.6667 305.8074 305.9480 306.0886 306.2292 306.3698 306.5104 306.6510 306.7916 306.9321 307.0727 307.2132 307.3537 307.4942 307.6347 307.7752 307.9157 308.0561 308.1966 308.3370 308.4775 308.6179 308.7583 308.8987 309.0391 309.1794 309.3198 309.4601 309.6005 309.7408 309.8811 310.0214 310.1617 310.3020 310.4423 310.5825 310.7228 310.8630 311.0032 311.1434 311.2836 311.4238 311.5640 311.7042 311.8443 311.9844 312.1246 312.2647 312.4048 312.5449 312.6850 312.8250 312.9651 313.1052 313.2452 313.3852 313.5252 313.6652 313.8052 313.9452 314.0852 314.2251 314.3651 314.5050 314.6449 314.7848 314.9247 315.0646 315.2045 315.3443 315.4842 315.6240 315.7639 315.9037 316.0435 316.1833 316.3231 316.4628 316.6026 316.7423 316.8821 317.0218 317.1615 317.3012 317.4409 317.5806 317.7202 317.8599 317.9995 318.1391 318.2788 318.4184 318.5580 318.6975 318.8371 318.9767 319.1162 319.2558 319.3953 319.5348 319.6743 319.8138 319.9533 320.0927 320.2322 320.3716 320.5110 320.6505 320.7899 320.9293 321.0686 321.2080 321.3474 321.4867 321.6261 321.7654 321.9047 322.0440 322.1833 322.3226 322.4618 322.6011 322.7403 322.8795 323.0188 323.1580 323.2972 323.4363 323.5755 323.7147 323.8538 323.9930 324.1321 324.2712 324.4103 324.5494 324.6884 324.8275 324.9666 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240821T105406.3Z 8999.454239 224 1 49.15 2 83.33 80.08 76.04 250.71 0.00 1 0.00 1 0 17 4.526e-01 2.888e-02 5.362e-01 2.910e-02 9.876433e-01 1.772585e-02 1.065206e-02 -6.000000e+00 2.768080e-01 231.26 -2.00 3.51 -2.00 322.45 0.00e+00 -5.047618e-03 1.175068e-02 1.130839e-03 -6.000000e+00 1.515859e-02 289.97 -2.00 20.00 -2.00 321.97 0.00e+00 7.819 0.009 302.00 328.00 3 1.5179e+00 8.0099e-02 9.5440e-02 -6.0000e+00 6.9072e-01 1.2335e+00 1.0318e-01 5.4868e-02 -6.0000e+00 7.4957e-01 -1.5409e+00 7.3202e-02 2.7290e-02 -6.0000e+00 4.4515e-01 5.9312e-01 3.3925e-02 7.7393e-03 -6.0000e+00 1.8663e-01 1.6470e-05 -1.0519e-03 8.1453e-04 1.1184e-04 -6.0000e+00 1.4145e-02 -1.4894e-04 5.1507e-05 12 8 8 10 0 0 62.52 21.60 0.61 -0.00015 -0.00805 35 8 1 5 0 1403.980 26.73 20.00 21.60 22.24 35.7 936.42 19779 64155 -101886 -23785 -119321 -65778 900000 -31165 -186370 900000 900000 -74610 83120 -105551 188116 -71074 900000 49815 -8319 -10843 -66946 -19531 900000 31431 900000 105668 900000 900000 -58222 68280 45052 20452 19912 2449 106144 900000 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-867 3120 502 -5193 2313 -3481 3754 3862 -654 -2001 1646 2308 -2055 2631 -1148 2936 -2050 -1040 -2047 -1019 1055 1460 -1498 -3528 -471 -471 -2429 934 -7524 -5294 -6077 -1838 1353 -397 2207 -3224 777 -5355 1054 1066 865 2421 3795 1202 2467 6607 -2537 3923 -301 1468 5029 2143 1535 -5147 1228 -2770 1233 -3902 6624 3393 -1239 -1103 -3914 -1615 -827 SS 20240821T110444.0Z 8999.461620 227 1 48.80 2 81.34 81.77 77.86 252.58 0.00 1 0.00 1 0 17 6.080e-01 1.142e-02 3.622e-01 7.425e-03 8.455806e-01 4.365469e-03 9.272824e-03 -6.000000e+00 3.640771e-01 231.26 -2.00 3.51 -2.00 322.12 0.00e+00 3.118628e-03 2.850668e-03 1.495759e-03 -6.000000e+00 1.681271e-02 289.97 -2.00 20.00 -2.00 321.59 0.00e+00 6.258 0.004 302.00 328.00 3 1.3901e+00 1.8998e-02 7.8166e-02 -6.0000e+00 9.1090e-01 3.2717e-01 2.8588e-02 4.8542e-02 -6.0000e+00 9.8650e-01 -4.2690e-01 2.7943e-02 2.6193e-02 -6.0000e+00 5.8598e-01 1.6915e-01 1.2322e-02 9.5477e-03 -6.0000e+00 2.4832e-01 1.0833e-04 -5.5285e-04 2.1558e-04 1.4155e-04 -6.0000e+00 1.8375e-02 -1.7970e-03 6.0212e-05 12 8 8 10 0 0 0.53 21.61 0.34 -0.00180 -0.00595 99 23 1 5 0 492.830 26.73 20.00 21.61 22.64 35.5 938.00 900000 900000 -203769 -195996 -173432 -62763 -255345 900000 -210176 -132844 -248132 -180367 900000 -201611 -83812 -129557 78957 -70943 -32291 -18360 -108603 -33869 -140311 -475 -99391 -29078 -94637 -23156 -38803 -96929 23850 -17290 10354 -9744 18335 -46284 -20997 20788 -16487 37844 -16771 40198 -4634 4165 18452 -10624 18193 -5818 17487 -929 8471 14471 15183 12658 6649 18935 3066 13792 6257 16454 -1726 5834 19436 8795 10915 7736 12458 4617 5676 8242 5771 6074 -358 6935 2204 5250 -5329 -392 -89 -4121 452 -2715 -853 -1634 374 -217 -1150 1477 -350 1300 218 332 -116 -180 431 -924 571 -1216 -213 -1747 -171 -1477 367 -1020 -1697 -1110 -2807 312 -1095 -2 306 40 -29 -329 -47 -633 879 -467 17 -208 640 680 574 758 21 1271 138 1027 311 215 376 31 -154 -226 177 -47 452 107 -288 6 -148 -52 -799 900000 900000 -1474 -1418 -1255 -454 -2519 900000 -1825 -961 -3428 -1697 900000 -3713 -667 -1969 571 -770 -257 -133 -1965 -294 -3756 -3 -2086 -316 -1986 -235 -477 -2455 224 -300 157 -190 265 -1306 -517 406 -573 904 -777 1134 -215 181 708 -561 750 -324 835 -59 558 1016 1176 1099 654 1726 335 1337 634 1488 -196 688 2306 1311 1690 1135 1965 768 1057 1708 1336 1446 -89 1483 447 1029 -1122 -84 -20 -1163 144 -1027 -349 -721 173 -107 -597 762 -182 637 102 147 -52 -86 237 -608 435 -1079 -203 -1685 -152 -1193 268 -758 -1346 -927 -2542 299 -1192 -3 419 59 -44 -484 -67 -878 1220 -687 26 -327 975 989 802 1021 27 1594 173 1376 481 381 740 67 -352 -555 462 -128 1261 303 -805 15 -368 -120 -1817 SS 20240821T111749.5Z 8999.470711 232 1 48.72 2 78.88 83.85 80.12 254.83 0.00 1 0.00 1 0 25 4.983e-01 9.259e-03 2.183e-01 3.489e-03 7.042099e-01 1.939425e-03 7.823039e-03 -6.000000e+00 2.965864e-01 231.26 -2.00 3.51 -2.00 321.45 0.00e+00 1.944438e-03 1.065337e-03 1.053895e-03 -6.000000e+00 1.360474e-02 289.97 -2.00 20.00 -2.00 320.84 0.00e+00 4.997 0.002 302.00 328.00 3 1.6297e+00 7.2705e-03 6.2715e-02 -6.0000e+00 7.4047e-01 1.2130e-01 1.0328e-02 3.8379e-02 -6.0000e+00 8.0085e-01 -1.2979e-01 9.9220e-03 1.9972e-02 -6.0000e+00 4.7805e-01 4.6899e-02 4.5685e-03 6.4166e-03 -6.0000e+00 2.0095e-01 3.2628e-04 -3.9419e-04 1.0161e-04 8.5035e-05 -6.0000e+00 1.4912e-02 -1.5463e-03 5.0033e-05 11 8 0 10 0 0 67.66 21.62 0.29 -0.00155 -0.00451 158 36 1 5 0 308.300 26.73 20.00 21.62 22.98 35.7 940.10 -115964 -117082 -169487 900000 -236291 -14407 -227950 -158534 -146548 -179750 -98727 -159871 49015 -136702 61788 -94621 -6854 -19166 -36889 76160 -51093 11923 -61638 -12282 -32734 -29211 -16140 -45031 -3482 -41880 16843 -23328 15061 -5074 6829 3797 -15056 12717 -12719 14425 -6400 9168 1746 5623 8956 -3572 8109 -6601 9607 -5202 6712 4777 3266 9093 1968 8187 2474 6696 1528 2463 1473 3171 7360 2560 6999 1878 4862 2298 3126 2044 1867 3179 -1126 2992 -2497 1592 -483 -2061 -802 -2617 900 -2014 -301 -1835 -641 -1146 -312 -8 -920 1191 -1178 1643 255 166 212 238 313 -324 595 -1088 -406 -523 -577 -1174 -1284 -402 -1666 -42 -435 283 -37 171 128 121 388 -91 692 -404 217 -515 9 80 -161 1366 -181 861 764 807 277 135 232 -153 292 -263 67 -50 167 -334 -274 205 -391 435 -513 -473 -558 -1442 900000 -3289 -49 -3314 -1456 -1346 -2507 -672 -2393 167 -2697 210 -1835 -63 -222 -552 389 -956 122 -1405 -188 -668 -606 -297 -1088 -57 -1126 304 -754 379 -164 193 114 -615 476 -753 770 -430 624 134 427 670 -283 648 -582 843 -526 677 551 422 1207 298 1221 400 1031 242 385 244 574 1452 589 1608 451 1140 584 884 665 663 1153 -418 999 -802 446 -132 -595 -260 -1026 398 -1041 -168 -1106 -408 -778 -220 -6 -660 803 -761 974 150 103 149 194 295 -349 680 -1255 -435 -507 -521 -1079 -1257 -412 -1836 -49 -564 408 -54 262 197 196 597 -137 1041 -642 361 -813 15 130 -252 2033 -263 1194 1043 1166 453 249 428 -302 608 -586 158 -124 423 -861 -698 498 -898 935 -1090 SS 20240821T112317.9Z 8999.474513 235 1 48.82 2 77.84 84.73 81.07 255.76 0.00 1 0.00 1 0 25 4.250e-01 7.308e-03 1.853e-01 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