File name: Pandora38s1_BayonneNJ_20250724_L2Fit_fwvt1c7d20230101p1-8.txt File generation date: 20250725T051529.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c7p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 38 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora38_OF_v4d20201028.txt Instrument calibration file used: Pandora38s1_CF_v7d20230101.txt Level 1 file used: Pandora38s1_BayonneNJ_20250724_L1_smca1c7d20230101p1-8.txt Full location name: Bayonne NJDEP (USEPA AQS ID 34-017-0006) Short location name: BayonneNJ Country of location: USA Location latitude [deg]: 40.6703 Location longitude [deg]: -74.1261 Location altitude [m]: 3 Local noon date: 20250724 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1682 1832 Nominal wavelengths inside fitting window [nm]: 492.0275 492.1481 492.2688 492.3894 492.5101 492.6307 492.7512 492.8718 492.9924 493.1129 493.2334 493.3539 493.4744 493.5949 493.7153 493.8358 493.9562 494.0766 494.1970 494.3173 494.4377 494.5580 494.6783 494.7986 494.9189 495.0392 495.1594 495.2797 495.3999 495.5201 495.6402 495.7604 495.8806 496.0007 496.1208 496.2409 496.3610 496.4810 496.6011 496.7211 496.8411 496.9611 497.0811 497.2010 497.3210 497.4409 497.5608 497.6807 497.8006 497.9204 498.0403 498.1601 498.2799 498.3997 498.5194 498.6392 498.7589 498.8787 498.9984 499.1180 499.2377 499.3574 499.4770 499.5966 499.7162 499.8358 499.9554 500.0749 500.1944 500.3139 500.4334 500.5529 500.6724 500.7918 500.9113 501.0307 501.1501 501.2694 501.3888 501.5081 501.6275 501.7468 501.8661 501.9853 502.1046 502.2238 502.3430 502.4622 502.5814 502.7006 502.8198 502.9389 503.0580 503.1771 503.2962 503.4153 503.5343 503.6533 503.7723 503.8913 504.0103 504.1293 504.2482 504.3672 504.4861 504.6050 504.7238 504.8427 504.9615 505.0804 505.1992 505.3179 505.4367 505.5555 505.6742 505.7929 505.9116 506.0303 506.1490 506.2676 506.3863 506.5049 506.6235 506.7421 506.8606 506.9792 507.0977 507.2162 507.3347 507.4532 507.5716 507.6901 507.8085 507.9269 508.0453 508.1637 508.2820 508.4003 508.5187 508.6370 508.7553 508.8735 508.9918 509.1100 509.2282 509.3464 509.4646 509.5828 509.7009 509.8190 509.9371 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250724T101909.1Z 9336.429967 67 1 48.62 2 85.16 68.00 79.98 66.69 0.00 1 0.00 1 0 22 4.897e-03 4.809e-03 5.418e-04 5.398e-04 1.693318e+04 4.052057e+01 1.080896e+03 -6.000000e+00 2.822851e+02 289.94 -2.00 20.00 -2.00 505.42 0.00e+00 3.831213e-03 1.531667e-05 2.239614e-04 -6.000000e+00 1.401130e-04 289.94 -2.00 20.00 -2.00 500.90 0.00e+00 8.692051e-01 1.058059e-02 1.085826e-01 -6.000000e+00 9.744181e-02 232.59 -2.00 3.51 -2.00 502.43 0.00e+00 10.029 0.018 489.00 513.00 1 5.1926e+00 8.1251e-04 1.8064e-02 -6.0000e+00 7.4941e-03 -6.2877e-02 2.0217e-04 2.6948e-03 -6.0000e+00 1.9312e-03 2.2454e-03 7.3843e-04 5.0942e-05 1.2137e-04 -6.0000e+00 5.1316e-04 -5.2963e-03 6.9748e-05 12 8 8 10 0 0 83.04 21.71 2.35 -0.00530 -0.00017 88 20 1 4 0 552.390 26.83 20.00 21.71 29.13 37.3 967.58 -1065 -624 -201 333 470 698 1055 954 999 731 231 63 -238 -309 -450 -336 -351 -27 277 430 132 293 395 351 544 465 386 285 -82 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-532 -250 -238 -333 -368 -408 -347 -80 24 141 426 691 907 942 1059 984 640 397 365 279 338 561 350 501 384 348 291 325 100 -325 -284 -475 -337 -20 34 -163 235 277 124 257 430 344 242 186 -204 -489 -646 -645 SQ 20250724T103013.9Z 9336.437660 70 1 48.92 2 83.21 69.73 78.13 68.29 0.00 1 0.00 1 0 22 3.650e-03 3.607e-03 2.765e-04 2.758e-04 1.364105e+04 1.987222e+01 8.819677e+02 -6.000000e+00 2.104194e+02 289.94 -2.00 20.00 -2.00 505.38 0.00e+00 3.276111e-03 7.757749e-06 1.927687e-04 -6.000000e+00 1.044420e-04 289.94 -2.00 20.00 -2.00 500.81 0.00e+00 6.875078e-01 5.379472e-03 8.963925e-02 -6.000000e+00 7.263401e-02 232.59 -2.00 3.51 -2.00 502.35 0.00e+00 7.704 0.008 489.00 513.00 1 4.2881e+00 4.1256e-04 1.4189e-02 -6.0000e+00 5.5861e-03 -5.0707e-02 1.0345e-04 2.1966e-03 -6.0000e+00 1.4395e-03 7.9388e-03 4.8948e-04 2.6605e-05 1.0724e-04 -6.0000e+00 3.8252e-04 1.0976e-03 3.1710e-05 10 0 0 10 0 0 99.29 21.76 1.34 0.00110 0.00449 289 66 1 4 0 169.260 26.83 20.01 21.76 29.13 37.3 967.83 -665 -358 -108 306 439 565 859 770 611 507 218 98 -56 -189 -308 -268 -136 -74 267 207 120 171 173 171 398 423 278 211 -19 -476 -637 -421 -415 -82 206 43 -65 4 -97 -229 -122 -20 6 194 270 296 328 177 30 -165 -565 -709 -775 -763 -470 -200 -69 10 77 188 189 321 409 335 272 218 36 -112 -203 -256 -469 -373 -262 -225 -83 -63 -261 -408 -408 -450 -595 -491 -484 -506 -302 -293 -266 -250 -178 -147 -30 122 293 406 364 379 250 -10 -245 -548 -843 -852 -733 -432 -178 -244 -291 -204 -310 -228 -98 35 100 333 508 629 767 796 682 440 345 304 224 314 436 278 296 331 95 228 279 45 -158 -116 -246 -294 -13 44 -9 183 206 149 216 276 231 188 98 -97 -374 -481 -452 -607 -329 -102 282 416 548 847 769 612 503 214 95 -53 -179 -290 -254 -130 -73 266 209 122 175 178 176 413 440 289 218 -19 -472 -619 -408 -408 -83 203 43 -65 4 -95 -224 -120 -20 6 197 276 306 338 181 30 -163 -547 -709 -765 -756 -474 -196 -70 10 80 193 195 332 425 349 282 224 36 -113 -201 -251 -457 -362 -256 -223 -83 -63 -258 -397 -392 -429 -567 -469 -466 -492 -296 -291 -265 -248 -176 -145 -29 121 295 409 363 367 235 -10 -231 -510 -781 -799 -670 -411 -176 -248 -298 -208 -314 -232 -100 37 99 334 511 637 783 822 709 457 353 306 222 310 432 278 297 333 96 229 279 45 -156 -113 -240 -289 -13 45 -10 192 219 161 234 301 252 205 106 -103 -392 -500 -471 SQ 20250724T112938.7Z 9336.478920 103 1 3.77 2 72.38 78.79 67.84 76.69 0.00 1 0.00 1 0 15 2.365e-03 2.358e-03 2.080e-03 2.077e-03 5.853248e+03 1.375543e+02 4.018704e+02 -6.000000e+00 1.363554e+02 289.94 -2.00 20.00 -2.00 505.28 0.00e+00 1.510319e-03 5.831890e-05 9.110249e-05 -6.000000e+00 6.767869e-05 289.94 -2.00 20.00 -2.00 500.52 0.00e+00 2.897755e-01 4.111681e-02 3.907283e-02 -6.000000e+00 4.706014e-02 232.59 -2.00 3.51 -2.00 502.10 0.00e+00 3.256 0.001 489.00 513.00 1 6.3195e+00 3.1589e-03 6.1139e-03 -6.0000e+00 3.6194e-03 -1.9333e-03 8.0646e-04 9.4316e-04 -6.0000e+00 9.3251e-04 2.1029e-03 1.8913e-04 2.0881e-04 5.1250e-05 -6.0000e+00 2.4786e-04 -6.9176e-03 9.3533e-05 12 1 1 12 1 1 999.00 21.77 0.81 -0.00692 -0.00561 2 9 1 4 0 1255.140 26.83 20.00 21.77 30.09 37.4 974.07 -84 -122 -174 485 432 363 196 436 -257 244 68 8 98 39 -178 -12 92 63 154 68 -79 584 117 190 294 -2 120 374 -121 -214 -285 -361 -241 -20 131 -374 -16 209 -34 61 -134 -196 6 -8 150 158 23 -348 -289 -13 -193 -337 -191 -30 -152 -140 90 -230 -231 -147 -46 -409 361 29 418 17 135 -228 259 179 -168 -110 -143 -189 -195 -58 -131 18 13 -122 -343 -489 -367 -27 -177 -147 -268 -353 -118 -382 -115 138 126 146 47 258 -69 338 65 -400 -435 -507 -367 -390 -94 -210 -232 -102 1 211 75 -35 188 111 200 136 218 191 300 334 146 131 269 -51 120 294 245 208 43 305 586 -93 -130 147 375 11 430 67 -379 108 105 252 -41 -26 52 -43 -554 210 -163 -181 -23 -82 -119 -170 486 433 373 200 448 -266 249 71 9 98 38 -176 -12 92 64 156 70 -82 604 122 198 307 -2 125 386 -123 -218 -283 -358 -243 -20 136 -394 -17 217 -35 62 -136 -200 6 -8 153 162 23 -356 -298 -13 -194 -331 -184 -29 -150 -138 91 -237 -239 -152 -48 -414 374 30 430 18 136 -226 260 177 -166 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