File name: Pandora80s1_BeltsvilleMD_20220906_L2Fit_fwvt1c8d20220601p1-8.txt File generation date: 20241115T012250.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: John Sullivan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 80 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora80_OF_v3d20220517.txt Instrument calibration file used: Pandora80s1_CF_v8d20220601.txt Level 1 file used: Pandora80s1_BeltsvilleMD_20220906_L1_smca1c8d20220601p1-8.txt Full location name: Howard University-Beltsville Campus, Beltsville, MD Short location name: BeltsvilleMD Country of location: United States Location latitude [deg]: 39.0567 Location longitude [deg]: -76.8758 Location altitude [m]: 70 Local noon date: 20220906 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1614 1763 Nominal wavelengths inside fitting window [nm]: 492.1005 492.2218 492.3431 492.4643 492.5855 492.7068 492.8280 492.9491 493.0703 493.1915 493.3126 493.4337 493.5548 493.6759 493.7970 493.9180 494.0390 494.1601 494.2811 494.4020 494.5230 494.6440 494.7649 494.8858 495.0067 495.1276 495.2485 495.3693 495.4901 495.6109 495.7317 495.8525 495.9733 496.0940 496.2148 496.3355 496.4562 496.5768 496.6975 496.8182 496.9388 497.0594 497.1800 497.3006 497.4211 497.5417 497.6622 497.7827 497.9032 498.0237 498.1441 498.2646 498.3850 498.5054 498.6258 498.7462 498.8665 498.9869 499.1072 499.2275 499.3478 499.4681 499.5883 499.7085 499.8288 499.9490 500.0692 500.1893 500.3095 500.4296 500.5497 500.6698 500.7899 500.9100 501.0300 501.1501 501.2701 501.3901 501.5101 501.6300 501.7500 501.8699 501.9898 502.1097 502.2296 502.3495 502.4693 502.5892 502.7090 502.8288 502.9485 503.0683 503.1880 503.3078 503.4275 503.5472 503.6668 503.7865 503.9061 504.0258 504.1454 504.2650 504.3845 504.5041 504.6236 504.7431 504.8627 504.9821 505.1016 505.2211 505.3405 505.4599 505.5793 505.6987 505.8181 505.9374 506.0567 506.1761 506.2954 506.4146 506.5339 506.6531 506.7724 506.8916 507.0108 507.1300 507.2491 507.3683 507.4874 507.6065 507.7256 507.8447 507.9637 508.0828 508.2018 508.3208 508.4398 508.5587 508.6777 508.7966 508.9155 509.0344 509.1533 509.2722 509.3910 509.5099 509.6287 509.7475 509.8663 509.9850 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20220906T142645.9Z 8284.601921 183 1 10.07 2 48.52 121.92 164.50 38.84 0.00 1 0.00 1 0 15 3.221e-03 3.198e-03 6.167e-04 6.153e-04 4.281398e+03 3.791437e+01 3.009074e+02 -6.000000e+00 1.761537e+02 289.46 -2.00 20.00 -2.00 505.26 0.00e+00 3.871846e-04 1.690814e-05 2.733106e-05 -6.000000e+00 9.042602e-05 289.46 -2.00 20.00 -2.00 500.42 0.00e+00 5.794806e-02 1.190473e-02 2.704836e-02 -6.000000e+00 6.231145e-02 229.97 -2.00 3.47 -2.00 502.02 0.00e+00 1.507 0.000 489.00 513.00 1 5.3930e+00 9.1229e-04 3.2175e-03 -6.0000e+00 4.7797e-03 1.6390e-02 2.3738e-04 6.7089e-04 -6.0000e+00 1.2491e-03 7.0861e-03 7.0840e-04 5.1210e-05 3.2510e-05 -6.0000e+00 2.7815e-04 -2.7092e-03 -1.7860e-06 12 1 1 12 1 1 99.93 23.61 1.61 -0.00271 0.00220 34 28 1 4 0 282.950 25.90 20.01 23.61 31.05 3.1 994.16 -966 -537 -362 76 319 281 471 350 261 80 -7 -164 -269 -400 -249 -237 36 -30 161 165 280 64 350 180 438 364 357 -124 -161 -520 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574 454 406 197 -13 192 -36 54 4 362 244 207 318 346 81 2 -175 -375 -322 -225 -116 -39 211 72 79 127 191 295 166 102 -84 -229 -498 -487 -477 SQ 20220906T143112.4Z 8284.605005 186 1 15.28 2 47.80 123.04 163.97 41.69 0.00 1 0.00 1 0 22 4.677e-03 4.647e-03 2.219e-03 2.214e-03 5.943419e+03 1.406087e+02 4.142349e+02 -6.000000e+00 2.557834e+02 289.46 -2.00 20.00 -2.00 505.27 0.00e+00 4.874535e-04 6.108997e-05 3.277980e-05 -6.000000e+00 1.313040e-04 289.46 -2.00 20.00 -2.00 500.42 0.00e+00 1.350953e-01 4.291441e-02 3.624027e-02 -6.000000e+00 9.047401e-02 229.97 -2.00 3.47 -2.00 502.02 0.00e+00 1.486 0.000 489.00 513.00 1 7.9845e+00 3.2943e-03 3.8354e-03 -6.0000e+00 6.9400e-03 1.2536e-02 8.5121e-04 9.0452e-04 -6.0000e+00 1.8136e-03 5.2695e-04 9.3987e-04 1.8322e-04 4.3460e-05 -6.0000e+00 4.0387e-04 -3.0607e-03 4.7712e-06 12 9 9 12 1 1 99.75 23.62 1.65 -0.00306 0.00346 3 2 1 4 0 3779.290 25.90 20.01 23.62 31.42 3.1 997.02 -1297 -675 -235 419 568 306 186 345 369 -131 -147 -267 -476 -448 -191 -319 -301 720 307 518 -37 78 168 212 382 636 376 150 -460 -454 -929 -399 44 38 394 374 -305 99 -288 -528 7 221 -119 631 984 782 613 362 -189 -630 -808 -1033 -690 -706 434 49 235 -38 470 166 448 -114 602 548 596 310 -4 -62 -293 -20 -503 -178 -471 -257 61 -289 -383 -556 -463 -812 -548 172 -315 -350 -438 -368 214 -134 256 190 299 481 786 168 1067 -8 231 -291 -1089 -663 -526 -294 -360 -73 95 -45 -85 -381 -39 -544 49 142 472 208 693 535 572 1185 184 0 8 -75 -423 185 571 -3 239 324 522 -183 277 -340 -894 -362 -427 -553 -236 424 -241 132 180 366 421 544 567 -2 -162 -794 -635 -742 -1267 -670 -242 429 592 327 196 364 400 -140 -155 -278 -487 -452 -193 -325 -312 759 322 544 -39 82 177 224 405 672 396 155 -478 -456 -934 -402 45 40 419 396 -320 102 -294 -537 7 227 -124 659 1031 820 636 371 -191 -640 -796 -998 -662 -691 436 49 239 -39 476 168 454 -117 615 557 598 317 -4 -62 -289 -20 -489 -175 -469 -259 61 -287 -373 -534 -440 -774 -526 165 -306 -345 -438 -370 213 -133 254 189 291 475 780 165 1054 -8 218 -269 -1026 -616 -493 -273 -351 -72 94 -44 -82 -364 -38 -528 48 141 470 209 694 541 583 1198 185 0 8 -72 -407 179 550 -3 231 312 501 -176 260 -327 -854 -342 -406 -523 -227 412 -239 132 180 367 424 548 569 -2 -157 -753 -596 -703 SQ 20220906T143923.4Z 8284.610688 192 1 7.08 2 46.48 125.16 162.92 46.52 0.00 1 0.00 1 0 15 3.681e-03 3.661e-03 2.122e-03 2.117e-03 4.699733e+03 1.316080e+02 3.250798e+02 -6.000000e+00 2.012512e+02 289.46 -2.00 20.00 -2.00 505.25 0.00e+00 3.162696e-04 5.823517e-05 2.696629e-05 -6.000000e+00 1.033566e-04 289.46 -2.00 20.00 -2.00 500.39 0.00e+00 7.347186e-02 4.099211e-02 2.982224e-02 -6.000000e+00 7.134314e-02 229.97 -2.00 3.47 -2.00 501.99 0.00e+00 1.450 0.000 489.00 513.00 1 7.2317e+00 3.1421e-03 3.3334e-03 -6.0000e+00 5.4704e-03 1.6296e-02 8.1698e-04 7.2976e-04 -6.0000e+00 1.4330e-03 1.1348e-03 3.5975e-03 1.7570e-04 3.5411e-05 -6.0000e+00 3.1830e-04 7.3283e-03 -1.9393e-04 12 1 1 12 1 1 -4808.49 23.65 1.69 0.00733 0.03228 3 5 1 4 0 1728.470 25.90 20.00 23.65 32.07 3.0 1001.65 -835 -665 -308 351 18 173 283 588 829 156 258 -147 -81 -596 54 -282 -154 154 -179 423 -191 154 277 199 96 157 532 -310 -396 -602 -485 -309 -176 296 152 395 -51 -6 -481 110 324 355 520 474 410 215 329 207 302 -411 -430 -988 -801 -422 -183 -210 -68 359 303 151 264 522 729 96 109 136 -254 -444 -112 -441 -658 -443 4 -88 191 46 89 -361 -95 -672 -264 -320 -317 30 -91 -204 106 -59 -7 -162 67 329 113 463 -48 228 -118 -254 -376 -895 -444 -312 -105 179 349 -184 -438 -186 -469 128 -235 399 494 548 243 557 826 269 85 6 186 -103 -90 306 278 30 -141 380 689 181 412 -228 -545 -391 -207 -126 37 534 -159 107 -205 125 285 506 -71 114 -258 -307 -520 -689 -821 -669 -312 357 18 183 298 620 887 166 269 -152 -82 -614 55 -284 -158 162 -189 446 -203 163 292 211 102 167 560 -324 -408 -601 -495 -309 -181 307 162 418 -53 -7 -493 115 338 364 537 496 432 226 343 213 311 -413 -429 -971 -782 -419 -183 -217 -70 366 307 152 268 532 743 98 110 138 -255 -441 -109 -425 -635 -431 4 -88 191 46 85 -352 -92 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