File name: Pandora80s1_BeltsvilleMD_20230127_L2Fit_fout2c8d20220601p1-8.txt File generation date: 20241115T030735.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: John Sullivan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 80 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora80_OF_v4d20220517.txt Instrument calibration file used: Pandora80s1_CF_v8d20220601.txt Level 1 file used: Pandora80s1_BeltsvilleMD_20230127_L1_smca1c8d20220601p1-8.txt Full location name: Howard University-Beltsville Campus, Beltsville, MD Short location name: BeltsvilleMD Country of location: United States Location latitude [deg]: 39.0567 Location longitude [deg]: -76.8758 Location altitude [m]: 70 Local noon date: 20230127 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 337 Nominal wavelengths inside fitting window [nm]: 305.1296 305.2706 305.4117 305.5527 305.6937 305.8347 305.9757 306.1167 306.2576 306.3986 306.5396 306.6805 306.8214 306.9623 307.1032 307.2441 307.3850 307.5259 307.6667 307.8076 307.9484 308.0893 308.2301 308.3709 308.5117 308.6524 308.7932 308.9340 309.0747 309.2155 309.3562 309.4969 309.6376 309.7783 309.9190 310.0596 310.2003 310.3409 310.4816 310.6222 310.7628 310.9034 311.0440 311.1846 311.3252 311.4657 311.6063 311.7468 311.8873 312.0278 312.1683 312.3088 312.4493 312.5898 312.7302 312.8707 313.0111 313.1515 313.2919 313.4323 313.5727 313.7131 313.8535 313.9938 314.1342 314.2745 314.4148 314.5551 314.6954 314.8357 314.9760 315.1162 315.2565 315.3967 315.5370 315.6772 315.8174 315.9576 316.0978 316.2380 316.3781 316.5183 316.6584 316.7985 316.9386 317.0788 317.2188 317.3589 317.4990 317.6391 317.7791 317.9191 318.0592 318.1992 318.3392 318.4792 318.6192 318.7591 318.8991 319.0390 319.1790 319.3189 319.4588 319.5987 319.7386 319.8785 320.0183 320.1582 320.2980 320.4378 320.5777 320.7175 320.8573 320.9971 321.1368 321.2766 321.4163 321.5561 321.6958 321.8355 321.9752 322.1149 322.2546 322.3943 322.5339 322.6736 322.8132 322.9528 323.0925 323.2321 323.3716 323.5112 323.6508 323.7903 323.9299 324.0694 324.2089 324.3485 324.4880 324.6274 324.7669 324.9064 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230127T132012.4Z 8427.555698 70 1 4.70 2 80.27 123.53 116.73 53.22 0.00 1 0.00 1 0 25 4.779e-01 2.235e-02 3.252e-01 1.245e-02 7.215898e-01 6.539333e-03 9.435892e-03 -6.000000e+00 2.656107e-01 224.32 -2.00 3.47 -2.00 321.04 0.00e+00 8.945856e-03 2.841100e-03 7.017547e-03 -6.000000e+00 1.225626e-02 276.48 -2.00 20.00 -2.00 320.56 0.00e+00 5.651 0.003 302.00 328.00 3 2.0650e+00 2.0725e-02 7.1826e-02 -6.0000e+00 6.5628e-01 3.5520e-01 2.7450e-02 4.8434e-02 -6.0000e+00 7.1446e-01 -5.2941e-01 2.7358e-02 3.0098e-02 -6.0000e+00 4.2505e-01 2.3003e-01 1.3388e-02 1.2281e-02 -6.0000e+00 1.8631e-01 1.1700e-04 2.6552e-04 3.1845e-04 1.9782e-04 -6.0000e+00 1.2259e-02 -1.0676e-02 2.5106e-04 12 9 9 12 1 1 -159.60 22.77 0.66 -0.01068 -0.00868 4 9 1 5 0 907.360 25.68 19.39 22.77 7.32 4.1 830.29 900000 -212709 -65490 5335 61996 -231910 64372 -168149 -135645 -44948 -203410 900000 -124752 -20270 -18725 -71838 -70857 -29701 98653 -37440 183569 12935 30197 -10470 12280 26738 900000 -34411 -39141 60849 -7233 79323 9640 27713 36424 30916 -7045 -14989 65233 9022 4088 18167 14288 5378 11200 30620 5373 26133 14560 11683 11089 8596 18580 12695 15931 1472 13120 3473 11967 18261 9612 13573 6350 11982 1466 6004 3921 9328 4145 4826 5060 816 4422 -596 255 4974 -5364 -776 -3703 2013 -5638 -644 -3042 162 -4168 190 1693 2321 -1055 664 -1326 -4451 -1876 -3879 -2923 -2334 -272 1233 -1537 -696 -2445 -175 -4015 -2453 -2218 -1893 -1282 -535 248 1284 535 345 -753 -864 -557 -11 -533 1576 697 1671 2500 2078 2858 570 1871 -1614 867 -302 769 18 481 -202 41 113 -195 587 -354 213 192 -613 -525 -1890 900000 -8912 -794 65 752 -9461 781 -4079 -2542 -545 -7849 900000 -3576 -268 -341 -2376 -2836 -865 1196 -1271 2226 251 513 -279 268 519 900000 -1169 -1424 959 -281 1539 433 1042 1149 1050 -393 -1073 2532 711 367 1498 1282 535 1073 2488 580 2409 1589 1431 1547 1355 2884 2248 2821 309 2466 695 2119 3034 1865 2881 1679 3357 460 1748 1184 2817 1513 2002 2031 345 1893 -247 93 1562 -1828 -273 -1603 899 -3164 -390 -2012 109 -3162 146 1331 1840 -850 494 -933 -3067 -1256 -2904 -2539 -2171 -290 1478 -1827 -852 -2775 -171 -3842 -2469 -2391 -2130 -1535 -640 331 1933 828 552 -1198 -1315 -860 -17 -843 2404 1134 2712 3857 3321 4396 860 2698 -2316 1209 -480 1296 35 923 -412 88 243 -449 1380 -851 514 448 -1353 -1152 -3956 SS 20230127T132740.9Z 8427.560890 75 1 5.37 2 79.07 124.85 115.58 54.73 0.00 1 0.00 1 0 17 4.092e-01 2.244e-02 3.018e-01 1.414e-02 6.675298e-01 7.382821e-03 7.875914e-03 -6.000000e+00 2.290088e-01 224.32 -2.00 3.47 -2.00 320.69 0.00e+00 4.796748e-03 2.935618e-03 2.947353e-03 -6.000000e+00 1.011236e-02 276.48 -2.00 20.00 -2.00 320.21 0.00e+00 5.083 0.002 302.00 328.00 3 2.9086e+00 2.2614e-02 6.1517e-02 -6.0000e+00 5.6820e-01 2.4275e-01 2.8935e-02 3.6296e-02 -6.0000e+00 6.1957e-01 -3.3642e-01 2.8319e-02 2.0575e-02 -6.0000e+00 3.6552e-01 1.4711e-01 1.4186e-02 7.8091e-03 -6.0000e+00 1.5924e-01 9.0898e-05 -7.5084e-04 3.6836e-04 1.0774e-04 -6.0000e+00 1.0624e-02 -1.0056e-02 -2.2574e-05 12 9 9 12 1 1 999.00 22.80 1.01 -0.01006 -0.01570 2 5 1 5 0 1735.510 25.68 20.16 22.80 8.16 4.1 838.73 900000 -171746 -49549 -159149 55127 -241086 900000 -119694 900000 -137018 -47225 -69426 -123672 900000 -90149 60468 -10647 23670 -28717 -29186 31543 -86658 -13289 12952 48376 11673 31515 -42622 71008 16122 -4374 72513 -5309 14543 -1382 21051 -11563 -7580 28887 12544 10098 13193 17341 4238 33243 28677 12832 14871 24 14937 9763 16331 9138 10864 10375 9517 9051 11261 -3082 -4884 7073 -1602 7520 -4534 7915 764 2590 1228 4352 6988 3820 3883 2831 1077 76 -7482 -3441 -5392 1791 -5631 -3878 198 -4776 836 -2687 1874 -1568 -550 862 -1894 2272 -567 -6051 -3868 857 -1075 2 1300 2734 -1314 -1021 -1600 -1440 317 -1288 -2974 -2688 -270 1171 -1378 225 1015 932 -1734 -1171 -1326 -424 761 1356 2502 56 1961 2568 1921 -61 445 381 -66 1850 417 -99 295 -343 -1035 -287 391 543 97 -679 -477 -1085 -345 900000 -4948 -683 -3788 760 -11777 900000 -2099 900000 -3261 -651 -1148 -4182 900000 -3850 833 -264 457 -989 -1046 608 -5373 -421 339 933 338 738 -1997 1076 489 -199 1798 -329 741 -76 957 -828 -627 2030 1210 1085 1454 1911 537 3206 2963 1591 1885 4 2161 1681 2903 1901 2395 2387 2282 2207 2607 -794 -1279 1754 -490 2414 -1658 2813 281 946 479 1717 3072 1852 1906 1344 480 30 -3216 -1380 -2355 783 -3160 -2477 137 -3703 648 -2125 1498 -1349 -475 720 -1527 1773 -431 -4798 -2989 733 -1091 2 1566 3375 -1616 -1141 -1727 -1469 341 -1394 -3420 -3290 -349 1668 -2112 369 1696 1525 -2768 -1750 -1950 -641 1203 2256 4162 92 3027 3821 2752 -86 644 548 -99 3106 736 -190 593 -682 -2220 -653 853 1199 218 -1490 -1040 -2231 -708 SS 20230127T133741.7Z 8427.567844 81 1 3.65 2 77.49 126.67 114.00 56.70 0.00 1 0.00 1 0 17 3.162e-01 1.391e-02 1.967e-01 8.965e-03 6.106884e-01 4.557384e-03 7.086745e-03 -6.000000e+00 1.753725e-01 224.32 -2.00 3.47 -2.00 320.11 0.00e+00 4.885436e-03 1.519073e-03 1.707193e-03 -6.000000e+00 7.620643e-03 276.48 -2.00 20.00 -2.00 319.60 0.00e+00 4.489 0.002 302.00 328.00 3 2.5133e+00 1.3171e-02 5.4164e-02 -6.0000e+00 4.3367e-01 1.5723e-01 1.6149e-02 3.1316e-02 -6.0000e+00 4.7197e-01 -1.8452e-01 1.5071e-02 1.8048e-02 -6.0000e+00 2.8067e-01 7.4710e-02 7.8301e-03 7.7515e-03 -6.0000e+00 1.2186e-01 2.5042e-04 -1.8199e-04 2.3032e-04 7.9659e-05 -6.0000e+00 7.9973e-03 -1.0528e-02 5.1800e-05 12 9 9 12 1 1 65.68 22.85 0.79 -0.01053 -0.01190 3 9 1 5 0 871.070 25.68 19.57 22.85 9.04 4.0 842.91 -59086 -156996 -101190 142470 -102702 -129936 -148934 -40150 -36931 -45294 -63159 -80945 -57886 981 -980 -35624 10573 -20605 -41686 15726 -8576 -9439 -15042 -9667 -16627 11634 2781 -5519 -13694 -12822 -16355 22005 -14835 -4054 -9852 -3061 -14905 22429 -8162 10158 -1441 12694 3807 3098 6454 2812 5779 -21 2574 2369 6351 5328 5610 7876 2143 2169 1147 583 -391 3083 5570 1465 6507 4004 3237 -3184 966 -2729 2595 315 2425 -397 474 406 -4562 -669 -3313 -4257 -4053 -1653 917 -3148 -1668 -1160 -1716 -1222 1059 1218 892 1301 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