File name: Pandora80s1_BeltsvilleMD_20230906_L2Fit_fout2c8d20220601p1-8.txt File generation date: 20230907T124302.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: John Sullivan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 80 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora80_OF_v4d20220517.txt Instrument calibration file used: Pandora80s1_CF_v8d20220601.txt Level 1 file used: Pandora80s1_BeltsvilleMD_20230906_L1_smca1c8d20220601p1-8.txt Full location name: Howard University-Beltsville Campus, Beltsville, MD Short location name: BeltsvilleMD Country of location: United States Location latitude [deg]: 39.0567 Location longitude [deg]: -76.8758 Location altitude [m]: 70 Local noon date: 20230906 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 337 Nominal wavelengths inside fitting window [nm]: 305.1296 305.2706 305.4117 305.5527 305.6937 305.8347 305.9757 306.1167 306.2576 306.3986 306.5396 306.6805 306.8214 306.9623 307.1032 307.2441 307.3850 307.5259 307.6667 307.8076 307.9484 308.0893 308.2301 308.3709 308.5117 308.6524 308.7932 308.9340 309.0747 309.2155 309.3562 309.4969 309.6376 309.7783 309.9190 310.0596 310.2003 310.3409 310.4816 310.6222 310.7628 310.9034 311.0440 311.1846 311.3252 311.4657 311.6063 311.7468 311.8873 312.0278 312.1683 312.3088 312.4493 312.5898 312.7302 312.8707 313.0111 313.1515 313.2919 313.4323 313.5727 313.7131 313.8535 313.9938 314.1342 314.2745 314.4148 314.5551 314.6954 314.8357 314.9760 315.1162 315.2565 315.3967 315.5370 315.6772 315.8174 315.9576 316.0978 316.2380 316.3781 316.5183 316.6584 316.7985 316.9386 317.0788 317.2188 317.3589 317.4990 317.6391 317.7791 317.9191 318.0592 318.1992 318.3392 318.4792 318.6192 318.7591 318.8991 319.0390 319.1790 319.3189 319.4588 319.5987 319.7386 319.8785 320.0183 320.1582 320.2980 320.4378 320.5777 320.7175 320.8573 320.9971 321.1368 321.2766 321.4163 321.5561 321.6958 321.8355 321.9752 322.1149 322.2546 322.3943 322.5339 322.6736 322.8132 322.9528 323.0925 323.2321 323.3716 323.5112 323.6508 323.7903 323.9299 324.0694 324.2089 324.3485 324.4880 324.6274 324.7669 324.9064 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230906T121221.1Z 8649.508578 255 1 51.86 2 73.09 95.52 25.68 244.42 0.00 1 0.00 1 0 17 8.097e-02 6.806e-03 4.231e-02 2.336e-03 4.268070e-01 1.202482e-03 5.040350e-03 -6.000000e+00 4.592683e-02 229.98 -2.00 3.47 -2.00 319.89 0.00e+00 1.125435e-03 3.743331e-04 1.372765e-03 -6.000000e+00 2.062204e-03 289.46 -2.00 20.00 -2.00 319.11 0.00e+00 3.385 0.001 302.00 328.00 3 3.3298e+00 3.5336e-03 4.0685e-02 -6.0000e+00 1.1456e-01 -1.6458e-02 4.2720e-03 2.3590e-02 -6.0000e+00 1.2386e-01 -1.3689e-02 3.4782e-03 1.1450e-02 -6.0000e+00 7.3896e-02 -7.3940e-04 1.8085e-03 3.1310e-03 -6.0000e+00 3.2091e-02 4.0819e-04 -1.5389e-04 6.5631e-05 3.6819e-05 -6.0000e+00 2.0508e-03 -1.4378e-02 6.2525e-05 11 8 0 10 0 0 97.50 24.87 0.54 -0.01438 -0.01553 76 11 1 5 0 682.300 27.26 20.00 24.87 32.96 4.5 1023.59 12063 -37953 -3000 -44093 -4440 -27706 -19449 -11561 -38565 -5429 -32881 -9470 -20704 -3141 -13193 -11373 -8074 -4828 7145 -4089 -560 -5243 3959 -5663 -5326 -97 -173 727 -9488 -5359 -2302 308 1078 -4255 -4216 -6824 -1727 -3339 76 184 -601 345 -88 119 -1008 1028 -1870 1525 -723 1450 810 1477 1748 372 2474 265 1904 -1285 -292 1081 1077 2063 2211 3169 -77 490 -1194 572 905 1420 1317 477 948 167 115 -1412 -873 -2612 -1417 -1370 -1552 -1373 -1890 -547 -725 531 -25 1453 833 443 1105 -331 -317 -623 -168 -297 590 336 -204 -189 -1375 -1413 -1617 -345 -1574 -654 -665 -626 511 640 1017 228 493 -253 -256 143 -228 242 298 282 271 721 556 195 391 -637 40 -82 -15 53 -99 -247 -609 42 13 -8 228 543 -72 6 -417 -454 140 -802 -46 -931 -57 -459 -330 -208 -1022 -108 -865 -222 -726 -112 -619 -588 -432 -269 374 -251 -34 -328 242 -413 -411 -7 -13 51 -715 -417 -199 29 114 -474 -433 -748 -206 -487 13 37 -132 79 -21 28 -245 248 -462 367 -180 373 232 457 580 134 900 102 734 -502 -110 405 428 898 1071 1638 -40 236 -570 275 492 879 875 327 630 106 65 -734 -424 -1311 -798 -897 -1156 -1134 -1658 -455 -654 504 -25 1455 829 415 1041 -292 -266 -547 -164 -301 671 428 -269 -238 -1612 -1501 -1665 -380 -1893 -814 -874 -874 763 1044 1752 397 820 -395 -371 201 -331 372 492 482 456 1176 882 296 567 -889 54 -120 -24 92 -184 -432 -1109 82 26 -18 493 1198 -157 13 -830 -867 SS 20230906T121834.7Z 8649.512901 259 1 52.54 2 71.89 96.54 26.75 246.40 0.00 1 0.00 1 0 17 4.972e-02 6.501e-03 1.393e-02 1.033e-03 4.032358e-01 5.239094e-04 4.726037e-03 -6.000000e+00 2.820053e-02 229.98 -2.00 3.47 -2.00 319.55 0.00e+00 7.205070e-04 1.469777e-04 9.873839e-04 -6.000000e+00 1.266254e-03 289.46 -2.00 20.00 -2.00 318.74 0.00e+00 3.174 0.001 302.00 328.00 3 2.0879e+00 1.4921e-03 3.8009e-02 -6.0000e+00 7.0343e-02 -1.6524e-02 1.7740e-03 2.1624e-02 -6.0000e+00 7.6052e-02 -1.2200e-02 1.3880e-03 1.0578e-02 -6.0000e+00 4.5374e-02 -9.4996e-04 7.3216e-04 2.9326e-03 -6.0000e+00 1.9705e-02 1.7786e-03 -2.9182e-05 2.8886e-05 2.9120e-05 -6.0000e+00 1.2592e-03 -1.4228e-02 7.0200e-05 11 8 0 10 0 0 98.70 24.92 0.60 -0.01423 -0.01445 350 53 1 5 0 148.830 27.26 20.00 24.92 33.53 4.5 1029.46 -3332 -11189 -5411 -25786 -12253 -20377 -20573 -21509 -9328 -8633 -18428 -8700 -13255 -5376 -6319 -3373 -1253 -3673 552 -1425 -2866 151 -774 -1784 -807 -1322 -2547 -2404 -4466 -212 -3798 -144 -462 -3051 -5352 -4489 -2250 -1341 159 -777 -823 -101 -359 214 -35 1048 -880 -218 -1349 647 1046 900 1595 1153 1067 737 937 60 583 243 1484 1768 2506 2355 133 278 -1195 -115 1124 913 1187 587 867 425 -495 -1410 -1799 -1978 -1277 -1491 -1192 -1627 -2047 -999 -634 311 496 971 1071 664 827 -404 -434 -608 -46 -239 688 716 -59 -292 -1138 -1453 -1306 -401 -1287 -894 -693 -418 412 508 872 536 477 -82 -302 -93 -111 200 206 214 281 762 434 422 362 -481 185 217 57 56 -224 -445 -436 -126 127 -75 459 452 -17 45 -414 -481 -62 -246 -115 -611 -229 -422 -475 -632 -272 -261 -614 -293 -565 -253 -356 -206 -80 -256 39 -107 -221 11 -62 -157 -75 -128 -247 -217 -396 -19 -405 -17 -60 -402 -666 -575 -322 -229 33 -187 -214 -27 -101 60 -10 296 -252 -62 -392 194 345 322 607 470 449 321 415 26 249 104 668 876 1369 1382 77 150 -634 -62 676 629 794 404 580 296 -316 -812 -973 -1085 -787 -1067 -876 -1331 -1773 -906 -620 320 534 1060 1153 673 769 -351 -358 -521 -44 -258 832 964 -83 -389 -1411 -1640 -1427 -471 -1645 -1187 -970 -567 597 802 1452 894 761 -122 -418 -137 -154 294 326 351 454 1194 662 611 549 -700 260 328 87 93 -392 -804 -814 -249 248 -152 940 946 -34 89 -850 -947 SS 20230906T123303.1Z 8649.522953 268 1 52.26 2 69.11 98.96 29.29 250.55 0.00 1 0.00 1 0 17 2.849e-02 6.461e-03 3.760e-03 4.888e-04 3.551464e-01 2.475419e-04 4.191825e-03 -6.000000e+00 1.616137e-02 229.97 -2.00 3.47 -2.00 318.86 0.00e+00 8.760672e-04 5.569393e-05 6.782111e-04 -6.000000e+00 7.256743e-04 289.46 -2.00 20.00 -2.00 318.02 0.00e+00 2.776 0.000 302.00 328.00 3 1.3125e+00 6.8489e-04 3.3233e-02 -6.0000e+00 4.0312e-02 -1.7791e-02 7.8967e-04 1.8667e-02 -6.0000e+00 4.3585e-02 -8.1078e-03 5.5269e-04 9.1196e-03 -6.0000e+00 2.6003e-02 -1.7602e-03 2.9269e-04 2.5384e-03 -6.0000e+00 1.1293e-02 5.9997e-03 -7.4729e-05 1.3551e-05 2.5426e-05 -6.0000e+00 7.2166e-04 -1.4463e-02 6.0786e-05 11 8 0 10 0 0 96.42 25.03 0.53 -0.01446 -0.01502 700 106 1 5 0 74.440 27.35 20.01 25.03 35.33 4.4 1041.40 -8624 -3536 -7392 -11285 -11881 -10318 -10385 -7241 -7985 -7131 -8355 -7991 -4089 -2812 -1047 -1335 -1017 -136 679 849 -644 214 84 86 -623 -394 -1569 -2880 -2891 -1619 -505 461 804 -2840 -4177 -3955 -3162 -993 -161 89 -353 -143 -95 103 409 58 22 -473 -668 467 966 904 1383 1060 934 1119 499 569 165 390 1203 1739 2432 1925 201 -108 -879 -394 841 1031 1032 491 638 299 -410 -825 -2037 -1820 -1350 -1465 -1183 -1629 -1845 -1133 -551 29 425 868 925 610 627 -265 -567 -414 -246 -53 650 721 -22 -412 -995 -1520 -1089 -562 -1217 -829 -744 -371 340 647 760 551 485 -56 -240 -70 -11 187 428 138 341 563 526 371 429 -316 162 303 13 134 -218 -357 -487 -127 137 -113 451 323 -11 -120 -405 -549 -342 -145 -320 -460 -437 -379 -422 -326 -404 -370 -434 -455 -266 -214 -92 -129 -103 -15 76 99 -76 25 10 11 -88 -58 -230 -396 -380 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