File name: Pandora80s1_BeltsvilleMD_20230927_L2Fit_fout2c9d20230401p1-8.txt File generation date: 20241115T065052.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: John Sullivan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 80 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora80_OF_v4d20220517.txt Instrument calibration file used: Pandora80s1_CF_v9d20230401.txt Level 1 file used: Pandora80s1_BeltsvilleMD_20230927_L1_smca1c9d20230401p1-8.txt Full location name: Howard University-Beltsville Campus, Beltsville, MD Short location name: BeltsvilleMD Country of location: United States Location latitude [deg]: 39.0567 Location longitude [deg]: -76.8758 Location altitude [m]: 70 Local noon date: 20230927 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 8 "testing blickC" First and last pixel inside fitting window: 196 337 Nominal wavelengths inside fitting window [nm]: 305.1205 305.2615 305.4025 305.5436 305.6846 305.8256 305.9666 306.1076 306.2485 306.3895 306.5305 306.6714 306.8123 306.9532 307.0941 307.2350 307.3759 307.5168 307.6577 307.7985 307.9393 308.0802 308.2210 308.3618 308.5026 308.6434 308.7841 308.9249 309.0657 309.2064 309.3471 309.4878 309.6285 309.7692 309.9099 310.0506 310.1912 310.3319 310.4725 310.6132 310.7538 310.8944 311.0350 311.1756 311.3161 311.4567 311.5972 311.7378 311.8783 312.0188 312.1593 312.2998 312.4403 312.5807 312.7212 312.8617 313.0021 313.1425 313.2829 313.4233 313.5637 313.7041 313.8445 313.9848 314.1252 314.2655 314.4058 314.5461 314.6864 314.8267 314.9670 315.1073 315.2475 315.3877 315.5280 315.6682 315.8084 315.9486 316.0888 316.2290 316.3691 316.5093 316.6494 316.7896 316.9297 317.0698 317.2099 317.3500 317.4900 317.6301 317.7701 317.9102 318.0502 318.1902 318.3302 318.4702 318.6102 318.7502 318.8901 319.0301 319.1700 319.3099 319.4498 319.5897 319.7296 319.8695 320.0094 320.1492 320.2891 320.4289 320.5687 320.7085 320.8483 320.9881 321.1279 321.2677 321.4074 321.5471 321.6869 321.8266 321.9663 322.1060 322.2457 322.3853 322.5250 322.6647 322.8043 322.9439 323.0835 323.2231 323.3627 323.5023 323.6419 323.7814 323.9210 324.0605 324.2000 324.3395 324.4790 324.6185 324.7580 324.8975 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230927T132859.8Z 8670.561803 242 1 51.70 2 62.92 117.20 142.81 307.39 0.00 1 0.00 1 0 17 5.359e-02 1.331e-02 3.738e-02 8.196e-03 2.723279e-01 4.112301e-03 3.240975e-03 -6.000000e+00 3.017261e-02 228.05 -2.00 3.47 -2.00 318.18 0.00e+00 1.147852e-03 7.527542e-04 1.926899e-04 -6.000000e+00 1.352668e-03 287.41 -2.00 20.00 -2.00 317.38 0.00e+00 2.184 0.000 302.00 328.00 3 6.1793e+00 1.1051e-02 2.5787e-02 -6.0000e+00 7.4970e-02 9.7688e-02 1.2569e-02 1.4017e-02 -6.0000e+00 8.1201e-02 -9.5346e-03 8.0674e-03 6.9287e-03 -6.0000e+00 4.8462e-02 -8.7434e-03 4.1619e-03 2.1217e-03 -6.0000e+00 2.1093e-02 8.7580e-05 -3.2248e-04 2.3013e-04 2.1013e-05 -6.0000e+00 1.3566e-03 -7.0205e-03 0.0000e+00 12 8 8 10 0 0 99.94 24.24 0.38 -0.00702 -0.00944 21 3 1 5 0 2461.800 26.73 20.00 24.24 25.39 4.7 965.06 19642 -12515 328 3695 15904 -14503 -7762 -13829 -14556 14315 -32672 880 -12924 2018 8241 -3536 6650 83 10163 -5226 7115 -771 6031 6096 -5621 1720 -2260 7 -6873 5136 -2024 2748 1405 100 -10332 -4079 29 -5858 1756 2194 5835 436 -42 -780 -228 4680 -2126 681 -2902 -2780 2242 -707 381 -596 3603 964 -13 -310 84 2868 1034 2631 4370 2009 -177 247 -3467 -58 -205 -156 -73 -106 1452 -1829 2364 -2845 -1955 -2754 -4252 -1875 -3470 -726 -2217 -872 -262 1550 1495 113 1593 306 1408 -2635 -574 -1535 -1198 -430 138 1587 -330 1898 -1205 -670 -2778 -11 -1145 -288 197 -475 1424 281 1748 134 977 -109 -990 -718 -868 527 -749 -198 256 551 629 -947 1224 -897 311 -514 783 -68 422 -834 -328 626 177 373 35 1043 -211 -93 -1455 -204 1227 -1155 27 260 878 -1085 -592 -1266 -1481 1113 -3940 81 -1587 246 1084 -565 990 14 1587 -987 1189 -137 1047 1120 -1213 356 -475 1 -1308 892 -410 575 326 23 -2402 -916 8 -1792 601 854 2327 190 -19 -353 -113 2196 -1040 317 -1375 -1349 1116 -386 217 -360 2125 595 -8 -193 51 1696 656 1789 3178 1572 -134 169 -2338 -38 -149 -129 -65 -95 1261 -1556 1753 -1976 -1234 -1726 -2987 -1465 -3076 -685 -2219 -907 -293 1809 1822 142 1951 356 1477 -2615 -516 -1413 -1205 -477 170 2124 -458 2451 -1485 -750 -3099 -13 -1472 -381 272 -693 2159 461 2941 226 1537 -160 -1337 -935 -1161 739 -1150 -317 405 851 940 -1358 1637 -1161 382 -672 1092 -101 654 -1331 -532 1064 322 701 67 2028 -409 -174 -2648 -353 SS 20230927T142701.5Z 8670.602101 276 1 2.09 2 53.55 130.27 149.81 328.36 0.00 1 0.00 1 0 17 1.390e-02 9.662e-03 8.931e-03 5.670e-03 2.063190e-01 2.865106e-03 2.478541e-03 -6.000000e+00 7.824244e-03 228.04 -2.00 3.47 -2.00 315.29 0.00e+00 4.051130e-04 2.643857e-04 6.075083e-05 -6.000000e+00 3.507497e-04 287.41 -2.00 20.00 -2.00 314.61 0.00e+00 1.679 0.000 302.00 328.00 3 4.0065e+00 7.3590e-03 1.9664e-02 -6.0000e+00 1.9441e-02 2.3545e-02 8.1783e-03 1.0464e-02 -6.0000e+00 2.1056e-02 -3.5397e-03 4.7011e-03 5.1154e-03 -6.0000e+00 1.2567e-02 -2.0907e-03 2.1582e-03 1.4414e-03 -6.0000e+00 5.4703e-03 1.4559e-03 -2.0428e-04 1.5087e-04 1.7025e-05 -6.0000e+00 3.5173e-04 -7.6795e-03 0.0000e+00 12 9 9 12 1 1 999.00 24.41 0.54 -0.00768 -0.00921 1 8 1 5 0 1042.120 26.83 20.00 24.41 26.34 4.7 974.33 4508 -1000 2301 -5657 -2762 -2687 -695 877 652 3725 -1209 -89 -3430 -513 -937 -1801 860 -929 3124 1846 1424 -345 4 1780 1922 1228 -1463 -1219 -1908 1746 -895 1573 870 -3555 -2688 -1405 -1250 256 -201 -1490 -1276 -1134 -422 -487 414 273 822 728 -876 -425 1616 -596 283 747 1009 505 167 1335 2078 -27 -13 669 3285 1439 -34 -302 -1186 -469 501 1224 944 590 -248 108 866 -100 -1960 -1825 -1560 -1805 -708 -1288 -2566 -1422 60 115 -308 955 1473 349 -150 -264 -41 -711 997 -740 610 988 -284 0 679 -1441 -1156 -712 -1711 -794 -458 -292 252 187 417 566 632 12 -557 -257 -160 416 463 -236 296 782 395 1573 795 -1683 790 875 2 301 -381 -401 543 -33 549 588 14 461 -1065 -194 -216 -1230 1290 -295 705 -1668 -696 -673 -186 260 213 1198 -391 -30 -1241 -204 -391 -805 380 -433 1441 891 691 -167 2 865 971 643 -763 -579 -909 809 -453 771 465 -1934 -1314 -696 -697 156 -139 -1123 -961 -879 -332 -382 321 210 641 550 -654 -320 1210 -482 239 622 850 436 146 1135 1720 -23 -12 613 3164 1404 -33 -279 -1037 -404 453 1190 983 604 -251 109 826 -90 -1718 -1554 -1375 -1720 -707 -1349 -2836 -1569 71 138 -374 1172 1846 414 -171 -283 -42 -736 1057 -845 732 1247 -370 0 800 -1663 -1307 -839 -2114 -1012 -609 -389 351 268 594 816 885 16 -712 -315 -202 532 620 -323 419 1081 531 2050 1034 -2122 969 1078 2 406 -516 -550 751 -47 793 880 21 699 -1620 -293 -315 -1814 SS 20230927T143230.5Z 8670.605908 279 1 52.15 2 52.75 131.65 150.30 330.71 0.00 1 0.00 1 0 17 2.050e-02 8.663e-03 1.367e-02 4.727e-03 2.035916e-01 2.368438e-03 2.450596e-03 -6.000000e+00 1.154327e-02 228.04 -2.00 3.47 -2.00 317.45 0.00e+00 5.507508e-04 3.491803e-04 2.251191e-04 -6.000000e+00 5.174369e-04 287.41 -2.00 20.00 -2.00 316.64 0.00e+00 1.648 0.000 302.00 328.00 3 5.3281e+00 6.2442e-03 1.9377e-02 -6.0000e+00 2.8681e-02 3.3043e-02 7.0309e-03 1.0420e-02 -6.0000e+00 3.1063e-02 -7.6640e-03 4.2151e-03 5.1134e-03 -6.0000e+00 1.8539e-02 -2.0674e-03 2.0983e-03 1.4527e-03 -6.0000e+00 8.0712e-03 4.0126e-04 -2.9219e-04 1.3146e-04 1.5017e-05 -6.0000e+00 5.1882e-04 -8.4456e-03 0.0000e+00 11 8 0 10 0 0 99.99 24.43 0.22 -0.00845 -0.01064 346 52 1 5 0 150.720 26.83 20.00 24.43 26.77 4.7 978.20 -2850 6453 -6794 2708 -11251 131 -5084 -2694 3883 -5274 1037 -86 -3422 -4597 4635 1178 932 1599 473 3585 -2618 3172 899 319 1307 355 14 -2761 -13 -2072 22 749 3166 -3045 -3204 -3861 -3177 772 -1292 907 -1501 -259 76 -163 451 -1482 756 -1978 -112 -59 309 80 2434 1576 582 1324 688 127 439 1404 788 1824 2382 1595 404 -807 190 -1876 1299 -349 922 936 310 629 -899 -62 -3181 -584 -1452 -2277 -512 -2596 -1530 -1874 -224 -131 1123 606 1130 922 -453 214 -1393 -69 -631 313 678 830 391 -404 -513 -2095 -1104 -793 -1207 -848 -385 71 222 930 284 665 255 -30 -672 -43 -155 -28 50 134 793 690 788 -69 752 107 -606 110 -508 338 64 198 -465 -162 267 472 539 -256 195 -699 -305 -610 -378 823 -981 316 -1327 15 -663 -386 573 -864 153 -13 -622 -955 989 276 222 392 121 918 -713 800 241 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