File name: Pandora80s1_BeltsvilleMD_20240107_L2Fit_fout2c8d20220601p1-8.txt File generation date: 20240224T001906.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: John Sullivan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 80 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora80_OF_v4d20220517.txt Instrument calibration file used: Pandora80s1_CF_v8d20220601.txt Level 1 file used: Pandora80s1_BeltsvilleMD_20240107_L1_smca1c8d20220601p1-8.txt Full location name: Howard University-Beltsville Campus, Beltsville, MD Short location name: BeltsvilleMD Country of location: United States Location latitude [deg]: 39.0567 Location longitude [deg]: -76.8758 Location altitude [m]: 70 Local noon date: 20240107 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 337 Nominal wavelengths inside fitting window [nm]: 305.1296 305.2706 305.4117 305.5527 305.6937 305.8347 305.9757 306.1167 306.2576 306.3986 306.5396 306.6805 306.8214 306.9623 307.1032 307.2441 307.3850 307.5259 307.6667 307.8076 307.9484 308.0893 308.2301 308.3709 308.5117 308.6524 308.7932 308.9340 309.0747 309.2155 309.3562 309.4969 309.6376 309.7783 309.9190 310.0596 310.2003 310.3409 310.4816 310.6222 310.7628 310.9034 311.0440 311.1846 311.3252 311.4657 311.6063 311.7468 311.8873 312.0278 312.1683 312.3088 312.4493 312.5898 312.7302 312.8707 313.0111 313.1515 313.2919 313.4323 313.5727 313.7131 313.8535 313.9938 314.1342 314.2745 314.4148 314.5551 314.6954 314.8357 314.9760 315.1162 315.2565 315.3967 315.5370 315.6772 315.8174 315.9576 316.0978 316.2380 316.3781 316.5183 316.6584 316.7985 316.9386 317.0788 317.2188 317.3589 317.4990 317.6391 317.7791 317.9191 318.0592 318.1992 318.3392 318.4792 318.6192 318.7591 318.8991 319.0390 319.1790 319.3189 319.4588 319.5987 319.7386 319.8785 320.0183 320.1582 320.2980 320.4378 320.5777 320.7175 320.8573 320.9971 321.1368 321.2766 321.4163 321.5561 321.6958 321.8355 321.9752 322.1149 322.2546 322.3943 322.5339 322.6736 322.8132 322.9528 323.0925 323.2321 323.3716 323.5112 323.6508 323.7903 323.9299 324.0694 324.2089 324.3485 324.4880 324.6274 324.7669 324.9064 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240107T134010.0Z 8772.569560 194 1 28.17 2 79.14 130.93 61.96 182.07 0.00 1 0.00 1 0 17 4.283e-01 8.264e-03 9.316e-02 2.351e-03 6.665539e-01 1.238612e-03 7.695358e-03 -6.000000e+00 2.374540e-01 223.70 -2.00 3.47 -2.00 321.04 0.00e+00 4.187099e-03 5.415484e-04 2.697361e-03 -6.000000e+00 1.034790e-02 277.03 -2.00 20.00 -2.00 320.57 0.00e+00 5.113 0.002 302.00 328.00 3 1.0576e+00 3.9327e-03 6.1626e-02 -6.0000e+00 5.8632e-01 1.0997e-01 5.4670e-03 3.6861e-02 -6.0000e+00 6.3781e-01 -1.4619e-01 5.9372e-03 2.2518e-02 -6.0000e+00 3.7955e-01 5.1449e-02 2.8961e-03 8.9631e-03 -6.0000e+00 1.6551e-01 5.8328e-04 -2.4633e-04 6.2313e-05 1.0552e-04 -6.0000e+00 1.0817e-02 -2.5364e-02 8.6769e-05 12 9 1 12 1 1 95.65 22.67 0.66 -0.02536 -0.02722 123 35 1 5 0 227.100 25.58 20.58 22.67 10.49 5.2 864.29 -153869 -129356 -101996 -165347 -139145 -145261 -147210 -154388 -105487 -134127 -120240 -111967 -76244 -55573 -40289 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-532 -609 -1297 -1071 -782 -758 -462 -932 -1317 -1003 -257 17 843 805 933 585 37 -223 -1147 -1067 -739 -291 617 659 317 39 -887 -1445 -1574 -1007 -1703 -1422 -677 -426 427 999 1374 889 307 -408 -1027 -463 -215 433 598 871 1019 1385 1087 673 409 -620 -287 476 -139 185 -474 -998 -916 -651 262 -96 1352 951 21 -40 -793 -1019 SS 20240107T134547.7Z 8772.573469 197 1 2.16 2 78.32 131.96 62.03 183.50 0.00 1 0.00 1 0 17 3.662e-01 2.086e-02 2.991e-01 1.659e-02 6.260088e-01 8.512628e-03 7.841317e-03 -6.000000e+00 2.030517e-01 223.70 -2.00 3.47 -2.00 320.27 0.00e+00 5.871713e-03 2.997623e-03 3.885144e-03 -6.000000e+00 9.258298e-03 277.03 -2.00 20.00 -2.00 319.76 0.00e+00 4.783 0.002 302.00 328.00 3 2.5814e+00 2.4924e-02 5.8441e-02 -6.0000e+00 5.0194e-01 1.7198e-01 3.0809e-02 3.5723e-02 -6.0000e+00 5.4636e-01 -2.3608e-01 2.8640e-02 2.0486e-02 -6.0000e+00 3.2479e-01 1.0007e-01 1.4761e-02 7.6994e-03 -6.0000e+00 1.4300e-01 1.7605e-04 -5.2743e-04 4.2482e-04 1.0925e-04 -6.0000e+00 9.3251e-03 -2.5654e-02 5.6887e-05 12 9 9 12 1 1 999.00 22.70 0.43 -0.02565 -0.02962 1 7 1 5 0 1078.080 25.58 20.40 22.70 11.01 5.2 867.89 900000 -161429 -41790 6507 -114683 -74585 -181115 -88361 -109510 900000 -88445 -86470 -125539 167292 39964 -1241 -35557 -67802 2710 -30201 -11283 -28570 10300 -26577 -4149 4071 -40495 38224 -18624 16297 -22269 -16923 -24708 -11798 -3964 -23702 21407 -11609 31626 17543 2325 14871 7833 8401 -9852 8969 1004 3041 10007 -4009 15224 8220 13356 5359 14207 -5887 13421 6856 -31 4178 8629 4052 2802 10876 5866 7782 2808 88 2435 661 332 346 1869 -6639 -2229 -984 -9712 392 -2051 -1429 -4876 2133 -657 36 880 -1387 118 -3469 2245 -482 -1337 3020 -997 -130 -1440 -830 -122 -968 -419 869 -1135 -2296 -1432 -1538 -3076 -1568 341 -3173 1456 -380 1012 984 -642 -453 -971 2360 -410 1353 1216 141 2215 286 2889 -109 1254 9 2282 1194 -528 -922 376 244 -1247 813 277 522 -530 -1239 -452 -73 -537 -226 900000 -5221 -676 105 -2023 -1206 -6657 -1572 -2657 900000 -1859 -2098 -5888 2705 646 -32 -1438 -4167 88 -1416 -438 -1294 333 -1332 -174 165 -2554 1051 -904 633 -1549 -1314 -2398 -1030 -295 -2185 1419 -1277 2762 2071 350 2092 1241 1345 -1928 1494 185 570 1829 -908 3201 1861 3122 1465 3697 -1930 3690 1966 -9 1185 2487 1376 1104 4413 2527 3146 1193 40 1228 358 194 206 1060 -3811 -1199 -469 -4840 185 -1062 -876 -3581 1525 -517 30 773 -1321 107 -3330 2164 -450 -1163 2363 -792 -109 -1410 -870 -137 -1251 -566 1114 -1362 -2652 -1537 -1756 -3592 -1884 428 -4166 2019 -568 1629 1628 -1056 -706 -1516 3473 -640 2064 1976 236 3527 445 4526 -169 1840 13 3114 1809 -873 -1606 698 452 -2450 1670 581 1128 -1173 -2675 -995 -150 -1102 -436 SS 20240107T135105.0Z 8772.577141 200 1 52.19 2 77.56 132.94 62.12 184.85 0.00 1 0.00 1 0 17 2.979e-01 6.955e-03 3.885e-02 1.075e-03 6.028999e-01 5.520920e-04 6.976487e-03 -6.000000e+00 1.651570e-01 223.70 -2.00 3.47 -2.00 320.79 0.00e+00 3.018794e-03 2.271346e-04 2.247329e-03 -6.000000e+00 7.197741e-03 277.03 -2.00 20.00 -2.00 320.28 0.00e+00 4.513 0.002 302.00 328.00 3 6.1452e-01 1.7118e-03 5.4725e-02 -6.0000e+00 4.0780e-01 6.0574e-02 2.2889e-03 3.2961e-02 -6.0000e+00 4.4362e-01 -7.9209e-02 2.3995e-03 1.9085e-02 -6.0000e+00 2.6399e-01 2.3014e-02 1.1916e-03 6.9948e-03 -6.0000e+00 1.1511e-01 1.7128e-03 -1.6790e-04 2.9035e-05 8.0842e-05 -6.0000e+00 7.5238e-03 -2.5292e-02 7.8463e-05 11 8 0 10 0 0 95.63 22.73 0.56 -0.02529 -0.02655 520 78 1 5 0 100.350 25.58 20.23 22.73 11.33 5.1 870.58 -111731 -79197 -100821 -88896 -116244 -119221 -85072 -81942 -82015 -101897 -71194 -78437 -51804 -51420 -34639 -26147 -25799 -14265 -22654 -10030 -20827 -17935 -16377 -22759 -16331 -22481 -14410 -23978 -16647 -17456 -8929 -6485 -2381 -6064 -10998 -6217 -10215 555 -1161 -280 633 577 1364 1247 2026 390 2634 43 1047 1315 2135 3154 2042 3512 2188 2076 1138 761 -350 209 2020 2548 3757 3176 1799 1450 -333 -302 1153 1811 1428 1238 582 788 -983 -1852 -2886 -2749 -1495 -1840 -365 -1203 -1818 -1438 -511 195 511 1168 1076 819 431 -554 -1026 -731 -555 -237 672 798 412 -312 -881 -1585 -1235 -739 -1471 -872 -776 -342 240 763 747 572 353 -246 -353 -254 15 173 382 344 411 774 610 397 186 -563 -77 90 -109 -33 -301 -399 -483 -266 130 -82 476 464 84 -48 -225 -375 -980 -574 -961 -703 -1097 -1182 -665 -711 -805 -1301 -692 -964 -632 -799 -571 -466 -509 -277 -565 -232 -544 -453 -438 -711 -512 -792 -470 -822 -527 -628 -357 -297 -121 -329 -582 -323 -630 37 -98 -28 68 66 163 151 248 50 335 6 146 198 360 583 416 764 505 497 282 185 -83 49 497 701 1167 1104 638 493 -115 -109 467 839 716 636 291 367 -419 -714 -1075 -1068 -667 -979 -221 -830 -1348 -1122 -387 156 424 980 892 642 344 -419 -759 -574 -454 -223 722 973 527 -386 -1008 -1625 -1189 -754 -1632 -1004 -949 -448 344 1121 1193 938 565 -375 -552 -386 23 262 614 564 655 1291 989 616 278 -814 -108 139 -176 -59 -580 -808 -1022 -601 289 -189 1104 1095 195 -104 -506 -798 SS 20240107T135712.8Z 8772.581398 203 1 52.18 2 76.70 134.09 62.25 186.40 0.00 1 0.00 1 0 17 2.340e-01 7.029e-03 2.670e-02 8.499e-04 5.673486e-01 4.368919e-04 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