File name: Pandora80s1_BeltsvilleMD_20240222_L2Fit_fout2c8d20220601p1-8.txt File generation date: 20240229T014919.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: John Sullivan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 80 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora80_OF_v4d20220517.txt Instrument calibration file used: Pandora80s1_CF_v8d20220601.txt Level 1 file used: Pandora80s1_BeltsvilleMD_20240222_L1_smca1c8d20220601p1-8.txt Full location name: Howard University-Beltsville Campus, Beltsville, MD Short location name: BeltsvilleMD Country of location: United States Location latitude [deg]: 39.0567 Location longitude [deg]: -76.8758 Location altitude [m]: 70 Local noon date: 20240222 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 337 Nominal wavelengths inside fitting window [nm]: 305.1296 305.2706 305.4117 305.5527 305.6937 305.8347 305.9757 306.1167 306.2576 306.3986 306.5396 306.6805 306.8214 306.9623 307.1032 307.2441 307.3850 307.5259 307.6667 307.8076 307.9484 308.0893 308.2301 308.3709 308.5117 308.6524 308.7932 308.9340 309.0747 309.2155 309.3562 309.4969 309.6376 309.7783 309.9190 310.0596 310.2003 310.3409 310.4816 310.6222 310.7628 310.9034 311.0440 311.1846 311.3252 311.4657 311.6063 311.7468 311.8873 312.0278 312.1683 312.3088 312.4493 312.5898 312.7302 312.8707 313.0111 313.1515 313.2919 313.4323 313.5727 313.7131 313.8535 313.9938 314.1342 314.2745 314.4148 314.5551 314.6954 314.8357 314.9760 315.1162 315.2565 315.3967 315.5370 315.6772 315.8174 315.9576 316.0978 316.2380 316.3781 316.5183 316.6584 316.7985 316.9386 317.0788 317.2188 317.3589 317.4990 317.6391 317.7791 317.9191 318.0592 318.1992 318.3392 318.4792 318.6192 318.7591 318.8991 319.0390 319.1790 319.3189 319.4588 319.5987 319.7386 319.8785 320.0183 320.1582 320.2980 320.4378 320.5777 320.7175 320.8573 320.9971 321.1368 321.2766 321.4163 321.5561 321.6958 321.8355 321.9752 322.1149 322.2546 322.3943 322.5339 322.6736 322.8132 322.9528 323.0925 323.2321 323.3716 323.5112 323.6508 323.7903 323.9299 324.0694 324.2089 324.3485 324.4880 324.6274 324.7669 324.9064 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240222T141419.9Z 8818.593286 319 1 9.14 2 65.65 128.21 115.00 331.89 0.00 1 0.00 1 0 17 3.156e-02 7.016e-03 8.080e-03 1.311e-03 3.897990e-01 6.517937e-04 4.615169e-03 -6.000000e+00 1.761317e-02 225.34 -2.00 3.47 -2.00 318.24 0.00e+00 1.227701e-03 1.213247e-04 4.202706e-04 -6.000000e+00 7.620491e-04 276.88 -2.00 20.00 -2.00 317.65 0.00e+00 2.409 0.000 302.00 328.00 3 2.2381e+00 1.7406e-03 3.0980e-02 -6.0000e+00 4.3652e-02 5.8020e-03 1.9746e-03 1.9609e-02 -6.0000e+00 4.7427e-02 -1.6636e-02 1.3501e-03 9.9043e-03 -6.0000e+00 2.8185e-02 3.4251e-03 7.2094e-04 3.0485e-03 -6.0000e+00 1.2249e-02 3.1464e-03 -9.2774e-06 3.4868e-05 2.8447e-05 -6.0000e+00 7.9723e-04 -2.7336e-02 1.0854e-04 12 9 1 12 1 1 99.97 22.44 0.51 -0.02734 -0.02741 67 58 1 5 0 134.280 25.39 19.57 22.44 12.90 5.2 887.76 -3610 -9423 -6054 -10300 -15260 -12163 -12200 -3897 -7930 -5958 -13966 -8917 -4869 -3707 38 -3301 -618 -629 239 877 379 2 -142 1078 -600 -333 -2273 -1783 -3898 -938 121 -132 2020 -1651 -3131 -3183 -3102 -1451 67 156 -876 263 40 129 307 746 644 25 -198 586 1244 972 1447 1405 1075 1005 755 561 -184 806 834 1682 2082 1783 394 132 -620 -639 694 915 932 557 680 475 -369 -1062 -1906 -2131 -1640 -1336 -1226 -1816 -1823 -1456 -638 -139 269 749 845 445 410 -77 -601 -198 -339 -73 606 633 166 -254 -801 -1356 -1094 -391 -1133 -859 -671 -352 198 700 700 683 556 91 -212 -33 -82 246 425 321 445 578 745 408 489 -384 244 466 73 280 -215 -260 -629 -106 82 -156 477 224 -20 -198 -416 -702 -165 -503 -322 -524 -726 -561 -617 -207 -490 -378 -951 -633 -398 -358 4 -421 -81 -88 35 133 59 0 -23 185 -111 -64 -442 -322 -684 -168 24 -29 450 -384 -745 -772 -773 -423 24 64 -358 111 17 57 136 331 283 11 -88 269 621 526 833 795 629 605 464 340 -109 473 515 1132 1546 1328 291 97 -442 -461 513 773 791 486 579 410 -292 -812 -1364 -1526 -1213 -1141 -1104 -1826 -1815 -1519 -713 -155 312 882 984 521 440 -82 -600 -202 -359 -88 763 841 230 -336 -1044 -1608 -1316 -472 -1492 -1110 -912 -504 287 1097 1104 1081 842 136 -309 -46 -118 352 653 488 704 888 1109 578 700 -527 321 650 106 440 -341 -425 -1060 -180 148 -279 861 415 -37 -362 -729 -1179 SS 20240222T142339.6Z 8818.599764 324 1 52.19 2 64.25 130.21 115.82 334.01 0.00 1 0.00 1 0 17 9.722e-02 1.252e-02 8.221e-02 8.240e-03 3.725392e-01 4.138153e-03 4.359710e-03 -6.000000e+00 5.439365e-02 225.34 -2.00 3.47 -2.00 319.27 0.00e+00 8.841083e-04 1.022317e-03 9.461579e-04 -6.000000e+00 2.348244e-03 276.88 -2.00 20.00 -2.00 318.70 0.00e+00 2.288 0.000 302.00 328.00 3 5.8884e+00 1.1442e-02 2.9588e-02 -6.0000e+00 1.3482e-01 5.3631e-02 1.3280e-02 1.8957e-02 -6.0000e+00 1.4635e-01 -3.3751e-02 1.0179e-02 9.8890e-03 -6.0000e+00 8.6974e-02 1.0013e-02 5.4108e-03 3.2265e-03 -6.0000e+00 3.7888e-02 9.2126e-05 2.5169e-03 2.3167e-04 3.2733e-05 -6.0000e+00 2.4501e-03 -3.2163e-02 6.6048e-04 12 8 8 10 0 0 99.99 22.50 0.22 -0.03216 -0.01325 66 10 1 5 0 790.690 25.39 19.85 22.50 13.34 5.2 891.88 -32856 -28355 31390 -61201 -613 -1770 17870 -19310 3423 20891 -31167 872 -10755 31579 -12517 10402 14661 -16162 20283 -2180 14258 -15483 8775 -2319 7227 -5776 -4884 16079 -10359 7865 -7234 11388 500 -154 -9280 -7976 1301 -7556 3030 -1505 3307 -2679 4402 -3573 1326 3822 -983 3739 -2017 2894 445 2857 1949 -776 -650 -3391 2812 -1923 2987 984 650 1577 2196 4171 523 -112 -300 1286 480 735 2992 -495 1968 -960 586 -2971 -2260 -3670 -2674 68 -798 -829 -3964 -695 -1380 -264 1116 226 2307 275 1637 -2283 1858 -2238 814 -376 -679 1066 -213 450 -1720 -1483 -1525 176 -1301 -1705 -196 -845 1254 403 1109 819 759 45 -498 -1084 -1390 -200 35 693 404 1050 1112 906 238 -1101 -67 -458 48 -99 -335 -54 -925 602 -76 1159 -123 970 -325 21 -44 -1754 -1254 -1139 779 -3531 -17 -49 444 -790 125 671 -1662 36 -597 1361 -987 729 1039 -1653 1511 -212 1187 -1707 795 -252 755 -717 -596 1480 -1173 770 -919 1331 73 -23 -1376 -1177 197 -1479 651 -395 894 -802 1270 -1120 396 1119 -298 1181 -674 951 163 1106 811 -353 -304 -1670 1326 -935 1344 450 312 822 1256 2517 320 -63 -163 690 289 506 2166 -381 1445 -686 375 -1754 -1224 -1996 -1598 46 -610 -703 -3663 -653 -1408 -284 1235 258 2550 292 1572 -2093 1527 -1951 761 -400 -815 1402 -294 590 -2129 -1659 -1630 199 -1613 -2209 -264 -1204 1872 660 1904 1411 1249 69 -710 -1494 -1965 -295 55 1137 658 1654 1698 1315 332 -1479 -86 -623 71 -158 -567 -93 -1660 1124 -152 2376 -261 2071 -691 42 -85 -3311 SS 20240222T143218.5Z 8818.605770 330 1 52.17 2 62.98 132.12 116.52 336.02 0.00 1 0.00 1 0 17 2.772e-02 6.158e-03 6.502e-03 7.982e-04 3.588709e-01 3.974679e-04 4.238148e-03 -6.000000e+00 1.546657e-02 225.34 -2.00 3.47 -2.00 318.87 0.00e+00 1.127165e-03 8.731085e-05 5.211932e-04 -6.000000e+00 6.692101e-04 276.88 -2.00 20.00 -2.00 318.28 0.00e+00 2.189 0.000 302.00 328.00 3 2.4779e+00 1.0805e-03 2.8374e-02 -6.0000e+00 3.8332e-02 3.4604e-03 1.2413e-03 1.8197e-02 -6.0000e+00 4.1648e-02 -5.5481e-03 9.1416e-04 9.2745e-03 -6.0000e+00 2.4751e-02 -3.1707e-03 4.8850e-04 2.8729e-03 -6.0000e+00 1.0756e-02 3.1848e-03 -6.0338e-05 2.2071e-05 2.8721e-05 -6.0000e+00 7.0012e-04 -2.7194e-02 1.0355e-04 10 0 0 10 0 0 99.99 22.55 0.58 -0.02719 -0.02765 771 116 1 5 0 67.660 25.47 19.83 22.55 13.62 5.2 893.34 -4179 -3676 -7048 -8004 -13585 -11870 -10908 -3686 -6793 -8521 -9288 -7916 -4073 -4207 -948 -996 53 33 633 208 -376 -151 -230 62 -1263 -343 -1742 -2695 -3096 163 -37 45 2181 -2196 -2962 -3880 -3152 -1616 -539 -168 -841 -172 -628 -140 201 50 -155 -648 -372 52 1513 900 1400 1023 1039 820 799 546 -168 412 916 1682 2303 1935 219 24 -979 -568 943 854 1035 548 663 334 -378 -569 -1804 -1688 -1168 -1116 -1125 -1580 -1934 -1467 -689 -323 358 808 964 536 509 -182 -599 -294 -247 -57 497 747 155 -246 -769 -1367 -978 -540 -921 -855 -748 -394 260 530 782 641 422 -57 -313 -82 -116 205 381 188 294 430 638 354 450 -353 86 224 -39 42 -312 -359 -466 -92 159 -117 417 331 16 -115 -285 -599 -143 -138 -280 -293 -467 -401 -439 -157 -334 -444 -481 -439 -258 -317 -81 -95 5 3 70 24 -44 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