File name: Pandora80s1_BeltsvilleMD_20241028_L2Fit_fout2c11d20240813p1-8.txt File generation date: 20250313T075233.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c11p1-8 Local principal investigator: John Sullivan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 80 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora80_OF_v4d20220517.txt Instrument calibration file used: Pandora80s1_CF_v11d20240813.txt Level 1 file used: Pandora80s1_BeltsvilleMD_20241028_L1_smca1c11d20240813p1-8.txt Full location name: Howard University-Beltsville Campus, Beltsville, MD Short location name: BeltsvilleMD Country of location: United States Location latitude [deg]: 39.0567 Location longitude [deg]: -76.8758 Location altitude [m]: 70 Local noon date: 20241028 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 337 Nominal wavelengths inside fitting window [nm]: 305.0863 305.2274 305.3685 305.5096 305.6507 305.7917 305.9328 306.0738 306.2149 306.3559 306.4969 306.6379 306.7789 306.9199 307.0609 307.2018 307.3428 307.4837 307.6247 307.7656 307.9065 308.0474 308.1882 308.3291 308.4700 308.6108 308.7517 308.8925 309.0333 309.1741 309.3149 309.4557 309.5964 309.7372 309.8779 310.0187 310.1594 310.3001 310.4408 310.5815 310.7222 310.8629 311.0035 311.1442 311.2848 311.4254 311.5660 311.7066 311.8472 311.9878 312.1283 312.2689 312.4094 312.5500 312.6905 312.8310 312.9715 313.1120 313.2525 313.3929 313.5334 313.6738 313.8142 313.9547 314.0951 314.2355 314.3758 314.5162 314.6566 314.7969 314.9373 315.0776 315.2179 315.3582 315.4985 315.6388 315.7790 315.9193 316.0595 316.1998 316.3400 316.4802 316.6204 316.7606 316.9008 317.0409 317.1811 317.3212 317.4614 317.6015 317.7416 317.8817 318.0218 318.1618 318.3019 318.4419 318.5820 318.7220 318.8620 319.0020 319.1420 319.2820 319.4220 319.5619 319.7019 319.8418 319.9817 320.1216 320.2615 320.4014 320.5413 320.6812 320.8210 320.9609 321.1007 321.2405 321.3803 321.5201 321.6599 321.7997 321.9394 322.0792 322.2189 322.3586 322.4983 322.6380 322.7777 322.9174 323.0571 323.1967 323.3364 323.4760 323.6156 323.7552 323.8948 324.0344 324.1740 324.3135 324.4531 324.5926 324.7322 324.8717 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241028T124125.5Z 9067.528767 181 1 30.95 2 78.27 118.23 40.98 143.78 0.00 1 0.00 1 0 17 3.349e-01 9.459e-03 4.933e-02 1.720e-03 5.916268e-01 8.922475e-04 7.281993e-03 -6.000000e+00 1.869437e-01 225.03 -2.00 3.47 -2.00 320.73 0.00e+00 2.771665e-03 3.756927e-04 4.173914e-03 -6.000000e+00 8.315243e-03 283.63 -2.00 20.00 -2.00 320.15 0.00e+00 4.761 0.002 302.00 328.00 3 9.7730e-01 2.8415e-03 5.8859e-02 -6.0000e+00 4.6193e-01 5.2566e-02 3.7319e-03 3.8853e-02 -6.0000e+00 5.0125e-01 -1.1346e-01 3.6512e-03 1.9739e-02 -6.0000e+00 2.9917e-01 3.9936e-02 1.8086e-03 5.5320e-03 -6.0000e+00 1.3096e-01 9.7354e-04 6.3844e-04 4.6120e-05 9.2350e-05 -6.0000e+00 8.4541e-03 -9.5988e-04 0.0000e+00 12 9 9 12 1 1 57.88 22.39 0.51 -0.00096 0.00384 177 45 1 5 0 173.850 25.39 20.42 22.39 11.16 6.3 869.89 -123751 -89595 -104232 -99226 -122271 -117275 -107359 -123403 -85629 -112284 -88693 -91100 -71885 -45085 -37748 -33068 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339 -454 -757 -1525 -1371 -1481 -1005 -994 -896 -1299 -1049 -369 30 965 1120 1329 576 435 -527 -1415 -959 -845 -374 605 798 514 -197 -1368 -2345 -2113 -965 -1703 -1480 -903 -295 484 1703 1964 1519 564 -433 -930 -877 -606 154 1007 785 1449 1563 1672 417 512 -908 -720 -87 -425 321 -504 -1089 -1650 -255 548 -73 1144 1439 444 -269 -731 -1355 SS 20241028T124711.1Z 9067.532767 184 1 52.21 2 77.29 119.26 40.37 145.74 0.00 1 0.00 1 0 17 2.648e-01 8.490e-03 3.040e-02 1.068e-03 5.558539e-01 5.497125e-04 6.698908e-03 -6.000000e+00 1.478471e-01 225.02 -2.00 3.47 -2.00 320.65 0.00e+00 2.249170e-03 2.241296e-04 3.371298e-03 -6.000000e+00 6.575936e-03 283.63 -2.00 20.00 -2.00 320.05 0.00e+00 4.421 0.001 302.00 328.00 3 7.2299e-01 1.7211e-03 5.4032e-02 -6.0000e+00 3.6532e-01 2.5079e-02 2.2410e-03 3.4394e-02 -6.0000e+00 3.9642e-01 -7.4057e-02 2.1690e-03 1.7632e-02 -6.0000e+00 2.3660e-01 2.3652e-02 1.0817e-03 5.0520e-03 -6.0000e+00 1.0358e-01 1.7994e-03 6.6583e-04 2.9241e-05 7.3858e-05 -6.0000e+00 6.6856e-03 -1.3165e-03 0.0000e+00 11 8 0 10 0 0 5.97 22.40 0.56 -0.00132 0.00369 513 77 1 5 0 101.570 25.39 20.43 22.40 11.90 6.4 879.08 -95620 -79798 -77630 -82197 -97935 -104334 -87663 -88898 -66387 -77482 -75881 -60169 -53915 -38673 -38172 -25531 -22412 -9880 -16980 -9972 -18025 -18342 -12013 -15897 -10465 -11995 -13886 -18173 -17353 -10399 -10305 -4138 -7202 -7991 -10188 -10861 -9253 -3299 -998 372 1733 1579 2199 2042 3127 1719 1508 1505 -576 1459 1600 2790 2729 2469 1993 2313 2273 1130 566 458 1381 2358 3920 3646 1928 1639 -275 -487 1009 1923 1916 1904 1147 801 -619 -2156 -3162 -4175 -2616 -2036 -1299 -1562 -1934 -1293 -497 319 918 1480 1481 1082 582 -826 -1587 -1385 -902 -657 388 910 332 -179 -1077 -1775 -1917 -879 -1583 -922 -844 -177 559 979 1192 749 493 -246 -578 -525 -206 188 485 404 474 897 751 292 225 -749 -389 61 35 -135 -178 -551 -673 -228 179 54 510 622 184 -48 -286 -631 -1014 -823 -830 -864 -1085 -1244 -979 -1153 -779 -1085 -1070 -831 -888 -688 -838 -578 -541 -254 -502 -290 -576 -584 -384 -579 -387 -476 -564 -732 -679 -418 -492 -216 -448 -517 -624 -683 -651 -263 -96 42 212 206 298 281 432 246 219 225 -91 242 297 565 601 590 500 600 605 299 146 118 372 704 1308 1352 731 591 -100 -184 425 926 998 1019 601 395 -280 -887 -1246 -1712 -1215 -1113 -812 -1105 -1467 -1030 -385 261 780 1278 1265 877 481 -648 -1209 -1109 -744 -621 417 1104 424 -222 -1239 -1840 -1878 -909 -1786 -1079 -1048 -234 804 1566 1889 1220 782 -371 -894 -787 -318 306 769 660 756 1501 1223 456 339 -1090 -550 94 56 -236 -335 -1089 -1391 -500 387 120 1155 1437 419 -112 -636 -1337 SS 20241028T125315.1Z 9067.536980 187 1 52.11 2 76.27 120.35 39.75 147.85 0.00 1 0.00 1 0 17 1.983e-01 8.238e-03 2.110e-02 8.479e-04 5.196728e-01 4.350060e-04 6.269661e-03 -6.000000e+00 1.107091e-01 225.02 -2.00 3.47 -2.00 320.39 0.00e+00 2.240189e-03 1.615467e-04 2.776751e-03 -6.000000e+00 4.924127e-03 283.63 -2.00 20.00 -2.00 319.76 0.00e+00 4.114 0.001 302.00 328.00 3 6.7448e-01 1.3066e-03 4.9718e-02 -6.0000e+00 2.7356e-01 7.7982e-03 1.6571e-03 3.0399e-02 -6.0000e+00 2.9684e-01 -4.7986e-02 1.5543e-03 1.5899e-02 -6.0000e+00 1.7717e-01 1.2934e-02 7.9132e-04 4.7562e-03 -6.0000e+00 7.7560e-02 2.6233e-03 7.1460e-04 2.3265e-05 6.2703e-05 -6.0000e+00 5.0062e-03 -1.2874e-03 0.0000e+00 11 8 0 10 0 0 1.68 22.42 0.53 -0.00129 0.00408 633 95 1 5 0 82.310 25.39 20.40 22.42 13.12 6.4 890.33 -72165 -63928 -63319 -73355 -70636 -75497 -64335 -61346 -46706 -56737 -55020 -48346 -40325 -23570 -22997 -15131 -14068 -10299 -11574 -10460 -9588 -14373 -10519 -8030 -6118 -8174 -9056 -10543 -13389 -8610 -10316 -3396 -1874 -4744 -7885 -8265 -7629 -4526 -1356 176 642 963 1558 1703 1968 1641 493 813 -301 728 1282 2009 2334 2374 2417 1718 1592 337 341 285 1166 2545 3846 3603 1478 798 -907 -631 775 1773 1771 1192 978 684 -542 -1963 -3330 -3803 -2354 -1983 -1183 -1491 -2016 -1196 -689 307 884 1478 1501 948 512 -743 -1422 -1532 -724 -446 397 907 367 -139 -1108 -1890 -1739 -768 -1425 -915 -713 -181 544 911 1047 754 514 -175 -637 -423 -216 178 486 444 546 797 867 388 192 -731 -293 -22 39 -4 -166 -549 -756 -243 112 -10 538 630 164 -59 -312 -570 -841 -778 -809 -970 -818 -925 -778 -825 -614 -878 -852 -796 -847 -522 -624 -440 -443 -341 -415 -391 -361 -563 -423 -344 -275 -395 -443 -497 -633 -424 -608 -216 -134 -360 -572 -614 -640 -441 -158 24 95 151 254 281 328 280 86 144 -56 142 277 474 595 653 693 514 488 103 101 84 362 868 1463 1515 635 325 -370 -265 362 946 1021 710 568 375 -272 -894 -1453 -1707 -1191 -1178 -800 -1138 -1500 -931 -576 271 811 1377 1384 830 415 -569 -1155 -1187 -630 -443 448 1152 489 -180 -1330 -2053 -1785 -834 -1687 -1126 -928 -251 748 1386 1716 1262 837 -270 -921 -592 -311 270 785 740 891 1256 1327 569 295 -1088 -423 -34 62 -7 -314 -1086 -1558 -490 240 -22 1215 1451 373 -127 -642 -1214 SS 20241028T130423.8Z 9067.544719 190 1 52.12 2 74.42 122.40 38.72 151.86 0.00 1 0.00 1 0 17 1.209e-01 8.000e-03 1.078e-02 5.895e-04 4.696305e-01 2.974464e-04 5.587633e-03 -6.000000e+00 6.750475e-02 225.02 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