File name: Pandora132s1_Berlin_20211116_L2Fit_fwvt1c13d20210422p1-8.txt File generation date: 20241123T161734.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Thomas Ruhtz Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 132 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora132_OF_v1d20200910.txt Instrument calibration file used: Pandora132s1_CF_v13d20210422.txt Level 1 file used: Pandora132s1_Berlin_20211116_L1_smca1c13d20210422p1-8.txt Full location name: Institute of Space Sciences FU Berlin Short location name: Berlin Country of location: Germany Location latitude [deg]: 52.4600 Location longitude [deg]: 13.3100 Location altitude [m]: 100 Local noon date: 20211116 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 11, but different RefDay (April 2021). First and last pixel inside fitting window: 1664 1813 Nominal wavelengths inside fitting window [nm]: 492.1018 492.2228 492.3437 492.4647 492.5856 492.7065 492.8273 492.9482 493.0690 493.1899 493.3107 493.4315 493.5523 493.6730 493.7938 493.9145 494.0352 494.1559 494.2766 494.3972 494.5179 494.6385 494.7591 494.8797 495.0003 495.1208 495.2414 495.3619 495.4824 495.6029 495.7234 495.8438 495.9643 496.0847 496.2051 496.3255 496.4459 496.5662 496.6866 496.8069 496.9272 497.0475 497.1677 497.2880 497.4082 497.5285 497.6487 497.7689 497.8890 498.0092 498.1293 498.2494 498.3695 498.4896 498.6097 498.7298 498.8498 498.9698 499.0898 499.2098 499.3298 499.4497 499.5697 499.6896 499.8095 499.9294 500.0492 500.1691 500.2889 500.4087 500.5285 500.6483 500.7681 500.8878 501.0076 501.1273 501.2470 501.3666 501.4863 501.6060 501.7256 501.8452 501.9648 502.0844 502.2039 502.3235 502.4430 502.5625 502.6820 502.8015 502.9210 503.0404 503.1598 503.2792 503.3986 503.5180 503.6374 503.7567 503.8760 503.9953 504.1146 504.2339 504.3531 504.4724 504.5916 504.7108 504.8300 504.9492 505.0683 505.1875 505.3066 505.4257 505.5448 505.6638 505.7829 505.9019 506.0209 506.1399 506.2589 506.3779 506.4968 506.6158 506.7347 506.8536 506.9725 507.0913 507.2102 507.3290 507.4478 507.5666 507.6854 507.8042 507.9229 508.0416 508.1603 508.2790 508.3977 508.5164 508.6350 508.7536 508.8722 508.9908 509.1094 509.2280 509.3465 509.4650 509.5835 509.7020 509.8205 509.9389 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-401: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20211116T104227.0Z 7990.446146 304 1 14.69 2 71.33 177.72 118.20 31.69 0.00 1 0.00 1 0 15 5.990e-03 5.977e-03 6.366e-03 6.348e-03 2.235036e+03 3.666553e+02 1.652508e+02 -6.000000e+00 3.182841e+02 270.92 -2.00 20.00 -2.00 505.31 0.00e+00 8.122584e-04 1.696246e-04 5.142561e-05 -6.000000e+00 1.633654e-04 270.92 -2.00 20.00 -2.00 500.58 0.00e+00 1.546892e-01 1.246599e-01 2.037458e-02 -6.000000e+00 1.187681e-01 220.75 -2.00 3.85 -2.00 502.16 0.00e+00 3.087 0.001 489.00 513.00 1 6.5991e+00 9.5116e-03 4.8239e-03 -6.0000e+00 9.0760e-03 1.5454e-02 2.4541e-03 5.1754e-04 -6.0000e+00 2.3606e-03 1.6878e-03 9.7712e-04 6.4264e-04 3.0563e-05 -6.0000e+00 6.1853e-04 -1.6073e-02 -4.5208e-07 12 8 8 10 0 0 70.66 16.06 1.01 -0.01607 -0.00930 584 124 3 2 0 24.000 14.98 16.06 15.14 20.46 20.96 23.2 986.65 -1008 -244 -589 822 -430 1762 419 459 154 -174 1022 -202 1084 -383 92 -107 99 -86 -206 260 -155 819 -452 1220 -55 579 -335 384 -680 -660 460 -1100 403 -885 -51 -589 -591 139 -627 193 -867 641 -409 556 915 -265 118 -739 1038 -809 804 -81 178 -1241 -19 55 -414 639 -282 899 -540 435 -587 -298 151 -334 -307 -341 747 -401 626 -740 -410 -128 -788 608 -615 474 -538 401 218 192 69 -235 776 -1084 -433 -661 -213 -100 554 -288 -403 -132 99 473 -704 127 -661 68 -545 -640 793 -66 360 -791 865 -614 295 200 265 -117 62 566 -280 1024 -513 813 97 -439 344 -240 460 -252 848 -888 -154 -744 16 1078 -577 785 -314 1034 -558 1026 -330 -12 184 246 566 -290 863 -981 781 69 803 -609 -753 -377 -922 -226 -566 803 -436 1783 436 480 161 -180 1027 -203 1057 -375 90 -105 98 -88 -215 272 -164 857 -479 1277 -58 610 -353 395 -688 -651 443 -1087 403 -924 -53 -627 -624 144 -647 196 -894 656 -428 582 961 -282 124 -770 1041 -804 765 -76 166 -1192 -18 55 -424 653 -290 914 -559 448 -611 -308 153 -337 -305 -334 715 -384 592 -712 -398 -125 -779 587 -591 444 -505 373 204 181 66 -226 749 -1073 -427 -653 -209 -99 549 -292 -413 -135 99 465 -684 120 -612 62 -499 -599 756 -66 362 -802 853 -607 287 197 264 -119 64 584 -293 1063 -542 846 100 -451 345 -239 455 -252 841 -897 -154 -749 16 1058 -570 752 -300 966 -531 978 -326 -12 186 251 579 -301 888 -1032 805 71 800 -601 -733 -366 SQ 20211116T104241.8Z 7990.446318 304 2 14.48 2 71.33 177.78 118.18 31.75 0.00 1 0.00 1 0 15 2.030e-02 2.021e-02 2.453e-02 2.445e-02 1.983869e+03 1.399864e+03 1.184196e+02 -6.000000e+00 1.078710e+03 270.92 -2.00 20.00 -2.00 505.31 0.00e+00 1.453829e-03 6.539885e-04 7.928695e-05 -6.000000e+00 5.537244e-04 270.92 -2.00 20.00 -2.00 500.57 0.00e+00 3.644464e-01 4.805306e-01 2.614469e-02 -6.000000e+00 4.028079e-01 220.75 -2.00 3.85 -2.00 502.16 0.00e+00 3.086 0.001 489.00 513.00 1 8.0075e+00 3.6692e-02 5.1861e-03 -6.0000e+00 3.0778e-02 1.2225e-02 9.4569e-03 5.5107e-04 -6.0000e+00 8.0126e-03 4.0269e-04 2.0214e-03 2.4861e-03 3.2175e-05 -6.0000e+00 2.0970e-03 -1.1976e-02 -8.0750e-05 12 8 8 10 0 0 9.66 16.06 1.93 -0.01198 0.00204 584 124 3 2 0 24.000 14.98 16.06 15.14 20.46 20.96 23.2 986.65 -4454 -61 -2122 1443 205 2439 2545 -159 2445 -3284 1932 -1543 3412 -1256 -3731 1901 -973 1388 -2970 1846 -853 1494 -646 1581 1272 -975 1971 -379 1844 -1527 -408 -2198 -488 -330 -1610 1126 -2394 1606 -1365 75 -2198 115 1032 471 5373 -1553 3016 -2854 1601 458 1500 4439 -277 -1118 335 677 -3416 2533 -2147 1937 448 246 1698 -4066 2224 -1848 -840 -1554 292 2858 2663 1072 -1645 1495 -3690 3564 -3554 2256 -2241 -515 2345 -1748 1786 -1600 477 -2915 -2547 -609 -3796 3576 -339 3936 -254 -711 1387 1323 -748 -2390 -523 -1489 641 -2072 4438 -433 23 216 1401 333 -938 3327 -1552 -374 940 1630 1180 1684 -272 -731 3080 -2720 859 -2416 442 898 1073 1174 -3992 922 -2073 3072 -2621 1489 -1117 -1727 617 565 1281 -940 155 -1721 1345 298 155 -1229 565 3012 1543 308 -3165 -931 -4220 -56 -2071 1402 206 2455 2595 -168 2493 -3497 1923 -1566 3248 -1239 -3763 1826 -979 1397 -3183 1901 -905 1549 -686 1646 1333 -1043 2031 -392 1820 -1516 -396 -2193 -491 -342 -1726 1178 -2571 1637 -1418 76 -2298 118 1065 494 5407 -1674 3081 -3046 1601 450 1422 4003 -260 -1076 327 677 -3624 2549 -2264 1957 461 254 1734 -4383 2228 -1900 -842 -1547 282 2658 2471 1015 -1619 1443 -3762 3345 -3522 2078 -2143 -483 2150 -1683 1673 -1565 461 -2934 -2557 -600 -3861 3396 -338 3815 -259 -730 1377 1291 -728 -2306 -484 -1372 579 -1963 4070 -430 23 215 1367 324 -922 3160 -1572 -381 956 1661 1216 1735 -287 -772 3100 -2856 857 -2463 437 888 1063 1163 -4164 914 -2113 2964 -2649 1421 -1078 -1663 582 541 1245 -950 157 -1791 1366 308 161 -1296 583 2999 1525 301 -3157 -909 SQ 20211116T104256.7Z 7990.446489 304 3 14.77 2 71.33 177.84 118.16 31.81 0.00 1 0.00 1 0 15 1.814e-02 1.798e-02 2.827e-02 2.818e-02 2.311960e+03 1.636453e+03 1.608314e+02 -6.000000e+00 9.639604e+02 270.92 -2.00 20.00 -2.00 505.31 0.00e+00 1.518885e-03 7.550420e-04 9.156373e-05 -6.000000e+00 4.948398e-04 270.92 -2.00 20.00 -2.00 500.56 0.00e+00 3.686634e-01 5.552903e-01 2.577035e-02 -6.000000e+00 3.600119e-01 220.75 -2.00 3.85 -2.00 502.15 0.00e+00 3.086 0.001 489.00 513.00 1 8.1530e+00 4.2398e-02 5.2924e-03 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