File name: Pandora132s1_Berlin_20220228_L2Fit_fout2c13d20210422p1-8.txt File generation date: 20241123T164433.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c13p1-8 Local principal investigator: Thomas Ruhtz Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 132 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora132_OF_v1d20200910.txt Instrument calibration file used: Pandora132s1_CF_v13d20210422.txt Level 1 file used: Pandora132s1_Berlin_20220228_L1_smca1c13d20210422p1-8.txt Full location name: Institute of Space Sciences FU Berlin Short location name: Berlin Country of location: Germany Location latitude [deg]: 52.4600 Location longitude [deg]: 13.3100 Location altitude [m]: 100 Local noon date: 20220228 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 11, but different RefDay (April 2021). First and last pixel inside fitting window: 243 385 Nominal wavelengths inside fitting window [nm]: 305.1071 305.2480 305.3889 305.5298 305.6707 305.8116 305.9524 306.0932 306.2341 306.3749 306.5157 306.6565 306.7973 306.9380 307.0788 307.2195 307.3603 307.5010 307.6417 307.7824 307.9231 308.0638 308.2044 308.3451 308.4857 308.6264 308.7670 308.9076 309.0482 309.1888 309.3293 309.4699 309.6104 309.7510 309.8915 310.0320 310.1725 310.3130 310.4534 310.5939 310.7344 310.8748 311.0152 311.1556 311.2960 311.4364 311.5768 311.7172 311.8575 311.9979 312.1382 312.2785 312.4188 312.5591 312.6994 312.8397 312.9800 313.1202 313.2604 313.4007 313.5409 313.6811 313.8213 313.9615 314.1016 314.2418 314.3819 314.5221 314.6622 314.8023 314.9424 315.0825 315.2225 315.3626 315.5026 315.6427 315.7827 315.9227 316.0627 316.2027 316.3427 316.4827 316.6226 316.7626 316.9025 317.0424 317.1823 317.3222 317.4621 317.6020 317.7418 317.8817 318.0215 318.1613 318.3012 318.4410 318.5807 318.7205 318.8603 319.0000 319.1398 319.2795 319.4192 319.5589 319.6986 319.8383 319.9780 320.1177 320.2573 320.3969 320.5366 320.6762 320.8158 320.9554 321.0949 321.2345 321.3741 321.5136 321.6531 321.7927 321.9322 322.0717 322.2111 322.3506 322.4901 322.6295 322.7689 322.9084 323.0478 323.1872 323.3266 323.4659 323.6053 323.7447 323.8840 324.0233 324.1627 324.3020 324.4413 324.5805 324.7198 324.8591 324.9983 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220228T072624.2Z 8094.310002 94 1 49.81 2 77.98 120.58 80.35 153.52 0.00 1 0.00 1 0 25 5.144e-01 1.319e-02 2.731e-01 7.186e-03 6.738193e-01 3.852815e-03 8.101114e-03 -6.000000e+00 2.909172e-01 224.25 -2.00 3.85 -2.00 321.25 0.00e+00 4.926504e-03 1.656364e-03 7.812967e-04 -6.000000e+00 1.315818e-02 267.17 -2.00 20.00 -2.00 320.84 0.00e+00 4.660 0.002 302.00 328.00 3 3.0108e+00 1.1965e-02 5.9989e-02 -6.0000e+00 7.1976e-01 1.4142e-01 1.6611e-02 3.9820e-02 -6.0000e+00 7.8731e-01 -1.4038e-01 1.8642e-02 2.1496e-02 -6.0000e+00 4.6570e-01 5.4206e-02 9.0954e-03 8.8147e-03 -6.0000e+00 1.9851e-01 1.2490e-04 -8.6281e-04 2.0681e-04 9.1433e-05 -6.0000e+00 1.4250e-02 -2.4782e-02 0.0000e+00 12 8 8 10 0 0 99.94 15.51 0.22 -0.02478 -0.03127 48 10 2 8 0 1037.480 15.01 15.51 7.85 20.04 20.46 23.5 989.85 900000 -194744 900000 -191397 900000 -187865 -83578 -180617 -198500 -128647 -165012 900000 -149808 36066 -85157 33732 -39362 -55554 21829 -82738 82100 -68240 122134 -64405 48954 -24211 -14950 14019 -59710 38508 -17925 166817 -20812 397 -4914 -9996 14081 -7938 34351 -6966 19139 2586 30530 4999 -2882 23466 4416 18099 1354 16727 -1279 13122 6423 8073 8373 3244 12159 -3121 11129 -1506 1203 686 3745 5403 1612 7183 378 7899 -3007 4497 1618 2085 750 -296 4245 -4041 1817 -5393 -884 -2776 -355 -1223 -3168 121 -2895 682 -810 1601 -357 670 310 -1771 909 -1823 37 -2342 557 363 239 -259 -1052 176 -1444 1916 -2096 -697 -1610 -666 519 -216 1455 -373 1044 -1427 449 -300 455 33 13 -398 -779 748 785 1717 -117 870 -262 488 707 -381 848 -93 -100 -94 257 -266 -362 658 -359 360 -119 -551 -579 900000 -2975 900000 -2924 900000 -2511 -585 -2759 -4044 -1392 -2731 900000 -3242 253 -1626 260 -651 -1202 236 -2686 575 -1955 855 -2009 583 -570 -356 245 -2015 593 -590 1168 -901 15 -185 -395 532 -409 1564 -514 1218 209 1963 426 -271 1748 410 1532 143 1640 -168 1671 961 1285 1402 595 2082 -616 1849 -281 228 146 884 1407 457 1888 105 2127 -1013 1609 650 862 307 -114 1424 -1325 531 -1754 -313 -1194 -175 -688 -1980 78 -2038 492 -622 1227 -276 490 213 -1160 563 -1217 27 -2072 555 377 268 -289 -1194 176 -1360 1773 -2160 -748 -1842 -809 633 -298 2169 -594 1634 -2197 641 -417 635 48 20 -637 -1229 1113 1225 2566 -171 1210 -361 708 1157 -653 1563 -183 -207 -207 602 -654 -908 1648 -898 856 -265 -1159 -1195 SS 20220228T082306.5Z 8094.349381 125 1 22.69 2 71.07 133.27 77.34 165.98 0.00 1 0.00 1 0 17 8.132e-02 5.283e-03 2.132e-02 1.324e-03 4.707157e-01 6.722840e-04 6.001690e-03 -6.000000e+00 4.587808e-02 224.25 -2.00 3.85 -2.00 319.77 0.00e+00 1.189609e-03 1.882490e-04 2.946234e-04 -6.000000e+00 1.929406e-03 267.18 -2.00 20.00 -2.00 319.34 0.00e+00 3.046 0.001 302.00 328.00 3 1.5245e+00 1.8783e-03 3.9964e-02 -6.0000e+00 1.1362e-01 3.2963e-02 2.2156e-03 2.6458e-02 -6.0000e+00 1.2418e-01 1.2213e-04 1.9285e-03 1.3497e-02 -6.0000e+00 7.3504e-02 -1.0138e-02 1.0216e-03 4.2445e-03 -6.0000e+00 3.0800e-02 3.2109e-03 -2.8112e-04 3.8526e-05 4.7947e-05 -6.0000e+00 2.2190e-03 -2.5520e-02 0.0000e+00 12 1 1 12 1 1 99.98 15.57 0.21 -0.02552 -0.02763 275 135 2 8 0 77.350 15.00 15.57 9.17 20.14 20.56 23.7 997.32 -17843 -26584 -12374 -30741 -26141 -44915 -28821 -31413 -26327 -23452 -19088 -13049 -17769 -3684 -6051 158 -6465 1619 -1859 1662 -613 -1658 840 -3931 67 -3798 -2615 -3530 -2443 -1960 1495 3125 1582 226 -4161 -1749 -2620 -418 36 -999 -617 -243 537 -508 906 -45 -398 -59 -652 372 968 1112 812 1698 444 1508 721 410 208 46 642 1312 1772 2073 869 -104 -309 -1103 918 901 233 391 -55 715 -161 -516 -812 -1733 -768 -1041 -1422 -1294 -1826 -1385 -732 -564 224 478 698 460 776 512 -138 526 283 230 413 783 317 1 -143 -980 -150 -110 -809 -1295 -598 -767 174 453 461 144 174 -6 -86 39 383 -150 69 -433 -233 -170 383 154 673 251 -156 1053 461 133 -90 -224 -193 48 -39 -221 -93 450 -87 -1 138 -468 -157 -274 -505 -213 -603 -449 -916 -547 -706 -632 -581 -468 -334 -576 -128 -259 7 -349 87 -110 100 -38 -106 54 -290 5 -316 -215 -281 -187 -156 131 311 179 27 -493 -202 -339 -58 6 -198 -135 -56 128 -124 221 -11 -100 -15 -169 100 283 357 283 625 173 602 296 167 83 18 263 587 879 1115 481 -55 -158 -578 521 533 151 262 -36 445 -101 -292 -427 -919 -444 -700 -1007 -1022 -1561 -1245 -698 -572 237 516 743 470 734 448 -115 443 263 242 492 958 413 1 -171 -1156 -166 -126 -998 -1564 -753 -1024 248 706 772 248 292 -9 -127 56 544 -224 110 -720 -387 -274 591 229 954 341 -222 1425 691 221 -160 -414 -343 90 -78 -460 -198 964 -186 -1 271 -876 -289 SS 20220228T083544.6Z 8094.358155 132 1 2.78 2 69.70 136.26 76.90 168.82 0.00 1 0.00 1 0 17 7.216e-02 9.073e-03 4.915e-02 5.167e-03 4.439152e-01 2.571727e-03 5.688529e-03 -6.000000e+00 4.071083e-02 224.25 -2.00 3.85 -2.00 318.86 0.00e+00 1.746854e-03 5.583118e-04 1.897804e-04 -6.000000e+00 1.712104e-03 267.18 -2.00 20.00 -2.00 318.42 0.00e+00 2.853 0.000 302.00 328.00 3 2.7230e+00 6.9516e-03 3.7363e-02 -6.0000e+00 1.0082e-01 5.0168e-02 7.9687e-03 2.4598e-02 -6.0000e+00 1.1019e-01 -2.1319e-02 6.0018e-03 1.2422e-02 -6.0000e+00 6.5225e-02 2.6218e-03 3.2156e-03 4.0364e-03 -6.0000e+00 2.7331e-02 1.1920e-03 -1.4349e-04 1.4639e-04 4.0940e-05 -6.0000e+00 1.9691e-03 -2.5473e-02 0.0000e+00 12 9 1 12 1 1 93.98 15.58 0.21 -0.02547 -0.02655 6 28 4 8 0 373.000 15.01 15.58 9.68 20.14 20.56 23.7 998.84 21870 -31005 -21154 -33054 -12786 4875 -28916 -8648 -21401 16353 -31016 -5418 -6983 -3223 534 529 16569 -6121 8554 -2543 6501 -3797 5975 -2528 -4647 10894 -10564 7951 -11517 5066 -462 1559 2425 -3514 -2724 -6815 -1186 -4903 4454 -1734 -2101 -615 -465 544 -1142 3235 -2467 757 -2019 967 572 2268 4176 2105 1908 442 3224 -153 -96 596 -690 1295 981 4015 -1260 716 -543 -1439 1106 277 1184 -432 1574 -873 106 -1186 710 -1095 -862 441 -937 -1199 -2647 -1534 -1280 -116 -372 -422 424 761 1005 -81 288 -662 1434 -390 215 1096 -448 139 -480 -847 -374 948 -895 -1257 -549 -1523 526 456 930 -274 399 -186 -44 350 650 -80 -515 248 -145 122 491 94 1504 -21 361 569 900 -555 177 -776 151 -138 -11 -168 81 678 -230 -158 428 -1134 -221 474 -1281 -821 -1366 -393 123 -1107 -309 -971 536 -1672 -248 -391 -213 37 42 1207 -600 768 -267 634 -411 608 -301 -607 1268 -1515 907 -1551 601 -65 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