File name: Pandora132s1_Berlin_20221228_L2Fit_fwvt1c13d20210422p1-8.txt File generation date: 20241123T185659.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Thomas Ruhtz Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 132 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora132_OF_v1d20200910.txt Instrument calibration file used: Pandora132s1_CF_v13d20210422.txt Level 1 file used: Pandora132s1_Berlin_20221228_L1_smca1c13d20210422p1-8.txt Full location name: Institute of Space Sciences FU Berlin Short location name: Berlin Country of location: Germany Location latitude [deg]: 52.4600 Location longitude [deg]: 13.3100 Location altitude [m]: 100 Local noon date: 20221228 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 11, but different RefDay (April 2021). First and last pixel inside fitting window: 1664 1813 Nominal wavelengths inside fitting window [nm]: 492.1018 492.2228 492.3437 492.4647 492.5856 492.7065 492.8273 492.9482 493.0690 493.1899 493.3107 493.4315 493.5523 493.6730 493.7938 493.9145 494.0352 494.1559 494.2766 494.3972 494.5179 494.6385 494.7591 494.8797 495.0003 495.1208 495.2414 495.3619 495.4824 495.6029 495.7234 495.8438 495.9643 496.0847 496.2051 496.3255 496.4459 496.5662 496.6866 496.8069 496.9272 497.0475 497.1677 497.2880 497.4082 497.5285 497.6487 497.7689 497.8890 498.0092 498.1293 498.2494 498.3695 498.4896 498.6097 498.7298 498.8498 498.9698 499.0898 499.2098 499.3298 499.4497 499.5697 499.6896 499.8095 499.9294 500.0492 500.1691 500.2889 500.4087 500.5285 500.6483 500.7681 500.8878 501.0076 501.1273 501.2470 501.3666 501.4863 501.6060 501.7256 501.8452 501.9648 502.0844 502.2039 502.3235 502.4430 502.5625 502.6820 502.8015 502.9210 503.0404 503.1598 503.2792 503.3986 503.5180 503.6374 503.7567 503.8760 503.9953 504.1146 504.2339 504.3531 504.4724 504.5916 504.7108 504.8300 504.9492 505.0683 505.1875 505.3066 505.4257 505.5448 505.6638 505.7829 505.9019 506.0209 506.1399 506.2589 506.3779 506.4968 506.6158 506.7347 506.8536 506.9725 507.0913 507.2102 507.3290 507.4478 507.5666 507.6854 507.8042 507.9229 508.0416 508.1603 508.2790 508.3977 508.5164 508.6350 508.7536 508.8722 508.9908 509.1094 509.2280 509.3465 509.4650 509.5835 509.7020 509.8205 509.9389 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-401: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20221228T115241.8Z 8397.494928 198 1 49.31 2 76.35 190.48 81.44 118.68 0.00 1 0.00 1 0 15 2.186e-03 2.186e-03 7.749e-04 7.737e-04 2.973130e+03 4.424450e+01 2.353495e+02 -6.000000e+00 1.143204e+02 266.96 -2.00 20.00 -2.00 505.27 0.00e+00 6.709573e-04 2.057863e-05 4.030645e-05 -6.000000e+00 5.906408e-05 266.96 -2.00 20.00 -2.00 500.52 0.00e+00 2.524528e-01 1.531669e-02 2.289590e-02 -6.000000e+00 4.350281e-02 220.69 -2.00 3.85 -2.00 502.10 0.00e+00 4.139 0.001 489.00 513.00 1 7.2800e+00 1.1699e-03 6.2191e-03 -6.0000e+00 3.3192e-03 8.1775e-03 3.0132e-04 6.5855e-04 -6.0000e+00 8.6573e-04 7.3310e-04 4.3526e-04 7.7068e-05 3.8747e-05 -6.0000e+00 2.2581e-04 -3.0302e-02 -1.6941e-05 10 0 0 10 0 0 99.65 16.04 0.71 -0.03030 -0.02728 37 8 1 2 0 1331.620 15.00 16.04 14.61 20.56 20.87 26.3 1025.99 -88 -135 -120 100 -24 318 358 391 395 82 298 77 63 -63 -4 -69 -116 219 31 -107 57 299 21 299 216 135 133 208 -218 -362 -25 -185 -99 43 -110 -245 -50 23 -261 -143 -46 -2 113 238 398 67 114 -31 -50 -339 -413 -337 -478 -324 -194 -249 -244 21 -65 163 211 297 176 150 238 -71 53 -98 -26 -531 -75 -27 -159 156 -73 -121 -217 3 -189 -224 -183 -171 -334 -2 -225 -301 -169 -81 -80 -54 -69 245 197 204 99 330 193 -66 -285 -409 -321 -601 -254 -104 -144 -319 -82 -159 -123 280 -92 -67 87 262 165 295 472 349 157 181 295 -51 120 241 52 60 449 51 50 398 -68 41 61 -138 -373 119 99 -154 157 86 92 117 352 133 124 13 -184 -146 -378 -119 -82 -130 -118 101 -26 338 360 395 398 88 315 80 64 -64 -4 -70 -121 233 31 -109 58 305 22 306 223 139 136 209 -231 -374 -25 -190 -104 43 -113 -254 -51 23 -261 -142 -46 -2 115 244 410 69 117 -31 -50 -329 -420 -335 -472 -323 -199 -244 -244 21 -65 163 212 299 178 151 238 -70 51 -94 -26 -538 -75 -27 -162 149 -70 -116 -220 3 -187 -221 -181 -171 -337 -2 -216 -290 -163 -79 -77 -52 -68 242 197 204 98 319 183 -66 -278 -393 -309 -591 -239 -101 -143 -318 -81 -154 -119 271 -91 -67 88 267 169 303 487 360 161 183 293 -50 118 237 51 60 443 50 49 390 -67 40 58 -129 -351 113 96 -153 158 87 94 120 362 137 128 14 -185 -143 -366 -115 SQ 20221228T122341.6Z 8397.516453 213 1 10.35 2 77.49 197.69 77.44 125.04 0.00 1 0.00 1 0 22 2.292e-03 2.282e-03 2.216e-04 2.213e-04 3.281650e+03 1.275549e+01 2.579153e+02 -6.000000e+00 1.198578e+02 266.96 -2.00 20.00 -2.00 505.27 0.00e+00 7.738735e-04 5.846707e-06 4.642962e-05 -6.000000e+00 6.193192e-05 266.96 -2.00 20.00 -2.00 500.54 0.00e+00 2.792078e-01 4.362291e-03 2.484468e-02 -6.000000e+00 4.563064e-02 220.69 -2.00 3.85 -2.00 502.11 0.00e+00 4.492 0.002 489.00 513.00 1 3.4702e+00 3.3205e-04 6.7615e-03 -6.0000e+00 3.4813e-03 1.2372e-02 8.6049e-05 7.1348e-04 -6.0000e+00 9.0852e-04 3.1370e-02 1.2072e-03 2.2140e-05 4.3680e-05 -6.0000e+00 2.3678e-04 -2.5561e-02 -7.9276e-05 12 1 1 12 1 1 99.82 16.07 0.69 -0.02556 -0.01719 174 180 1 2 0 57.490 14.98 16.07 15.28 20.56 20.96 26.4 1029.67 -120 -190 7 102 137 495 501 420 406 224 287 136 -88 -119 -92 -47 -131 107 121 -142 102 240 67 256 296 118 85 113 -325 -389 -7 -275 -208 138 -42 -240 -31 37 -159 -126 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161 374 92 -81 75 -68 -228 75 95 -106 88 236 151 225 265 185 161 104 -134 -318 -343 -300 SQ 20221228T123754.2Z 8397.526322 221 1 29.08 2 78.21 200.95 75.70 128.06 0.00 1 0.00 1 0 22 2.623e-03 2.608e-03 1.036e-03 1.033e-03 3.640208e+03 6.102619e+01 2.808190e+02 -6.000000e+00 1.371697e+02 266.96 -2.00 20.00 -2.00 505.28 0.00e+00 8.311439e-04 2.727047e-05 4.864762e-05 -6.000000e+00 7.087234e-05 266.96 -2.00 20.00 -2.00 500.48 0.00e+00 2.825033e-01 2.045426e-02 2.756333e-02 -6.000000e+00 5.220513e-02 220.69 -2.00 3.85 -2.00 502.07 0.00e+00 4.744 0.002 489.00 513.00 1 7.3513e+00 1.5559e-03 7.1768e-03 -6.0000e+00 3.9831e-03 1.9421e-02 4.0362e-04 7.7748e-04 -6.0000e+00 1.0391e-03 6.2361e-04 7.0109e-04 1.0337e-04 4.6460e-05 -6.0000e+00 2.7096e-04 -2.8500e-02 -3.7448e-05 12 1 1 12 1 1 99.86 16.09 0.72 -0.02850 -0.02364 9 4 1 2 0 2890.250 15.03 16.09 15.78 20.56 20.96 26.4 1031.06 -270 -390 -162 56 -5 661 479 550 179 345 396 108 -340 -124 -346 -285 -105 66 306 -154 111 113 91 566 445 -23 109 224 -206 -197 -105 -85 -57 53 -147 -376 -137 49 9 -180 31 -304 37 192 262 158 93 100 -262 -215 -528 -183 -589 -330 -95 -219 -111 74 162 200 181 347 272 227 20 153 -37 -24 -219 -452 -362 -100 -219 -50 -21 -348 -258 -154 -134 -403 -234 -47 -367 -69 58 -145 -304 -119 -106 42 -9 346 423 0 120 311 215 -70 -391 -522 -281 -573 -438 -101 -334 -331 -35 -208 -169 111 25 98 193 143 443 403 440 540 148 156 412 -91 286 303 40 -29 257 -13 113 237 -99 -182 233 -286 -159 44 -34 -146 157 202 59 426 118 214 121 233 -98 -251 -296 -444 -260 -382 -164 55 -5 675 497 574 187 355 401 108 -337 -122 -337 -280 -104 67 317 -162 117 120 96 597 472 -24 115 233 -209 -195 -103 -84 -57 55 -155 -402 -145 51 9 -185 32 -316 39 203 278 168 99 105 -269 -215 -514 -174 -557 -315 -93 -220 -114 76 167 206 187 360 283 235 20 155 -37 -24 -213 -437 -348 -97 -213 -49 -21 -343 -249 -146 -126 -379 -221 -44 -353 -66 57 -142 -301 -117 -105 41 -9 349 431 0 121 306 207 -66 -360 -474 -255 -532 -419 -100 -338 -336 -35 -206 -167 110 25 100 199 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