File name: Pandora132s1_Berlin_20230209_L2Fit_fout2c13d20210422p1-8.txt File generation date: 20241123T191015.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c13p1-8 Local principal investigator: Thomas Ruhtz Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 132 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora132_OF_v1d20200910.txt Instrument calibration file used: Pandora132s1_CF_v13d20210422.txt Level 1 file used: Pandora132s1_Berlin_20230209_L1_smca1c13d20210422p1-8.txt Full location name: Institute of Space Sciences FU Berlin Short location name: Berlin Country of location: Germany Location latitude [deg]: 52.4600 Location longitude [deg]: 13.3100 Location altitude [m]: 100 Local noon date: 20230209 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 11, but different RefDay (April 2021). First and last pixel inside fitting window: 243 385 Nominal wavelengths inside fitting window [nm]: 305.1071 305.2480 305.3889 305.5298 305.6707 305.8116 305.9524 306.0932 306.2341 306.3749 306.5157 306.6565 306.7973 306.9380 307.0788 307.2195 307.3603 307.5010 307.6417 307.7824 307.9231 308.0638 308.2044 308.3451 308.4857 308.6264 308.7670 308.9076 309.0482 309.1888 309.3293 309.4699 309.6104 309.7510 309.8915 310.0320 310.1725 310.3130 310.4534 310.5939 310.7344 310.8748 311.0152 311.1556 311.2960 311.4364 311.5768 311.7172 311.8575 311.9979 312.1382 312.2785 312.4188 312.5591 312.6994 312.8397 312.9800 313.1202 313.2604 313.4007 313.5409 313.6811 313.8213 313.9615 314.1016 314.2418 314.3819 314.5221 314.6622 314.8023 314.9424 315.0825 315.2225 315.3626 315.5026 315.6427 315.7827 315.9227 316.0627 316.2027 316.3427 316.4827 316.6226 316.7626 316.9025 317.0424 317.1823 317.3222 317.4621 317.6020 317.7418 317.8817 318.0215 318.1613 318.3012 318.4410 318.5807 318.7205 318.8603 319.0000 319.1398 319.2795 319.4192 319.5589 319.6986 319.8383 319.9780 320.1177 320.2573 320.3969 320.5366 320.6762 320.8158 320.9554 321.0949 321.2345 321.3741 321.5136 321.6531 321.7927 321.9322 322.0717 322.2111 322.3506 322.4901 322.6295 322.7689 322.9084 323.0478 323.1872 323.3266 323.4659 323.6053 323.7447 323.8840 324.0233 324.1627 324.3020 324.4413 324.5805 324.7198 324.8591 324.9983 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230209T072312.0Z 8440.307777 215 1 50.10 2 84.37 123.19 83.96 266.06 0.00 1 0.00 1 0 33 5.272e-01 4.490e-02 5.501e-01 5.067e-02 9.324983e-01 2.786205e-02 1.096349e-02 -6.000000e+00 2.979700e-01 223.18 -2.00 3.85 -2.00 322.16 0.00e+00 -6.107837e-03 1.089174e-02 4.017526e-03 -6.000000e+00 1.261129e-02 266.00 -2.00 20.00 -2.00 321.70 0.00e+00 9.008 0.016 302.00 328.00 3 8.8953e-01 8.9465e-02 1.0638e-01 -6.0000e+00 7.3518e-01 1.5680e+00 1.0676e-01 6.4260e-02 -6.0000e+00 8.0343e-01 -1.8247e+00 7.8321e-02 2.8119e-02 -6.0000e+00 4.7715e-01 6.8349e-01 4.2825e-02 9.9243e-03 -6.0000e+00 2.0140e-01 1.2142e-05 -2.2490e-03 1.3496e-03 1.0770e-04 -6.0000e+00 1.4476e-02 -3.3757e-02 0.0000e+00 12 8 8 10 0 0 28.37 15.33 1.00 -0.03376 -0.05066 32 7 4 8 0 1565.220 15.01 15.33 3.63 20.04 20.35 25.3 1009.87 -44244 -14763 55999 80335 59607 116673 25610 -124473 -79104 -65293 -59123 -36835 -31211 900000 53081 8958 31542 -19922 13468 -42371 -14241 131590 102060 900000 183219 142244 -84601 -50512 84694 64307 239233 24332 56869 -11362 26608 249738 33785 -50190 28871 43550 9065 -6288 -11623 6136 29298 66065 30667 900000 51164 49710 -13763 21423 8082 11050 23574 100200 119170 15940 81054 16184 6009 51692 -10951 95316 47221 11591 8571 5446 11424 12526 14027 24932 46807 14113 -886 60261 -2569 -15662 -1600 -3406 -6298 14347 -981 -6471 -2151 18098 19413 13618 699 12772 -3369 -12847 16613 -3349 -694 -10397 -5749 -2942 -7503 -5848 -5950 -1542 -8546 -8660 3183 1751 -5652 -4268 -1270 -2544 1901 1995 4290 -5367 -506 1135 -2299 5249 35 -587 -430 1509 2630 9888 1549 3040 -632 -1385 736 989 61 -402 -348 1412 -304 -1578 -264 3550 1743 -1047 -107 -3211 -1339 -3095 -790 2765 3967 2944 5762 1265 -13411 -5682 -4104 -3451 -1819 -1681 900000 2621 483 1558 -1520 726 -3804 -895 6498 5040 900000 9048 7024 -10255 -3855 4182 3176 11814 1202 2808 -816 1314 12333 1668 -5408 1685 2542 814 -677 -1305 551 2170 3262 2120 900000 3032 3191 -1835 2222 1038 1473 2910 5938 5885 2125 5203 1838 742 4340 -1947 6590 5597 1946 1481 1022 2257 2783 3325 5417 7859 2997 -193 6249 -469 -3403 -348 -908 -2053 4393 -387 -2876 -967 6971 7669 5783 331 5109 -1481 -5900 5661 -1505 -353 -6931 -4315 -2484 -6635 -5146 -5377 -1181 -6331 -6372 2217 1314 -4857 -3941 -1292 -2775 2270 2597 5643 -7710 -670 1442 -3065 6810 50 -869 -618 2213 3650 12452 2065 3873 -824 -1962 1196 1875 120 -863 -802 3461 -815 -4499 -759 9866 4868 -2858 -292 -8356 -3300 SS 20230209T072917.2Z 8440.312005 218 1 49.48 2 83.60 124.45 84.88 267.22 0.00 1 0.00 1 0 17 5.601e-01 3.220e-02 4.832e-01 2.660e-02 8.924676e-01 1.475918e-02 1.018125e-02 -6.000000e+00 3.199287e-01 223.18 -2.00 3.85 -2.00 322.21 0.00e+00 1.105899e-02 7.002963e-03 3.666754e-03 -6.000000e+00 1.391729e-02 266.00 -2.00 20.00 -2.00 321.79 0.00e+00 8.128 0.012 302.00 328.00 3 8.8388e-01 5.0019e-02 9.9678e-02 -6.0000e+00 7.9490e-01 1.2419e+00 6.3747e-02 6.8970e-02 -6.0000e+00 8.7239e-01 -1.5294e+00 5.7768e-02 2.7710e-02 -6.0000e+00 5.1362e-01 5.9693e-01 2.8940e-02 1.3773e-02 -6.0000e+00 2.1594e-01 2.9465e-05 2.0874e-04 7.2934e-04 1.5146e-04 -6.0000e+00 1.5540e-02 -3.4223e-02 0.0000e+00 12 8 8 10 0 0 7.44 15.33 0.75 -0.03422 -0.03265 57 12 4 8 0 867.900 15.00 15.33 4.02 20.04 20.35 25.2 1010.96 -17932 900000 900000 -84671 -63059 -154022 -53338 -82944 900000 -134841 48548 101891 900000 223603 -54323 900000 -20509 163843 35155 133539 25455 -37986 91229 -62209 -67972 107807 241041 -53760 40535 51672 10697 -18459 -6739 900000 41412 89406 11137 23996 32763 63855 95020 -50594 76585 35750 109187 3448 71480 106642 143722 150986 7768 65130 12429 45297 54542 65981 44686 -1320 9995 1613 46034 -5533 26993 12377 56922 9190 6352 47648 4819 49901 3889 20886 15079 18379 20669 30 -2885 -12188 20162 -13864 3193 -6515 10898 2906 -4804 5974 -552 11742 -5723 5987 -4220 782 -3861 -824 -1477 -3708 3794 -4796 2967 -4051 259 -8005 -3891 1233 -4674 4530 -7897 -901 -2936 -89 -3973 284 -688 -1634 369 -3487 2173 -2033 -510 932 799 4903 1210 3923 207 2832 664 2832 -12 1796 -424 1668 636 -643 685 -1587 1427 184 806 -351 -97 -1315 -2126 -465 900000 900000 -3590 -1782 -9433 -1382 -2345 900000 -6035 1258 2640 900000 5794 -2559 900000 -870 4245 911 3460 660 -1700 2364 -3370 -3843 2793 6245 -2279 1050 1339 360 -1004 -367 900000 1288 2317 462 995 1443 2316 2708 -6423 2778 1945 2829 259 2778 3039 3724 3912 745 3881 1353 3756 4240 4616 3821 -171 1088 184 3459 -774 3147 1892 5900 1524 1086 5679 986 7370 978 4492 3282 3524 3427 5 -516 -2558 3605 -4239 976 -2515 3868 1182 -2228 2616 -269 5142 -2936 2606 -1902 318 -1641 -369 -781 -2402 2703 -3920 2453 -3598 224 -6637 -2813 850 -3645 3415 -7182 -836 -3165 -99 -5175 382 -954 -2248 479 -4616 2779 -2859 -744 1366 1135 6962 1712 5265 281 3624 864 3940 -20 3131 -846 3521 1453 -1603 1803 -4455 3952 520 2223 -927 -236 -3292 -5227 SS 20230209T074230.4Z 8440.321185 221 1 49.36 2 81.97 127.22 86.88 269.74 0.00 1 0.00 1 0 25 5.155e-01 1.753e-02 3.021e-01 8.550e-03 8.072747e-01 4.791094e-03 9.490478e-03 -6.000000e+00 2.938505e-01 223.18 -2.00 3.85 -2.00 322.00 0.00e+00 4.051583e-03 2.294380e-03 2.489168e-03 -6.000000e+00 1.227088e-02 266.00 -2.00 20.00 -2.00 321.60 0.00e+00 6.704 0.007 302.00 328.00 3 8.6768e-01 1.6049e-02 8.0696e-02 -6.0000e+00 7.2838e-01 4.8586e-01 2.3400e-02 4.8066e-02 -6.0000e+00 7.9838e-01 -6.8865e-01 2.6355e-02 2.9023e-02 -6.0000e+00 4.7070e-01 2.9305e-01 1.2562e-02 1.2255e-02 -6.0000e+00 1.9746e-01 1.4366e-04 -7.5705e-06 2.4770e-04 1.7659e-04 -6.0000e+00 1.4450e-02 -3.4265e-02 0.0000e+00 12 8 8 10 0 0 20.25 15.35 0.39 -0.03426 -0.03432 146 31 4 8 0 337.960 15.00 15.35 4.39 20.04 20.46 25.3 1013.46 900000 -93292 -134076 -141053 -218426 -54807 -202605 900000 -237634 -46131 -161929 -160936 -126198 -99097 900000 -109275 900000 -62691 1869 -54477 43766 -5762 -30290 10374 -93369 26093 -91973 1617 -28401 -22160 -13412 -22209 101928 -36339 40797 -18380 47464 -8951 19629 43046 28853 33327 -6624 48748 -18856 65206 18062 10144 11184 18537 25238 2951 40725 8519 33878 10561 25647 9504 -892 12006 -182 17464 3987 17684 4700 6881 5916 6265 12549 6925 14538 8420 8546 1222 6230 -2086 -2588 3622 -4634 6291 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