File name: Pandora132s1_Berlin_20240319_L2Fit_fout2c13d20210422p1-8.txt File generation date: 20241123T212725.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c13p1-8 Local principal investigator: Thomas Ruhtz Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 132 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora132_OF_v1d20200910.txt Instrument calibration file used: Pandora132s1_CF_v13d20210422.txt Level 1 file used: Pandora132s1_Berlin_20240319_L1_smca1c13d20210422p1-8.txt Full location name: Institute of Space Sciences FU Berlin Short location name: Berlin Country of location: Germany Location latitude [deg]: 52.4600 Location longitude [deg]: 13.3100 Location altitude [m]: 100 Local noon date: 20240319 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 11, but different RefDay (April 2021). First and last pixel inside fitting window: 243 385 Nominal wavelengths inside fitting window [nm]: 305.1071 305.2480 305.3889 305.5298 305.6707 305.8116 305.9524 306.0932 306.2341 306.3749 306.5157 306.6565 306.7973 306.9380 307.0788 307.2195 307.3603 307.5010 307.6417 307.7824 307.9231 308.0638 308.2044 308.3451 308.4857 308.6264 308.7670 308.9076 309.0482 309.1888 309.3293 309.4699 309.6104 309.7510 309.8915 310.0320 310.1725 310.3130 310.4534 310.5939 310.7344 310.8748 311.0152 311.1556 311.2960 311.4364 311.5768 311.7172 311.8575 311.9979 312.1382 312.2785 312.4188 312.5591 312.6994 312.8397 312.9800 313.1202 313.2604 313.4007 313.5409 313.6811 313.8213 313.9615 314.1016 314.2418 314.3819 314.5221 314.6622 314.8023 314.9424 315.0825 315.2225 315.3626 315.5026 315.6427 315.7827 315.9227 316.0627 316.2027 316.3427 316.4827 316.6226 316.7626 316.9025 317.0424 317.1823 317.3222 317.4621 317.6020 317.7418 317.8817 318.0215 318.1613 318.3012 318.4410 318.5807 318.7205 318.8603 319.0000 319.1398 319.2795 319.4192 319.5589 319.6986 319.8383 319.9780 320.1177 320.2573 320.3969 320.5366 320.6762 320.8158 320.9554 321.0949 321.2345 321.3741 321.5136 321.6531 321.7927 321.9322 322.0717 322.2111 322.3506 322.4901 322.6295 322.7689 322.9084 323.0478 323.1872 323.3266 323.4659 323.6053 323.7447 323.8840 324.0233 324.1627 324.3020 324.4413 324.5805 324.7198 324.8591 324.9983 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240319T055720.8Z 8844.248158 186 1 49.22 2 83.77 98.75 100.61 345.54 0.00 1 0.00 1 0 25 5.028e-01 3.779e-02 5.348e-01 3.892e-02 1.192222e+00 2.401991e-02 1.360013e-02 -6.000000e+00 2.990926e-01 225.44 -2.00 3.85 -2.00 322.57 0.00e+00 -3.803435e-03 1.146419e-02 4.168211e-03 -6.000000e+00 1.385059e-02 269.02 -2.00 20.00 -2.00 322.17 0.00e+00 8.303 0.013 302.00 328.00 3 8.0832e-01 8.4867e-02 1.0941e-01 -6.0000e+00 7.4411e-01 2.0048e+00 1.0804e-01 7.4497e-02 -6.0000e+00 8.1488e-01 -2.3456e+00 9.5522e-02 4.1670e-02 -6.0000e+00 4.7143e-01 8.6091e-01 4.9763e-02 1.3991e-02 -6.0000e+00 1.9918e-01 1.6480e-05 -1.1204e-03 1.0193e-03 1.8964e-04 -6.0000e+00 1.5424e-02 -5.4138e-02 0.0000e+00 12 9 8 11 4 0 -2.83 9.93 0.83 -0.05414 -0.06256 45 10 4 8 0 1093.580 14.72 9.93 7.21 20.56 20.87 28.4 932.83 900000 -8483 45250 900000 900000 900000 900000 900000 900000 28848 -122682 174434 900000 74814 900000 64368 111146 -25285 900000 104763 54089 -55221 900000 900000 -12575 -31376 -100955 900000 -121925 6387 58910 44693 21173 4764 3910 -60201 165877 900000 125526 30047 30637 900000 -696 75136 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884 1719 -319 2691 -2616 3795 6809 -1847 331 12 1571 -5824 1487 -1285 -3663 2505 -3885 -1325 799 -931 -4719 -280 -4788 3288 2639 -3088 1134 -5213 6526 -1336 4537 -2136 -1872 -1855 -843 -1287 -921 2431 -508 4136 1911 -2506 2200 3652 4741 -2795 2245 -2699 5242 -588 -2050 -3585 -3023 -591 -4277 122 -637 13834 967 4165 -1294 -9069 -2184 SS 20240319T060322.8Z 8844.252347 189 1 49.71 2 82.86 99.96 100.83 346.84 0.00 1 0.00 1 0 25 5.143e-01 2.549e-02 4.357e-01 2.015e-02 1.098661e+00 1.195172e-02 1.247191e-02 -6.000000e+00 2.964725e-01 225.44 -2.00 3.85 -2.00 322.49 0.00e+00 -3.094254e-03 6.014007e-03 2.738843e-03 -6.000000e+00 1.270233e-02 269.02 -2.00 20.00 -2.00 322.09 0.00e+00 7.418 0.009 302.00 328.00 3 8.9324e-01 4.3343e-02 9.8698e-02 -6.0000e+00 7.3611e-01 1.5474e+00 5.4757e-02 6.6694e-02 -6.0000e+00 8.0275e-01 -2.0142e+00 4.7076e-02 3.5148e-02 -6.0000e+00 4.7238e-01 7.8659e-01 2.3769e-02 1.1787e-02 -6.0000e+00 1.9855e-01 4.3684e-05 2.7135e-05 5.3286e-04 1.7241e-04 -6.0000e+00 1.4473e-02 -5.5423e-02 0.0000e+00 12 9 8 11 4 0 -11.21 10.19 0.56 -0.05542 -0.05522 80 17 4 8 0 621.120 15.11 10.19 7.62 20.56 20.87 28.2 933.89 22206 96013 -66351 900000 -111439 900000 -57434 900000 -119223 -107128 -13568 -68480 3503 -28856 52627 -28436 291822 -34645 -10319 81160 -28349 -17592 -76896 -24441 -20135 -47522 -12110 20247 -24387 900000 6333 -3557 77979 15921 53083 -39486 76785 171350 1716 203696 51726 98207 24431 55479 40276 70930 101696 31333 80029 41384 113710 48186 68454 79973 53346 56576 48411 38717 8898 27073 -13759 50874 11808 18190 39834 24004 40990 24128 26783 8687 29377 24372 31999 15602 23278 13124 -15380 -9001 -7343 14236 1229 8646 4497 -2138 5668 6778 9242 -2364 2257 -786 1112 2459 -5377 -3422 -7693 -9688 -6069 714 321 -2015 -3451 -3974 -1148 -297 -2019 -2902 -3814 -2393 99 -2432 -2462 -394 -2122 -1754 -569 -584 -439 -1574 107 337 2161 3255 3511 2319 2890 2052 433 2491 1432 395 961 414 -252 -760 -304 220 960 1488 741 -473 -1341 -1460 -2232 436 1886 -2843 900000 -5173 900000 -1333 900000 -5535 -4399 -266 -2079 69 -876 1034 -1168 5732 -1670 -387 1594 -1114 -565 -4394 -873 -719 -2206 -368 398 -697 900000 187 -140 1532 594 1251 -2171 1508 3365 88 4001 2032 2507 1296 2070 1661 2090 2197 1415 2358 1951 2903 2650 3361 3770 3458 3667 3423 2890 821 1914 -1432 2998 1183 1965 3755 2687 3945 2938 3577 1587 4731 4212 4902 2543 3063 1675 -2477 -1450 -1370 2628 311 2377 1440 -781 2015 2489 3431 -998 891 -304 395 826 -1975 -1357 -3777 -5345 -3868 499 250 -1640 -2662 -2704 -740 -185 -1352 -2080 -2669 -1811 84 -2514 -2967 -517 -2971 -2458 -770 -775 -590 -2242 157 500 3017 4196 4282 2791 3374 2348 498 3064 2121 705 1952 931 -619 -2039 -875 657 2894 4466 2199 -1337 -3485 -3443 -5062 SS 20240319T061606.5Z 8844.261186 192 1 50.33 2 80.96 102.53 101.23 349.61 0.00 1 0.00 1 0 25 6.801e-01 1.608e-02 2.857e-01 6.505e-03 9.423357e-01 3.715513e-03 1.082947e-02 -6.000000e+00 3.868799e-01 225.44 -2.00 3.85 -2.00 322.21 0.00e+00 6.684286e-03 1.934501e-03 2.694099e-03 -6.000000e+00 1.627419e-02 269.02 -2.00 20.00 -2.00 321.82 0.00e+00 6.038 0.005 302.00 328.00 3 8.7446e-01 1.3223e-02 8.4803e-02 -6.0000e+00 9.6022e-01 5.8992e-01 2.0191e-02 6.6633e-02 -6.0000e+00 1.0468e+00 -8.4149e-01 2.2862e-02 3.3369e-02 -6.0000e+00 6.1970e-01 3.5481e-01 1.0614e-02 1.3861e-02 -6.0000e+00 2.6062e-01 2.1288e-04 -4.6404e-04 1.8038e-04 1.7321e-04 -6.0000e+00 1.8540e-02 -5.5172e-02 0.0000e+00 12 9 8 11 4 0 17.07 10.19 0.28 -0.05517 -0.05866 197 42 4 8 0 251.610 15.02 10.19 8.06 20.56 20.87 28.2 935.75 -264921 -43857 -147914 -99041 -238323 -218241 -265299 -213814 -196131 -216432 -181584 -216077 -62321 -163424 -66888 -124687 -86407 1541 -95682 -11190 -71028 -54183 -73692 -47290 -58440 -59646 -77424 -116731 -3669 -79311 -34442 -47872 13343 -21412 -41242 -1191 -7144 46450 -32279 33995 2538 28055 21285 6813 7618 11456 26703 24616 35598 3037 34227 16003 24659 28831 11886 38818 27262 26958 8804 18323 5583 25272 17321 18276 18193 7021 23172 7079 13255 7825 12002 10793 9000 9344 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