File name: Pandora132s1_Berlin_20240425_L2Fit_fout2c13d20210422p1-8.txt File generation date: 20241123T215121.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c13p1-8 Local principal investigator: Thomas Ruhtz Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 132 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora132_OF_v1d20200910.txt Instrument calibration file used: Pandora132s1_CF_v13d20210422.txt Level 1 file used: Pandora132s1_Berlin_20240425_L1_smca1c13d20210422p1-8.txt Full location name: Institute of Space Sciences FU Berlin Short location name: Berlin Country of location: Germany Location latitude [deg]: 52.4600 Location longitude [deg]: 13.3100 Location altitude [m]: 100 Local noon date: 20240425 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 11, but different RefDay (April 2021). First and last pixel inside fitting window: 243 385 Nominal wavelengths inside fitting window [nm]: 305.1071 305.2480 305.3889 305.5298 305.6707 305.8116 305.9524 306.0932 306.2341 306.3749 306.5157 306.6565 306.7973 306.9380 307.0788 307.2195 307.3603 307.5010 307.6417 307.7824 307.9231 308.0638 308.2044 308.3451 308.4857 308.6264 308.7670 308.9076 309.0482 309.1888 309.3293 309.4699 309.6104 309.7510 309.8915 310.0320 310.1725 310.3130 310.4534 310.5939 310.7344 310.8748 311.0152 311.1556 311.2960 311.4364 311.5768 311.7172 311.8575 311.9979 312.1382 312.2785 312.4188 312.5591 312.6994 312.8397 312.9800 313.1202 313.2604 313.4007 313.5409 313.6811 313.8213 313.9615 314.1016 314.2418 314.3819 314.5221 314.6622 314.8023 314.9424 315.0825 315.2225 315.3626 315.5026 315.6427 315.7827 315.9227 316.0627 316.2027 316.3427 316.4827 316.6226 316.7626 316.9025 317.0424 317.1823 317.3222 317.4621 317.6020 317.7418 317.8817 318.0215 318.1613 318.3012 318.4410 318.5807 318.7205 318.8603 319.0000 319.1398 319.2795 319.4192 319.5589 319.6986 319.8383 319.9780 320.1177 320.2573 320.3969 320.5366 320.6762 320.8158 320.9554 321.0949 321.2345 321.3741 321.5136 321.6531 321.7927 321.9322 322.0717 322.2111 322.3506 322.4901 322.6295 322.7689 322.9084 323.0478 323.1872 323.3266 323.4659 323.6053 323.7447 323.8840 324.0233 324.1627 324.3020 324.4413 324.5805 324.7198 324.8591 324.9983 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240425T051848.7Z 8881.221397 200 1 7.85 2 77.32 84.51 101.47 250.16 0.00 1 0.00 1 0 17 6.213e-01 2.661e-02 4.184e-01 1.774e-02 8.332490e-01 9.695994e-03 1.068755e-02 -6.000000e+00 3.590420e-01 228.85 -2.00 3.85 -2.00 321.44 0.00e+00 1.291648e-02 4.464055e-03 4.810342e-03 -6.000000e+00 1.578364e-02 273.68 -2.00 20.00 -2.00 320.99 0.00e+00 4.432 0.002 302.00 328.00 3 3.4720e+00 3.1574e-02 6.6369e-02 -6.0000e+00 8.9791e-01 5.1944e-01 4.2362e-02 4.8970e-02 -6.0000e+00 9.7723e-01 -7.1494e-01 4.1855e-02 3.2913e-02 -6.0000e+00 5.7900e-01 3.0974e-01 2.0023e-02 1.8596e-02 -6.0000e+00 2.4386e-01 7.1978e-05 9.7156e-04 4.6048e-04 2.7143e-04 -6.0000e+00 1.7210e-02 -4.4001e-02 0.0000e+00 12 9 9 12 1 1 87.23 17.11 0.22 -0.04400 -0.03670 3 5 1 8 0 1959.180 15.74 17.11 11.39 21.69 21.98 28.8 952.01 -192362 900000 -183396 900000 -244351 -179590 -193285 -216031 -156429 -155311 -123305 43731 -17971 -73970 6440 -35752 54801 105363 900000 183457 -26138 900000 -103559 -40744 -79433 56051 88509 -65735 31467 25177 48452 61385 255486 3508 53067 56951 50656 21432 -10647 -16286 -10654 21977 485 19902 44851 53938 98537 493 668 10576 28091 16040 25021 21027 27495 50841 13581 18302 9963 25192 7342 30372 3156 13965 16053 14274 12321 7755 14435 5149 8872 5791 2365 4293 1844 11154 -1843 2631 -8360 -454 -1070 4090 -2992 -2166 193 -6640 1381 -2222 3135 2380 1063 -3726 -4494 -1864 -4792 306 -4707 -375 -2289 -656 -2333 -434 -2227 -2608 -484 -5680 968 -2150 852 -1322 1248 -1221 -394 639 -2645 484 -486 -322 1472 1040 1500 2707 2909 1349 711 -404 1941 689 959 1241 453 1695 -579 517 -184 292 -926 442 298 120 134 -2430 -1630 -5140 900000 -5477 900000 -10210 -3952 -4861 -7131 -2951 -2929 -2132 756 -311 -1395 111 -731 948 1822 900000 3172 -657 900000 -5372 -1153 -3371 969 1530 -2376 544 479 921 1274 4417 143 1376 1379 1401 842 -686 -1280 -871 1382 40 1376 2467 2798 3748 48 69 1081 2693 1941 3028 2842 3630 5434 2113 2647 1503 3207 1166 4296 680 3073 3684 3321 2924 2023 3948 1617 2915 2011 821 1348 580 2858 -513 740 -2806 -171 -479 1992 -1711 -1302 120 -4659 935 -1591 2100 1536 649 -2249 -2687 -1161 -3549 255 -4495 -395 -2679 -755 -2529 -407 -1934 -2275 -440 -5741 970 -2405 1038 -1883 1804 -1928 -624 974 -3982 738 -759 -489 2311 1670 2328 4233 4337 1976 1010 -558 2576 994 1592 2191 891 3529 -1222 1152 -440 723 -2354 1112 737 283 291 -5364 -3458 SS 20240425T052403.1Z 8881.225036 203 1 6.85 2 76.52 85.53 102.21 251.10 0.00 1 0.00 1 0 17 6.432e-01 1.333e-02 3.335e-01 8.558e-03 8.235590e-01 4.673793e-03 9.941346e-03 -6.000000e+00 3.697278e-01 228.86 -2.00 3.85 -2.00 321.27 0.00e+00 2.876570e-03 2.121816e-03 2.363248e-03 -6.000000e+00 1.633910e-02 273.68 -2.00 20.00 -2.00 320.82 0.00e+00 4.187 0.002 302.00 328.00 3 2.5457e+00 1.4930e-02 6.4335e-02 -6.0000e+00 9.2346e-01 2.1689e-01 2.1335e-02 4.9647e-02 -6.0000e+00 1.0047e+00 -2.5805e-01 2.3560e-02 2.7442e-02 -6.0000e+00 5.9464e-01 1.0071e-01 1.1218e-02 9.3033e-03 -6.0000e+00 2.4901e-01 2.4737e-04 -3.1266e-04 2.2130e-04 1.2454e-04 -6.0000e+00 1.7572e-02 -3.4175e-02 0.0000e+00 12 9 9 12 1 1 97.96 17.00 0.24 -0.03418 -0.03652 11 18 1 8 0 569.700 15.08 17.00 11.65 21.69 21.98 29.1 954.26 -225737 -277772 -90923 -232288 -182324 -211969 -243383 -196607 -232193 11387 -141378 900000 -174378 -65906 -113960 -83460 -45179 -95702 67119 -47853 900000 -45428 11256 -88531 -30157 -24746 -95292 -42315 -75797 48866 -6216 47030 -29365 -14111 -17112 8465 31308 -35594 13272 8150 39911 10867 17119 20767 2890 7807 -335 21824 1132 25212 7139 5290 475 10524 6385 9339 10542 2649 10415 5698 2725 6466 5433 4273 5335 7902 1349 2251 5187 7638 4539 523 1327 -1790 2210 -3726 -1635 -2188 -1215 246 -1272 -2522 -1132 -1021 -3142 1183 -530 -690 718 117 -391 -487 -2083 -1803 -1037 211 -245 -1008 21 240 -842 -730 -1050 272 -1997 -1942 -153 -907 -329 884 508 139 1002 -25 -437 -52 725 37 100 -55 -484 1005 550 1987 -149 608 -248 -284 883 739 -189 186 205 356 -596 -640 -383 551 -77 -49 -54 45 -573 -2055 -5056 -759 -2819 -1521 -1929 -3323 -1939 -3698 95 -1180 900000 -2910 -550 -1815 -1203 -565 -2032 560 -798 900000 -758 113 -2659 -554 -454 -3252 -918 -2340 489 -135 746 -1176 -518 -628 240 784 -1917 598 462 1865 668 1039 1369 210 557 -27 1639 102 1970 758 650 68 1493 1007 1502 1719 462 1619 908 463 1182 1162 1053 1388 2002 367 644 1629 2469 1657 205 504 -651 758 -1215 -497 -703 -448 99 -615 -1416 -689 -661 -2206 841 -402 -534 539 85 -265 -312 -1335 -1230 -807 177 -241 -1144 26 292 -957 -734 -965 247 -1979 -2030 -166 -1071 -432 1214 784 229 1653 -40 -678 -77 1087 59 166 -93 -799 1548 813 2799 -206 866 -350 -397 1405 1349 -358 377 441 766 -1382 -1548 -940 1345 -187 -113 -122 94 -1181 SS 20240425T083416.6Z 8881.357136 310 1 45.18 2 49.21 128.37 130.03 287.81 0.00 1 0.00 1 0 17 5.732e-02 1.065e-02 3.601e-02 5.909e-03 3.333138e-01 2.976638e-03 4.306403e-03 -6.000000e+00 3.293613e-02 228.87 -2.00 3.85 -2.00 318.50 0.00e+00 4.825963e-04 5.744109e-04 1.925831e-04 -6.000000e+00 1.397094e-03 273.70 -2.00 20.00 -2.00 317.91 0.00e+00 1.528 0.000 302.00 328.00 3 6.2090e+00 8.0474e-03 2.4514e-02 -6.0000e+00 8.2269e-02 7.0624e-02 9.1528e-03 1.8819e-02 -6.0000e+00 8.9483e-02 -4.5997e-03 6.1336e-03 9.3064e-03 -6.0000e+00 5.2971e-02 -5.7125e-03 3.1796e-03 2.6414e-03 -6.0000e+00 2.2128e-02 1.4323e-04 6.5962e-05 1.7434e-04 2.8293e-05 -6.0000e+00 1.5655e-03 -3.2868e-02 0.0000e+00 12 8 8 10 0 0 99.52 17.18 0.01 -0.03287 -0.03237 14 3 1 8 0 3226.130 14.99 17.18 17.58 21.88 22.29 29.9 981.14 23405 -15286 19745 -19188 14018 -27652 -1349 5852 18478 4312 -14533 13047 -14858 14342 1807 5091 -7183 2604 4455 555 5395 -6133 5313 -6011 5911 1516 -1512 -1382 -1763 4667 -6495 8521 -4156 5288 -5426 -1773 -2308 -5314 2034 -2618 2095 -6083 3921 -3862 1868 -442 -1543 607 -3676 -811 624 2421 -349 3042 302 2194 2141 54 1474 -2125 2037 1288 2324 1323 981 1072 -1589 -454 204 2431 -158 1602 125 919 893 -1187 -716 -3427 447 -3778 -281 -1112 -1495 -1061 -1683 374 -155 937 -349 1107 -400 548 -2281 -143 931 -1109 1269 105 1150 -569 506 -1413 -959 437 -770 -383 -730 342 -962 671 762 621 134 -515 -228 -1000 918 -1307 1056 -256 -66 385 290 755 507 525 -509 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