File name: Pandora132s1_Berlin_20240919_L2Fit_fout2c13d20210422p1-8.txt File generation date: 20241123T225725.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c13p1-8 Local principal investigator: Thomas Ruhtz Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 132 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora132_OF_v1d20200910.txt Instrument calibration file used: Pandora132s1_CF_v13d20210422.txt Level 1 file used: Pandora132s1_Berlin_20240919_L1_smca1c13d20210422p1-8.txt Full location name: Institute of Space Sciences FU Berlin Short location name: Berlin Country of location: Germany Location latitude [deg]: 52.4600 Location longitude [deg]: 13.3100 Location altitude [m]: 100 Local noon date: 20240919 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 11, but different RefDay (April 2021). First and last pixel inside fitting window: 243 385 Nominal wavelengths inside fitting window [nm]: 305.1071 305.2480 305.3889 305.5298 305.6707 305.8116 305.9524 306.0932 306.2341 306.3749 306.5157 306.6565 306.7973 306.9380 307.0788 307.2195 307.3603 307.5010 307.6417 307.7824 307.9231 308.0638 308.2044 308.3451 308.4857 308.6264 308.7670 308.9076 309.0482 309.1888 309.3293 309.4699 309.6104 309.7510 309.8915 310.0320 310.1725 310.3130 310.4534 310.5939 310.7344 310.8748 311.0152 311.1556 311.2960 311.4364 311.5768 311.7172 311.8575 311.9979 312.1382 312.2785 312.4188 312.5591 312.6994 312.8397 312.9800 313.1202 313.2604 313.4007 313.5409 313.6811 313.8213 313.9615 314.1016 314.2418 314.3819 314.5221 314.6622 314.8023 314.9424 315.0825 315.2225 315.3626 315.5026 315.6427 315.7827 315.9227 316.0627 316.2027 316.3427 316.4827 316.6226 316.7626 316.9025 317.0424 317.1823 317.3222 317.4621 317.6020 317.7418 317.8817 318.0215 318.1613 318.3012 318.4410 318.5807 318.7205 318.8603 319.0000 319.1398 319.2795 319.4192 319.5589 319.6986 319.8383 319.9780 320.1177 320.2573 320.3969 320.5366 320.6762 320.8158 320.9554 321.0949 321.2345 321.3741 321.5136 321.6531 321.7927 321.9322 322.0717 322.2111 322.3506 322.4901 322.6295 322.7689 322.9084 323.0478 323.1872 323.3266 323.4659 323.6053 323.7447 323.8840 324.0233 324.1627 324.3020 324.4413 324.5805 324.7198 324.8591 324.9983 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240919T074225.0Z 9028.321123 287 1 0.60 2 65.62 123.41 100.82 293.80 0.00 1 0.00 1 0 17 3.527e-02 1.213e-02 3.885e-02 1.047e-02 3.136295e-01 5.341244e-03 4.175850e-03 -6.000000e+00 2.031898e-02 227.99 -2.00 3.85 -2.00 317.59 0.00e+00 7.123584e-04 8.193084e-04 1.276354e-04 -6.000000e+00 8.830536e-04 278.99 -2.00 20.00 -2.00 316.92 0.00e+00 2.406 0.000 302.00 328.00 3 2.8000e+00 1.4171e-02 2.9756e-02 -6.0000e+00 5.0568e-02 -4.7456e-03 1.5919e-02 1.7908e-02 -6.0000e+00 5.4904e-02 -1.6801e-02 9.8734e-03 8.7961e-03 -6.0000e+00 3.2611e-02 7.5587e-03 4.9835e-03 2.5323e-03 -6.0000e+00 1.3889e-02 2.0884e-03 -7.4734e-04 3.0526e-04 2.9578e-05 -6.0000e+00 9.6969e-04 6.6831e-02 0.0000e+00 12 9 9 12 1 1 999.00 18.32 0.17 0.06683 0.06121 1 36 4 8 0 292.730 15.01 18.32 25.43 29.90 30.32 30.7 997.83 -1830 -4624 -11854 -1149 4041 8683 -1479 16461 2193 -2666 -14772 3299 -857 3975 1914 1895 11780 3465 9890 -7818 6151 -5257 6941 7022 3596 1075 -3728 3731 -2550 4526 -916 4052 -1860 -625 -1106 -11886 -1760 -1769 1023 -5253 -196 256 -1390 -1499 -607 -1009 -2515 3200 -1417 1520 -153 -455 -549 360 344 -976 1463 -903 3235 -2120 3113 1586 961 1787 -1545 313 -1618 1575 -403 884 596 914 -184 1393 414 54 1273 -1826 1147 563 -2550 -2087 -1066 -317 -427 1010 -567 -538 -295 1238 331 1701 -173 2692 -100 777 1520 -830 478 -455 -119 -224 39 -1251 -1111 -1518 -1591 -442 1561 913 -346 -1478 -933 1043 1464 -860 668 -265 539 -1126 -978 -201 885 486 59 285 2574 209 -944 468 170 380 373 -313 -507 265 462 -98 284 -1169 61 -37 900000 -168 -456 -1211 -95 323 685 -133 1528 230 -295 -1886 393 -125 643 355 376 2215 686 2071 -1855 1266 -1226 1510 1633 907 280 -972 850 -605 1056 -250 1156 -590 -188 -321 -4080 -636 -717 475 -2700 -102 137 -767 -831 -334 -553 -1377 1634 -764 837 -93 -277 -354 240 235 -692 1013 -628 2135 -1509 2249 1200 789 1489 -1261 232 -1184 1178 -347 787 561 863 -170 1187 341 40 942 -1358 930 493 -2431 -2139 -1140 -341 -492 1161 -687 -656 -349 1416 350 1710 -171 2710 -108 893 1928 -1108 634 -576 -144 -266 46 -1561 -1410 -2029 -2230 -619 2298 1381 -545 -2303 -1360 1436 1967 -1165 925 -379 813 -1702 -1464 -303 1271 699 81 390 3427 289 -1372 714 258 587 600 -516 -882 454 808 -173 493 -2058 102 -61 900000 SS 20240919T075251.7Z 9028.328377 293 1 3.67 2 64.32 125.91 102.17 295.95 0.00 1 0.00 1 0 17 4.587e-02 1.240e-02 4.372e-02 1.076e-02 3.033995e-01 5.467469e-03 4.026486e-03 -6.000000e+00 2.641994e-02 227.99 -2.00 3.85 -2.00 317.84 0.00e+00 1.392653e-03 9.032581e-04 9.410789e-05 -6.000000e+00 1.148248e-03 278.99 -2.00 20.00 -2.00 317.17 0.00e+00 2.293 0.000 302.00 328.00 3 4.6964e+00 1.4559e-02 2.8532e-02 -6.0000e+00 6.5751e-02 4.2324e-02 1.6423e-02 1.7375e-02 -6.0000e+00 7.1391e-02 -1.4723e-02 1.0356e-02 8.5455e-03 -6.0000e+00 4.2404e-02 2.2198e-03 5.2667e-03 2.6432e-03 -6.0000e+00 1.8058e-02 3.4482e-04 -6.5125e-04 3.1415e-04 2.8729e-05 -6.0000e+00 1.2609e-03 6.7236e-02 0.0000e+00 12 9 9 12 1 1 999.00 18.48 0.33 0.06724 0.06234 2 10 1 8 0 1091.910 15.00 18.48 25.39 29.90 30.32 30.9 998.00 7563 20472 -4548 7026 -10064 3012 -6828 -4357 2579 -16665 13063 -14875 6923 -842 3106 948 851 -230 -6507 9139 -5138 11927 2517 13954 -4860 9604 -5432 -7287 7689 -7913 12543 -3848 7939 -5556 4452 -6038 -1711 -2715 -5727 1920 -1657 -1090 501 2719 -1031 54 -4733 3467 18 -3688 4901 -2329 2366 -19 3565 291 -1852 2056 1619 186 -177 395 330 72 612 -515 -726 1019 2578 -1474 699 -756 2654 -420 503 -3024 -807 2009 -659 -1698 -1330 -1319 -773 -781 -812 409 391 -679 478 -536 716 -397 1497 -93 1342 2282 -222 1379 440 -1287 -394 -530 348 -511 -836 -1262 -116 -402 -496 116 728 327 1434 -1244 567 152 37 -454 -677 -180 -780 49 656 1913 -579 323 1446 939 311 -572 -924 -864 400 -139 60 146 131 -395 -291 -247 -453 1007 900000 606 1504 -412 509 -807 218 -612 -428 251 -1972 1172 -1973 865 -133 484 161 151 -43 -1355 1671 -1078 2322 517 2722 -1194 2050 -1287 -1657 1607 -1869 2908 -1057 2027 -1555 1083 -1727 -545 -1052 -2478 854 -809 -548 251 1339 -528 27 -2449 1629 9 -1965 2584 -1410 1442 -13 2282 197 -1277 1338 1046 125 -127 287 259 58 461 -389 -532 773 2016 -1326 648 -715 2346 -359 384 -2322 -572 1431 -502 -1483 -1287 -1282 -787 -845 -942 498 463 -815 588 -623 751 -412 1468 -97 1423 2678 -278 1828 592 -1662 -492 -621 409 -652 -1069 -1698 -161 -592 -736 182 1163 513 2086 -1820 763 203 51 -671 -1007 -275 -1186 72 976 2682 -792 416 1954 1271 458 -850 -1422 -1358 646 -238 102 256 235 -716 -519 -424 -789 1683 900000 SS 20240919T080546.5Z 9028.337344 301 1 51.87 2 62.76 129.07 103.80 298.64 0.00 1 0.00 1 0 17 1.129e-02 5.714e-03 2.420e-03 5.413e-04 2.877818e-01 2.759228e-04 3.820933e-03 -6.000000e+00 6.506337e-03 227.99 -2.00 3.85 -2.00 318.21 0.00e+00 5.741346e-04 4.905358e-05 1.020298e-04 -6.000000e+00 2.827436e-04 278.99 -2.00 20.00 -2.00 317.54 0.00e+00 2.173 0.000 302.00 328.00 3 1.6371e+00 7.4037e-04 2.7052e-02 -6.0000e+00 1.6192e-02 3.9904e-03 8.3731e-04 1.6447e-02 -6.0000e+00 1.7580e-02 -6.8365e-03 5.3539e-04 8.0983e-03 -6.0000e+00 1.0442e-02 -3.7131e-03 2.7327e-04 2.3320e-03 -6.0000e+00 4.4476e-03 8.6406e-03 -4.9447e-04 1.6131e-05 2.6597e-05 -6.0000e+00 3.1049e-04 6.6228e-02 0.0000e+00 10 0 0 10 0 0 99.92 18.62 0.22 0.06623 0.06251 726 154 2 8 0 68.140 15.04 18.62 25.50 30.01 30.43 31.1 999.17 -1131 -2481 -2830 -5030 -3813 -1129 -1865 491 -3439 -2078 -3593 -951 -1421 71 775 -1045 582 -65 1340 34 99 830 342 475 -164 -739 -2000 -571 -1022 1249 1046 1991 -298 -3031 -1633 -2336 -995 -322 -345 -1188 -682 -480 -635 -243 -60 -610 -286 -493 -216 828 786 890 1126 635 1014 1001 309 489 613 725 1302 1477 1418 565 -249 315 -288 850 1092 32 372 -92 238 10 -299 -64 -597 -107 -406 -880 -1331 -2032 -1483 -762 -780 -216 26 145 309 417 695 359 876 1081 384 378 484 -51 -472 -244 -432 -119 524 -563 -1312 -696 -747 -226 325 33 -77 -70 6 132 470 831 383 254 -342 -710 -239 -65 265 446 723 210 1553 880 300 237 -493 305 26 271 -204 -282 255 -187 -337 -149 -204 -293 900000 -86 -199 -218 -356 -249 -74 -139 40 -312 -187 -333 -95 -166 10 115 -168 96 -11 238 6 18 153 67 99 -36 -163 -427 -113 -197 247 228 469 -75 -750 -383 -585 -286 -111 -140 -490 -296 -215 -289 -110 -27 -302 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