File name: Pandora132s1_Berlin_20250525_L2Fit_fwvt1c13d20210422p1-8.txt File generation date: 20250525T230550.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Thomas Ruhtz Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 132 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora132_OF_v1d20200910.txt Instrument calibration file used: Pandora132s1_CF_v13d20210422.txt Level 1 file used: Pandora132s1_Berlin_20250525_L1_smca1c13d20210422p1-8.txt Full location name: Institute of Space Sciences FU Berlin Short location name: Berlin Country of location: Germany Location latitude [deg]: 52.4600 Location longitude [deg]: 13.3100 Location altitude [m]: 100 Local noon date: 20250525 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 11, but different RefDay (April 2021). First and last pixel inside fitting window: 1664 1813 Nominal wavelengths inside fitting window [nm]: 492.1018 492.2228 492.3437 492.4647 492.5856 492.7065 492.8273 492.9482 493.0690 493.1899 493.3107 493.4315 493.5523 493.6730 493.7938 493.9145 494.0352 494.1559 494.2766 494.3972 494.5179 494.6385 494.7591 494.8797 495.0003 495.1208 495.2414 495.3619 495.4824 495.6029 495.7234 495.8438 495.9643 496.0847 496.2051 496.3255 496.4459 496.5662 496.6866 496.8069 496.9272 497.0475 497.1677 497.2880 497.4082 497.5285 497.6487 497.7689 497.8890 498.0092 498.1293 498.2494 498.3695 498.4896 498.6097 498.7298 498.8498 498.9698 499.0898 499.2098 499.3298 499.4497 499.5697 499.6896 499.8095 499.9294 500.0492 500.1691 500.2889 500.4087 500.5285 500.6483 500.7681 500.8878 501.0076 501.1273 501.2470 501.3666 501.4863 501.6060 501.7256 501.8452 501.9648 502.0844 502.2039 502.3235 502.4430 502.5625 502.6820 502.8015 502.9210 503.0404 503.1598 503.2792 503.3986 503.5180 503.6374 503.7567 503.8760 503.9953 504.1146 504.2339 504.3531 504.4724 504.5916 504.7108 504.8300 504.9492 505.0683 505.1875 505.3066 505.4257 505.5448 505.6638 505.7829 505.9019 506.0209 506.1399 506.2589 506.3779 506.4968 506.6158 506.7347 506.8536 506.9725 507.0913 507.2102 507.3290 507.4478 507.5666 507.6854 507.8042 507.9229 508.0416 508.1603 508.2790 508.3977 508.5164 508.6350 508.7536 508.8722 508.9908 509.1094 509.2280 509.3465 509.4650 509.5835 509.7020 509.8205 509.9389 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-401: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250525T034648.5Z 9276.157505 98 1 49.72 2 84.46 62.34 71.60 87.35 0.00 1 0.00 1 0 22 2.460e-03 2.451e-03 4.034e-04 4.026e-04 1.051378e+04 2.737660e+01 7.179025e+02 -6.000000e+00 1.344063e+02 277.35 -2.00 20.00 -2.00 505.35 0.00e+00 1.614850e-03 1.103126e-05 1.035514e-04 -6.000000e+00 6.802650e-05 277.35 -2.00 20.00 -2.00 500.71 0.00e+00 1.067362e+00 7.968946e-03 7.697298e-02 -6.000000e+00 4.895835e-02 231.82 -2.00 3.85 -2.00 502.26 0.00e+00 9.089 0.017 489.00 513.00 1 5.2830e+00 6.1114e-04 1.4794e-02 -6.0000e+00 3.7488e-03 -7.1371e-03 1.5338e-04 2.0083e-03 -6.0000e+00 9.6816e-04 2.4593e-03 -3.2828e-04 3.8345e-05 9.1974e-05 -6.0000e+00 2.5298e-04 1.5888e-02 2.4729e-04 10 0 0 10 0 0 99.73 17.46 0.77 0.01589 0.01361 84 18 1 2 0 591.690 14.98 17.46 19.31 30.54 30.99 31.2 998.69 -61 -71 81 64 397 604 408 497 312 387 338 79 -65 -22 -66 -40 -3 -69 -93 -13 249 174 187 385 210 54 69 -108 -230 67 42 -245 8 -157 -317 -194 8 -160 -133 -124 -77 -64 -2 123 91 163 -46 44 -184 -450 -309 -323 -315 -191 -214 -264 -208 61 105 222 301 204 209 6 59 11 -99 -91 -360 -275 -80 -73 -244 -151 -301 -382 -248 -187 -280 -324 -220 -212 -181 -140 -326 -306 -211 -89 11 17 135 224 115 -23 212 60 -133 -336 -564 -524 -374 -441 -233 -383 -460 -200 -108 -111 67 111 -99 74 269 440 502 618 603 271 155 240 271 195 317 202 -44 343 258 189 382 171 -148 100 176 -187 13 185 -49 32 279 159 188 253 155 156 -10 -79 -256 -256 -243 -261 -57 -69 76 62 394 611 418 509 317 388 334 77 -63 -21 -63 -39 -3 -70 -97 -13 260 182 196 406 223 58 73 -111 -229 66 41 -245 8 -157 -321 -196 8 -167 -138 -128 -80 -64 -2 125 94 166 -47 44 -190 -453 -303 -313 -307 -190 -219 -262 -209 62 105 223 303 207 212 6 59 11 -101 -92 -360 -273 -79 -74 -248 -154 -308 -384 -245 -182 -272 -315 -214 -208 -180 -140 -331 -311 -214 -90 11 17 131 218 112 -22 210 58 -124 -306 -507 -470 -341 -417 -230 -370 -453 -196 -105 -107 64 108 -99 74 270 444 509 633 623 281 159 242 268 191 311 200 -44 341 257 188 378 169 -145 96 168 -179 13 183 -49 33 290 168 200 270 157 159 -10 -83 -265 -260 -246 -266 SQ 20250525T054851.7Z 9276.242265 157 1 50.84 2 66.71 85.41 53.54 112.11 0.00 1 0.00 1 0 15 3.281e-03 3.266e-03 1.804e-03 1.799e-03 4.119095e+03 1.128370e+02 2.978891e+02 -6.000000e+00 1.792270e+02 277.36 -2.00 20.00 -2.00 505.32 0.00e+00 5.304622e-04 4.880590e-05 3.678969e-05 -6.000000e+00 9.071297e-05 277.36 -2.00 20.00 -2.00 500.54 0.00e+00 2.143210e-01 3.577761e-02 3.141247e-02 -6.000000e+00 6.530988e-02 231.83 -2.00 3.85 -2.00 502.13 0.00e+00 2.510 0.000 489.00 513.00 1 8.8864e+00 2.7352e-03 4.5130e-03 -6.0000e+00 5.0005e-03 1.5650e-02 6.9831e-04 7.8936e-04 -6.0000e+00 1.2921e-03 1.8487e-04 2.0703e-04 1.7871e-04 3.7388e-05 -6.0000e+00 3.3741e-04 3.7186e-02 8.7759e-05 10 0 0 10 0 0 -11.37 17.69 0.78 0.03719 0.03862 13 3 1 2 0 3909.920 15.06 17.69 19.93 30.76 31.19 31.1 1002.13 33 267 -355 130 -224 475 95 785 -95 368 26 -266 30 -313 263 121 71 69 -66 13 186 52 215 452 -64 -101 -391 -36 -215 265 63 -44 553 -501 -404 -333 77 -314 244 -294 -112 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-196 -117 657 -45 -273 -58 271 -429 58 -28 -336 -88 174 -97 -100 410 226 49 552 -437 69 384 32 -378 136 -193 -248 SQ 20250525T055756.8Z 9276.248574 161 1 50.19 2 65.33 87.17 52.27 114.22 0.00 1 0.00 1 0 15 2.625e-03 2.639e-03 1.569e-03 1.565e-03 3.895286e+03 9.748302e+01 2.670039e+02 -6.000000e+00 1.433975e+02 277.36 -2.00 20.00 -2.00 505.32 0.00e+00 5.467081e-04 4.245401e-05 3.692339e-05 -6.000000e+00 7.258338e-05 277.36 -2.00 20.00 -2.00 500.56 0.00e+00 2.873028e-01 3.107557e-02 3.316104e-02 -6.000000e+00 5.227632e-02 231.83 -2.00 3.85 -2.00 502.14 0.00e+00 2.379 0.000 489.00 513.00 1 8.6783e+00 2.3759e-03 4.4331e-03 -6.0000e+00 4.0024e-03 1.2219e-02 6.0719e-04 7.8930e-04 -6.0000e+00 1.0347e-03 2.3065e-04 1.9629e-04 1.5661e-04 3.3750e-05 -6.0000e+00 2.6999e-04 4.4271e-02 1.7135e-05 10 0 0 10 0 0 14.71 17.62 0.75 0.04427 0.04563 14 3 1 2 0 3584.180 15.03 17.62 20.14 30.76 31.19 31.1 1002.98 -359 -103 -83 33 313 461 -348 276 -130 348 447 -47 138 224 262 -62 42 -44 -123 -80 489 44 212 490 -54 -305 -206 -115 -172 62 -122 -297 345 -173 -387 -146 18 -106 402 -143 -9 -131 145 -141 291 378 -17 46 -222 -147 -174 -212 -218 -279 -19 48 -437 -219 138 13 515 291 306 197 171 7 84 -139 -403 -136 -206 -24 -122 -12 -434 -91 -197 -36 -271 -366 94 11 -88 -278 -419 -280 -388 172 -155 296 -182 64 88 -186 654 -283 -254 -355 -317 -118 -25 -450 44 -210 -144 -242 108 101 -104 28 -272 -197 99 583 806 418 221 118 245 275 288 32 478 -23 8 440 -212 -213 412 -269 13 88 -25 -314 151 -57 -22 -396 100 530 71 357 136 192 -73 -242 -458 148 -239 -228 -362 -97 -82 33 320 480 -369 291 -136 358 453 -47 136 220 257 -62 42 -46 -131 -85 518 46 226 522 -58 -326 -217 -119 -172 60 -119 -296 353 -183 -415 -156 19 -110 412 -147 -9 -137 152 -150 309 399 -18 47 -223 -143 -166 -200 -206 -269 -18 49 -451 -226 142 13 529 301 316 202 173 7 82 -135 -388 -130 -196 -23 -119 -12 -426 -87 -187 -34 -253 -342 88 10 -84 -269 -410 -274 -381 168 -152 291 -182 64 89 -187 639 -273 -239 -325 -285 -105 -23 -421 43 -209 -144 -241 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