File name: Pandora83s1_BondvilleIL_20241003_L2Fit_fwvt1c2d20230316p1-8.txt File generation date: 20250327T114626.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 83 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora83_OF_v3d20231115.txt Instrument calibration file used: Pandora83s1_CF_v2d20240316.txt Level 1 file used: Pandora83s1_BondvilleIL_20241003_L1_smca1c2d20230316p1-8.txt Full location name: Bondville, Illinois EPA Castnet Site Short location name: BondvilleIL Country of location: USA Location latitude [deg]: 40.0520 Location longitude [deg]: -88.3725 Location altitude [m]: 213 Local noon date: 20241003 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 1623 1773 Nominal wavelengths inside fitting window [nm]: 492.0660 492.1867 492.3074 492.4280 492.5486 492.6692 492.7898 492.9104 493.0310 493.1515 493.2720 493.3925 493.5130 493.6335 493.7540 493.8744 493.9948 494.1152 494.2356 494.3560 494.4764 494.5967 494.7170 494.8374 494.9576 495.0779 495.1982 495.3184 495.4386 495.5589 495.6790 495.7992 495.9194 496.0395 496.1596 496.2797 496.3998 496.5199 496.6400 496.7600 496.8800 497.0000 497.1200 497.2400 497.3600 497.4799 497.5998 497.7197 497.8396 497.9595 498.0793 498.1992 498.3190 498.4388 498.5586 498.6784 498.7981 498.9178 499.0376 499.1573 499.2770 499.3966 499.5163 499.6359 499.7555 499.8751 499.9947 500.1143 500.2338 500.3534 500.4729 500.5924 500.7119 500.8313 500.9508 501.0702 501.1896 501.3090 501.4284 501.5478 501.6671 501.7864 501.9058 502.0251 502.1443 502.2636 502.3828 502.5021 502.6213 502.7405 502.8597 502.9788 503.0980 503.2171 503.3362 503.4553 503.5744 503.6934 503.8125 503.9315 504.0505 504.1695 504.2885 504.4074 504.5263 504.6453 504.7642 504.8831 505.0019 505.1208 505.2396 505.3584 505.4772 505.5960 505.7148 505.8335 505.9523 506.0710 506.1897 506.3084 506.4270 506.5457 506.6643 506.7829 506.9015 507.0201 507.1387 507.2572 507.3758 507.4943 507.6128 507.7312 507.8497 507.9681 508.0866 508.2050 508.3234 508.4417 508.5601 508.6784 508.7968 508.9151 509.0334 509.1516 509.2699 509.3881 509.5063 509.6245 509.7427 509.8609 509.9790 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20241003T120615.4Z 9042.504345 59 1 35.56 2 88.20 97.11 96.83 95.83 0.00 1 0.00 1 0 22 3.587e-03 3.558e-03 1.116e-03 1.114e-03 1.213305e+04 7.820359e+01 7.556060e+02 -6.000000e+00 2.031935e+02 285.14 -2.00 20.00 -2.00 505.38 0.00e+00 2.096959e-03 3.128451e-05 1.399334e-04 -6.000000e+00 1.016621e-04 285.14 -2.00 20.00 -2.00 500.87 0.00e+00 1.345649e+00 2.179117e-02 9.059013e-02 -6.000000e+00 7.156323e-02 227.15 -2.00 3.49 -2.00 502.39 0.00e+00 16.548 0.082 489.00 513.00 1 5.1897e+00 1.6699e-03 2.7120e-02 -6.0000e+00 5.4898e-03 -2.3261e-02 4.2204e-04 2.4974e-03 -6.0000e+00 1.4282e-03 9.4120e-04 -2.1718e-03 1.0757e-04 9.2868e-05 -6.0000e+00 3.7734e-04 -6.6587e-03 2.6584e-04 10 0 0 10 0 0 17.51 24.67 1.75 -0.00666 -0.02172 10 1 1 4 0 3555.860 33.50 20.02 24.67 11.98 2.4 1041.24 -191 209 370 -107 199 582 1049 840 736 899 -3 501 -113 672 -183 131 -278 -156 -255 -533 207 -194 63 -258 420 438 -235 -284 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387 210 -10 504 608 494 -74 -111 86 428 724 457 250 -236 50 402 151 370 -236 123 159 323 -50 34 -85 315 -261 -224 -261 -41 170 -404 -246 -138 488 300 671 32 129 183 140 86 -55 37 163 -171 900000 SO 20241003T120757.0Z 9042.505521 62 1 36.70 2 87.87 97.38 96.52 96.10 0.00 1 0.00 1 0 15 3.392e-03 3.384e-03 9.292e-04 9.273e-04 1.153281e+04 6.474481e+01 7.428113e+02 -6.000000e+00 1.920772e+02 285.14 -2.00 20.00 -2.00 505.40 0.00e+00 2.022307e-03 2.594568e-05 1.296917e-04 -6.000000e+00 9.593769e-05 285.14 -2.00 20.00 -2.00 500.87 0.00e+00 1.282790e+00 1.802523e-02 8.340916e-02 -6.000000e+00 6.697769e-02 227.15 -2.00 3.49 -2.00 502.41 0.00e+00 15.695 0.070 489.00 513.00 1 5.0185e+00 1.3827e-03 2.5219e-02 -6.0000e+00 5.1490e-03 -1.8669e-02 3.4503e-04 2.3480e-03 -6.0000e+00 1.3199e-03 1.2668e-03 9.1637e-04 8.9799e-05 8.7651e-05 -6.0000e+00 3.5519e-04 3.4740e-03 5.7531e-05 10 0 0 10 0 0 51.83 24.68 1.44 0.00347 0.00983 13 1 1 4 0 2822.690 33.50 20.02 24.68 12.11 2.4 1041.86 -373 45 210 95 235 688 936 979 781 857 104 543 -77 400 -59 -91 -173 -220 -282 -300 127 -186 -56 -193 199 338 14 -357 -446 -309 -259 321 -1 -559 -385 -471 -257 186 -414 -151 -110 -71 147 118 126 14 247 147 -23 -260 -151 -201 -242 -385 -40 -357 -345 149 -196 503 380 580 325 209 179 212 319 -127 -21 137 -245 128 -72 -304 -308 -289 -660 -498 -306 -44 -227 -538 -624 -487 -501 -648 -793 -283 -510 -155 0 -38 -550 131 -356 -19 159 -284 -160 -215 -198 24 -45 15 117 -24 157 556 713 389 43 38 255 316 699 257 366 -152 117 257 -98 442 -98 163 284 99 -76 -57 -116 157 -119 -357 -89 67 150 -174 -241 -399 247 371 446 72 119 509 136 296 19 127 241 -191 -492 -340 41 195 91 223 668 923 973 776 843 102 522 -73 376 -56 -86 -168 -219 -278 -300 127 -187 -56 -196 203 345 14 -360 -440 -297 -253 314 -1 -567 -388 -479 -260 185 -411 -154 -109 -71 149 121 131 14 255 151 -23 -256 -149 -195 -233 -375 -40 -357 -353 154 -203 518 392 584 330 213 181 218 322 -127 -21 134 -239 124 -71 -305 -311 -290 -654 -486 -295 -42 -218 -522 -611 -482 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111 66 -78 SQ 20241003T205217.3Z 9042.869644 441 3 5.94 2 62.22 236.20 61.73 222.84 0.00 1 0.00 1 0 15 2.422e-03 2.427e-03 6.639e-05 6.630e-05 1.926175e+03 3.973296e+00 1.063573e+02 -6.000000e+00 1.371398e+02 285.10 -2.00 20.00 -2.00 505.28 0.00e+00 6.036003e-04 1.839566e-06 4.250617e-05 -6.000000e+00 6.849584e-05 285.10 -2.00 20.00 -2.00 500.53 0.00e+00 8.950403e-02 1.300132e-03 2.145058e-02 -6.000000e+00 4.779969e-02 227.11 -2.00 3.49 -2.00 502.11 0.00e+00 2.135 0.000 489.00 513.00 1 4.6106e-02 9.9944e-05 3.5843e-03 -6.0000e+00 3.6750e-03 -3.0173e-03 2.5501e-05 4.4852e-04 -6.0000e+00 9.4138e-04 1.3672e+00 4.3687e-04 6.7590e-06 1.8033e-05 -6.0000e+00 2.5354e-04 -2.3292e-02 2.6175e-04 10 0 0 10 0 0 9.47 26.06 0.84 -0.02329 -0.02026 1969 221 1 4 0 3.010 34.50 20.00 26.06 34.72 1.7 1100.00 -184 -152 -171 126 337 444 556 435 568 562 345 297 220 161 77 67 -1 -195 -205 -206 -234 -28 19 -36 65 -4 -270 -381 -116 -197 -143 82 -125 -319 -357 -346 -286 -150 -95 -89 -22 40 85 104 102 137 171 40 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134 178 30 -35 -70 -37 136 221 278 296 236 52 -92 -83 53 126 57 -89 SQ 20241003T205223.3Z 9042.869714 441 4 5.93 2 62.24 236.22 61.74 222.86 0.00 1 0.00 1 0 15 2.411e-03 2.416e-03 6.638e-05 6.630e-05 1.935035e+03 3.973612e+00 1.073767e+02 -6.000000e+00 1.365354e+02 285.10 -2.00 20.00 -2.00 505.28 0.00e+00 6.011192e-04 1.838786e-06 4.232249e-05 -6.000000e+00 6.819407e-05 285.10 -2.00 20.00 -2.00 500.53 0.00e+00 8.902685e-02 1.300654e-03 2.144585e-02 -6.000000e+00 4.758974e-02 227.11 -2.00 3.49 -2.00 502.11 0.00e+00 2.136 0.000 489.00 513.00 1 4.6383e-02 9.9978e-05 3.5846e-03 -6.0000e+00 3.6588e-03 -3.0431e-03 2.5509e-05 4.4945e-04 -6.0000e+00 9.3726e-04 1.3667e+00 4.5542e-04 6.7622e-06 1.8009e-05 -6.0000e+00 2.5242e-04 -2.3039e-02 2.5922e-04 10 0 0 10 0 0 0.94 26.06 0.84 -0.02304 -0.01988 1969 221 1 4 0 3.010 34.50 20.00 26.06 34.72 1.7 1100.00 -185 -153 -194 131 341 454 575 432 575 558 342 303 214 153 86 68 12 -194 -195 -224 -231 -38 33 -33 88 -5 -273 -370 -127 -185 -154 69 -112 -302 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