File name: Pandora83s1_BondvilleIL_20241120_L2Fit_fout2c8d20241002p1-8.txt File generation date: 20250725T070445.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 83 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora83_OF_v3d20231115.txt Instrument calibration file used: Pandora83s1_CF_v8d20241002.txt Level 1 file used: Pandora83s1_BondvilleIL_20241120_L1_smca1c8d20241002p1-8.txt Full location name: Bondville, Illinois EPA Castnet Site Short location name: BondvilleIL Country of location: USA Location latitude [deg]: 40.0520 Location longitude [deg]: -88.3725 Location altitude [m]: 213 Local noon date: 20241120 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 199 341 Nominal wavelengths inside fitting window [nm]: 305.0376 305.1782 305.3189 305.4595 305.6001 305.7407 305.8813 306.0219 306.1625 306.3031 306.4436 306.5841 306.7247 306.8652 307.0057 307.1462 307.2867 307.4271 307.5676 307.7081 307.8485 307.9889 308.1293 308.2697 308.4101 308.5505 308.6909 308.8312 308.9716 309.1119 309.2522 309.3925 309.5328 309.6731 309.8134 309.9537 310.0939 310.2342 310.3744 310.5146 310.6548 310.7950 310.9352 311.0754 311.2155 311.3557 311.4958 311.6359 311.7761 311.9162 312.0563 312.1963 312.3364 312.4765 312.6165 312.7565 312.8966 313.0366 313.1766 313.3166 313.4565 313.5965 313.7365 313.8764 314.0163 314.1563 314.2962 314.4361 314.5760 314.7158 314.8557 314.9955 315.1354 315.2752 315.4150 315.5548 315.6946 315.8344 315.9742 316.1139 316.2537 316.3934 316.5331 316.6728 316.8125 316.9522 317.0919 317.2316 317.3712 317.5109 317.6505 317.7901 317.9297 318.0693 318.2089 318.3485 318.4880 318.6276 318.7671 318.9066 319.0462 319.1857 319.3251 319.4646 319.6041 319.7435 319.8830 320.0224 320.1618 320.3013 320.4407 320.5800 320.7194 320.8588 320.9981 321.1375 321.2768 321.4161 321.5554 321.6947 321.8340 321.9733 322.1125 322.2518 322.3910 322.5302 322.6694 322.8086 322.9478 323.0870 323.2262 323.3653 323.5045 323.6436 323.7827 323.9218 324.0609 324.2000 324.3391 324.4781 324.6172 324.7562 324.8952 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241120T140153.4Z 9090.584646 301 1 53.97 2 78.42 128.74 51.77 271.18 0.00 1 0.00 1 0 25 1.750e-01 6.055e-03 2.755e-02 9.113e-04 6.018001e-01 4.658771e-04 6.992970e-03 -6.000000e+00 9.895220e-02 223.23 -2.00 3.49 -2.00 319.96 0.00e+00 3.380846e-03 1.555130e-04 9.185026e-04 -6.000000e+00 4.442802e-03 279.31 -2.00 20.00 -2.00 319.39 0.00e+00 4.820 0.002 302.00 328.00 3 5.3175e-01 1.3486e-03 5.5862e-02 -6.0000e+00 2.4352e-01 5.8975e-02 1.6609e-03 3.0835e-02 -6.0000e+00 2.6500e-01 -4.9161e-02 1.5445e-03 1.6604e-02 -6.0000e+00 1.5796e-01 7.2828e-03 8.0110e-04 6.2418e-03 -6.0000e+00 6.7978e-02 1.4966e-03 -4.6548e-04 2.4398e-05 6.6024e-05 -6.0000e+00 4.7983e-03 1.2075e-02 0.0000e+00 10 0 0 10 0 0 51.82 24.70 0.25 0.01207 0.00858 322 36 1 5 0 167.580 33.75 20.01 24.70 9.43 2.4 1056.88 -99100 -10965 -45403 -59781 900000 -58155 -71535 -27172 -74348 -12936 -46641 -54323 -24580 -40760 -899 -19960 -22093 -21146 -12032 -14192 -16812 -9590 -14399 -16458 -18730 -6757 -9332 -11930 -9636 1115 -4025 970 1030 -3207 -3874 -4607 -3787 -2905 486 837 727 -1058 -1825 -1888 446 1412 2530 983 2746 1812 2118 897 2359 2618 1704 1385 -595 -24 -1019 -1078 2107 1631 2612 1869 1561 473 392 1652 1316 586 795 239 63 374 86 -382 -783 -1803 -2005 -1055 -929 -1139 -1252 -1388 -1033 -229 19 260 443 573 604 125 266 1009 -68 -16 231 -111 -151 -693 -646 -476 -340 -424 -1079 -1408 -1222 -116 356 786 650 468 378 367 365 521 475 429 -11 -224 -435 122 32 7 -95 47 466 659 243 20 -206 -88 -161 13 -206 -164 -71 109 116 -119 -233 -47 95 -1233 -67 -428 -643 900000 -553 -833 -232 -1156 -118 -630 -888 -373 -942 -18 -573 -738 -776 -439 -562 -708 -378 -617 -781 -990 -337 -488 -629 -490 54 -240 66 82 -289 -343 -403 -355 -320 63 119 118 -189 -348 -372 87 281 509 207 592 419 538 258 737 813 568 483 -219 -9 -368 -383 742 630 1134 921 760 230 185 781 679 350 491 157 41 233 53 -214 -405 -932 -1134 -694 -666 -874 -1061 -1254 -928 -218 19 254 433 578 571 110 237 896 -63 -16 265 -138 -196 -925 -817 -573 -393 -483 -1247 -1743 -1506 -150 497 1156 1009 741 605 596 560 794 716 640 -17 -359 -702 200 50 11 -146 69 658 939 366 33 -353 -162 -295 25 -410 -331 -149 230 246 -248 -478 -94 182 SS 20241120T140717.8Z 9090.588401 304 1 53.87 2 77.62 129.75 52.78 271.98 0.00 1 0.00 1 0 25 1.445e-01 6.114e-03 2.381e-02 9.146e-04 5.720396e-01 4.658627e-04 6.653620e-03 -6.000000e+00 8.170974e-02 223.23 -2.00 3.49 -2.00 319.78 0.00e+00 3.238953e-03 1.454532e-04 7.246912e-04 -6.000000e+00 3.668566e-03 279.31 -2.00 20.00 -2.00 319.19 0.00e+00 4.532 0.002 302.00 328.00 3 8.3540e-01 1.3292e-03 5.2644e-02 -6.0000e+00 2.0109e-01 5.9381e-02 1.6087e-03 2.9182e-02 -6.0000e+00 2.1882e-01 -4.8645e-02 1.4390e-03 1.5521e-02 -6.0000e+00 1.3043e-01 7.8872e-03 7.5542e-04 5.7942e-03 -6.0000e+00 5.6134e-02 1.4836e-03 -5.0747e-04 2.4700e-05 5.9390e-05 -6.0000e+00 3.9622e-03 1.1919e-02 0.0000e+00 10 0 0 10 0 0 99.76 24.71 0.27 0.01192 0.00811 309 35 1 5 0 174.310 33.75 19.97 24.71 9.84 2.4 1061.38 -68086 -5717 -19580 -54871 900000 -63043 -55885 16975 -74890 -3274 -38926 -49127 -6010 -33857 -8835 -10499 -22086 -17083 -6007 -9902 -12229 -4745 -9844 -10286 -15194 -1374 -1869 -7323 -7683 395 -3798 -168 -369 -4577 -2054 -5277 -3584 -2219 471 994 99 -1088 -1478 -2133 -542 33 3429 957 1426 1339 2329 1063 2732 2819 2129 1722 -216 -546 -645 -637 2116 1160 2899 1501 1821 -47 265 1564 725 640 517 116 -225 616 -151 -141 -484 -1390 -1277 -963 -982 -1295 -1141 -1577 -945 -343 15 174 313 448 609 300 283 594 64 -3 404 -107 -239 -689 -654 -479 -322 -461 -1104 -1446 -1111 -211 217 731 713 582 518 367 325 488 480 412 -110 -220 -511 44 -62 224 -91 64 627 654 310 -39 -76 -63 -124 81 -171 -181 -132 223 -13 -120 -245 -64 22 -862 -46 -196 -768 900000 -855 -753 126 -1576 -36 -649 -1008 -99 -945 -241 -349 -934 -757 -259 -470 -614 -222 -500 -568 -957 -80 -112 -451 -467 23 -270 -14 -35 -491 -209 -543 -391 -282 72 164 19 -224 -322 -483 -123 8 778 229 351 348 658 339 863 964 777 658 -87 -220 -255 -247 818 492 1367 744 955 -24 134 787 399 405 339 80 -157 406 -92 -84 -264 -754 -751 -613 -731 -1031 -998 -1382 -876 -337 15 176 317 468 595 272 259 542 60 -3 468 -134 -312 -923 -830 -580 -375 -530 -1288 -1808 -1379 -275 304 1075 1102 914 820 589 491 732 711 634 -172 -363 -813 71 -97 336 -138 94 917 916 479 -64 -133 -112 -230 151 -340 -366 -276 454 -27 -250 -486 -125 41 SS 20241120T141243.2Z 9090.592166 307 1 53.93 2 76.83 130.77 53.80 272.78 0.00 1 0.00 1 0 25 1.066e-01 5.616e-03 1.352e-02 6.585e-04 5.475580e-01 3.326188e-04 6.415471e-03 -6.000000e+00 6.017828e-02 223.23 -2.00 3.49 -2.00 319.43 0.00e+00 2.423515e-03 9.231128e-05 5.852615e-04 -6.000000e+00 2.658247e-03 279.31 -2.00 20.00 -2.00 318.82 0.00e+00 4.278 0.001 302.00 328.00 3 4.9472e-01 9.2960e-04 4.9904e-02 -6.0000e+00 1.4819e-01 4.2729e-02 1.1014e-03 2.7847e-02 -6.0000e+00 1.6124e-01 -3.5996e-02 9.2445e-04 1.4406e-02 -6.0000e+00 9.6168e-02 4.4143e-03 4.9069e-04 4.9492e-03 -6.0000e+00 4.1359e-02 2.7222e-03 -4.0970e-04 1.7884e-05 5.2483e-05 -6.0000e+00 2.8884e-03 1.1843e-02 0.0000e+00 10 0 0 10 0 0 45.20 24.71 0.26 0.01184 0.00876 430 48 1 5 0 125.400 33.75 19.99 24.71 10.28 2.4 1066.19 -48103 -19349 -39371 -40493 28146 -32188 -45692 -21544 -39971 -16399 -29548 -33903 -15369 -21103 -1817 -8760 -7784 -9183 -5339 -5286 -6255 -5305 -2113 -6254 -7025 -3899 -4046 -4191 -4019 358 -2099 1734 1964 -1978 -1900 -3651 -2011 -751 -1 -158 -724 -1472 -1607 -1564 -379 -307 1494 141 1189 1030 1246 1169 1830 2224 1528 1589 210 153 -322 -28 1843 1214 2205 1707 1099 278 294 1062 1122 353 309 344 102 341 -70 -591 -594 -1218 -1159 -812 -955 -1107 -1424 -1381 -1069 -502 -259 50 288 481 722 297 261 685 315 -85 173 45 -123 -778 -683 -527 -449 -278 -988 -1241 -1005 -176 523 692 770 496 381 403 403 620 436 280 -57 -229 -436 17 -82 156 -8 -5 542 673 221 3 -141 -47 -178 98 -156 -135 -23 134 -43 -74 -193 -117 -23 -729 -258 -693 -707 228 -461 -801 -339 -860 -302 -649 -858 -396 -729 -64 -396 -392 -514 -311 -326 -403 -339 -135 -452 -557 -318 -337 -340 -318 28 -195 184 239 -245 -252 -482 -282 -112 0 -34 -179 -363 -418 -418 -101 -84 407 40 342 312 412 431 677 886 650 703 97 71 -147 -12 826 595 1120 974 668 167 169 611 698 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