File name: Pandora83s1_BondvilleIL_20250216_L2Fit_fnvs5c2d20230316p1-8.txt File generation date: 20250217T071031.5Z Data description: Level 2 spectral fitting results file Data file version: fnvs5c2p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 83 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora83_OF_v3d20231115.txt Instrument calibration file used: Pandora83s1_CF_v2d20240316.txt Level 1 file used: Pandora83s1_BondvilleIL_20250216_L1_smca1c2d20230316p1-8.txt Full location name: Bondville, Illinois EPA Castnet Site Short location name: BondvilleIL Country of location: United States Location latitude [deg]: 40.0520 Location longitude [deg]: -88.3725 Location altitude [m]: 213 Local noon date: 20250216 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 895 1442 Nominal wavelengths inside fitting window [nm]: 400.0198 400.1516 400.2835 400.4153 400.5471 400.6789 400.8107 400.9425 401.0743 401.2061 401.3378 401.4695 401.6012 401.7329 401.8646 401.9963 402.1279 402.2596 402.3912 402.5228 402.6544 402.7860 402.9176 403.0491 403.1807 403.3122 403.4437 403.5752 403.7067 403.8382 403.9696 404.1011 404.2325 404.3639 404.4953 404.6267 404.7581 404.8894 405.0208 405.1521 405.2834 405.4147 405.5460 405.6773 405.8085 405.9398 406.0710 406.2022 406.3334 406.4646 406.5958 406.7269 406.8581 406.9892 407.1203 407.2514 407.3825 407.5136 407.6446 407.7757 407.9067 408.0377 408.1687 408.2997 408.4307 408.5617 408.6926 408.8235 408.9544 409.0853 409.2162 409.3471 409.4780 409.6088 409.7396 409.8704 410.0012 410.1320 410.2628 410.3936 410.5243 410.6550 410.7857 410.9164 411.0471 411.1778 411.3084 411.4391 411.5697 411.7003 411.8309 411.9615 412.0921 412.2226 412.3532 412.4837 412.6142 412.7447 412.8752 413.0057 413.1361 413.2666 413.3970 413.5274 413.6578 413.7882 413.9185 414.0489 414.1792 414.3095 414.4399 414.5702 414.7004 414.8307 414.9609 415.0912 415.2214 415.3516 415.4818 415.6120 415.7422 415.8723 416.0024 416.1326 416.2627 416.3928 416.5228 416.6529 416.7829 416.9130 417.0430 417.1730 417.3030 417.4330 417.5629 417.6929 417.8228 417.9527 418.0826 418.2125 418.3424 418.4722 418.6021 418.7319 418.8617 418.9915 419.1213 419.2511 419.3808 419.5106 419.6403 419.7700 419.8997 420.0294 420.1591 420.2887 420.4184 420.5480 420.6776 420.8072 420.9368 421.0664 421.1959 421.3254 421.4550 421.5845 421.7140 421.8434 421.9729 422.1024 422.2318 422.3612 422.4906 422.6200 422.7494 422.8787 423.0081 423.1374 423.2667 423.3960 423.5253 423.6546 423.7839 423.9131 424.0423 424.1715 424.3007 424.4299 424.5591 424.6883 424.8174 424.9465 425.0756 425.2047 425.3338 425.4629 425.5919 425.7210 425.8500 425.9790 426.1080 426.2370 426.3659 426.4949 426.6238 426.7527 426.8816 427.0105 427.1394 427.2683 427.3971 427.5259 427.6547 427.7835 427.9123 428.0411 428.1699 428.2986 428.4273 428.5560 428.6847 428.8134 428.9421 429.0707 429.1994 429.3280 429.4566 429.5852 429.7138 429.8423 429.9709 430.0994 430.2279 430.3564 430.4849 430.6134 430.7419 430.8703 430.9987 431.1271 431.2555 431.3839 431.5123 431.6406 431.7690 431.8973 432.0256 432.1539 432.2822 432.4105 432.5387 432.6669 432.7952 432.9234 433.0516 433.1797 433.3079 433.4360 433.5642 433.6923 433.8204 433.9485 434.0765 434.2046 434.3326 434.4607 434.5887 434.7167 434.8446 434.9726 435.1006 435.2285 435.3564 435.4843 435.6122 435.7401 435.8679 435.9958 436.1236 436.2514 436.3792 436.5070 436.6348 436.7625 436.8903 437.0180 437.1457 437.2734 437.4011 437.5288 437.6564 437.7840 437.9117 438.0393 438.1669 438.2944 438.4220 438.5495 438.6771 438.8046 438.9321 439.0596 439.1870 439.3145 439.4419 439.5693 439.6967 439.8241 439.9515 440.0789 440.2062 440.3336 440.4609 440.5882 440.7155 440.8427 440.9700 441.0972 441.2245 441.3517 441.4789 441.6060 441.7332 441.8604 441.9875 442.1146 442.2417 442.3688 442.4959 442.6229 442.7500 442.8770 443.0040 443.1310 443.2580 443.3850 443.5119 443.6389 443.7658 443.8927 444.0196 444.1465 444.2733 444.4002 444.5270 444.6538 444.7806 444.9074 445.0342 445.1609 445.2876 445.4144 445.5411 445.6678 445.7944 445.9211 446.0478 446.1744 446.3010 446.4276 446.5542 446.6808 446.8073 446.9339 447.0604 447.1869 447.3134 447.4399 447.5663 447.6928 447.8192 447.9456 448.0720 448.1984 448.3248 448.4511 448.5775 448.7038 448.8301 448.9564 449.0827 449.2089 449.3352 449.4614 449.5876 449.7138 449.8400 449.9662 450.0923 450.2185 450.3446 450.4707 450.5968 450.7229 450.8490 450.9750 451.1010 451.2270 451.3530 451.4790 451.6050 451.7310 451.8569 451.9828 452.1087 452.2346 452.3605 452.4864 452.6122 452.7380 452.8638 452.9896 453.1154 453.2412 453.3669 453.4927 453.6184 453.7441 453.8698 453.9955 454.1211 454.2468 454.3724 454.4980 454.6236 454.7492 454.8748 455.0003 455.1258 455.2514 455.3769 455.5024 455.6278 455.7533 455.8787 456.0042 456.1296 456.2550 456.3803 456.5057 456.6310 456.7564 456.8817 457.0070 457.1323 457.2576 457.3828 457.5080 457.6333 457.7585 457.8837 458.0088 458.1340 458.2591 458.3843 458.5094 458.6345 458.7596 458.8846 459.0097 459.1347 459.2597 459.3847 459.5097 459.6347 459.7597 459.8846 460.0095 460.1344 460.2593 460.3842 460.5091 460.6339 460.7587 460.8835 461.0083 461.1331 461.2579 461.3826 461.5074 461.6321 461.7568 461.8815 462.0062 462.1308 462.2555 462.3801 462.5047 462.6293 462.7539 462.8784 463.0030 463.1275 463.2520 463.3765 463.5010 463.6255 463.7499 463.8744 463.9988 464.1232 464.2476 464.3719 464.4963 464.6206 464.7450 464.8693 464.9936 465.1178 465.2421 465.3663 465.4906 465.6148 465.7390 465.8632 465.9873 466.1115 466.2356 466.3597 466.4838 466.6079 466.7320 466.8560 466.9801 467.1041 467.2281 467.3521 467.4761 467.6000 467.7240 467.8479 467.9718 468.0957 468.2196 468.3434 468.4673 468.5911 468.7149 468.8387 468.9625 469.0863 469.2100 469.3338 469.4575 469.5812 469.7049 469.8286 469.9522 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Molecular iodine slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of molecular iodine slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Molecular iodine effective temperature [K] Column 39: Independent uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective molecular iodine fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for molecular iodine [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Nitrogen dioxide effective temperature [K] Column 50: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Oxygen dimer slant column amount [moles squared per meter to the 5th], -9e99=fitting not successful Column 56: Independent uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 57: Structured uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 58: Common uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 59: rms-based uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 60: Oxygen dimer effective temperature [K] Column 61: Independent uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 62: Structured uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 63: Common uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 64: Effective oxygen dimer fitting wavelength [nm], -9=fitting not successful Column 65: Diffuse correction applied before fitting at effective fitting wavelength for oxygen dimer [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 66: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 67: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 68: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 69: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 70: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 71: Ozone effective temperature [K] Column 72: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 73: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 74: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 75: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 76: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 77: Iodine dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 78: Independent uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 79: Structured uncertainty of iodine dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 80: Common uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 81: rms-based uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 82: Iodine dioxide effective temperature [K] Column 83: Independent uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 84: Structured uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 85: Common uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 86: Effective iodine dioxide fitting wavelength [nm], -9=fitting not successful Column 87: Diffuse correction applied before fitting at effective fitting wavelength for iodine dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 88: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 89: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 90: Lower limit used for wavelength scaling [nm] Column 91: Upper limit used for wavelength scaling [nm] Column 92: Order of smoothing polynomial Column 93: Smoothing polynomial coefficient, order 0 Column 94: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 95: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 96: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 97: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 98: Smoothing polynomial coefficient, order 1 Column 99: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 100: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 101: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 102: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 103: Smoothing polynomial coefficient, order 2 Column 104: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 105: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 106: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 107: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 108: Smoothing polynomial coefficient, order 3 Column 109: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 110: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 111: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 112: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 113: Smoothing polynomial coefficient, order 4 Column 114: Independent uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 115: Structured uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 116: Common uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 117: rms-based uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 118: Mean value of measured data inside fitting window [same units as measurements] Column 119: Offset polynomial coefficient, order 0 Column 120: Independent uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 121: Structured uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 122: Common uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 123: rms-based uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 124: Wavelength change polynomial coefficient, order 0 Column 125: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 126: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 127: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 128: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 129: Wavelength change polynomial coefficient, order 1 Column 130: Independent uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 131: Structured uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 132: Common uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 133: rms-based uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 134: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 135: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 136: Resolution change polynomial coefficient, order 0 Column 137: Independent uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 138: Structured uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 139: Common uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 140: rms-based uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 141: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 142: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 143: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 144: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 145: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 146: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 147: Atmospheric variability [%], 999=no atmospheric variability was determined Column 148: Wavelength effective temperature [°C], 999=no effective temperature given Column 149: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 150: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 151: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 152: Number of bright count cycles Column 153: Number of dark count cycles Column 154: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 155: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 156: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 157: Integration time [ms] Column 158: Temperature at electronics board [°C], 999=no temperature signal Column 159: Spectrometer control temperature [°C], 999=no temperature signal Column 160: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 161: Temperature in head sensor [°C], 999=no temperature signal Column 162: Humidity in head sensor [%], -9=no humidity signal Column 163: Pressure in head sensor [hPa], -9=no pressure signal Columns 164-711: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 712-1259: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250216T204439.4Z 9178.864345 557 1 53.77 2 63.55 223.77 148.19 351.50 0.00 1 0.00 1 0 33 1.842e-03 1.783e-03 9.995e-04 9.691e-04 -3.752169e+02 1.864680e+02 5.139707e+01 3.601935e+02 3.610266e+02 274.82 -2.00 20.00 -2.00 446.02 0.00e+00 1.424792e-04 1.086232e-04 1.830662e-06 1.512388e-05 2.010204e-04 274.82 -2.00 20.00 -2.00 455.62 0.00e+00 1.203790e-04 8.777522e-06 8.301047e-07 6.481339e-07 1.670279e-05 226.30 -2.00 2.15 -2.00 436.26 0.00e+00 4.519782e+05 1.360536e+05 1.460633e+04 2.263618e+05 2.638509e+05 257.02 -2.00 11.19 -2.00 458.31 0.00e+00 5.205034e-01 2.637631e-02 1.137305e-03 1.031117e-02 5.739114e-02 224.92 -2.00 3.49 -2.00 455.01 0.00e+00 -3.907593e-06 3.395058e-06 1.955097e-07 1.135661e-06 7.040937e-06 274.82 -2.00 20.00 -2.00 456.22 0.00e+00 2.232 0.000 397.00 473.00 4 7.3669e+00 1.0513e-03 5.5331e-03 3.8708e-04 1.8725e-03 6.5178e-02 1.2454e-03 1.1556e-03 2.3544e-04 2.3173e-03 -3.2172e-03 7.2841e-04 1.5252e-04 9.9270e-05 1.3413e-03 -2.1035e-03 2.4015e-04 1.7689e-05 2.4745e-05 4.4535e-04 -7.4895e-04 1.2278e-04 3.3786e-06 1.3584e-05 2.2279e-04 7.1765e-04 3.8511e-03 7.0197e-04 1.2827e-05 4.0567e-05 1.1369e-03 -4.9801e-06 1.0488e-05 1.6554e-07 3.3689e-07 1.9231e-05 1.5516e-04 1.4101e-05 1.2795e-07 4.0652e-07 2.6243e-05 -5.0656e-03 2.7211e-05 2.4657e-01 1.0318e-01 1.1300e-03 2.3296e-03 1.7881e-01 12 8 8 10 0 0 100.00 24.73 0.89 -0.00507 -0.01836 111 12 1 4 0 484.400 33.50 20.00 24.73 0.78 2.6 992.59 -294 -105 224 200 -57 -93 -314 16 174 -17 71 143 212 133 -331 -153 -121 84 287 -255 -175 72 -306 -139 263 -208 -240 29 268 -94 195 609 -13 -134 221 167 -71 239 454 -236 163 137 70 -182 -174 129 117 125 -135 -433 -178 249 -244 87 -41 -356 320 0 30 240 -68 236 118 -7 129 -19 -51 248 -86 -82 -47 113 10 -21 -280 -358 28 -149 -89 -55 99 123 -60 -255 -18 73 45 -229 229 67 -27 82 175 146 -212 179 -243 -101 -113 201 -299 -523 62 98 22 80 105 158 217 -143 26 61 -166 249 -24 166 -221 -340 -165 -109 -335 -266 -111 -180 211 -23 -21 45 -313 33 -7 -104 -95 -71 -249 58 289 -45 20 -169 -195 -244 -40 196 -2 29 -266 116 125 204 28 -387 15 65 60 105 -240 -245 -197 181 286 -79 124 -1 -34 215 -207 -206 261 -39 27 -119 27 30 374 -183 -326 392 278 237 -22 48 -292 139 82 70 414 529 59 148 -233 -11 -76 315 -84 118 -174 -171 -72 -87 220 288 39 251 -186 -73 37 191 -142 46 223 -130 -21 -47 227 216 -217 32 72 55 -77 251 189 72 43 -60 20 -306 55 -265 402 79 106 -121 -255 19 -241 373 -278 -22 86 58 218 312 89 -24 137 -21 74 257 346 -7 228 -94 11 500 -46 -103 -118 -2 220 583 -285 100 -295 158 -229 49 394 -34 -18 -93 -41 140 69 -139 157 265 -57 163 -245 -253 218 -40 279 -332 -66 -220 99 -54 -343 -497 -272 -20 120 -309 288 158 18 21 -243 -323 -241 -85 -433 263 -155 -168 -164 40 -38 -17 82 -317 -168 -140 143 -11 18 -379 13 -31 -131 169 14 -181 -71 137 -99 57 86 -130 27 -17 125 -179 77 54 -382 -69 -188 168 -126 -66 -313 14 -124 -39 157 144 308 546 -50 -346 -72 26 223 73 60 80 -115 -197 -63 -55 250 -284 -143 -175 136 -55 -150 285 -107 -27 -92 372 -90 -81 -296 -238 -149 -404 -164 -248 296 15 -249 -71 -119 206 74 37 -97 -158 63 -94 56 130 -95 428 164 -134 14 88 47 -12 -171 109 9 77 -138 -83 -233 130 -119 37 -7 -220 42 230 -24 194 -96 74 212 257 -55 442 -47 -90 158 109 34 175 77 44 323 6 177 96 254 183 -15 -81 206 -20 98 -14 -154 109 96 -51 -18 40 -187 145 264 141 -138 69 224 36 -192 423 149 -53 74 93 -25 87 -1 60 -107 -109 38 283 88 -186 23 87 -10 165 266 -66 -191 20 -142 -80 -251 -300 -93 -86 90 -85 -90 -52 -12 -171 -1 -2 66 -36 -98 -220 -117 -155 84 -80 -34 42 -161 -56 149 -73 -41 -285 -112 50 -149 26 -65 -83 -167 21 -83 2 -27 -85 93 -316 60 251 -180 -168 -145 220 -31 -31 -14 125 122 249 157 197 66 230 -38 73 -237 -86 180 156 -46 -75 -246 13 146 -14 61 120 178 112 -281 -131 -104 72 245 -220 -153 62 -271 -117 210 -165 -198 25 232 -84 174 532 -11 -110 181 136 -58 209 414 -218 146 120 60 -153 -147 110 104 109 -114 -363 -154 225 -214 76 -37 -326 289 0 26 211 -62 212 108 -6 119 -18 -49 245 -85 -81 -46 107 10 -19 -255 -308 24 -124 -75 -46 89 117 -56 -239 -17 70 44 -230 231 67 -26 80 169 142 -209 174 -236 -97 -107 186 -272 -501 57 93 22 82 108 159 208 -133 24 57 -162 244 -24 161 -211 -321 -154 -102 -319 -260 -111 -185 208 -22 -22 45 -312 32 -7 -97 -86 -64 -228 54 273 -43 19 -161 -185 -230 -38 182 -2 27 -264 110 124 198 27 -350 13 58 54 98 -233 -233 -192 177 281 -78 122 -1 -32 200 -193 -198 255 -38 25 -110 22 25 326 -164 -301 374 264 218 -21 45 -273 132 76 66 397 508 56 137 -219 -10 -70 297 -76 109 -161 -156 -68 -80 202 260 38 246 -182 -69 33 168 -119 38 189 -118 -19 -43 211 199 -199 29 65 49 -70 219 164 63 39 -52 18 -267 45 -210 297 57 77 -89 -188 14 -168 271 -196 -16 68 49 205 302 90 -24 135 -19 66 223 295 -6 210 -88 11 492 -45 -100 -110 -1 190 469 -230 85 -258 147 -214 47 378 -32 -17 -88 -37 129 65 -134 153 260 -57 158 -241 -248 210 -40 273 -323 -63 -206 91 -50 -322 -477 -262 -19 108 -260 234 133 16 19 -222 -299 -225 -80 -415 255 -145 -157 -160 38 -35 -15 73 -285 -155 -135 137 -11 17 -369 13 -29 -126 168 14 -183 -71 136 -98 57 87 -131 27 -17 121 -171 74 52 -368 -67 -182 159 -124 -63 -301 14 -122 -38 153 137 297 508 -45 -312 -65 24 205 68 58 75 -109 -188 -60 -52 241 -281 -145 -180 141 -57 -152 279 -102 -26 -90 372 -92 -82 -297 -237 -147 -401 -163 -247 294 15 -254 -73 -123 216 79 40 -105 -172 68 -101 60 137 -99 441 169 -139 14 92 49 -12 -182 113 9 75 -134 -85 -229 128 -118 37 -8 -235 45 251 -26 209 -104 79 223 280 -60 475 -51 -98 172 120 38 191 86 49 362 7 202 109 289 211 -17 -94 239 -23 115 -17 -183 127 110 -57 -20 47 -216 169 296 161 -160 80 255 43 -228 498 176 -63 87 110 -29 104 -2 73 -131 -135 45 353 110 -230 28 108 -12 203 328 -82 -239 24 -179 -101 -315 -377 -116 -108 113 -107 -111 -64 -15 -207 -1 -2 81 -44 -119 -263 -138 -180 99 -96 -41 51 -196 -68 181 -90 -52 -360 -140 62 -180 31 -74 -97 -188 24 -98 3 -33 -104 114 -386 72 298 -215 -202 -176 269 -38 -38 -17 151 147 303 192 242 81 279 -45 85 SQ 20250216T204829.0Z 9178.867002 560 1 0.57 2 64.06 224.65 148.30 353.21 0.00 1 0.00 1 0 33 3.030e-03 2.979e-03 2.871e-03 2.805e-03 -4.693995e+02 5.409118e+02 7.290437e+01 3.602153e+02 5.938850e+02 274.82 -2.00 20.00 -2.00 445.73 0.00e+00 -5.128413e-05 3.116863e-04 2.673540e-06 1.488666e-05 3.300408e-04 274.82 -2.00 20.00 -2.00 455.27 0.00e+00 1.201239e-04 2.530814e-05 8.830925e-07 6.341157e-07 2.747542e-05 226.31 -2.00 2.15 -2.00 435.92 0.00e+00 8.014346e+05 3.927003e+05 2.142935e+04 2.264094e+05 4.337996e+05 257.02 -2.00 11.19 -2.00 457.92 0.00e+00 5.629882e-01 7.737763e-02 1.801480e-03 1.037023e-02 9.437160e-02 224.92 -2.00 3.49 -2.00 454.66 0.00e+00 -6.083979e-06 9.860538e-06 2.439271e-07 1.135010e-06 1.158217e-05 274.82 -2.00 20.00 -2.00 455.89 0.00e+00 2.272 0.000 397.00 473.00 4 4.4448e+00 2.9883e-03 5.6327e-03 3.8822e-04 3.0780e-03 4.6097e-02 3.5953e-03 1.1768e-03 2.3256e-04 3.8241e-03 2.3592e-03 2.0779e-03 1.5626e-04 9.6719e-05 2.1925e-03 -2.4295e-03 6.9095e-04 1.9046e-05 2.4402e-05 7.3298e-04 -1.1418e-03 3.5280e-04 6.2501e-06 1.3584e-05 3.6630e-04 1.3173e-02 7.8103e-03 1.9631e-03 1.7660e-05 3.6381e-05 1.8457e-03 -6.3744e-05 2.9814e-05 2.0720e-07 3.3438e-07 3.1643e-05 4.2135e-05 4.0342e-05 1.8367e-07 4.0631e-07 4.3165e-05 -1.1588e-02 1.2749e-04 -2.1250e-01 2.9495e-01 1.6195e-03 2.3323e-03 2.9515e-01 12 9 9 12 1 1 999.00 24.73 0.87 -0.01159 -0.01657 1 22 1 4 0 280.550 33.75 20.00 24.73 0.82 2.6 993.03 -449 368 648 59 -37 244 -671 246 -432 224 -424 106 -41 -270 -131 48 382 -71 -55 101 870 -224 -240 -172 -630 456 214 -177 -44 -263 -551 116 -364 -145 236 410 -196 552 62 -193 67 201 42 173 -285 180 161 90 -86 552 -305 -200 -239 251 498 56 287 -152 -717 -180 -83 406 -442 320 -421 -104 39 165 162 698 61 287 148 -2 74 69 267 -104 -126 -852 727 92 5 207 -148 186 98 -110 153 71 52 -469 30 19 111 -557 291 517 -505 281 -344 -290 -102 50 -55 -126 110 421 -194 -147 -50 -11 -62 -434 -44 -371 -701 -829 -217 69 28 155 -301 205 -326 480 215 -3 -287 141 -77 177 87 -46 -323 386 487 -66 513 3 693 -271 -84 -54 36 91 -67 -466 81 -2 150 -172 -267 -495 -193 164 -528 89 36 488 82 75 94 -170 -228 59 -68 -120 434 549 282 108 482 -25 -228 59 -480 -71 258 -582 -401 38 18 120 246 145 -462 512 201 165 72 114 -283 -324 454 493 1 -221 228 -147 296 -353 -61 -74 84 -279 149 70 -84 259 71 -212 -195 -499 259 474 -263 147 38 -418 -677 107 259 741 -214 73 -590 137 -74 -286 142 -302 -403 -217 -516 -299 -416 -595 -393 999 861 -10 93 240 112 119 76 426 -200 102 747 -45 -67 -29 171 180 -248 282 -159 164 301 368 212 331 639 306 -173 -181 -68 173 542 59 -142 -298 182 121 113 -41 109 -315 -110 220 -70 -333 182 -159 92 -434 321 326 10 312 -250 94 127 -290 125 -640 -37 88 178 -156 -242 232 -425 150 134 -497 69 133 51 -80 -247 -467 -397 15 52 139 108 331 -395 518 -159 -430 465 7 -389 -382 357 -367 -251 43 307 -563 -51 -158 -49 -287 42 -59 -96 -54 537 8 105 -33 361 -11 48 177 -273 -32 -219 -257 425 -24 659 -186 -407 137 -403 -717 -212 12 348 -1 671 237 -94 -168 14 -76 142 -457 -450 -256 8 -215 -303 -70 391 -290 -31 69 -202 -241 87 -146 427 -638 -408 264 232 66 108 -425 67 -52 -60 -62 -407 -138 -107 -285 -208 220 5 172 -243 398 418 323 -401 64 -394 -46 200 -170 133 -50 372 362 197 -76 69 583 207 -36 183 22 -9 10 312 264 -58 624 357 151 -145 528 -344 -113 -12 -10 -4 -46 -41 175 22 -222 448 69 330 297 67 -101 -333 214 -222 -69 183 311 -36 12 -341 662 -21 -428 291 -134 200 98 373 -110 -337 27 -183 -123 493 -466 -347 223 227 -129 -203 -36 203 204 -235 25 -450 -30 131 -105 -454 13 42 429 79 479 200 221 -49 234 -409 -454 396 -137 -108 -422 -90 -120 -285 -63 267 -375 -126 -459 371 38 -273 111 -68 149 -46 57 -665 205 -331 -365 -234 -323 -118 87 119 -495 1 569 -124 -244 199 -213 -62 599 383 392 827 -154 -373 303 534 48 -30 194 -556 206 -367 191 -366 91 -35 -230 -112 42 331 -62 -48 88 761 -196 -207 -144 -517 375 179 -155 -39 -238 -505 104 -323 -125 194 335 -167 483 56 -175 60 180 37 151 -248 157 142 77 -73 462 -266 -177 -215 224 440 50 257 -136 -631 -157 -74 373 -414 297 -392 -97 37 161 156 677 59 274 137 -2 66 60 227 -88 -105 -748 650 86 4 195 -141 180 96 -108 150 69 51 -455 29 19 108 -544 280 492 -489 264 -325 -271 -96 48 -54 -127 109 411 -186 -138 -47 -10 -60 -421 -43 -361 -674 -786 -206 65 26 151 -297 203 -328 479 212 -3 -282 135 -73 167 80 -43 -304 361 462 -63 487 3 656 -256 -78 -51 34 88 -66 -455 78 -1 140 -159 -243 -451 -179 153 -507 87 35 478 81 74 93 -166 -223 57 -66 -116 424 537 273 100 423 -21 -198 54 -455 -69 246 -553 -377 35 17 113 233 138 -451 496 193 156 67 105 -262 -304 423 467 1 -208 212 -135 270 -331 -59 -72 82 -268 138 62 -73 225 62 -192 -182 -472 243 441 -244 137 35 -383 -614 95 228 655 -191 66 -538 121 -64 -232 112 -237 -311 -170 -406 -234 -317 -447 -302 799 720 -9 88 236 113 119 75 407 -181 89 646 -40 -62 -28 167 177 -246 277 -153 150 260 310 177 286 574 285 -165 -175 -65 166 511 54 -132 -281 175 117 110 -40 108 -312 -110 219 -70 -328 179 -155 88 -417 300 305 9 299 -242 88 115 -254 108 -566 -34 82 166 -147 -231 219 -410 144 130 -485 66 127 48 -74 -230 -429 -370 14 51 138 108 327 -384 496 -157 -425 464 7 -387 -376 354 -365 -250 43 304 -555 -50 -152 -47 -279 42 -59 -94 -53 520 8 103 -33 361 -11 48 172 -263 -30 -205 -238 392 -22 619 -176 -390 133 -394 -705 -206 12 344 -1 668 241 -95 -172 14 -75 140 -450 -445 -261 8 -218 -308 -70 394 -291 -31 69 -204 -247 90 -150 440 -673 -429 280 248 70 114 -452 71 -55 -63 -65 -428 -145 -113 -304 -221 231 5 177 -249 401 416 324 -408 65 -408 -47 210 -182 144 -54 405 391 212 -82 73 623 220 -38 195 24 -10 10 339 292 -65 701 400 170 -162 590 -384 -127 -13 -12 -4 -52 -47 201 26 -256 513 78 371 332 76 -115 -377 245 -258 -80 210 359 -41 14 -393 756 -24 -496 336 -156 233 116 444 -131 -405 33 -218 -146 590 -563 -419 267 273 -156 -243 -43 243 244 -283 30 -544 -37 160 -128 -552 15 50 514 95 575 238 264 -59 276 -478 -536 467 -163 -130 -504 -107 -142 -340 -76 325 -456 -152 -557 442 44 -314 127 -78 173 -54 67 -799 246 -400 -437 -277 -377 -138 102 141 -586 1 669 -146 -287 236 -250 -73 706 451 458 964 -177