File name: Pandora83s1_BondvilleIL_20250224_L2Fit_fout2c2d20230316p1-8.txt File generation date: 20250327T114355.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 83 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora83_OF_v3d20231115.txt Instrument calibration file used: Pandora83s1_CF_v2d20240316.txt Level 1 file used: Pandora83s1_BondvilleIL_20250224_L1_smca1c2d20230316p1-8.txt Full location name: Bondville, Illinois EPA Castnet Site Short location name: BondvilleIL Country of location: United States Location latitude [deg]: 40.0520 Location longitude [deg]: -88.3725 Location altitude [m]: 213 Local noon date: 20250224 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 199 341 Nominal wavelengths inside fitting window [nm]: 305.0622 305.2028 305.3435 305.4841 305.6247 305.7653 305.9059 306.0465 306.1871 306.3276 306.4681 306.6087 306.7492 306.8897 307.0302 307.1707 307.3112 307.4516 307.5921 307.7325 307.8730 308.0134 308.1538 308.2942 308.4346 308.5749 308.7153 308.8556 308.9960 309.1363 309.2766 309.4169 309.5572 309.6975 309.8378 309.9780 310.1183 310.2585 310.3987 310.5389 310.6791 310.8193 310.9595 311.0997 311.2398 311.3800 311.5201 311.6602 311.8003 311.9404 312.0805 312.2206 312.3606 312.5007 312.6407 312.7808 312.9208 313.0608 313.2008 313.3407 313.4807 313.6207 313.7606 313.9006 314.0405 314.1804 314.3203 314.4602 314.6001 314.7399 314.8798 315.0196 315.1595 315.2993 315.4391 315.5789 315.7187 315.8584 315.9982 316.1380 316.2777 316.4174 316.5571 316.6968 316.8365 316.9762 317.1159 317.2555 317.3952 317.5348 317.6744 317.8141 317.9537 318.0932 318.2328 318.3724 318.5119 318.6515 318.7910 318.9305 319.0700 319.2095 319.3490 319.4885 319.6280 319.7674 319.9068 320.0463 320.1857 320.3251 320.4645 320.6039 320.7432 320.8826 321.0219 321.1613 321.3006 321.4399 321.5792 321.7185 321.8577 321.9970 322.1363 322.2755 322.4147 322.5539 322.6932 322.8323 322.9715 323.1107 323.2499 323.3890 323.5281 323.6673 323.8064 323.9455 324.0846 324.2236 324.3627 324.5018 324.6408 324.7798 324.9188 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250224T141825.6Z 9186.596129 132 1 18.75 2 72.08 119.47 68.51 167.49 0.00 1 0.00 1 0 25 9.434e-02 9.793e-03 4.505e-02 3.084e-03 4.664371e-01 1.554341e-03 5.496811e-03 -6.000000e+00 5.365160e-02 225.28 -2.00 3.49 -2.00 319.12 0.00e+00 3.102299e-03 3.799992e-04 3.420889e-04 -6.000000e+00 2.315671e-03 275.31 -2.00 20.00 -2.00 318.57 0.00e+00 3.206 0.001 302.00 328.00 3 3.4742e+00 4.2739e-03 3.9235e-02 -6.0000e+00 1.3290e-01 5.1354e-02 4.9425e-03 2.3851e-02 -6.0000e+00 1.4454e-01 -3.8670e-02 3.8587e-03 1.2279e-02 -6.0000e+00 8.5868e-02 9.6982e-03 2.0645e-03 4.6085e-03 -6.0000e+00 3.6603e-02 4.0186e-04 -7.2202e-04 8.6091e-05 4.6352e-05 -6.0000e+00 2.5592e-03 -6.0394e-03 0.0000e+00 12 9 9 12 1 1 64.10 24.62 -0.01 -0.00604 -0.01146 12 4 1 5 0 1442.200 33.50 20.01 24.62 8.25 2.5 1072.07 -44502 43280 26072 4022 -43020 10906 -24722 35703 -21195 15014 -18654 -15320 -4633 -6481 15775 7059 -1221 -7395 800 -13041 -12433 2004 -3774 -5518 -7789 345 2007 -5221 5560 16885 4432 4450 2530 -29822 2087 -5232 -7377 -1691 283 1802 1888 -458 -4991 -3120 30 416 4209 2646 352 1095 1924 1392 2910 4471 2329 2415 -1592 925 -84 -198 5278 1911 3182 2331 1435 -1443 272 2829 1508 639 209 -67 -343 556 343 -790 -188 -1358 -1938 -838 -1115 -1893 -830 -2465 -1509 -949 -704 -210 161 37 854 -714 -151 2201 97 -662 1000 -329 168 -404 -626 158 -373 -326 -629 -1217 -1287 -38 202 631 624 290 451 89 342 703 458 170 94 -186 -240 211 -142 263 -199 257 1083 278 409 56 75 263 -131 456 -76 -175 -451 -81 -15 -62 -386 -241 11 -1285 599 455 85 -1320 187 -639 569 -669 352 -628 -539 -176 -310 735 418 -87 -603 64 -1263 -1230 171 -350 -554 -857 37 212 -575 532 1483 494 574 377 -5927 319 -839 -1300 -331 60 445 521 -139 -1651 -1038 10 137 1345 866 120 383 720 576 1179 1908 1065 1139 -801 453 -41 -95 2448 993 1820 1483 886 -885 169 1696 983 442 161 -54 -279 430 246 -516 -120 -853 -1306 -593 -915 -1640 -776 -2475 -1489 -995 -780 -240 184 41 878 -736 -144 2020 98 -707 1194 -421 219 -537 -839 191 -443 -385 -749 -1555 -1726 -50 283 910 978 477 737 140 527 1017 655 252 140 -294 -386 331 -216 408 -297 365 1545 399 599 86 125 436 -224 814 -138 -336 -894 -162 -30 -122 -730 -455 20 SS 20250224T142326.1Z 9186.599608 135 1 54.00 2 71.25 120.44 68.31 168.64 0.00 1 0.00 1 0 25 3.141e-01 7.367e-03 8.767e-02 1.611e-03 4.483074e-01 8.097492e-04 5.306444e-03 -6.000000e+00 1.786286e-01 225.28 -2.00 3.49 -2.00 318.94 0.00e+00 1.525426e-03 1.860677e-04 5.067387e-04 -6.000000e+00 7.710396e-03 275.31 -2.00 20.00 -2.00 318.37 0.00e+00 3.073 0.000 302.00 328.00 3 3.4738e+00 2.2129e-03 3.7641e-02 -6.0000e+00 4.4246e-01 2.8152e-02 2.5487e-03 2.2861e-02 -6.0000e+00 4.8123e-01 -1.4117e-02 1.9351e-03 1.1616e-02 -6.0000e+00 2.8590e-01 -6.2419e-04 1.0373e-03 3.6045e-03 -6.0000e+00 1.2186e-01 4.7058e-04 -7.4474e-04 4.5047e-05 3.8370e-05 -6.0000e+00 8.5214e-03 -5.5361e-03 0.0000e+00 11 8 0 10 0 0 99.62 24.63 0.12 -0.00554 -0.01113 52 6 1 5 0 1038.420 33.50 19.97 24.63 8.42 2.5 1074.28 -38789 10047 21559 -4174 358454 -12391 -24094 25758 -31294 1465 -13217 -7318 6391 -9570 10904 -6901 -7775 -10708 244 -7663 -6596 4590 -5281 -5556 -10345 521 227 -3237 758 7333 -124 764 547 -458 -452 -4671 -6222 -2380 -807 1103 169 -97 -2630 -2178 -1564 413 3333 1188 31 943 930 475 1212 2707 2371 1707 -1446 336 21 -88 3139 1638 3485 1458 1139 -966 -326 2173 1313 624 777 71 134 908 757 62 -521 -1040 -1477 -778 -986 -2050 -1109 -2205 -1200 -505 -406 187 48 330 431 -608 8 175 265 -279 941 -90 -153 -1088 -759 56 -397 -543 -810 -1303 -1070 -106 329 676 918 671 325 245 369 699 405 517 -11 -311 -73 262 -188 39 -99 2 1033 446 262 140 152 138 -219 186 -178 -128 -172 -19 44 -27 -447 -310 22 -1213 221 447 -108 563 -306 -712 526 -1278 46 -496 -278 251 -540 605 -529 -660 -1006 22 -782 -686 427 -558 -631 -1329 63 28 -398 86 794 -16 113 91 -82 -78 -817 -1192 -469 -191 304 53 -32 -940 -792 -569 149 1174 429 12 358 380 196 538 1268 1170 877 -787 180 11 -45 1610 921 2139 927 755 -629 -199 1286 840 458 586 57 107 692 577 43 -330 -692 -967 -580 -789 -1867 -1090 -2162 -1239 -554 -441 209 54 359 468 -614 8 171 259 -308 1092 -112 -207 -1504 -988 70 -458 -625 -1003 -1629 -1399 -144 477 1005 1398 1071 518 393 549 1033 591 738 -17 -503 -113 422 -294 59 -142 2 1420 616 392 218 243 232 -380 320 -326 -247 -327 -36 86 -52 -859 -564 39 SS 20250224T142853.2Z 9186.603394 138 1 53.64 2 70.35 121.50 68.11 169.89 0.00 1 0.00 1 0 25 7.822e-02 8.224e-03 1.983e-02 1.726e-03 4.303166e-01 8.711102e-04 5.101198e-03 -6.000000e+00 4.453566e-02 225.28 -2.00 3.49 -2.00 318.90 0.00e+00 2.067747e-03 1.982732e-04 3.757028e-04 -6.000000e+00 1.953541e-03 275.31 -2.00 20.00 -2.00 318.34 0.00e+00 2.941 0.000 302.00 328.00 3 3.7237e+00 2.3705e-03 3.6069e-02 -6.0000e+00 1.1025e-01 2.6562e-02 2.7255e-03 2.1949e-02 -6.0000e+00 1.1992e-01 -8.3223e-03 2.0541e-03 1.1178e-02 -6.0000e+00 7.1196e-02 -3.6032e-03 1.1003e-03 3.6918e-03 -6.0000e+00 3.0366e-02 4.2267e-04 -7.9017e-04 4.8813e-05 3.8186e-05 -6.0000e+00 2.1441e-03 -5.5411e-03 0.0000e+00 11 8 0 10 0 0 99.47 24.63 0.18 -0.00554 -0.01148 60 7 1 5 0 893.910 33.75 19.99 24.63 8.71 2.5 1076.88 -29555 38866 18426 -297 900000 -16386 -16913 42828 -30013 24192 -5685 -2460 8734 -12190 17971 -1458 -8950 -10773 1356 -6502 -7238 8341 -4265 -5117 -13077 197 3656 -2477 573 14619 1899 2924 957 -2670 943 -5698 -6574 -3241 -940 -797 468 -1420 -3819 2639 -1753 -3 4209 1809 531 60 1282 -639 1036 3156 1273 1537 -1151 -88 -632 -983 3960 1202 3845 1074 1603 -1401 -359 1912 1754 360 659 96 -456 1307 628 80 -355 -1081 -2115 -1200 -1246 -1680 -735 -2242 -1452 -327 -315 411 1 424 845 -350 421 2372 422 -156 410 -168 -264 -1110 -773 17 -580 -624 -535 -1472 -1214 -209 189 913 734 450 344 89 504 574 461 450 -92 48 -322 384 -233 55 -350 106 317 405 186 190 446 267 -79 306 -202 118 -379 -119 -19 128 -524 -450 142 -930 707 434 -8 900000 -461 -507 800 -1309 656 -212 -95 357 -751 986 -112 -812 -1068 127 -691 -797 785 -467 -603 -1792 25 450 -312 67 1518 248 433 162 -498 163 -1024 -1284 -719 -225 -226 147 -483 -1389 919 -644 -1 1478 652 196 23 519 -289 456 1455 626 779 -614 -47 -328 -505 1984 668 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