File name: Pandora83s1_BondvilleIL_20250227_L2Fit_fout2c8d20241002p1-8.txt File generation date: 20250725T074943.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 83 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora83_OF_v3d20231115.txt Instrument calibration file used: Pandora83s1_CF_v8d20241002.txt Level 1 file used: Pandora83s1_BondvilleIL_20250227_L1_smca1c8d20241002p1-8.txt Full location name: Bondville, Illinois EPA Castnet Site Short location name: BondvilleIL Country of location: United States Location latitude [deg]: 40.0520 Location longitude [deg]: -88.3725 Location altitude [m]: 213 Local noon date: 20250227 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 199 341 Nominal wavelengths inside fitting window [nm]: 305.0376 305.1782 305.3189 305.4595 305.6001 305.7407 305.8813 306.0219 306.1625 306.3031 306.4436 306.5841 306.7247 306.8652 307.0057 307.1462 307.2867 307.4271 307.5676 307.7081 307.8485 307.9889 308.1293 308.2697 308.4101 308.5505 308.6909 308.8312 308.9716 309.1119 309.2522 309.3925 309.5328 309.6731 309.8134 309.9537 310.0939 310.2342 310.3744 310.5146 310.6548 310.7950 310.9352 311.0754 311.2155 311.3557 311.4958 311.6359 311.7761 311.9162 312.0563 312.1963 312.3364 312.4765 312.6165 312.7565 312.8966 313.0366 313.1766 313.3166 313.4565 313.5965 313.7365 313.8764 314.0163 314.1563 314.2962 314.4361 314.5760 314.7158 314.8557 314.9955 315.1354 315.2752 315.4150 315.5548 315.6946 315.8344 315.9742 316.1139 316.2537 316.3934 316.5331 316.6728 316.8125 316.9522 317.0919 317.2316 317.3712 317.5109 317.6505 317.7901 317.9297 318.0693 318.2089 318.3485 318.4880 318.6276 318.7671 318.9066 319.0462 319.1857 319.3251 319.4646 319.6041 319.7435 319.8830 320.0224 320.1618 320.3013 320.4407 320.5800 320.7194 320.8588 320.9981 321.1375 321.2768 321.4161 321.5554 321.6947 321.8340 321.9733 322.1125 322.2518 322.3910 322.5302 322.6694 322.8086 322.9478 323.0870 323.2262 323.3653 323.5045 323.6436 323.7827 323.9218 324.0609 324.2000 324.3391 324.4781 324.6172 324.7562 324.8952 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250227T131403.5Z 9189.551430 52 1 16.08 2 82.51 107.26 82.70 114.14 0.00 1 0.00 1 0 84 1.507e+00 6.486e-02 4.147e-01 1.901e-02 1.073407e+00 1.198123e-02 1.312544e-02 -6.000000e+00 9.387159e-01 225.42 -2.00 3.49 -2.00 322.19 0.00e+00 6.056518e-02 6.396649e-03 4.200497e-02 -6.000000e+00 5.246320e-02 275.50 -2.00 20.00 -2.00 321.81 0.00e+00 7.116 0.006 302.00 328.00 3 9.5420e-01 4.1763e-02 2.8725e-01 -6.0000e+00 2.3222e+00 2.6925e+00 4.5089e-02 3.4063e-01 -6.0000e+00 2.5343e+00 -3.1579e+00 3.7886e-02 2.8658e-02 -6.0000e+00 1.5010e+00 1.2279e+00 2.1803e-02 8.8056e-02 -6.0000e+00 6.4839e-01 3.2700e-05 -4.0048e-03 4.9878e-04 3.3426e-04 -6.0000e+00 4.6411e-02 1.0625e-02 0.0000e+00 12 9 9 12 33 1 45.68 24.72 0.68 0.01063 -0.01947 8 3 1 5 0 1785.700 33.50 19.97 24.72 5.58 2.5 1038.91 689472 463237 900000 900000 900000 900000 269170 900000 900000 173853 900000 900000 900000 217721 900000 336498 359076 246737 900000 258070 277464 529988 306366 142468 93902 211971 900000 84080 900000 900000 900000 900000 236887 -64338 900000 177671 109011 123352 163760 900000 900000 217957 86998 166713 80842 900000 900000 379322 900000 296869 173482 74885 110122 900000 287743 200776 56898 79044 50796 10308 900000 149489 900000 100974 114635 50378 42139 147407 96495 52519 60271 100199 25724 110468 61662 57577 68148 21005 -20088 26379 7727 11527 35678 4117 -3079 12484 -2274 13409 7181 528 7975 -4179 -5832 36508 -5522 -7286 4265 -7627 574 -1357 5460 17812 3387 -8249 -10358 -12925 1901 -4490 -6556 -8651 780 -1656 -4325 -6211 -2331 -1040 46 -4754 -2163 1232 2295 6073 -1095 3790 -3721 3351 16892 -2667 -1483 1601 4401 3427 1998 3239 -885 724 -742 -1824 -37 2 -1807 -1634 -755 12714 8542 900000 900000 900000 900000 9024 900000 900000 4663 900000 900000 900000 6570 900000 6205 6621 11995 900000 9950 7442 9773 5649 6209 4722 3909 900000 2819 900000 900000 900000 900000 4765 -26855 900000 4765 5117 4756 4118 900000 900000 4019 4375 3913 4608 900000 900000 6995 900000 5474 5235 6402 6830 900000 5306 4813 5141 5101 3934 1140 900000 4686 900000 7075 7821 6688 5983 7339 8363 7747 8780 9793 4981 8148 6367 5309 5152 2634 -4482 4670 2023 3380 9079 1503 -1238 4420 -960 4945 2807 213 2794 -1533 -2086 8886 -2373 -3937 2548 -5664 456 -1169 4651 11857 2217 -5507 -7182 -9724 1300 -3544 -5972 -8643 837 -2062 -5888 -8715 -3080 -1322 58 -6623 -3115 1780 3217 7666 -1385 4390 -4522 4066 17443 -3161 -2026 2573 8056 7088 4541 7172 -2189 1858 -1966 -4893 -96 6 -4260 -3771 -1579 SS 20250227T133750.7Z 9189.567947 63 1 22.71 2 78.21 111.34 78.67 118.12 0.00 1 0.00 1 0 25 4.507e-01 8.805e-03 1.129e-01 1.999e-03 7.804962e-01 1.055718e-03 8.809649e-03 -6.000000e+00 2.568361e-01 225.42 -2.00 3.49 -2.00 320.71 0.00e+00 6.226518e-03 4.338363e-04 1.040217e-03 -6.000000e+00 1.125941e-02 275.50 -2.00 20.00 -2.00 320.25 0.00e+00 4.742 0.002 302.00 328.00 3 1.0284e+00 3.2230e-03 6.1485e-02 -6.0000e+00 6.3604e-01 1.2402e-01 4.3582e-03 4.1154e-02 -6.0000e+00 6.9154e-01 -1.7026e-01 4.7357e-03 2.4109e-02 -6.0000e+00 4.1059e-01 5.9021e-02 2.3415e-03 1.1119e-02 -6.0000e+00 1.7530e-01 7.8640e-04 -7.3827e-04 4.9912e-05 1.1100e-04 -6.0000e+00 1.2360e-02 1.1854e-02 0.0000e+00 12 9 1 12 1 1 79.41 24.72 0.29 0.01185 0.00631 83 22 1 5 0 270.260 33.50 19.97 24.72 7.00 2.5 1053.23 -199074 -143633 -115446 -139072 900000 -125209 -164625 -45078 -185033 -129485 -144848 -93645 -114364 -81275 19987 -67025 -68641 -57747 -34645 -59456 -53613 -25877 -59780 -42598 -44081 -32595 6242 -24552 -13139 -5669 -30220 2805 -11207 -60604 4190 -7957 -9214 -9302 2122 932 5242 -1515 -3198 2752 -2226 6337 10416 7129 3183 3550 796 2255 4454 6890 3653 3461 -1088 -784 -1902 -1450 5926 678 5040 3974 3607 1804 1134 3207 2320 1744 1734 730 1156 1970 735 -1502 -1467 -3368 -3107 -915 -770 -1525 -506 -1723 -578 -164 -110 -55 662 535 380 620 -445 661 -779 -626 194 -39 59 -562 -471 -340 -466 -914 -1345 -1715 -1696 -262 58 477 731 497 312 194 257 328 306 361 -142 -154 -250 229 251 475 40 12 1003 676 157 222 -21 104 -26 168 -275 -186 -179 39 -98 -177 -76 -140 19 -1552 -789 -585 -894 900000 -634 -1315 -123 -2308 -1009 -1412 -639 -1271 -887 105 -1058 -1298 -1114 -587 -1379 -1212 -444 -1491 -971 -1108 -775 103 -550 -266 -118 -995 84 -461 -4512 161 -338 -427 -511 128 69 425 -144 -329 278 -242 655 1076 805 400 484 125 399 782 1296 761 757 -257 -185 -440 -326 1267 168 1382 1271 1266 651 410 1177 948 760 843 378 592 945 325 -663 -600 -1426 -1351 -468 -470 -1004 -368 -1356 -444 -134 -94 -49 581 455 304 499 -349 527 -657 -577 209 -46 72 -715 -569 -390 -509 -972 -1518 -1939 -2018 -328 75 660 1140 800 517 316 400 515 476 552 -231 -261 -420 366 383 737 60 18 1470 962 253 372 -40 202 -50 350 -589 -421 -399 87 -222 -404 -161 -291 37 SS 20250227T134250.7Z 9189.571421 66 1 53.88 2 77.32 112.22 77.84 118.98 0.00 1 0.00 1 0 25 3.887e-01 7.977e-03 7.775e-02 9.412e-04 7.348911e-01 4.910549e-04 8.328307e-03 -6.000000e+00 2.215468e-01 225.42 -2.00 3.49 -2.00 320.44 0.00e+00 4.641374e-03 1.850243e-04 9.558318e-04 -6.000000e+00 9.711868e-03 275.50 -2.00 20.00 -2.00 319.95 0.00e+00 4.433 0.002 302.00 328.00 3 7.8980e-01 1.4598e-03 5.7456e-02 -6.0000e+00 5.4865e-01 6.8208e-02 1.9052e-03 3.8214e-02 -6.0000e+00 5.9652e-01 -9.7163e-02 1.9862e-03 2.1582e-02 -6.0000e+00 3.5417e-01 2.8456e-02 1.0012e-03 8.9926e-03 -6.0000e+00 1.5122e-01 1.4055e-03 -6.0686e-04 2.3838e-05 8.8169e-05 -6.0000e+00 1.0662e-02 1.1445e-02 0.0000e+00 11 8 0 10 0 0 87.46 24.71 0.25 0.01145 0.00689 331 37 1 5 0 162.770 33.75 19.98 24.71 7.28 2.5 1057.01 -173773 -68558 -62799 -138402 900000 -137791 -159496 72579 -177785 -76453 -111872 -116977 -72573 -84017 -35989 -58241 -45357 -48939 -28294 -40542 -43496 -16155 -36832 -24541 -40275 -22743 -9133 -17340 -11868 5574 -7356 -2902 507 -34515 56 -10237 -9771 -5080 -470 296 3442 -1679 -1471 -9667 289 2731 9064 4831 3908 2443 5198 3439 5244 5045 3652 2870 623 -386 -1037 -940 2965 1058 3936 2136 3124 932 1006 2453 1176 799 896 664 -50 937 -281 -658 -1528 -2407 -2311 -990 -849 -1190 -975 -1717 -1001 -397 -14 186 529 589 697 177 -123 565 -210 -241 431 -59 -206 -665 -618 -324 -404 -707 -1284 -1484 -1197 -207 214 694 632 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