File name: Pandora83s1_BondvilleIL_20250403_L2Fit_fwvt1c8d20241002p1-8.txt File generation date: 20250725T080737.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 83 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora83_OF_v3d20231115.txt Instrument calibration file used: Pandora83s1_CF_v8d20241002.txt Level 1 file used: Pandora83s1_BondvilleIL_20250403_L1_smca1c8d20241002p1-8.txt Full location name: Bondville, Illinois EPA Castnet Site Short location name: BondvilleIL Country of location: United States Location latitude [deg]: 40.0520 Location longitude [deg]: -88.3725 Location altitude [m]: 213 Local noon date: 20250403 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1623 1773 Nominal wavelengths inside fitting window [nm]: 492.0733 492.1940 492.3147 492.4354 492.5561 492.6767 492.7974 492.9180 493.0386 493.1592 493.2798 493.4003 493.5208 493.6414 493.7619 493.8824 494.0028 494.1233 494.2437 494.3642 494.4846 494.6050 494.7253 494.8457 494.9660 495.0863 495.2066 495.3269 495.4472 495.5675 495.6877 495.8079 495.9281 496.0483 496.1685 496.2886 496.4088 496.5289 496.6490 496.7691 496.8892 497.0092 497.1292 497.2493 497.3693 497.4893 497.6092 497.7292 497.8491 497.9690 498.0889 498.2088 498.3287 498.4485 498.5684 498.6882 498.8080 498.9278 499.0475 499.1673 499.2870 499.4067 499.5264 499.6461 499.7658 499.8854 500.0051 500.1247 500.2443 500.3639 500.4834 500.6030 500.7225 500.8420 500.9615 501.0810 501.2005 501.3199 501.4393 501.5588 501.6782 501.7975 501.9169 502.0362 502.1556 502.2749 502.3942 502.5134 502.6327 502.7519 502.8712 502.9904 503.1096 503.2288 503.3479 503.4670 503.5862 503.7053 503.8244 503.9434 504.0625 504.1815 504.3006 504.4196 504.5386 504.6575 504.7765 504.8954 505.0143 505.1332 505.2521 505.3710 505.4898 505.6087 505.7275 505.8463 505.9651 506.0838 506.2026 506.3213 506.4400 506.5587 506.6774 506.7961 506.9147 507.0334 507.1520 507.2706 507.3891 507.5077 507.6263 507.7448 507.8633 507.9818 508.1003 508.2187 508.3372 508.4556 508.5740 508.6924 508.8108 508.9291 509.0474 509.1658 509.2841 509.4024 509.5206 509.6389 509.7571 509.8753 509.9935 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250403T115130.6Z 9224.494104 51 1 17.18 2 87.45 84.94 110.14 17.44 0.00 1 0.00 1 0 22 2.793e-03 2.768e-03 4.258e-04 4.252e-04 1.023170e+04 2.862113e+01 6.687150e+02 -6.000000e+00 1.542187e+02 278.49 -2.00 20.00 -2.00 505.37 0.00e+00 1.709876e-03 1.170085e-05 1.123721e-04 -6.000000e+00 7.770708e-05 278.49 -2.00 20.00 -2.00 500.82 0.00e+00 1.274834e+00 8.322199e-03 8.047078e-02 -6.000000e+00 5.544201e-02 227.63 -2.00 3.49 -2.00 502.36 0.00e+00 14.668 0.057 489.00 513.00 1 2.7535e+00 6.3700e-04 2.3185e-02 -6.0000e+00 4.2508e-03 -1.8458e-02 1.5968e-04 2.2263e-03 -6.0000e+00 1.0925e-03 1.4155e-02 -1.3200e-04 4.1350e-05 8.6771e-05 -6.0000e+00 2.9249e-04 8.6024e-03 -9.2068e-05 12 1 1 12 1 1 77.87 24.80 1.39 0.00860 0.00769 45 16 1 4 0 373.280 33.50 19.99 24.80 11.45 2.5 1090.96 -509 -257 -223 176 408 558 798 790 752 765 391 419 196 148 -161 -62 -94 -194 -153 -121 -167 -45 66 45 207 193 -131 -213 -129 -401 -443 -213 -302 -286 -244 -231 -275 -76 -159 -201 -103 -51 117 201 259 270 324 127 0 -59 -360 -370 -381 -460 -281 -163 -143 40 40 374 311 393 428 403 352 362 265 -27 -14 -79 -135 -104 -133 -240 -230 -231 -335 -345 -309 -360 -541 -488 -452 -470 -329 -438 -501 -296 -256 -226 -105 -161 -225 -156 -89 -32 -100 -210 -207 -114 -181 156 89 100 289 290 286 525 513 303 137 51 -30 95 214 196 137 91 31 -42 43 163 27 87 53 -22 -3 86 118 106 5 -1 -56 50 34 -161 -68 -16 29 114 349 230 282 303 195 116 16 -55 -122 -216 -186 -469 -240 -211 169 396 545 791 778 741 759 384 406 191 143 -156 -60 -92 -190 -153 -121 -168 -46 67 46 208 195 -132 -216 -128 -394 -428 -206 -300 -289 -249 -234 -282 -77 -160 -201 -103 -51 118 205 267 279 333 130 0 -59 -356 -358 -371 -445 -279 -163 -145 41 40 382 314 399 436 411 357 369 266 -27 -14 -78 -133 -102 -132 -238 -230 -230 -329 -339 -300 -348 -525 -476 -445 -461 -326 -431 -496 -292 -252 -223 -104 -161 -225 -156 -89 -31 -97 -199 -195 -107 -171 146 85 96 285 292 287 522 508 301 139 51 -31 96 218 201 140 94 32 -43 44 164 27 88 54 -22 -3 88 120 108 5 -1 -56 50 34 -161 -70 -16 30 119 367 241 298 321 207 122 17 -58 -125 -221 -191 SQ 20250403T115548.7Z 9224.497091 54 1 53.95 2 86.63 85.63 109.90 18.36 0.00 1 0.00 1 0 22 2.706e-03 2.689e-03 9.101e-05 9.090e-05 8.672951e+03 6.009886e+00 5.629437e+02 -6.000000e+00 1.493926e+02 278.49 -2.00 20.00 -2.00 505.36 0.00e+00 1.516880e-03 2.499239e-06 1.004878e-04 -6.000000e+00 7.527064e-05 278.49 -2.00 20.00 -2.00 500.79 0.00e+00 1.159229e+00 1.780369e-03 7.083333e-02 -6.000000e+00 5.369069e-02 227.63 -2.00 3.49 -2.00 502.33 0.00e+00 12.737 0.037 489.00 513.00 1 1.1288e+00 1.3631e-04 1.9632e-02 -6.0000e+00 4.1167e-03 -1.9452e-02 3.4274e-05 1.9130e-03 -6.0000e+00 1.0577e-03 9.5349e-02 -5.6496e-04 8.9459e-06 7.4062e-05 -6.0000e+00 2.8327e-04 8.3276e-03 -7.0848e-05 10 0 0 10 0 0 87.67 24.78 1.23 0.00833 0.00441 946 106 1 4 0 57.020 33.75 19.99 24.78 11.70 2.5 1092.42 -412 -296 -211 141 414 571 771 689 785 699 468 366 223 90 -44 -82 -124 -209 -120 -131 -171 -17 44 34 167 160 -108 -195 -97 -308 -387 -176 -280 -311 -252 -251 -273 -154 -151 -183 -130 -17 66 134 193 251 275 144 -20 -141 -301 -355 -313 -395 -269 -191 -122 -13 164 341 384 409 388 343 346 348 243 18 -1 -15 -99 -86 -109 -229 -240 -260 -320 -380 -311 -368 -548 -508 -441 -419 -406 -422 -427 -334 -266 -219 -136 -235 -264 -188 -144 -90 -82 -222 -178 -134 -84 110 140 214 295 274 352 531 499 346 165 -12 -33 53 196 201 161 81 41 -26 37 145 77 46 67 -30 40 170 76 5 62 -15 -84 49 12 -93 -47 -18 22 187 227 237 290 292 189 50 -8 -55 -76 -130 -186 -381 -279 -199 136 404 561 770 686 781 699 463 357 218 87 -43 -79 -121 -207 -120 -132 -173 -17 44 34 170 164 -110 -197 -97 -304 -376 -171 -275 -313 -257 -258 -280 -156 -152 -185 -132 -17 67 136 199 259 282 146 -21 -142 -299 -345 -305 -383 -264 -191 -123 -14 167 347 392 415 396 349 350 353 243 18 -1 -15 -97 -85 -108 -229 -239 -258 -316 -371 -303 -357 -534 -492 -431 -414 -401 -420 -422 -334 -265 -219 -135 -236 -265 -188 -144 -89 -79 -214 -169 -125 -79 104 133 208 292 273 350 528 493 344 165 -12 -34 54 199 205 167 83 42 -27 37 147 77 46 67 -30 40 171 77 5 63 -15 -83 49 12 -93 -48 -19 22 194 235 247 305 305 198 52 -8 -56 -77 -134 -190 SQ 20250403T120603.3Z 9224.504205 57 1 28.42 2 84.67 87.26 109.27 20.54 0.00 1 0.00 1 0 22 2.456e-03 2.451e-03 1.100e-04 1.099e-04 6.178222e+03 7.031536e+00 3.962679e+02 -6.000000e+00 1.356256e+02 278.49 -2.00 20.00 -2.00 505.33 0.00e+00 1.192206e-03 3.013276e-06 7.934550e-05 -6.000000e+00 6.833246e-05 278.49 -2.00 20.00 -2.00 500.68 0.00e+00 9.366516e-01 2.158575e-03 5.422839e-02 -6.000000e+00 4.873802e-02 227.63 -2.00 3.49 -2.00 502.24 0.00e+00 9.373 0.015 489.00 513.00 1 1.3627e+00 1.6534e-04 1.4140e-02 -6.0000e+00 3.7370e-03 -9.8069e-03 4.1820e-05 1.4068e-03 -6.0000e+00 9.6000e-04 1.2357e-01 -6.7533e-04 1.0986e-05 5.2878e-05 -6.0000e+00 2.5714e-04 9.5319e-03 -7.1743e-05 10 0 0 10 0 0 91.77 24.76 0.87 0.00953 0.00485 634 71 1 4 0 44.820 33.75 20.02 24.76 12.11 2.4 1095.10 -362 -283 -250 102 289 476 649 587 657 652 417 356 194 93 -45 -65 -96 -208 -138 -169 -210 -53 26 20 168 113 -140 -204 -70 -257 -280 -90 -225 -270 -238 -262 -281 -146 -133 -156 -89 13 70 130 187 210 254 106 -34 -112 -229 -250 -208 -282 -183 -174 -124 -46 137 309 331 374 335 310 308 337 225 73 63 33 -27 -24 -51 -210 -205 -228 -280 -340 -244 -292 -489 -428 -382 -377 -364 -392 -396 -320 -289 -220 -169 -279 -302 -242 -210 -165 -140 -230 -107 -25 37 279 260 295 339 284 349 554 518 382 190 15 -39 6 120 106 59 6 -17 -29 9 127 45 16 8 -85 2 146 38 -35 32 -55 -92 29 40 -55 -60 -30 -15 152 221 247 281 264 126 -4 -18 -42 -24 -75 -142 -342 -272 -241 101 287 478 654 597 667 656 419 353 193 92 -44 -64 -95 -208 -140 -174 -215 -54 27 20 173 116 -144 -208 -71 -255 -277 -89 -225 -273 -243 -271 -290 -149 -136 -158 -90 14 71 134 193 217 260 109 -35 -112 -226 -244 -203 -274 -180 -174 -125 -47 139 316 335 380 342 316 312 342 225 73 63 33 -26 -24 -50 -208 -203 -228 -276 -333 -236 -282 -474 -418 -371 -371 -357 -389 -394 -318 -287 -219 -168 -279 -303 -243 -209 -162 -138 -222 -102 -23 34 264 248 289 335 284 348 545 512 379 189 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