File name: Pandora83s1_BondvilleIL_20250421_L2Fit_fout2c8d20241002p1-8.txt
File generation date: 20250725T081905.9Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c8p1-8
Local principal investigator: Alexander Cede
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 83
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora83_OF_v3d20231115.txt
Instrument calibration file used: Pandora83s1_CF_v8d20241002.txt
Level 1 file used: Pandora83s1_BondvilleIL_20250421_L1_smca1c8d20241002p1-8.txt
Full location name: Bondville, Illinois EPA Castnet Site
Short location name: BondvilleIL
Country of location: United States
Location latitude [deg]: 40.0520
Location longitude [deg]: -88.3725
Location altitude [m]: 213
Local noon date: 20250421
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 199 341
Nominal wavelengths inside fitting window [nm]: 305.0376 305.1782 305.3189 305.4595 305.6001 305.7407 305.8813 306.0219 306.1625 306.3031 306.4436 306.5841 306.7247 306.8652 307.0057 307.1462 307.2867 307.4271 307.5676 307.7081 307.8485 307.9889 308.1293 308.2697 308.4101 308.5505 308.6909 308.8312 308.9716 309.1119 309.2522 309.3925 309.5328 309.6731 309.8134 309.9537 310.0939 310.2342 310.3744 310.5146 310.6548 310.7950 310.9352 311.0754 311.2155 311.3557 311.4958 311.6359 311.7761 311.9162 312.0563 312.1963 312.3364 312.4765 312.6165 312.7565 312.8966 313.0366 313.1766 313.3166 313.4565 313.5965 313.7365 313.8764 314.0163 314.1563 314.2962 314.4361 314.5760 314.7158 314.8557 314.9955 315.1354 315.2752 315.4150 315.5548 315.6946 315.8344 315.9742 316.1139 316.2537 316.3934 316.5331 316.6728 316.8125 316.9522 317.0919 317.2316 317.3712 317.5109 317.6505 317.7901 317.9297 318.0693 318.2089 318.3485 318.4880 318.6276 318.7671 318.9066 319.0462 319.1857 319.3251 319.4646 319.6041 319.7435 319.8830 320.0224 320.1618 320.3013 320.4407 320.5800 320.7194 320.8588 320.9981 321.1375 321.2768 321.4161 321.5554 321.6947 321.8340 321.9733 322.1125 322.2518 322.3910 322.5302 322.6694 322.8086 322.9478 323.0870 323.2262 323.3653 323.5045 323.6436 323.7827 323.9218 324.0609 324.2000 324.3391 324.4781 324.6172 324.7562 324.8952
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20250421T191444.8Z 9242.801907 441 1 1.34 2 33.32 218.89 108.78 257.08 0.00 1 0.00 1 0 17 8.154e-03 6.618e-03 4.720e-03 3.488e-03 1.747348e-01 1.809347e-03 2.142310e-03 -6.000000e+00 4.707499e-03 229.07 -2.00 3.49 -2.00 314.53 0.00e+00 6.625865e-04 1.410578e-04 2.853073e-05 -6.000000e+00 2.044158e-04 280.46 -2.00 20.00 -2.00 314.02 0.00e+00 1.196 0.000 302.00 328.00 3 3.1910e+00 4.6320e-03 1.4819e-02 -6.0000e+00 1.1744e-02 2.8371e-02 5.1268e-03 9.0317e-03 -6.0000e+00 1.2723e-02 -1.7880e-03 2.9360e-03 4.4126e-03 -6.0000e+00 7.5589e-03 -3.8692e-03 1.2828e-03 1.3097e-03 -6.0000e+00 3.2145e-03 5.6283e-03 -9.9333e-05 9.8012e-05 1.6895e-05 -6.0000e+00 2.2135e-04 1.1319e-02 0.0000e+00 12 9 1 12 1 1 999.00 24.85 0.30 0.01132 0.01057 2 14 1 5 0 443.380 33.75 19.98 24.85 18.40 2.2 1100.00 -1260 -777 -1431 -2277 -1155 538 1280 1797 -50 -64 199 345 1754 -471 514 728 -197 358 783 67 578 -717 1375 156 630 -254 -24 -835 -469 -582 2247 1962 1429 -687 -2351 -1339 -926 -248 -345 -900 -1147 -1117 -820 -1461 -582 -1061 -350 213 304 725 1377 -197 846 1232 1217 968 1436 363 791 841 1252 973 967 808 -307 -209 -617 -265 -12 766 -167 259 -621 -419 42 -38 -767 -136 315 -437 -629 -1244 -1569 -1550 -981 -421 -47 -308 161 681 76 289 286 401 77 652 236 -517 -449 -461 -331 -506 321 -251 -815 -779 -930 366 10 957 1193 219 373 556 349 667 4 544 256 -390 -493 56 -563 -315 701 -100 579 451 601 139 -143 -197 36 118 -229 65 152 -131 356 99 -557 -594 -200 -474 -315 -590 -884 -418 191 435 676 -20 -26 81 139 751 -218 249 381 -107 197 418 37 324 -402 758 90 381 -152 -14 -493 -269 -319 1223 1136 839 -421 -1379 -745 -545 -159 -240 -699 -935 -913 -684 -1236 -486 -884 -295 171 246 575 1117 -165 708 1071 1085 878 1315 322 714 752 1142 909 937 800 -307 -200 -558 -235 -11 751 -170 274 -646 -438 43 -36 -687 -116 270 -399 -620 -1304 -1698 -1694 -1094 -486 -57 -380 198 841 88 324 299 408 80 708 274 -622 -560 -576 -402 -586 359 -288 -979 -968 -1171 474 13 1269 1653 302 512 729 444 810 5 667 325 -521 -667 76 -746 -414 894 -122 684 539 721 173 -187 -255 48 158 -314 91 215 -190 519 144 -813 -837 -281
SS 20250421T195319.6Z 9242.828699 469 1 53.95 2 38.60 232.25 115.68 262.69 0.00 1 0.00 1 0 17 7.644e-03 5.799e-03 5.040e-04 3.203e-04 1.849907e-01 1.647752e-04 2.250145e-03 -6.000000e+00 4.413085e-03 229.07 -2.00 3.49 -2.00 315.27 0.00e+00 2.898744e-04 1.473235e-05 4.200726e-05 -6.000000e+00 1.916199e-04 280.46 -2.00 20.00 -2.00 314.68 0.00e+00 1.278 0.000 302.00 328.00 3 2.2816e+00 4.2490e-04 1.5756e-02 -6.0000e+00 1.1010e-02 1.9643e-02 4.7229e-04 9.4854e-03 -6.0000e+00 1.1927e-02 -3.9841e-03 2.7026e-04 4.6561e-03 -6.0000e+00 7.0861e-03 -2.5948e-03 1.2070e-04 1.3070e-03 -6.0000e+00 3.0137e-03 1.2721e-02 5.3804e-05 9.0701e-06 1.6528e-05 -6.0000e+00 2.0749e-04 1.0819e-02 0.0000e+00 10 0 0 10 0 0 100.00 24.84 0.16 0.01082 0.01122 2423 272 1 5 0 22.260 33.75 20.00 24.84 19.22 2.2 1100.00 -468 -1186 -2008 -2493 -2126 -1110 379 795 461 -707 -907 -643 184 154 566 -120 160 397 1020 1042 852 738 1311 1118 386 63 -324 -381 -101 864 1268 1734 712 -998 -1868 -1465 -966 -288 -339 -594 -826 -986 -1085 -794 -574 -665 -488 -413 -347 442 1072 1137 1152 1192 1117 1034 815 732 598 700 1042 1065 1169 723 -122 -522 -481 178 598 371 -94 -84 -11 -72 -4 -270 -394 -337 -255 -492 -841 -1367 -1645 -1310 -911 -512 -403 -188 42 230 220 219 381 666 473 139 273 97 -221 -686 -761 -622 -371 -204 -690 -830 -688 -82 369 708 714 545 411 393 409 637 517 417 213 15 -386 -92 -162 239 258 252 497 815 469 137 -105 -93 -129 93 -80 -103 -76 31 -86 -220 -313 -335 -314 -141 -358 -618 -786 -591 -285 99 232 150 -223 -306 -216 61 57 235 -54 69 173 456 479 400 343 609 542 198 34 -172 -190 -46 408 610 815 360 -527 -936 -701 -489 -168 -219 -417 -637 -796 -841 -619 -444 -546 -391 -318 -258 321 799 900 960 972 936 882 707 635 509 590 896 973 1083 712 -122 -483 -428 149 518 362 -95 -90 -11 -76 -4 -256 -334 -283 -216 -431 -827 -1401 -1806 -1415 -1043 -594 -496 -239 54 287 256 244 404 663 484 155 317 118 -288 -899 -944 -747 -418 -234 -813 -1048 -906 -106 495 999 1006 782 571 534 534 811 642 508 278 21 -541 -129 -222 313 339 315 616 983 591 175 -141 -128 -180 127 -115 -148 -113 48 -133 -338 -468 -483 -462
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