File name: Pandora83s1_BondvilleIL_20250423_L2Fit_fout2c8d20241002p1-8.txt File generation date: 20250725T082444.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 83 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora83_OF_v3d20231115.txt Instrument calibration file used: Pandora83s1_CF_v8d20241002.txt Level 1 file used: Pandora83s1_BondvilleIL_20250423_L1_smca1c8d20241002p1-8.txt Full location name: Bondville, Illinois EPA Castnet Site Short location name: BondvilleIL Country of location: United States Location latitude [deg]: 40.0520 Location longitude [deg]: -88.3725 Location altitude [m]: 213 Local noon date: 20250423 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 199 341 Nominal wavelengths inside fitting window [nm]: 305.0376 305.1782 305.3189 305.4595 305.6001 305.7407 305.8813 306.0219 306.1625 306.3031 306.4436 306.5841 306.7247 306.8652 307.0057 307.1462 307.2867 307.4271 307.5676 307.7081 307.8485 307.9889 308.1293 308.2697 308.4101 308.5505 308.6909 308.8312 308.9716 309.1119 309.2522 309.3925 309.5328 309.6731 309.8134 309.9537 310.0939 310.2342 310.3744 310.5146 310.6548 310.7950 310.9352 311.0754 311.2155 311.3557 311.4958 311.6359 311.7761 311.9162 312.0563 312.1963 312.3364 312.4765 312.6165 312.7565 312.8966 313.0366 313.1766 313.3166 313.4565 313.5965 313.7365 313.8764 314.0163 314.1563 314.2962 314.4361 314.5760 314.7158 314.8557 314.9955 315.1354 315.2752 315.4150 315.5548 315.6946 315.8344 315.9742 316.1139 316.2537 316.3934 316.5331 316.6728 316.8125 316.9522 317.0919 317.2316 317.3712 317.5109 317.6505 317.7901 317.9297 318.0693 318.2089 318.3485 318.4880 318.6276 318.7671 318.9066 319.0462 319.1857 319.3251 319.4646 319.6041 319.7435 319.8830 320.0224 320.1618 320.3013 320.4407 320.5800 320.7194 320.8588 320.9981 321.1375 321.2768 321.4161 321.5554 321.6947 321.8340 321.9733 322.1125 322.2518 322.3910 322.5302 322.6694 322.8086 322.9478 323.0870 323.2262 323.3653 323.5045 323.6436 323.7827 323.9218 324.0609 324.2000 324.3391 324.4781 324.6172 324.7562 324.8952 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250423T121048.8Z 9244.507509 122 1 5.93 2 78.26 83.17 60.02 144.52 0.00 1 0.00 1 0 25 4.135e-01 1.425e-02 3.094e-01 8.576e-03 6.924670e-01 4.657361e-03 7.871370e-03 -6.000000e+00 2.410979e-01 229.21 -2.00 3.49 -2.00 320.79 0.00e+00 4.786018e-03 1.983007e-03 1.121512e-03 -6.000000e+00 1.209187e-02 280.65 -2.00 20.00 -2.00 320.24 0.00e+00 4.759 0.002 302.00 328.00 3 2.2707e+00 1.4672e-02 5.9253e-02 -6.0000e+00 6.0057e-01 1.1423e-01 1.9642e-02 3.6988e-02 -6.0000e+00 6.5186e-01 -1.5086e-01 2.0001e-02 2.0380e-02 -6.0000e+00 3.8696e-01 5.3367e-02 9.7943e-03 7.8984e-03 -6.0000e+00 1.6520e-01 2.4092e-04 -7.7584e-04 2.3161e-04 8.4533e-05 -6.0000e+00 1.1445e-02 1.3011e-02 0.0000e+00 12 9 9 12 1 1 -306.31 24.78 0.14 0.01301 0.00718 5 6 1 5 0 988.190 33.75 19.98 24.78 16.99 2.3 1100.00 -158725 900000 39576 -186266 900000 -12449 -190721 -22414 -10214 900000 -106210 -166605 900000 28788 94828 900000 4447 -107353 -32844 -73637 -5851 28006 31432 -33201 -66624 900000 900000 -18391 -8455 193957 13979 31136 -11177 -35094 45030 -30824 -23156 -9125 -18576 3153 10006 -2472 -14604 1338 322 6176 32697 23925 11131 555 1428 -6208 3573 17360 4712 -1442 409 6988 -1650 152 -10243 -1856 11538 3122 10917 -408 2801 10965 -377 1479 2277 1257 281 3407 5228 1444 1035 -325 -4921 1077 398 -2265 -391 -3059 -2138 -1208 -978 -677 1041 791 1409 -2405 193 4334 -458 -2160 -320 -310 9 -1299 -1143 893 -2006 -1896 -1236 -1732 -881 -91 29 1388 903 743 205 187 906 465 604 -312 -171 -17 -848 61 -199 -329 692 -322 2149 522 -179 144 772 161 1220 -145 -728 272 -312 -490 1 405 -726 -213 -103 -1326 900000 331 -2687 900000 -104 -2752 -187 -85 900000 -1065 -3479 900000 240 792 900000 52 -4304 -686 -2460 -103 351 394 -860 -2616 900000 900000 -476 -198 1620 339 780 -504 -2198 1241 -1777 -1335 -541 -1490 245 827 -252 -1781 144 36 665 2786 2318 1292 77 218 -1156 668 3089 1015 -346 99 1594 -400 35 -2712 -495 3074 936 3266 -136 889 3618 -139 617 1051 619 139 1555 2148 553 367 -117 -2051 502 221 -1489 -256 -2202 -1622 -969 -827 -591 895 662 1100 -1820 135 2968 -365 -2031 -318 -354 11 -1585 -1425 982 -2046 -1891 -1301 -1954 -1037 -113 37 1938 1321 1173 332 295 1348 710 913 -461 -267 -28 -1401 97 -302 -517 1038 -469 2937 737 -283 243 1345 302 2390 -288 -1554 608 -683 -1092 3 923 -1577 -430 -209 SS 20250423T121519.9Z 9244.510647 125 1 23.14 2 77.40 83.87 59.52 145.63 0.00 1 0.00 1 0 25 3.100e-01 9.699e-03 1.579e-01 3.118e-03 6.475029e-01 1.672720e-03 7.434284e-03 -6.000000e+00 1.805678e-01 229.21 -2.00 3.49 -2.00 320.50 0.00e+00 4.216568e-03 6.509453e-04 1.478290e-03 -6.000000e+00 8.240016e-03 280.65 -2.00 20.00 -2.00 319.94 0.00e+00 4.458 0.002 302.00 328.00 3 2.1807e+00 5.0944e-03 5.5516e-02 -6.0000e+00 4.5192e-01 5.8215e-02 6.5633e-03 3.4587e-02 -6.0000e+00 4.9035e-01 -8.3623e-02 6.4719e-03 1.9169e-02 -6.0000e+00 2.8910e-01 2.4253e-02 3.2343e-03 7.3797e-03 -6.0000e+00 1.2322e-01 3.7120e-04 -3.4770e-04 8.4983e-05 8.4517e-05 -6.0000e+00 8.6432e-03 1.4769e-02 0.0000e+00 12 9 9 12 1 1 99.83 24.79 0.34 0.01477 0.01216 35 9 1 5 0 642.580 33.75 19.99 24.79 17.29 2.3 1100.00 -162741 900000 130201 19320 900000 -60080 -93633 900000 -163293 900000 -64748 -58614 -59514 -108977 54167 -10324 -53408 -56882 8841 -31477 -48991 4905 -26839 -43239 -43421 23960 19591 -735 903 39904 9340 -1316 2267 -9152 7122 -5392 -10755 -8772 -5695 -2917 7635 -3848 -8088 -3811 -1810 4354 16028 3492 7421 -1219 2834 766 1978 8162 3140 4853 -1747 103 -2647 -4104 7193 3360 6251 1580 4302 -924 -787 2700 1362 602 1648 1458 -905 2417 1339 -1913 -295 -2277 -3880 -1259 -85 -1533 -255 -1954 -1404 -639 141 1016 438 219 589 93 -285 1675 -123 -1141 665 -525 -422 -1489 -480 -29 -815 -555 -1108 -1850 -1395 -289 727 543 1039 965 147 560 165 759 278 191 -314 -378 -260 342 -147 281 -137 133 843 339 -73 198 362 -48 -157 240 -278 126 -85 8 -39 -251 -251 -22 -80 -1933 900000 396 59 900000 -329 -768 900000 -3473 900000 -590 -570 -741 -2914 362 -160 -1460 -1797 158 -899 -1727 101 -791 -1629 -1781 531 464 -21 25 812 306 -58 114 -559 361 -305 -696 -661 -512 -307 821 -504 -1170 -547 -260 603 2031 520 1114 -213 528 164 462 1949 763 1212 -481 28 -719 -1112 1967 950 1956 586 1661 -372 -309 1046 585 300 831 776 -492 1319 679 -900 -126 -989 -1887 -705 -51 -1066 -193 -1483 -1128 -544 126 931 404 197 494 73 -231 1349 -103 -1112 685 -628 -519 -1891 -571 -33 -852 -571 -1221 -2190 -1730 -352 953 797 1581 1572 244 900 252 1096 401 285 -500 -633 -437 553 -228 421 -212 198 1192 490 -111 338 642 -91 -296 478 -563 268 -187 17 -88 -549 -520 -44 -157 SS 20250423T122013.5Z 9244.514046 128 1 53.89 2 76.47 84.64 58.99 146.84 0.00 1 0.00 1 0 25 2.654e-01 6.241e-03 8.975e-02 9.183e-04 6.140010e-01 4.767057e-04 7.043364e-03 -6.000000e+00 1.532496e-01 229.21 -2.00 3.49 -2.00 319.94 0.00e+00 3.554751e-03 1.553525e-04 9.638971e-04 -6.000000e+00 6.658655e-03 280.65 -2.00 20.00 -2.00 319.33 0.00e+00 4.171 0.001 302.00 328.00 3 1.0820e+00 1.3843e-03 5.1964e-02 -6.0000e+00 3.8242e-01 3.7424e-02 1.6897e-03 3.2127e-02 -6.0000e+00 4.1428e-01 -5.5737e-02 1.5421e-03 1.7111e-02 -6.0000e+00 2.4613e-01 1.1649e-02 7.9883e-04 6.4499e-03 -6.0000e+00 1.0461e-01 1.5108e-03 -2.8802e-04 2.4402e-05 6.5597e-05 -6.0000e+00 7.2054e-03 1.3935e-02 0.0000e+00 10 0 0 10 0 0 60.08 24.80 0.26 0.01393 0.01177 269 30 1 5 0 200.320 33.75 20.00 24.80 17.68 2.3 1100.00 -96596 -21810 -64659 -28040 216295 -60810 -80138 -56428 -88789 -7651 -50554 -59993 -36252 -45648 -11217 -20630 -22924 -25538 -10332 -15136 -13963 -7844 -9838 -15723 -14890 -3944 -5862 -10742 -7503 3002 -1778 483 1376 -1069 -2149 -6148 -3371 -2978 -2006 -119 275 -2316 -2728 12396 -1416 499 2699 172 1337 603 1000 676 1692 2885 2036 1362 -823 -106 -1181 -1023 1567 1141 2935 1966 1490 456 336 1314 913 601 760 504 -148 547 226 -453 -770 -1797 -1567 -663 -904 -1169 -935 -1246 -893 -342 19 212 539 548 705 285 274 624 -253 -451 259 52 -255 -586 -699 -472 -567 -389 -1107 -1339 -1016 -127 395 735 631 533 262 244 275 594 518 421 20 -118 -308 55 -112 150 -70 -70 641 510 190 32 -134 -46 -147 84 -180 -142 -69 130 2 -148 -205 -43 44 -1168 -148 -735 -218 194 -594 -1019 -647 -1598 -66 -711 -1042 -623 -1116 -246 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