File name: Pandora83s1_BondvilleIL_20250508_L2Fit_fout2c8d20241002p1-8.txt File generation date: 20250725T083429.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 83 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora83_OF_v3d20231115.txt Instrument calibration file used: Pandora83s1_CF_v8d20241002.txt Level 1 file used: Pandora83s1_BondvilleIL_20250508_L1_smca1c8d20241002p1-8.txt Full location name: Bondville, Illinois EPA Castnet Site Short location name: BondvilleIL Country of location: United States Location latitude [deg]: 40.0520 Location longitude [deg]: -88.3725 Location altitude [m]: 213 Local noon date: 20250508 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 199 341 Nominal wavelengths inside fitting window [nm]: 305.0376 305.1782 305.3189 305.4595 305.6001 305.7407 305.8813 306.0219 306.1625 306.3031 306.4436 306.5841 306.7247 306.8652 307.0057 307.1462 307.2867 307.4271 307.5676 307.7081 307.8485 307.9889 308.1293 308.2697 308.4101 308.5505 308.6909 308.8312 308.9716 309.1119 309.2522 309.3925 309.5328 309.6731 309.8134 309.9537 310.0939 310.2342 310.3744 310.5146 310.6548 310.7950 310.9352 311.0754 311.2155 311.3557 311.4958 311.6359 311.7761 311.9162 312.0563 312.1963 312.3364 312.4765 312.6165 312.7565 312.8966 313.0366 313.1766 313.3166 313.4565 313.5965 313.7365 313.8764 314.0163 314.1563 314.2962 314.4361 314.5760 314.7158 314.8557 314.9955 315.1354 315.2752 315.4150 315.5548 315.6946 315.8344 315.9742 316.1139 316.2537 316.3934 316.5331 316.6728 316.8125 316.9522 317.0919 317.2316 317.3712 317.5109 317.6505 317.7901 317.9297 318.0693 318.2089 318.3485 318.4880 318.6276 318.7671 318.9066 319.0462 319.1857 319.3251 319.4646 319.6041 319.7435 319.8830 320.0224 320.1618 320.3013 320.4407 320.5800 320.7194 320.8588 320.9981 321.1375 321.2768 321.4161 321.5554 321.6947 321.8340 321.9733 322.1125 322.2518 322.3910 322.5302 322.6694 322.8086 322.9478 323.0870 323.2262 323.3653 323.5045 323.6436 323.7827 323.9218 324.0609 324.2000 324.3391 324.4781 324.6172 324.7562 324.8952 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250508T123951.7Z 9259.527681 202 1 53.73 2 69.60 84.23 131.36 312.33 0.00 1 0.00 1 0 17 8.619e-02 6.310e-03 1.293e-02 1.117e-03 4.487542e-01 5.729988e-04 5.258211e-03 -6.000000e+00 4.999574e-02 230.44 -2.00 3.49 -2.00 318.71 0.00e+00 1.220037e-03 1.248647e-04 5.036083e-04 -6.000000e+00 2.177518e-03 282.31 -2.00 20.00 -2.00 318.01 0.00e+00 2.840 0.000 302.00 328.00 3 2.8916e+00 1.5699e-03 3.6484e-02 -6.0000e+00 1.2506e-01 9.8462e-03 1.7954e-03 2.3338e-02 -6.0000e+00 1.3531e-01 -2.2401e-02 1.2809e-03 1.1542e-02 -6.0000e+00 8.0393e-02 2.3001e-03 6.7819e-04 3.3697e-03 -6.0000e+00 3.4132e-02 1.0358e-03 -2.1322e-04 3.1224e-05 3.5510e-05 -6.0000e+00 2.3408e-03 1.4252e-02 0.0000e+00 10 0 0 10 0 0 98.73 24.78 0.18 0.01425 0.01265 84 9 1 5 0 639.580 33.75 19.99 24.78 15.81 2.3 1100.00 -25988 6192 -12858 -2151 83111 -8516 -20917 10731 -27915 4149 -14904 -13317 -4534 -10256 2322 -1049 -5564 -7869 -816 -3724 -5877 2805 -1317 -4557 -6590 1456 1672 -1751 -962 3774 1948 2604 1020 -1336 -767 -3735 -3626 -1591 -791 -39 1148 -1324 -2320 -1897 -209 -245 2205 465 1002 490 1230 536 1649 2366 1418 1219 277 556 -204 275 2471 1006 2466 1010 960 -468 -65 1151 1112 222 331 82 1 320 507 -101 -640 -1325 -829 -640 -1242 -1422 -1144 -1798 -1154 -446 -373 203 196 227 423 -41 105 1173 78 -42 222 34 -139 -829 -858 -438 -610 -536 -838 -1140 -984 68 454 783 664 510 345 343 320 657 547 418 89 -130 -271 185 -13 178 15 -5 616 394 279 38 -27 -10 -198 176 -97 43 -135 60 14 -194 -310 -164 -166 -852 169 -448 -65 978 -241 -716 305 -1323 153 -684 -644 -237 -693 166 -90 -546 -850 -88 -433 -720 315 -159 -610 -883 190 220 -252 -132 502 293 405 182 -258 -142 -695 -728 -369 -222 -12 386 -487 -899 -748 -82 -97 853 183 398 202 542 242 795 1213 771 688 151 302 -117 155 1398 579 1554 662 654 -311 -43 755 782 168 260 68 1 255 399 -72 -447 -900 -594 -489 -1033 -1334 -1098 -1836 -1176 -484 -428 227 220 261 456 -43 103 1113 80 -46 259 42 -190 -1098 -1129 -549 -706 -620 -1044 -1443 -1304 94 634 1134 1044 803 540 535 465 938 770 611 132 -206 -438 292 -19 262 21 -7 866 554 404 58 -42 -16 -341 302 -177 80 -259 113 27 -374 -572 -298 -290 SS 20250508T130032.3Z 9259.542041 208 1 53.86 2 65.66 87.43 134.12 317.97 0.00 1 0.00 1 0 17 1.564e-01 2.522e-02 2.975e-02 2.806e-03 3.864700e-01 1.447901e-03 4.531319e-03 -6.000000e+00 9.081907e-02 230.44 -2.00 3.49 -2.00 318.68 0.00e+00 -4.054814e-03 3.080110e-04 4.392227e-04 -6.000000e+00 4.020685e-03 282.31 -2.00 20.00 -2.00 317.95 0.00e+00 2.409 0.000 302.00 328.00 3 4.8918e+00 3.9607e-03 3.1337e-02 -6.0000e+00 2.2704e-01 2.6822e-02 4.5277e-03 2.1130e-02 -6.0000e+00 2.4569e-01 -3.5531e-02 3.1528e-03 1.0028e-02 -6.0000e+00 1.4589e-01 1.1389e-02 1.6579e-03 4.7230e-03 -6.0000e+00 6.1964e-02 2.3008e-04 -2.7027e-04 8.1096e-05 3.9653e-05 -6.0000e+00 4.2945e-03 1.5387e-02 0.0000e+00 12 9 8 11 8 0 99.77 24.76 -0.49 0.01539 0.01336 16 2 1 5 0 3365.820 33.75 20.02 24.76 16.72 2.3 1100.00 -33330 74466 9294 24394 900000 14278 -5277 119148 -4919 68885 11867 10289 19757 -13905 32297 5310 -5569 -7596 3683 -9461 -4077 14316 1155 -444 -3239 17275 16309 6362 17423 23613 15773 8450 9514 796 2783 -4306 -1787 -3438 7575 4470 10009 4349 -892 -40547 732 1841 7314 1759 1724 1376 1525 -2239 1709 4916 4306 4936 78 5061 2299 806 8435 988 4584 484 1406 -2374 -343 2078 2835 -277 699 1129 337 3329 3500 715 -663 -1504 -2950 -343 -2651 -2233 27 -2740 -2498 575 -195 724 -411 -290 595 -672 319 4658 -206 -255 1158 -1443 -248 -1332 -1112 919 -1135 -1291 127 -1419 -1917 366 74 642 1049 646 -120 -215 260 765 370 385 -442 -339 35 530 -209 336 -335 -316 2247 -612 107 326 498 -30 -283 941 -380 521 -302 -346 35 540 -722 -483 -227 -1733 1467 364 781 900000 441 -215 1630 -268 1941 604 555 1092 -1252 2121 511 -638 -935 426 -1302 -547 1602 153 -65 -535 2467 2365 963 2198 2746 2119 1360 1674 160 526 -851 -372 -861 2081 1372 3254 1589 -354 -24105 286 709 2633 660 645 527 623 -1035 818 2432 2250 2661 45 2818 1286 448 4406 594 2915 319 941 -1568 -227 1316 1900 -200 553 937 284 2618 2559 529 -449 -977 -2031 -261 -2156 -2025 26 -2863 -2559 613 -222 844 -487 -333 632 -719 312 4237 -208 -265 1331 -1901 -324 -1775 -1505 1111 -1299 -1489 155 -1881 -2485 486 105 974 1702 1020 -189 -342 383 1048 499 538 -662 -539 57 846 -325 502 -481 -434 3071 -854 147 490 802 -51 -458 1568 -680 977 -589 -645 65 1055 -1367 -868 -393 SS 20250508T131333.6Z 9259.551083 217 1 53.37 2 63.16 89.50 135.71 321.79 0.00 1 0.00 1 0 17 4.088e-02 7.686e-03 8.849e-03 1.689e-03 3.509512e-01 8.622582e-04 4.168771e-03 -6.000000e+00 2.371553e-02 230.44 -2.00 3.49 -2.00 318.02 0.00e+00 1.111858e-03 1.519891e-04 2.680905e-04 -6.000000e+00 1.032865e-03 282.32 -2.00 20.00 -2.00 317.31 0.00e+00 2.203 0.000 302.00 328.00 3 4.3063e+00 2.3170e-03 2.8409e-02 -6.0000e+00 5.9322e-02 2.2366e-02 2.6154e-03 1.8225e-02 -6.0000e+00 6.4186e-02 -8.3712e-03 1.6825e-03 8.9677e-03 -6.0000e+00 3.8134e-02 -3.2778e-03 8.6881e-04 2.6211e-03 -6.0000e+00 1.6192e-02 5.1792e-04 -1.7032e-04 4.8024e-05 2.8085e-05 -6.0000e+00 1.1103e-03 1.3876e-02 0.0000e+00 11 9 0 11 32 0 99.88 24.78 0.13 0.01388 0.01260 28 3 1 5 0 1905.770 33.75 19.99 24.78 17.07 2.3 1100.00 -12522 15192 949 7755 -16431 -2598 -5689 29924 -7403 -7871 -1990 -5274 364 -7377 8623 1109 -2941 -3762 931 -3638 -3411 3653 4156 -3177 -3733 1346 2165 -658 1767 6840 2898 3229 3802 -5504 445 -3369 -2260 -2664 615 -420 764 -2071 -2610 -565 -1586 -2188 -1247 -29 965 989 1412 433 694 2462 2104 1638 -407 998 191 -444 1027 1334 3266 732 987 -1199 -218 1584 1479 233 148 85 -106 1054 615 128 -186 -1032 -2121 -741 -1192 -1574 -410 -1948 -1549 -189 -140 302 -62 -149 520 -46 20 2143 -90 -70 470 -174 -306 -630 -778 -587 -367 -355 -449 -1241 -982 -148 387 677 1025 708 193 283 285 494 347 237 -101 -182 -3 319 -434 208 31 -56 143 338 399 379 232 -48 -206 458 -355 3 -200 -112 -87 208 -330 -246 -178 -806 833 62 456 -1109 -145 -347 1444 -583 -661 -159 -454 34 -881 1029 161 -477 -649 162 -627 -602 659 760 -603 -761 273 437 -131 356 1303 618 697 902 -1501 109 -832 -593 -821 222 -165 330 -976 -1281 -276 -786 -1096 -614 -14 457 475 717 241 413 1407 1257 1011 -262 634 120 -276 646 897 2368 547 754 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