File name: Pandora83s1_BondvilleIL_20250725_L2Fit_fout2c8d20241002p1-8.txt File generation date: 20250729T071314.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Kevin Mishoe Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 83 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora83_OF_v4d20231115.txt Instrument calibration file used: Pandora83s1_CF_v8d20241002.txt Level 1 file used: Pandora83s1_BondvilleIL_20250725_L1_smca1c8d20241002p1-8.txt Full location name: Bondville, Illinois EPA Castnet Site Short location name: BondvilleIL Country of location: United States Location latitude [deg]: 40.0520 Location longitude [deg]: -88.3725 Location altitude [m]: 213 Local noon date: 20250725 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 199 341 Nominal wavelengths inside fitting window [nm]: 305.0376 305.1782 305.3189 305.4595 305.6001 305.7407 305.8813 306.0219 306.1625 306.3031 306.4436 306.5841 306.7247 306.8652 307.0057 307.1462 307.2867 307.4271 307.5676 307.7081 307.8485 307.9889 308.1293 308.2697 308.4101 308.5505 308.6909 308.8312 308.9716 309.1119 309.2522 309.3925 309.5328 309.6731 309.8134 309.9537 310.0939 310.2342 310.3744 310.5146 310.6548 310.7950 310.9352 311.0754 311.2155 311.3557 311.4958 311.6359 311.7761 311.9162 312.0563 312.1963 312.3364 312.4765 312.6165 312.7565 312.8966 313.0366 313.1766 313.3166 313.4565 313.5965 313.7365 313.8764 314.0163 314.1563 314.2962 314.4361 314.5760 314.7158 314.8557 314.9955 315.1354 315.2752 315.4150 315.5548 315.6946 315.8344 315.9742 316.1139 316.2537 316.3934 316.5331 316.6728 316.8125 316.9522 317.0919 317.2316 317.3712 317.5109 317.6505 317.7901 317.9297 318.0693 318.2089 318.3485 318.4880 318.6276 318.7671 318.9066 319.0462 319.1857 319.3251 319.4646 319.6041 319.7435 319.8830 320.0224 320.1618 320.3013 320.4407 320.5800 320.7194 320.8588 320.9981 321.1375 321.2768 321.4161 321.5554 321.6947 321.8340 321.9733 322.1125 322.2518 322.3910 322.5302 322.6694 322.8086 322.9478 323.0870 323.2262 323.3653 323.5045 323.6436 323.7827 323.9218 324.0609 324.2000 324.3391 324.4781 324.6172 324.7562 324.8952 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250725T122803.1Z 9337.519480 85 1 53.32 2 72.37 78.99 80.52 72.31 0.00 1 0.00 1 0 25 9.275e-02 9.236e-03 4.296e-02 2.786e-03 4.280087e-01 1.446092e-03 5.014624e-03 -6.000000e+00 5.429175e-02 232.35 -2.00 3.49 -2.00 319.36 0.00e+00 1.365988e-03 3.876362e-04 5.502463e-04 -6.000000e+00 2.455801e-03 289.30 -2.00 20.00 -2.00 318.55 0.00e+00 3.255 0.001 302.00 328.00 3 3.9963e+00 4.1072e-03 3.9179e-02 -6.0000e+00 1.3605e-01 2.1204e-02 4.8211e-03 2.2738e-02 -6.0000e+00 1.4677e-01 -1.5491e-02 3.6661e-03 1.1165e-02 -6.0000e+00 8.7394e-02 -2.2113e-03 1.9279e-03 3.2322e-03 -6.0000e+00 3.7275e-02 2.3968e-04 -3.0628e-04 8.0100e-05 3.5296e-05 -6.0000e+00 2.5499e-03 7.7040e-03 0.0000e+00 11 9 0 11 8 0 99.95 26.06 0.32 0.00770 0.00540 35 4 1 5 0 1523.270 34.50 20.00 26.06 30.22 1.8 1100.00 -22958 15367 34400 28015 900000 -19708 -26257 47832 -30859 37421 1733 26218 -4771 -11471 27132 -4569 -5658 -1811 923 -17280 -18894 9936 -2806 -4355 -5585 3077 5274 -13557 8301 5521 4901 3845 3874 -4656 -1673 -5363 2964 -3462 -3516 899 1332 -4300 -3366 -2278 -6683 1440 3808 -1373 1716 785 1429 -1126 1003 3634 4012 1947 -1904 1657 -283 -1328 4134 1257 3722 895 1204 -1115 -624 1763 364 901 1718 -8 -779 1555 1651 -738 929 -1771 -1714 -92 -1137 -1845 -72 -3872 -1089 78 457 351 757 392 1066 74 -461 2239 90 -432 611 -247 -502 -1143 -712 -84 -465 -837 -1252 -1325 -1354 -490 -261 683 1319 643 228 -20 162 323 583 571 -199 245 -187 375 -628 -168 -409 463 1563 -144 285 351 526 -47 275 322 -459 289 -420 -33 -200 344 -569 -604 242 -518 271 533 449 900000 -444 -671 663 -1065 702 48 598 -174 -542 1047 -279 -383 -126 67 -1582 -1817 718 -236 -399 -558 298 506 -1514 713 492 483 438 496 -691 -233 -752 411 -601 -744 217 359 -1193 -965 -661 -2044 451 1169 -444 543 258 455 -403 381 1438 1662 852 -891 751 -128 -599 1807 609 1951 530 739 -673 -353 960 214 601 1265 -6 -573 1175 1163 -480 539 -1013 -1030 -62 -894 -1508 -63 -3728 -1085 83 471 376 814 412 1131 73 -423 1948 85 -460 673 -308 -685 -1483 -940 -100 -514 -928 -1495 -1694 -1818 -685 -360 1015 2107 1010 383 -32 242 452 860 810 -303 396 -310 611 -999 -257 -600 693 2206 -206 403 548 886 -79 469 573 -874 578 -822 -66 -402 676 -1153 -1166 446 SS 20250725T123317.2Z 9337.523116 89 1 53.99 2 71.39 79.77 79.60 73.08 0.00 1 0.00 1 0 25 2.994e-02 6.185e-03 3.685e-03 6.263e-04 4.054604e-01 3.226509e-04 4.792458e-03 -6.000000e+00 1.750822e-02 232.35 -2.00 3.49 -2.00 318.21 0.00e+00 1.064604e-03 6.049197e-05 5.325947e-04 -6.000000e+00 7.791182e-04 289.30 -2.00 20.00 -2.00 317.36 0.00e+00 3.093 0.000 302.00 328.00 3 1.6513e+00 8.7654e-04 3.7095e-02 -6.0000e+00 4.3899e-02 -5.6626e-03 9.9472e-04 2.1323e-02 -6.0000e+00 4.7356e-02 -2.5757e-02 6.4611e-04 1.0348e-02 -6.0000e+00 2.8210e-02 6.6518e-03 3.3515e-04 2.8717e-03 -6.0000e+00 1.2024e-02 3.0585e-03 -1.7611e-04 1.7568e-05 3.0663e-05 -6.0000e+00 8.1350e-04 8.1309e-03 0.0000e+00 10 0 0 10 0 0 99.31 26.06 0.24 0.00813 0.00681 227 26 1 5 0 237.800 34.50 19.99 26.06 30.51 1.8 1100.00 -11159 -7955 -5128 -11858 -6799 -14017 -9813 -6985 -13219 -5439 -8429 -7056 -6397 -4094 -1157 -1506 -658 -1193 -289 -17 -414 398 553 -508 -926 -20 -512 -2131 -1897 -552 -581 1600 733 -924 -2431 -2664 -1994 -1436 -465 -361 -188 -795 -524 356 47 392 393 -4 -154 599 1369 1490 1514 1593 1504 1289 805 460 536 236 1094 1175 2027 1462 989 135 -9 568 542 615 609 73 32 202 -137 -588 -724 -1177 -1121 -998 -1130 -1398 -1512 -1749 -921 -407 -155 80 354 492 453 237 64 327 57 -291 135 -61 -320 -789 -1060 -999 -821 -498 -976 -1155 -804 -38 324 901 896 793 652 531 383 588 466 446 163 83 -275 154 59 252 55 120 445 555 413 206 -104 -97 -202 34 -162 -28 14 105 -9 -148 -265 -362 -337 -541 -426 -282 -673 -333 -705 -502 -395 -899 -367 -598 -521 -545 -410 -122 -182 -86 -167 -43 -3 -66 63 90 -89 -176 -4 -103 -419 -355 -102 -118 359 170 -231 -595 -635 -507 -426 -153 -141 -76 -347 -238 164 22 183 184 -2 -72 287 648 772 847 892 884 785 507 291 333 145 682 741 1402 1051 740 97 -6 400 383 495 517 62 28 176 -112 -461 -546 -853 -851 -814 -1005 -1332 -1496 -1751 -974 -440 -178 91 405 570 493 249 66 322 60 -326 156 -76 -420 -1056 -1405 -1259 -955 -603 -1222 -1488 -1042 -52 446 1291 1339 1238 1011 813 566 814 659 628 237 129 -423 242 90 370 80 173 613 758 583 309 -163 -159 -329 58 -283 -50 26 192 -16 -270 -480 -644 -579 SS 20250725T123918.2Z 9337.527294 92 1 53.94 2 70.25 80.68 78.55 73.97 0.00 1 0.00 1 0 25 1.924e-02 5.883e-03 3.179e-03 6.076e-04 3.849028e-01 3.131520e-04 4.544400e-03 -6.000000e+00 1.124792e-02 232.35 -2.00 3.49 -2.00 318.06 0.00e+00 8.662500e-04 5.617834e-05 4.596951e-04 -6.000000e+00 5.005499e-04 289.30 -2.00 20.00 -2.00 317.21 0.00e+00 2.927 0.000 302.00 328.00 3 1.7659e+00 8.4819e-04 3.5125e-02 -6.0000e+00 2.8202e-02 -1.0205e-02 9.5854e-04 2.0201e-02 -6.0000e+00 3.0424e-02 -2.0413e-02 6.0975e-04 9.7726e-03 -6.0000e+00 1.8123e-02 4.1663e-03 3.1435e-04 2.6854e-03 -6.0000e+00 7.7243e-03 3.2816e-03 -1.4628e-04 1.7137e-05 2.8408e-05 -6.0000e+00 5.2266e-04 8.5450e-03 0.0000e+00 10 0 0 10 0 0 99.59 26.06 0.23 0.00854 0.00745 291 33 1 5 0 185.340 34.50 20.00 26.06 31.15 1.8 1100.00 -8737 -1541 -3097 -5060 -7068 -8814 -6831 -3866 -7396 -2228 -3393 -4858 -3811 -964 -419 -1644 -1516 -961 809 -481 -72 -49 27 275 -970 -347 -1050 -2684 -1184 -272 -485 1321 362 -772 -2223 -2903 -2032 -1281 -531 -412 -618 -822 -708 747 -217 278 316 -55 4 488 1326 1193 1414 1329 1332 1267 798 478 256 354 1213 1358 1700 1517 732 167 -150 572 539 646 374 178 22 -1 -135 -498 -715 -1240 -1145 -990 -1046 -1389 -1526 -1568 -837 -359 35 177 374 470 492 196 266 243 88 -116 123 -2 -231 -799 -969 -986 -971 -609 -903 -1042 -867 -117 251 836 892 790 591 572 405 451 365 460 131 84 -250 44 27 270 159 168 318 489 318 202 -116 -31 -246 36 -101 -17 20 91 52 -160 -293 -239 -397 -496 -92 -198 -318 -411 -498 -401 -250 -560 -172 -269 -410 -334 -98 -50 -227 -227 -152 133 -84 -13 -9 5 54 -189 -71 -218 -543 -244 -56 -99 298 92 -209 -588 -750 -559 -379 -189 -161 -272 -386 -322 342 -101 130 147 -27 2 230 661 650 777 779 818 804 523 315 166 226 787 889 1224 1127 566 124 -111 411 389 529 324 155 19 -1 -113 -398 -549 -913 -880 -815 -936 -1329 -1514 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