File name: Pandora83s1_BondvilleIL_20250728_L2Fit_fout2c3d20240316p1-8.txt File generation date: 20250729T064226.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Kevin Mishoe Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 83 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora83_OF_v4d20231115.txt Instrument calibration file used: Pandora83s1_CF_v3d20240316.txt Level 1 file used: Pandora83s1_BondvilleIL_20250728_L1_smca1c3d20240316p1-8.txt Full location name: Bondville, Illinois EPA Castnet Site Short location name: BondvilleIL Country of location: United States Location latitude [deg]: 40.0520 Location longitude [deg]: -88.3725 Location altitude [m]: 213 Local noon date: 20250728 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 199 341 Nominal wavelengths inside fitting window [nm]: 305.0622 305.2028 305.3435 305.4841 305.6247 305.7653 305.9059 306.0465 306.1871 306.3276 306.4681 306.6087 306.7492 306.8897 307.0302 307.1707 307.3112 307.4516 307.5921 307.7325 307.8730 308.0134 308.1538 308.2942 308.4346 308.5749 308.7153 308.8556 308.9960 309.1363 309.2766 309.4169 309.5572 309.6975 309.8378 309.9780 310.1183 310.2585 310.3987 310.5389 310.6791 310.8193 310.9595 311.0997 311.2398 311.3800 311.5201 311.6602 311.8003 311.9404 312.0805 312.2206 312.3606 312.5007 312.6407 312.7808 312.9208 313.0608 313.2008 313.3407 313.4807 313.6207 313.7606 313.9006 314.0405 314.1804 314.3203 314.4602 314.6001 314.7399 314.8798 315.0196 315.1595 315.2993 315.4391 315.5789 315.7187 315.8584 315.9982 316.1380 316.2777 316.4174 316.5571 316.6968 316.8365 316.9762 317.1159 317.2555 317.3952 317.5348 317.6744 317.8141 317.9537 318.0932 318.2328 318.3724 318.5119 318.6515 318.7910 318.9305 319.0700 319.2095 319.3490 319.4885 319.6280 319.7674 319.9068 320.0463 320.1857 320.3251 320.4645 320.6039 320.7432 320.8826 321.0219 321.1613 321.3006 321.4399 321.5792 321.7185 321.8577 321.9970 322.1363 322.2755 322.4147 322.5539 322.6932 322.8323 322.9715 323.1107 323.2499 323.3890 323.5281 323.6673 323.8064 323.9455 324.0846 324.2236 324.3627 324.5018 324.6408 324.7798 324.9188 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250728T145209.1Z 9340.619550 161 1 53.20 2 45.42 103.70 90.40 86.86 0.00 1 0.00 1 0 17 2.049e-02 1.356e-02 3.759e-03 2.006e-03 1.933406e-01 1.039938e-03 2.321625e-03 -6.000000e+00 1.197364e-02 232.24 -2.00 3.49 -2.00 315.93 0.00e+00 -2.448115e-04 1.085998e-04 8.391682e-05 -6.000000e+00 5.334210e-04 289.37 -2.00 20.00 -2.00 315.14 0.00e+00 1.422 0.000 302.00 328.00 3 5.6784e+00 2.7175e-03 1.7245e-02 -6.0000e+00 3.0012e-02 2.8144e-02 3.0229e-03 1.0069e-02 -6.0000e+00 3.2384e-02 -3.3842e-03 1.7329e-03 4.8741e-03 -6.0000e+00 1.9293e-02 -6.4202e-03 7.9014e-04 1.3693e-03 -6.0000e+00 8.2211e-03 3.6466e-04 -5.5797e-04 5.7407e-05 1.6792e-05 -6.0000e+00 5.5692e-04 -1.1980e-02 0.0000e+00 12 9 8 11 8 0 93.27 25.90 -0.54 -0.01198 -0.01617 14 2 1 5 0 3799.500 34.25 20.00 25.90 31.86 1.8 1100.00 -6473 -1557 197 488 4494 -2516 -3274 7721 728 2436 1199 4178 592 -1490 3541 -235 -1044 529 1299 -1624 -926 1602 920 153 835 1168 1441 -882 3174 2440 3984 2712 2874 -1627 -1648 -2806 -1185 -1851 814 515 534 -1666 -1284 -14792 -975 10 -48 -1307 -367 99 900 626 1336 1997 2401 2611 663 2182 1780 788 2699 1935 1435 1216 554 -295 -992 532 952 300 481 0 -354 1067 689 -226 39 -709 -1697 -195 -1739 -1579 -227 -2739 -1246 103 147 127 445 214 335 -109 -465 1209 3 -665 467 -121 320 -333 -1126 286 -635 -923 -729 -1034 -685 58 16 888 820 790 161 -79 -88 461 317 504 -297 -416 -512 287 -439 121 -240 -30 1605 188 597 12 2 542 -357 364 -205 273 -185 139 -168 374 -485 -309 -330 -1574 -391 49 114 896 -503 -685 1622 183 632 310 1044 166 -436 1104 -82 -382 194 489 -648 -375 626 365 64 365 528 646 -381 1215 899 1476 1084 1225 -745 -713 -1176 -519 -946 484 329 374 -1248 -982 -12045 -745 7 -35 -938 -252 67 621 461 1032 1601 1972 2179 530 1859 1496 662 2271 1607 1293 1163 535 -267 -819 445 822 270 477 0 -377 1090 665 -200 33 -563 -1370 -171 -1601 -1599 -242 -2919 -1390 122 184 155 545 274 401 -120 -496 1191 3 -742 529 -151 428 -420 -1452 335 -704 -1042 -888 -1351 -932 76 22 1270 1232 1211 240 -110 -121 580 389 638 -404 -571 -734 409 -617 163 -329 -39 1944 225 742 16 3 778 -488 508 -303 425 -300 215 -265 580 -785 -483 -500 SS 20250728T150327.9Z 9340.627407 168 1 54.48 2 43.32 106.09 88.33 88.66 0.00 1 0.00 1 0 17 8.328e-03 6.249e-03 1.620e-03 1.014e-03 1.845351e-01 5.287677e-04 2.241190e-03 -6.000000e+00 4.866059e-03 232.24 -2.00 3.49 -2.00 315.34 0.00e+00 3.757127e-04 4.876536e-05 6.802443e-05 -6.000000e+00 2.167738e-04 289.37 -2.00 20.00 -2.00 314.60 0.00e+00 1.373 0.000 302.00 328.00 3 4.6290e+00 1.3726e-03 1.6593e-02 -6.0000e+00 1.2197e-02 1.3065e-02 1.5201e-03 9.6314e-03 -6.0000e+00 1.3161e-02 -2.4886e-03 8.6906e-04 4.6673e-03 -6.0000e+00 7.8406e-03 -4.3212e-03 3.8926e-04 1.2828e-03 -6.0000e+00 3.3411e-03 1.1144e-03 -3.8094e-04 2.8780e-05 1.6907e-05 -6.0000e+00 2.2632e-04 -1.2235e-02 0.0000e+00 10 0 0 10 0 0 99.27 25.91 0.14 -0.01224 -0.01510 46 5 1 5 0 1184.240 34.25 20.00 25.91 32.60 1.7 1100.00 -1749 -878 -1003 -1831 -582 -1367 -608 2637 58 145 -1203 1206 271 -623 1629 -558 74 293 831 -104 442 1085 1172 802 -109 -195 -193 -1053 357 901 1264 2228 707 -1717 -2234 -1346 -955 -912 -319 -789 -868 -1097 -1338 -248 -1019 -404 -780 -878 -422 404 916 962 1233 1318 1305 1390 695 834 658 669 1523 1113 1427 941 156 -652 -569 478 632 436 307 -35 -70 130 85 -320 -341 -637 -519 -567 -985 -1471 -1079 -1687 -1067 -560 -341 -100 115 167 289 -146 46 583 204 6 337 138 -15 -587 -809 -434 -476 -407 -811 -795 -723 -44 254 836 894 644 515 244 300 589 373 503 92 -116 -338 119 -258 197 55 339 818 494 346 152 73 -61 -86 -23 -249 53 -104 89 -118 -98 -278 -370 -311 -485 -262 -303 -523 -159 -350 -160 751 17 45 -372 396 89 -233 667 -234 32 128 372 -48 209 505 547 391 -56 -104 -103 -533 165 428 565 1049 360 -920 -1134 -649 -487 -539 -208 -560 -634 -840 -1052 -195 -802 -314 -596 -690 -319 298 694 726 977 1090 1109 1201 614 735 571 575 1328 974 1344 943 149 -617 -518 408 559 408 300 -36 -73 132 86 -294 -297 -549 -450 -508 -935 -1546 -1140 -1877 -1189 -668 -409 -125 143 204 346 -168 48 599 216 6 381 173 -20 -753 -984 -510 -555 -482 -989 -985 -936 -59 336 1159 1301 912 741 328 386 736 457 634 119 -161 -468 165 -350 269 71 439 997 590 430 193 98 -83 -118 -32 -355 79 -155 135 -183 -150 -414 -559 -456 SS 20250728T150807.1Z 9340.630638 171 1 53.82 2 42.47 107.11 87.48 89.40 0.00 1 0.00 1 0 17 7.750e-03 6.177e-03 1.122e-03 7.506e-04 1.816586e-01 3.926401e-04 2.210448e-03 -6.000000e+00 4.528786e-03 232.24 -2.00 3.49 -2.00 315.06 0.00e+00 2.629914e-04 3.438683e-05 5.745473e-05 -6.000000e+00 2.017417e-04 289.37 -2.00 20.00 -2.00 314.36 0.00e+00 1.354 0.000 302.00 328.00 3 4.0985e+00 1.0149e-03 1.6353e-02 -6.0000e+00 1.1351e-02 1.0378e-02 1.1219e-03 9.4767e-03 -6.0000e+00 1.2248e-02 -2.9967e-03 6.4174e-04 4.5977e-03 -6.0000e+00 7.2971e-03 -3.7171e-03 2.8515e-04 1.2615e-03 -6.0000e+00 3.1097e-03 1.9432e-03 -3.7747e-04 2.1208e-05 1.6645e-05 -6.0000e+00 2.1063e-04 -1.2513e-02 0.0000e+00 10 0 0 10 0 0 99.85 25.91 0.19 -0.01251 -0.01535 82 9 1 5 0 656.320 34.25 20.00 25.91 32.68 1.7 1100.00 -813 -881 -1335 -2333 -2117 -927 -63 932 301 -431 -909 290 86 -294 874 -292 77 282 1051 698 546 622 1429 1021 500 186 -247 -474 317 982 1115 1815 863 -1385 -1764 -1494 -905 -534 -360 -453 -839 -1221 -1170 -654 -1007 -621 -397 -896 -392 449 1053 994 1103 1308 1195 1152 806 770 755 572 1122 1176 1365 775 124 -497 -418 471 545 606 48 -54 -126 63 -114 -446 -421 -528 -483 -601 -935 -1477 -1518 -1769 -976 -517 -347 -105 141 217 301 145 31 671 356 -70 246 157 -182 -688 -603 -618 -349 -215 -701 -899 -688 -106 265 815 743 628 518 404 239 586 480 556 278 -55 -431 -51 -138 287 258 327 672 692 374 307 -22 -111 -330 98 -145 -63 -124 175 -196 -143 -315 -354 -364 -264 -287 -442 -792 -634 -256 -18 292 106 -147 -332 104 31 -119 391 -133 36 134 511 351 280 316 724 541 261 101 -134 -259 159 467 541 929 475 -747 -964 -780 -499 -317 -239 -329 -634 -968 -950 -533 -820 -501 -312 -682 -303 339 814 772 902 1115 1047 973 694 662 675 507 959 1066 1265 765 124 -462 -370 413 495 584 49 -55 -129 66 -113 -424 -378 -438 -403 -553 -916 -1521 -1593 -1947 -1081 -613 -418 -131 176 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