File name: Pandora83s1_BondvilleIL_20250801_L2Fit_fout2c8d20241002p1-8.txt File generation date: 20250802T061301.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Kevin Mishoe Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 83 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora83_OF_v4d20231115.txt Instrument calibration file used: Pandora83s1_CF_v8d20241002.txt Level 1 file used: Pandora83s1_BondvilleIL_20250801_L1_smca1c8d20241002p1-8.txt Full location name: Bondville, Illinois EPA Castnet Site Short location name: BondvilleIL Country of location: United States Location latitude [deg]: 40.0520 Location longitude [deg]: -88.3725 Location altitude [m]: 213 Local noon date: 20250801 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 199 341 Nominal wavelengths inside fitting window [nm]: 305.0376 305.1782 305.3189 305.4595 305.6001 305.7407 305.8813 306.0219 306.1625 306.3031 306.4436 306.5841 306.7247 306.8652 307.0057 307.1462 307.2867 307.4271 307.5676 307.7081 307.8485 307.9889 308.1293 308.2697 308.4101 308.5505 308.6909 308.8312 308.9716 309.1119 309.2522 309.3925 309.5328 309.6731 309.8134 309.9537 310.0939 310.2342 310.3744 310.5146 310.6548 310.7950 310.9352 311.0754 311.2155 311.3557 311.4958 311.6359 311.7761 311.9162 312.0563 312.1963 312.3364 312.4765 312.6165 312.7565 312.8966 313.0366 313.1766 313.3166 313.4565 313.5965 313.7365 313.8764 314.0163 314.1563 314.2962 314.4361 314.5760 314.7158 314.8557 314.9955 315.1354 315.2752 315.4150 315.5548 315.6946 315.8344 315.9742 316.1139 316.2537 316.3934 316.5331 316.6728 316.8125 316.9522 317.0919 317.2316 317.3712 317.5109 317.6505 317.7901 317.9297 318.0693 318.2089 318.3485 318.4880 318.6276 318.7671 318.9066 319.0462 319.1857 319.3251 319.4646 319.6041 319.7435 319.8830 320.0224 320.1618 320.3013 320.4407 320.5800 320.7194 320.8588 320.9981 321.1375 321.2768 321.4161 321.5554 321.6947 321.8340 321.9733 322.1125 322.2518 322.3910 322.5302 322.6694 322.8086 322.9478 323.0870 323.2262 323.3653 323.5045 323.6436 323.7827 323.9218 324.0609 324.2000 324.3391 324.4781 324.6172 324.7562 324.8952 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250801T121520.7Z 9344.510656 75 1 54.42 2 75.72 78.48 156.92 25.22 0.00 1 0.00 1 0 25 4.958e-01 5.382e-02 1.313e-01 4.646e-03 5.371187e-01 2.541723e-03 6.204085e-03 -6.000000e+00 2.943466e-01 232.11 -2.00 3.49 -2.00 320.26 0.00e+00 -2.480857e-02 8.931956e-04 3.193518e-04 -6.000000e+00 1.489825e-02 289.46 -2.00 20.00 -2.00 319.48 0.00e+00 3.967 0.001 302.00 328.00 3 4.1439e+00 7.7978e-03 5.0113e-02 -6.0000e+00 7.3771e-01 1.1680e-01 9.6185e-03 3.8293e-02 -6.0000e+00 7.9847e-01 -3.9050e-01 7.8048e-03 2.8242e-02 -6.0000e+00 4.7069e-01 1.8928e-01 3.9533e-03 2.8513e-02 -6.0000e+00 2.0330e-01 1.0551e-04 -1.1159e-03 1.3996e-04 2.5624e-04 -6.0000e+00 1.4153e-02 1.9688e-02 0.0000e+00 12 9 8 11 8 0 84.80 24.90 -0.10 0.01969 0.01130 18 2 1 5 0 3023.070 33.75 20.00 24.90 21.35 2.1 1100.00 -67783 900000 900000 900000 900000 900000 -21531 900000 114077 900000 141614 193534 323308 8811 900000 48904 25183 22019 46956 -9296 5114 97881 39275 49008 45423 137659 127387 54647 84188 141582 90616 81020 44693 14243 20701 17584 25834 9207 45138 57014 60054 39251 30367 -87017 12980 28045 47082 18316 20594 12763 14977 950 15288 21385 24597 27407 12729 29596 17847 14426 29426 10070 17579 3935 7788 -4355 -3193 9755 7734 335 4346 4209 1492 12340 12240 7189 4669 -82 -6781 -4376 -4098 -4504 311 -10526 -2536 1658 1539 1398 801 -1347 2634 -1410 -627 8835 -60 -1184 -585 -4619 -3520 -4280 -2712 797 -1921 -2849 -797 -3073 -2553 -496 -1149 -92 1502 718 -44 579 1264 1503 787 416 -1221 -206 233 1387 -256 1157 100 1477 5511 -769 269 121 939 368 -70 1409 -74 1555 -544 -175 47 735 -1996 -1197 -1534 -2676 900000 900000 900000 900000 900000 -540 900000 1290 900000 1473 1226 1463 395 900000 1703 1151 1066 1827 -652 317 2435 1919 2594 2979 3985 4091 3263 3237 2818 3074 3299 2871 1302 1704 1464 2174 1116 4880 6783 7960 6818 5797 -47201 2707 4821 6432 3256 3587 2494 3110 252 3845 5514 6643 7736 4417 8810 5756 4549 7787 3366 5940 1659 3269 -1986 -1374 3725 3292 177 2243 2311 849 6671 6135 3398 2051 -36 -3377 -2423 -2612 -2980 217 -8740 -2085 1405 1385 1303 751 -1250 2201 -1141 -476 6067 -48 -1089 -604 -5581 -4202 -5232 -3101 876 -2009 -3019 -891 -3763 -2991 -600 -1500 -131 2299 1174 -73 921 1878 2106 1093 599 -1896 -334 383 2211 -401 1732 145 2035 7601 -1038 390 196 1641 631 -125 2622 -149 3274 -1206 -394 105 1604 -4245 -2379 -2934 SS 20250801T122646.3Z 9344.518591 78 1 53.38 2 73.58 80.21 155.96 31.25 0.00 1 0.00 1 0 25 1.408e-01 1.019e-02 5.046e-02 2.495e-03 4.576726e-01 1.303024e-03 5.313861e-03 -6.000000e+00 8.278518e-02 232.11 -2.00 3.49 -2.00 319.59 0.00e+00 1.589423e-03 3.781037e-04 7.005410e-04 -6.000000e+00 3.732906e-03 289.46 -2.00 20.00 -2.00 318.80 0.00e+00 3.479 0.001 302.00 328.00 3 3.6346e+00 3.7588e-03 4.1822e-02 -6.0000e+00 2.0761e-01 -5.0438e-03 4.4644e-03 2.4267e-02 -6.0000e+00 2.2428e-01 -2.3019e-02 3.5124e-03 1.2007e-02 -6.0000e+00 1.3298e-01 2.7268e-03 1.8385e-03 3.5504e-03 -6.0000e+00 5.6400e-02 2.7497e-04 9.1872e-06 7.1480e-05 3.9106e-05 -6.0000e+00 3.9258e-03 1.9079e-02 0.0000e+00 12 8 8 10 0 0 57.58 24.90 0.34 0.01908 0.01915 34 4 1 5 0 1569.770 33.75 20.00 24.90 22.16 2.0 1100.00 -83806 41278 51783 24000 900000 -10794 -38888 900000 -31199 55748 7083 38084 31110 -23067 50745 1608 -12715 -22843 3363 -19773 -16659 6300 -11463 -11501 -15882 11160 6192 -12154 8621 20476 2368 5632 -500 -2425 -1053 -9115 -545 -5259 -539 -5510 4773 -2059 -3068 -3113 -3301 709 9248 607 2005 -320 3605 -1224 1737 4523 3647 -1310 -1668 1854 -757 -1015 6546 1706 4470 1190 2442 -1432 -709 2584 1555 69 891 451 -1101 2669 1739 -197 1426 -2228 -2739 -1300 -1415 -2069 -217 -4251 -1733 154 220 398 546 -479 764 -216 -799 3071 145 -172 560 -875 -218 -914 -908 720 -502 -1259 -464 -1434 -1082 -88 7 787 1553 571 250 -55 269 313 189 92 -334 69 -233 501 -189 129 -381 273 67 -22 28 581 629 312 17 521 -430 317 -162 -124 -63 68 -592 -377 -32 -2609 422 504 298 900000 -168 -861 900000 -827 664 141 602 628 -982 1246 75 -748 -1605 195 -1520 -1280 386 -867 -937 -1460 825 486 -1105 614 1330 206 546 -58 -305 -126 -1157 -69 -827 -99 -1261 1104 -496 -779 -809 -869 182 2407 173 573 -88 1035 -406 608 1650 1411 -552 -726 780 -321 -426 2618 777 2205 666 1402 -821 -383 1346 884 42 592 317 -787 1763 1077 -122 795 -1251 -1652 -890 -1026 -1703 -191 -3807 -1615 151 229 427 588 -506 746 -196 -737 2691 141 -174 640 -1063 -287 -1221 -1146 875 -571 -1452 -571 -1766 -1394 -118 10 1145 2435 945 411 -86 395 463 277 131 -510 111 -384 803 -295 194 -551 403 95 -31 43 918 1074 527 29 951 -843 615 -325 -253 -131 137 -1149 -738 -61 SS 20250801T123941.7Z 9344.527566 81 1 53.94 2 71.13 82.17 154.66 37.55 0.00 1 0.00 1 0 25 1.092e-01 7.536e-03 2.098e-02 1.641e-03 4.084735e-01 8.473464e-04 4.810930e-03 -6.000000e+00 6.372058e-02 232.11 -2.00 3.49 -2.00 318.82 0.00e+00 1.458734e-03 1.911157e-04 5.688773e-04 -6.000000e+00 2.844216e-03 289.46 -2.00 20.00 -2.00 317.98 0.00e+00 3.054 0.000 302.00 328.00 3 3.4045e+00 2.3515e-03 3.6917e-02 -6.0000e+00 1.5964e-01 2.8914e-03 2.7058e-03 2.1559e-02 -6.0000e+00 1.7234e-01 -1.9758e-02 1.8858e-03 1.0573e-02 -6.0000e+00 1.0269e-01 -5.5259e-04 9.9260e-04 3.0601e-03 -6.0000e+00 4.3713e-02 5.4430e-04 -4.0448e-05 4.6744e-05 3.3030e-05 -6.0000e+00 2.9689e-03 1.9761e-02 0.0000e+00 11 8 0 10 0 0 55.43 24.90 0.15 0.01976 0.01946 52 6 1 5 0 1037.130 33.75 20.00 24.90 22.96 2.0 1100.00 -31736 6182 5169 -8747 112693 -6408 -17719 24619 -21502 7803 275 599 -3151 -15610 5272 320 -6770 -8251 145 -8964 -6770 1595 -2466 -3608 -6180 3534 -1077 -3993 1944 8095 -253 5009 750 -3064 -2273 -5201 -1877 -4001 237 585 1458 -1700 -2054 -1426 -1632 740 3261 722 1710 815 998 -308 1899 3049 -537 1901 -786 1363 -641 -649 3597 867 2813 545 1339 -747 -188 1798 1324 211 778 595 -526 921 761 -279 -531 -1164 -1479 -828 -755 -1765 -832 -2530 -1254 -57 20 115 340 -166 598 3 -13 1528 295 -82 556 -427 -605 -647 -895 -253 -706 -764 -925 -1311 -1273 -90 319 869 967 590 374 182 408 451 478 292 -122 -65 -257 353 -290 200 -30 -44 1043 579 355 136 151 163 -99 305 -182 272 -276 -125 34 -179 -406 -339 -135 -1203 182 161 -301 1046 -189 -624 646 -1008 291 11 26 -167 -1131 369 27 -664 -878 15 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