File name: Pandora155s1_BostonMA_20210906_L2Fit_fwvt1c10d20190627p1-8.txt File generation date: 20241210T052134.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Jeff Gedes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 155 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora155_OF_v4d20190702.txt Instrument calibration file used: Pandora155s1_CF_v10d20190627.txt Level 1 file used: Pandora155s1_BostonMA_20210906_L1_smca1c10d20190627p1-8.txt Full location name: Boston University Short location name: BostonMA Country of location: USA Location latitude [deg]: 42.3497 Location longitude [deg]: -71.1040 Location altitude [m]: 40 Local noon date: 20210906 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1653 1802 Nominal wavelengths inside fitting window [nm]: 492.0684 492.1894 492.3103 492.4313 492.5522 492.6731 492.7940 492.9149 493.0358 493.1566 493.2775 493.3983 493.5191 493.6399 493.7606 493.8814 494.0021 494.1229 494.2436 494.3642 494.4849 494.6056 494.7262 494.8468 494.9674 495.0880 495.2086 495.3291 495.4497 495.5702 495.6907 495.8112 495.9316 496.0521 496.1725 496.2930 496.4134 496.5337 496.6541 496.7745 496.8948 497.0151 497.1354 497.2557 497.3760 497.4962 497.6165 497.7367 497.8569 497.9771 498.0972 498.2174 498.3375 498.4577 498.5778 498.6978 498.8179 498.9380 499.0580 499.1780 499.2980 499.4180 499.5380 499.6579 499.7779 499.8978 500.0177 500.1376 500.2574 500.3773 500.4971 500.6169 500.7367 500.8565 500.9763 501.0960 501.2158 501.3355 501.4552 501.5749 501.6945 501.8142 501.9338 502.0534 502.1730 502.2926 502.4122 502.5317 502.6513 502.7708 502.8903 503.0098 503.1292 503.2487 503.3681 503.4875 503.6069 503.7263 503.8457 503.9650 504.0843 504.2037 504.3230 504.4422 504.5615 504.6807 504.8000 504.9192 505.0384 505.1576 505.2767 505.3959 505.5150 505.6341 505.7532 505.8723 505.9913 506.1104 506.2294 506.3484 506.4674 506.5864 506.7053 506.8243 506.9432 507.0621 507.1810 507.2999 507.4187 507.5376 507.6564 507.7752 507.8940 508.0128 508.1315 508.2503 508.3690 508.4877 508.6064 508.7250 508.8437 508.9623 509.0810 509.1996 509.3181 509.4367 509.5553 509.6738 509.7923 509.9108 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20210906T121822.9Z 7919.512765 107 1 5.03 2 68.22 101.88 61.06 99.19 0.00 1 0.00 1 0 15 2.298e-03 2.288e-03 1.184e-04 1.182e-04 4.493388e+03 7.601157e+00 3.121737e+02 -6.000000e+00 1.307405e+02 287.43 -2.00 20.00 -2.00 505.25 0.00e+00 6.637456e-04 3.294564e-06 4.146433e-05 -6.000000e+00 6.538040e-05 287.43 -2.00 20.00 -2.00 500.40 0.00e+00 7.079401e-02 2.350727e-03 3.002742e-02 -6.000000e+00 4.583881e-02 229.99 -2.00 3.54 -2.00 501.99 0.00e+00 2.671 0.000 489.00 513.00 1 8.1353e-01 1.8025e-04 4.6903e-03 -6.0000e+00 3.5176e-03 -7.0236e-03 4.6593e-05 7.4351e-04 -6.0000e+00 9.1544e-04 5.8185e-01 7.0811e-04 1.1763e-05 3.5867e-05 -6.0000e+00 2.3747e-04 1.6877e-03 -1.1883e-04 10 0 0 10 0 0 18.16 17.27 1.81 0.00169 0.00660 683 129 1 4 0 6.920 19.85 14.99 17.27 28.06 35.7 1008.12 -556 -597 -412 -66 84 318 469 359 314 179 113 86 -107 -151 -156 -102 -74 19 141 11 49 163 139 156 248 228 153 153 -107 -364 -254 -188 -241 75 189 137 169 191 43 -49 -34 -20 44 105 112 104 112 56 -6 -208 -469 -499 -527 -470 -273 -171 -102 8 161 259 312 410 302 248 207 147 28 -47 -100 -209 -170 25 -7 14 47 -66 -149 -108 -110 -291 -285 -238 -300 -228 -109 -160 -156 -138 -97 36 46 118 172 155 599 228 108 -101 -237 -401 -373 -241 -241 -69 -139 -195 -127 -167 -219 -99 -28 -29 155 282 377 388 383 353 204 188 236 134 32 155 21 -24 149 132 -4 46 -112 -234 -108 -45 -173 -48 -14 -74 80 302 334 350 337 129 -23 -187 -297 -376 -329 -254 -540 -588 -406 -67 85 329 494 382 334 188 117 88 -108 -155 -159 -105 -74 19 149 11 51 171 146 164 262 240 161 159 -112 -370 -253 -188 -246 77 198 145 178 199 44 -51 -35 -20 46 111 116 107 116 58 -6 -208 -470 -488 -511 -459 -272 -171 -105 9 166 267 322 424 306 251 208 150 28 -47 -98 -203 -168 24 -7 13 47 -66 -145 -104 -107 -283 -278 -227 -290 -222 -108 -159 -156 -138 -97 36 45 117 172 156 591 222 105 -96 -221 -378 -351 -225 -232 -67 -138 -196 -127 -165 -214 -97 -28 -28 153 282 379 391 389 359 206 188 232 130 32 149 20 -23 145 128 -4 45 -108 -227 -103 -43 -164 -46 -14 -72 79 301 327 344 334 128 -23 -185 -289 -367 -315 -243 SQ 20210906T121829.0Z 7919.512835 107 2 4.97 2 68.20 101.90 61.04 99.20 0.00 1 0.00 1 0 22 2.303e-03 2.291e-03 1.144e-04 1.142e-04 4.486861e+03 7.332737e+00 3.120162e+02 -6.000000e+00 1.310124e+02 287.43 -2.00 20.00 -2.00 505.25 0.00e+00 6.749550e-04 3.183600e-06 4.185726e-05 -6.000000e+00 6.551603e-05 287.43 -2.00 20.00 -2.00 500.41 0.00e+00 7.132458e-02 2.271254e-03 3.004971e-02 -6.000000e+00 4.593336e-02 229.99 -2.00 3.54 -2.00 502.00 0.00e+00 2.669 0.000 489.00 513.00 1 7.5268e-01 1.7418e-04 4.6903e-03 -6.0000e+00 3.5249e-03 -7.0417e-03 4.5002e-05 7.4409e-04 -6.0000e+00 9.1731e-04 6.1842e-01 7.5672e-04 1.1391e-05 3.5954e-05 -6.0000e+00 2.3797e-04 1.5918e-03 -1.1684e-04 10 0 0 10 0 0 31.36 17.27 1.81 0.00159 0.00684 683 129 1 4 0 6.920 19.85 14.99 17.27 28.06 35.7 1008.12 -533 -612 -410 -80 80 310 456 368 309 192 122 90 -87 -163 -160 -121 -71 -4 134 34 55 143 129 159 269 247 164 129 -107 -380 -257 -198 -253 70 201 132 186 181 55 -63 -47 -20 52 112 137 134 138 53 -26 -230 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-14 -91 77 315 296 325 336 145 -34 -168 -281 -365 -310 -250 SQ 20210906T121835.1Z 7919.512906 107 3 4.97 2 68.18 101.92 61.03 99.22 0.00 1 0.00 1 0 29 2.325e-03 2.314e-03 1.092e-04 1.090e-04 4.468631e+03 6.992788e+00 3.099200e+02 -6.000000e+00 1.322758e+02 287.43 -2.00 20.00 -2.00 505.26 0.00e+00 6.686802e-04 3.042007e-06 4.152588e-05 -6.000000e+00 6.614771e-05 287.43 -2.00 20.00 -2.00 500.41 0.00e+00 7.095720e-02 2.166863e-03 3.009965e-02 -6.000000e+00 4.637608e-02 229.99 -2.00 3.54 -2.00 502.00 0.00e+00 2.667 0.000 489.00 513.00 1 6.6809e-01 1.6618e-04 4.6882e-03 -6.0000e+00 3.5589e-03 -7.1340e-03 4.2897e-05 7.4363e-04 -6.0000e+00 9.2615e-04 6.7331e-01 7.6623e-04 1.0863e-05 3.6194e-05 -6.0000e+00 2.4026e-04 1.5270e-03 -1.1604e-04 10 0 0 10 0 0 -5.69 17.27 1.81 0.00153 0.00684 683 129 1 4 0 6.920 19.85 14.99 17.27 28.06 35.7 1008.12 -557 -609 -421 -76 72 306 451 353 319 183 95 65 -126 -164 -158 -120 -59 -1 144 21 44 162 112 170 275 234 178 157 -115 -382 -248 -177 -252 67 193 158 173 184 50 -40 -51 -18 91 109 157 129 132 54 -4 -212 -481 -485 -521 -477 -249 -156 -64 37 162 237 307 390 325 257 190 124 32 -57 -119 -215 -186 19 -10 31 33 -72 -135 -118 -109 -306 -285 -236 -286 -243 -123 -179 -141 -132 -115 41 58 115 178 180 616 239 91 -121 -247 -393 -358 -273 -238 -48 -175 -216 -125 -173 -210 -95 -56 -15 166 299 378 388 418 364 214 202 249 147 91 108 19 -16 154 144 4 17 -108 -234 -125 -71 -186 -59 14 -85 96 319 301 325 327 134 -46 -178 -327 -363 -339 -261 -541 -600 -415 -77 73 318 476 376 339 193 99 67 -128 -168 -162 -120 -59 -1 149 22 47 171 118 179 291 248 187 163 -117 -389 -248 -178 -257 68 203 163 183 192 52 -41 -52 -18 95 112 163 134 136 55 -4 -213 -483 -476 -506 -467 -249 -157 -66 37 164 239 310 395 331 262 192 127 32 -57 -117 -209 -180 18 -10 31 33 -72 -132 -114 -104 -291 -272 -227 -277 -238 -122 -179 -137 -129 -112 40 57 115 179 181 611 234 90 -116 -231 -371 -338 -255 -230 -47 -176 -213 -126 -171 -207 -94 -56 -15 166 301 382 394 417 364 213 203 246 143 89 105 19 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