File name: Pandora155s1_BostonMA_20240531_L2Fit_fwvt1c2d20231025p1-8.txt File generation date: 20240902T142151.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Jeff Gedes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 155 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora155_OF_v4d20190702.txt Instrument calibration file used: Pandora155s1_CF_v2d20231025.txt Level 1 file used: Pandora155s1_BostonMA_20240531_L1_smca1c2d20231025p1-8.txt Full location name: Boston University Short location name: BostonMA Country of location: USA Location latitude [deg]: 42.3497 Location longitude [deg]: -71.1040 Location altitude [m]: 40 Local noon date: 20240531 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 1653 1802 Nominal wavelengths inside fitting window [nm]: 492.1069 492.2279 492.3489 492.4699 492.5909 492.7118 492.8328 492.9537 493.0746 493.1955 493.3163 493.4372 493.5580 493.6789 493.7997 493.9205 494.0412 494.1620 494.2827 494.4034 494.5241 494.6448 494.7655 494.8862 495.0068 495.1274 495.2480 495.3686 495.4892 495.6097 495.7303 495.8508 495.9713 496.0918 496.2123 496.3327 496.4532 496.5736 496.6940 496.8144 496.9347 497.0551 497.1754 497.2958 497.4161 497.5364 497.6566 497.7769 497.8971 498.0173 498.1375 498.2577 498.3779 498.4980 498.6182 498.7383 498.8584 498.9785 499.0986 499.2186 499.3386 499.4587 499.5787 499.6987 499.8186 499.9386 500.0585 500.1784 500.2983 500.4182 500.5381 500.6579 500.7778 500.8976 501.0174 501.1372 501.2569 501.3767 501.4964 501.6161 501.7358 501.8555 501.9752 502.0948 502.2144 502.3341 502.4537 502.5732 502.6928 502.8124 502.9319 503.0514 503.1709 503.2904 503.4098 503.5293 503.6487 503.7681 503.8875 504.0069 504.1263 504.2456 504.3649 504.4842 504.6035 504.7228 504.8421 504.9613 505.0805 505.1997 505.3189 505.4381 505.5573 505.6764 505.7955 505.9146 506.0337 506.1528 506.2719 506.3909 506.5099 506.6289 506.7479 506.8669 506.9858 507.1048 507.2237 507.3426 507.4615 507.5804 507.6992 507.8180 507.9369 508.0557 508.1745 508.2932 508.4120 508.5307 508.6494 508.7681 508.8868 509.0055 509.1241 509.2428 509.3614 509.4800 509.5985 509.7171 509.8357 509.9542 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240531T091739.3Z 8917.387261 123 1 28.26 2 89.70 59.86 58.08 139.58 0.00 1 0.00 1 0 29 1.315e-02 1.299e-02 6.936e-04 6.904e-04 1.579827e+04 4.943426e+01 9.990879e+02 -6.000000e+00 7.394645e+02 284.24 -2.00 20.00 -2.00 505.46 0.00e+00 3.917061e-03 1.933982e-05 2.220372e-04 -6.000000e+00 3.706755e-04 284.24 -2.00 20.00 -2.00 501.12 0.00e+00 1.397125e+00 1.339292e-02 1.204697e-01 -6.000000e+00 2.623908e-01 232.08 -2.00 3.54 -2.00 502.61 0.00e+00 19.961 0.151 489.00 513.00 1 3.3108e+00 1.0252e-03 3.7539e-02 -6.0000e+00 2.0123e-02 -5.3544e-02 2.5591e-04 3.3871e-03 -6.0000e+00 5.2161e-03 3.5038e-03 9.3903e-04 6.4578e-05 1.3186e-04 -6.0000e+00 1.3568e-03 1.5902e-02 -1.5324e-04 12 9 9 12 1 1 60.18 18.12 8.44 0.01590 0.02242 34 12 1 4 0 807.400 21.17 15.00 18.12 18.27 3.3 921.09 -3472 -2540 -1062 144 1095 1756 2175 2189 1661 995 253 -369 -1097 -1397 -1511 -1099 -601 344 778 1058 900 857 1155 1245 1396 1257 906 -41 -1147 -2124 -2138 -1827 -898 455 882 801 409 142 -271 -78 -95 441 976 1339 1493 1582 1254 779 -80 -1018 -1990 -2547 -2462 -1662 -561 343 911 1240 1291 1205 1560 1634 1796 1598 1097 527 -76 -593 -1043 -1449 -1552 -1098 -690 -381 -513 -946 -1571 -1856 -2123 -2082 -1784 -1390 -1429 -1175 -809 -867 -651 -669 -376 74 501 980 1554 1355 1387 843 -94 -1162 -1993 -2657 -2487 -1725 -758 30 154 -180 -716 -964 -883 -540 24 572 1350 2140 2475 2668 2602 2102 1369 643 440 219 506 951 932 953 909 767 403 499 -194 -592 -1112 -1274 -1458 -549 -208 182 696 825 731 848 983 943 670 33 -787 -1782 -2114 -2087 -3065 -2279 -939 131 1010 1647 2066 2018 1534 948 240 -348 -1028 -1305 -1414 -999 -555 323 743 1019 872 835 1128 1225 1335 1206 869 -39 -1118 -2040 -2042 -1762 -853 442 873 797 407 141 -268 -77 -95 442 955 1327 1493 1586 1255 774 -79 -988 -1970 -2496 -2411 -1646 -549 343 923 1265 1319 1235 1602 1636 1803 1606 1099 524 -77 -600 -1050 -1452 -1554 -1103 -699 -377 -510 -936 -1538 -1857 -2112 -2066 -1773 -1387 -1394 -1158 -804 -867 -649 -664 -371 73 497 981 1554 1342 1337 817 -89 -1084 -1841 -2451 -2316 -1645 -727 30 154 -182 -726 -975 -894 -552 25 596 1408 2229 2588 2735 2712 2223 1455 680 458 225 517 975 964 993 952 806 426 525 -203 -617 -1158 -1331 -1544 -571 -221 196 758 911 795 929 1083 1041 740 36 -861 -1940 -2294 -2279 SQ 20240531T092039.8Z 8917.389350 127 1 50.60 2 89.21 60.36 57.72 140.33 0.00 1 0.00 1 0 22 9.876e-03 9.749e-03 3.358e-04 3.343e-04 1.545676e+04 2.407051e+01 9.843745e+02 -6.000000e+00 5.554747e+02 284.24 -2.00 20.00 -2.00 505.45 0.00e+00 3.305608e-03 9.349969e-06 1.913630e-04 -6.000000e+00 2.784499e-04 284.24 -2.00 20.00 -2.00 501.08 0.00e+00 1.531397e+00 6.515829e-03 1.150990e-01 -6.000000e+00 1.971213e-01 232.08 -2.00 3.54 -2.00 502.57 0.00e+00 19.068 0.132 489.00 513.00 1 2.5576e+00 4.9941e-04 3.4782e-02 -6.0000e+00 1.5117e-02 -5.1572e-02 1.2421e-04 3.2379e-03 -6.0000e+00 3.9189e-03 8.4326e-03 3.9242e-04 3.1244e-05 1.2204e-04 -6.0000e+00 1.0192e-03 5.9895e-03 -9.9165e-05 12 8 8 10 0 0 42.74 18.12 6.27 0.00599 0.00871 142 27 1 4 0 356.270 21.17 15.00 18.12 18.30 3.3 921.60 -2506 -1938 -946 123 783 1442 1594 1581 1319 890 265 -128 -685 -943 -1055 -895 -325 129 691 577 651 630 758 912 1088 908 728 33 -735 -1534 -1612 -1332 -719 264 583 663 345 113 -261 -265 -43 288 626 956 1115 1011 876 434 -58 -881 -1485 -1971 -1849 -1389 -513 100 621 862 967 1037 1220 1321 1257 1141 727 413 -98 -408 -875 -1005 -1106 -796 -540 -288 -295 -704 -1044 -1415 -1518 -1602 -1384 -1191 -1036 -913 -612 -732 -603 -613 -309 31 388 793 1023 1118 1191 663 -63 -784 -1625 -2001 -1939 -1310 -673 -33 87 -194 -487 -855 -739 -394 7 419 1061 1481 1832 2075 1987 1646 1030 618 340 311 385 700 688 679 660 471 326 291 -173 -544 -756 -1013 -977 -543 -65 181 603 700 664 697 803 607 442 -52 -664 -1243 -1566 -1456 -2228 -1688 -847 113 734 1376 1488 1487 1239 831 246 -117 -626 -890 -961 -822 -303 123 670 567 642 624 753 879 1055 885 707 32 -696 -1484 -1548 -1292 -688 259 584 667 346 112 -260 -263 -43 290 617 954 1122 1022 883 434 -57 -886 -1466 -1923 -1800 -1370 -500 100 630 881 989 1062 1253 1366 1305 1185 752 423 -99 -411 -875 -998 -1097 -792 -542 -292 -301 -714 -1045 -1401 -1491 -1572 -1360 -1178 -1033 -891 -602 -725 -597 -605 -303 31 383 789 1021 1101 1142 640 -59 -724 -1485 -1821 -1782 -1234 -638 -32 89 -194 -488 -855 -739 -397 8 432 1095 1531 1901 2174 2050 1721 1082 643 348 325 400 730 701 697 681 487 338 302 -179 -556 -770 -1036 -1010 -570 -69 191 645 759 729 772 894 679 494 -58 -732 -1359 -1705 -1594 SQ 20240531T092349.2Z 8917.391542 131 1 50.50 2 88.70 60.89 57.35 141.13 0.00 1 0.00 1 0 22 7.436e-03 7.347e-03 2.193e-04 2.186e-04 1.413500e+04 1.561975e+01 9.053001e+02 -6.000000e+00 4.182343e+02 284.24 -2.00 20.00 -2.00 505.43 0.00e+00 2.930246e-03 6.114861e-06 1.722623e-04 -6.000000e+00 2.096683e-04 284.24 -2.00 20.00 -2.00 500.96 0.00e+00 1.627339e+00 4.277864e-03 1.042200e-01 -6.000000e+00 1.484582e-01 232.08 -2.00 3.54 -2.00 502.48 0.00e+00 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