File name: Pandora155s1_BostonMA_20240810_L2Fit_fout2c9d20240425p1-8.txt File generation date: 20241210T070514.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Jeff Gedes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 155 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora155_OF_v4d20190702.txt Instrument calibration file used: Pandora155s1_CF_v9d20240425.txt Level 1 file used: Pandora155s1_BostonMA_20240810_L1_smca1c9d20240425p1-8.txt Full location name: Boston University Short location name: BostonMA Country of location: USA Location latitude [deg]: 42.3497 Location longitude [deg]: -71.1040 Location altitude [m]: 40 Local noon date: 20240810 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 232 374 Nominal wavelengths inside fitting window [nm]: 305.0903 305.2311 305.3720 305.5128 305.6537 305.7945 305.9353 306.0761 306.2169 306.3576 306.4984 306.6391 306.7799 306.9206 307.0613 307.2020 307.3427 307.4834 307.6241 307.7647 307.9054 308.0460 308.1866 308.3273 308.4679 308.6085 308.7490 308.8896 309.0302 309.1707 309.3113 309.4518 309.5923 309.7328 309.8733 310.0138 310.1543 310.2947 310.4352 310.5756 310.7160 310.8565 310.9969 311.1372 311.2776 311.4180 311.5584 311.6987 311.8390 311.9794 312.1197 312.2600 312.4003 312.5406 312.6808 312.8211 312.9613 313.1016 313.2418 313.3820 313.5222 313.6624 313.8026 313.9428 314.0829 314.2231 314.3632 314.5033 314.6434 314.7835 314.9236 315.0637 315.2038 315.3438 315.4839 315.6239 315.7639 315.9039 316.0439 316.1839 316.3239 316.4638 316.6038 316.7437 316.8837 317.0236 317.1635 317.3034 317.4433 317.5831 317.7230 317.8629 318.0027 318.1425 318.2823 318.4221 318.5619 318.7017 318.8415 318.9812 319.1210 319.2607 319.4005 319.5402 319.6799 319.8196 319.9592 320.0989 320.2386 320.3782 320.5178 320.6575 320.7971 320.9367 321.0762 321.2158 321.3554 321.4949 321.6345 321.7740 321.9135 322.0530 322.1925 322.3320 322.4715 322.6109 322.7504 322.8898 323.0292 323.1686 323.3080 323.4474 323.5868 323.7262 323.8655 324.0049 324.1442 324.2835 324.4228 324.5621 324.7014 324.8407 324.9800 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240810T125649.4Z 8988.539461 147 1 50.43 2 56.41 100.16 120.50 77.44 0.00 1 0.00 1 0 17 1.121e-02 6.161e-03 1.095e-03 3.938e-04 2.400964e-01 2.020720e-04 2.873583e-03 -6.000000e+00 6.569875e-03 232.05 -2.00 3.54 -2.00 317.18 0.00e+00 4.339691e-04 2.846634e-05 9.054363e-05 -6.000000e+00 2.949478e-04 289.05 -2.00 20.00 -2.00 316.33 0.00e+00 1.802 0.000 302.00 328.00 3 1.9323e+00 5.3803e-04 2.2062e-02 -6.0000e+00 1.6449e-02 1.9662e-02 6.0560e-04 1.2687e-02 -6.0000e+00 1.7801e-02 3.7944e-03 3.5499e-04 6.1196e-03 -6.0000e+00 1.0609e-02 -6.2078e-03 1.6884e-04 1.6812e-03 -6.0000e+00 4.4515e-03 9.5609e-03 4.3681e-04 1.1663e-05 1.9494e-05 -6.0000e+00 3.1669e-04 -6.0045e-03 0.0000e+00 10 0 0 10 0 0 99.97 19.50 0.35 -0.00600 -0.00272 658 124 1 5 0 76.630 22.29 15.00 19.50 31.55 4.0 1020.60 -536 -634 -774 -4342 -4029 -3442 -1402 -1160 -576 -2574 -3683 -2764 -1511 -949 153 -314 -332 642 532 1228 -28 404 763 1008 309 909 147 -707 -507 523 1262 1218 1626 -1803 -3219 -2695 -2171 -1302 -234 -608 -820 -365 -285 -374 520 203 -124 -31 -441 501 1116 946 995 1324 786 1325 849 510 301 697 1014 1630 1686 1643 -16 -495 -284 -632 1030 306 87 218 129 334 -209 -531 -751 -1105 -443 -1618 -1313 -1389 -2296 -1429 -920 -491 -231 99 340 276 335 187 -127 453 229 -12 462 670 -54 -540 -435 -811 -107 224 -639 -1002 -428 -603 216 472 540 226 347 202 149 315 352 192 288 -182 -467 -31 226 82 624 254 370 1310 691 228 213 -371 -48 48 76 -260 43 194 -195 -277 -126 -518 -381 -71 -90 -111 -594 -496 -410 -175 -162 -88 -414 -594 -460 -278 -180 32 -72 -79 158 136 321 -8 108 208 288 93 281 45 -204 -138 140 354 368 524 -603 -1029 -858 -759 -530 -113 -336 -492 -208 -166 -220 302 129 -77 -19 -261 298 696 578 641 890 546 933 609 364 212 489 738 1268 1416 1447 -14 -401 -214 -471 816 274 85 203 129 320 -186 -425 -549 -781 -329 -1367 -1237 -1433 -2341 -1520 -1044 -593 -293 128 437 339 379 193 -131 457 247 -13 560 889 -70 -685 -554 -957 -121 265 -823 -1365 -564 -831 311 719 858 361 526 285 207 416 467 269 401 -270 -706 -46 326 113 874 340 472 1684 954 313 305 -547 -72 75 126 -422 71 329 -332 -459 -215 -859 -623 SS 20240810T130115.3Z 8988.542538 150 1 50.40 2 55.61 101.01 119.74 78.27 0.00 1 0.00 1 0 17 1.125e-02 6.267e-03 3.638e-04 1.453e-04 2.358098e-01 7.501227e-05 2.829958e-03 -6.000000e+00 6.589585e-03 232.05 -2.00 3.54 -2.00 316.87 0.00e+00 4.213629e-04 9.793363e-06 6.766086e-05 -6.000000e+00 2.958114e-04 289.05 -2.00 20.00 -2.00 316.01 0.00e+00 1.765 0.000 302.00 328.00 3 1.4503e-01 1.9843e-04 2.1624e-02 -6.0000e+00 1.6498e-02 1.3501e-02 2.2238e-04 1.2444e-02 -6.0000e+00 1.7854e-02 1.8502e-03 1.2940e-04 6.0082e-03 -6.0000e+00 1.0641e-02 -5.0300e-03 6.0971e-05 1.6561e-03 -6.0000e+00 4.4653e-03 5.9841e-02 4.8795e-04 4.3042e-06 1.9514e-05 -6.0000e+00 3.1761e-04 -6.7333e-03 0.0000e+00 10 0 0 10 0 0 49.65 19.51 0.37 -0.00673 -0.00307 2965 561 1 5 0 16.970 22.40 15.00 19.51 31.76 4.0 1022.21 -481 -854 -903 -3999 -4304 -3267 -1784 -422 -826 -2621 -3937 -2639 -1698 -889 224 -200 -228 858 697 1292 170 336 1158 925 833 993 275 -591 -472 382 1320 1415 1777 -1651 -3234 -2384 -2366 -1197 -295 -498 -813 -418 -320 -285 403 154 -188 5 -444 546 1077 887 1090 1233 854 1331 928 499 363 612 1049 1464 1611 1568 -34 -534 -322 -637 885 297 -69 255 69 356 -260 -544 -766 -1169 -422 -1168 -1345 -1474 -2320 -1496 -899 -565 -216 16 331 251 290 201 -61 467 204 37 456 714 -63 -492 -380 -761 -63 235 -590 -986 -440 -589 229 433 535 231 358 206 224 397 385 202 308 -189 -462 -42 209 151 602 321 398 1376 697 236 204 -375 -81 65 74 -263 1 176 -223 -290 -109 -555 -380 -73 -126 -147 -622 -605 -442 -254 -66 -143 -479 -722 -497 -322 -190 53 -52 -61 237 200 380 51 100 353 297 281 344 94 -191 -143 114 413 476 637 -614 -1152 -843 -922 -542 -145 -281 -497 -265 -207 -186 260 99 -119 3 -267 330 682 600 776 918 655 956 678 363 282 475 778 1163 1380 1408 -30 -441 -247 -484 714 271 -69 242 70 346 -235 -444 -617 -910 -345 -997 -1286 -1434 -2414 -1625 -1040 -697 -261 20 406 315 336 212 -63 478 206 41 563 901 -83 -639 -460 -915 -73 283 -723 -1279 -593 -831 337 634 816 353 521 296 297 497 486 268 439 -286 -671 -60 309 212 803 408 518 1802 915 332 299 -566 -124 97 118 -438 2 288 -367 -494 -180 -885 -597 SS 20240810T130633.5Z 8988.546221 153 1 50.43 2 54.65 102.04 118.82 79.26 0.00 1 0.00 1 0 17 1.104e-02 6.336e-03 3.365e-04 1.394e-04 2.307881e-01 7.186970e-05 2.773013e-03 -6.000000e+00 6.471046e-03 232.05 -2.00 3.54 -2.00 316.77 0.00e+00 3.881665e-04 9.160493e-06 6.430056e-05 -6.000000e+00 2.904874e-04 289.05 -2.00 20.00 -2.00 315.92 0.00e+00 1.723 0.000 302.00 328.00 3 1.1786e-01 1.8975e-04 2.1133e-02 -6.0000e+00 1.6202e-02 1.1893e-02 2.1269e-04 1.2176e-02 -6.0000e+00 1.7532e-02 2.2958e-03 1.2348e-04 5.8779e-03 -6.0000e+00 1.0449e-02 -5.1756e-03 5.7787e-05 1.6156e-03 -6.0000e+00 4.3850e-03 6.4635e-02 4.9000e-04 4.1131e-06 1.9101e-05 -6.0000e+00 3.1189e-04 -6.8405e-03 0.0000e+00 10 0 0 10 0 0 11.63 19.52 0.38 -0.00684 -0.00316 3094 585 1 5 0 16.260 22.40 15.00 19.52 32.37 4.1 1026.94 -300 -1136 -723 -4091 -3814 -3320 -1417 -566 -760 -2461 -3810 -2453 -1744 -675 165 -59 -296 840 535 1378 121 375 1251 1202 744 975 290 -493 -336 391 1393 1311 1771 -1699 -3196 -2498 -2316 -1195 -286 -531 -781 -388 -325 -296 411 207 -194 10 -515 527 1084 939 1048 1292 800 1300 913 518 315 557 1046 1438 1635 1557 11 -541 -334 -705 934 307 -42 242 95 385 -244 -482 -781 -1150 -495 -1156 -1400 -1443 -2321 -1491 -893 -577 -249 26 342 236 310 163 -59 472 240 33 473 684 -47 -500 -379 -763 -49 251 -592 -989 -461 -544 224 472 524 223 362 230 202 414 374 168 321 -187 -463 -60 203 114 613 314 427 1368 697 234 218 -361 -72 61 60 -246 -17 186 -230 -285 -134 -530 -401 -48 -178 -113 -671 -562 -474 -212 -94 -139 -472 -733 -484 -346 -151 41 -16 -83 241 160 421 38 117 395 400 261 350 103 -165 -106 121 450 456 654 -651 -1172 -909 -928 -556 -144 -307 -490 -252 -216 -198 272 137 -125 6 -318 325 701 648 762 980 577 952 680 384 230 407 791 1165 1426 1422 10 -453 -260 -543 763 283 -43 233 91 380 -225 -398 -638 -906 -410 -998 -1353 -1418 -2439 -1635 -1044 -671 -304 33 423 279 363 174 -63 487 245 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