File name: Pandora155s1_BostonMA_20240828_L2Fit_fout2c2d20231025p1-8.txt File generation date: 20240829T045340.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Jeff Gedes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 155 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora155_OF_v6d20190702.txt Instrument calibration file used: Pandora155s1_CF_v2d20231025.txt Level 1 file used: Pandora155s1_BostonMA_20240828_L1_smca1c2d20231025p1-8.txt Full location name: Boston University Short location name: BostonMA Country of location: USA Location latitude [deg]: 42.3497 Location longitude [deg]: -71.1040 Location altitude [m]: 40 Local noon date: 20240828 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 232 374 Nominal wavelengths inside fitting window [nm]: 305.1059 305.2467 305.3875 305.5283 305.6692 305.8100 305.9507 306.0915 306.2323 306.3730 306.5138 306.6545 306.7952 306.9359 307.0766 307.2173 307.3580 307.4987 307.6393 307.7800 307.9206 308.0612 308.2018 308.3424 308.4830 308.6236 308.7641 308.9047 309.0452 309.1857 309.3263 309.4668 309.6073 309.7477 309.8882 310.0287 310.1691 310.3096 310.4500 310.5904 310.7308 310.8712 311.0116 311.1519 311.2923 311.4326 311.5730 311.7133 311.8536 311.9939 312.1342 312.2745 312.4148 312.5550 312.6953 312.8355 312.9757 313.1159 313.2561 313.3963 313.5365 313.6767 313.8168 313.9569 314.0971 314.2372 314.3773 314.5174 314.6575 314.7976 314.9376 315.0777 315.2177 315.3577 315.4978 315.6378 315.7778 315.9177 316.0577 316.1977 316.3376 316.4776 316.6175 316.7574 316.8973 317.0372 317.1771 317.3169 317.4568 317.5966 317.7365 317.8763 318.0161 318.1559 318.2957 318.4355 318.5752 318.7150 318.8547 318.9945 319.1342 319.2739 319.4136 319.5533 319.6930 319.8326 319.9723 320.1119 320.2515 320.3912 320.5308 320.6704 320.8099 320.9495 321.0891 321.2286 321.3682 321.5077 321.6472 321.7867 321.9262 322.0657 322.2051 322.3446 322.4840 322.6235 322.7629 322.9023 323.0417 323.1811 323.3204 323.4598 323.5992 323.7385 323.8778 324.0171 324.1565 324.2957 324.4350 324.5743 324.7136 324.8528 324.9920 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240828T123841.2Z 9006.526865 262 1 0.95 2 62.89 102.59 14.23 192.48 0.00 1 0.00 1 0 17 1.788e-02 7.857e-03 1.290e-02 4.904e-03 2.918186e-01 2.522755e-03 3.536396e-03 -6.000000e+00 1.041981e-02 230.69 -2.00 3.54 -2.00 316.84 0.00e+00 -3.232620e-04 3.294302e-04 7.628082e-05 -6.000000e+00 4.684155e-04 288.07 -2.00 20.00 -2.00 316.01 0.00e+00 2.182 0.000 302.00 328.00 3 2.5089e+00 6.6423e-03 2.6693e-02 -6.0000e+00 2.6008e-02 9.9068e-03 7.4516e-03 1.5386e-02 -6.0000e+00 2.8187e-02 5.2313e-03 4.3535e-03 7.4528e-03 -6.0000e+00 1.6808e-02 -7.7331e-03 2.0723e-03 2.0409e-03 -6.0000e+00 7.0608e-03 3.4428e-03 -3.6987e-04 1.4263e-04 2.4954e-05 -6.0000e+00 5.0508e-04 -1.3587e-02 0.0000e+00 12 9 1 12 1 1 999.00 23.64 0.41 -0.01359 -0.01637 2 31 1 5 0 315.640 26.51 20.00 23.64 30.61 4.2 1012.87 -4316 -4389 2913 -3203 -6931 3970 -8256 4027 -5942 305 -5221 -1969 -3047 -852 281 -564 -1003 -661 1940 -419 1166 1003 3357 1354 2057 825 2913 -1063 -469 -2501 2356 -673 3458 -1521 -2479 -1659 -3812 -1310 -960 -1159 -1075 -227 -164 -612 810 435 795 638 -244 -234 971 1117 1694 999 1021 555 977 409 1000 -710 1278 1117 1602 799 -517 -381 775 -167 970 1628 81 1172 -33 -71 -988 -745 -743 -1058 -150 -1760 -1436 -1712 -2672 -1113 -484 -1293 15 -378 -191 170 691 -196 337 339 1240 81 -475 610 -388 -213 -563 238 24 948 -611 -805 -402 4 407 693 292 239 745 533 98 -58 354 66 37 -63 -1133 -469 202 77 -61 500 404 1919 1060 -65 621 -602 6 151 -147 -613 385 80 -410 -335 149 -210 -576 -573 -631 394 -428 -873 482 -1122 547 -988 50 -903 -348 -618 -180 67 -148 -278 -191 570 -121 337 314 987 433 691 290 989 -353 -146 -800 771 -248 1317 -615 -959 -640 -1556 -616 -506 -665 -671 -139 -103 -388 505 272 486 406 -155 -143 625 772 1170 732 772 432 732 306 768 -555 967 914 1349 716 -462 -316 627 -136 807 1447 79 1125 -32 -68 -886 -628 -600 -834 -125 -1608 -1402 -1764 -2836 -1226 -546 -1509 19 -471 -236 201 779 -212 350 350 1301 92 -579 780 -505 -280 -720 289 28 1150 -782 -1048 -526 5 567 994 442 363 1082 746 132 -77 472 89 52 -93 -1660 -695 289 110 -83 663 514 2457 1418 -90 908 -884 9 228 -236 -1005 642 132 -681 -558 237 -333 -906 SS 20240828T123907.2Z 9006.527167 264 1 3.81 2 62.81 102.67 14.25 192.85 0.00 1 0.00 1 0 17 1.234e-02 6.560e-03 4.337e-03 1.608e-03 2.883852e-01 8.238770e-04 3.470068e-03 -6.000000e+00 7.190546e-03 230.69 -2.00 3.54 -2.00 316.96 0.00e+00 2.956407e-04 1.103983e-04 1.092568e-04 -6.000000e+00 3.233281e-04 288.07 -2.00 20.00 -2.00 316.12 0.00e+00 2.176 0.000 302.00 328.00 3 2.0161e+00 2.1756e-03 2.6498e-02 -6.0000e+00 1.7948e-02 3.9448e-03 2.4443e-03 1.5128e-02 -6.0000e+00 1.9453e-02 1.5487e-03 1.4324e-03 7.3297e-03 -6.0000e+00 1.1600e-02 -3.8245e-03 6.8420e-04 1.9943e-03 -6.0000e+00 4.8716e-03 5.7079e-03 -3.7204e-04 4.6803e-05 2.3789e-05 -6.0000e+00 3.4864e-04 -1.2075e-02 0.0000e+00 12 9 1 12 1 1 71.51 23.65 0.28 -0.01207 -0.01487 20 54 1 5 0 181.360 26.51 20.01 23.65 30.61 4.2 1013.15 -1996 -1464 -2792 -3066 -5354 -3878 -2412 -1931 -809 -3122 -2108 -2984 -752 -1468 1648 -931 1025 629 825 385 -206 429 744 313 866 1825 -1107 18 -1534 781 742 2517 1070 -1501 -3706 -2050 -2641 -1178 -189 -448 -1340 -611 -403 44 569 -262 25 -400 -292 803 1334 1179 1815 1083 799 1164 782 605 170 1019 983 1732 1491 1220 -99 -428 -186 199 1233 569 14 -32 -244 53 -284 -560 -515 -1015 -33 -1507 -1049 -1558 -2394 -1410 -937 -695 -150 -27 324 133 100 423 296 686 23 341 129 536 -567 -459 -400 -475 -17 191 -844 -1007 -428 -418 525 340 521 -48 579 180 543 640 501 191 314 -455 -435 -42 243 262 447 292 593 1403 393 138 156 -269 7 147 114 -372 -11 37 -319 -429 -74 -449 -246 -266 -193 -376 -419 -680 -477 -315 -283 -119 -487 -326 -493 -138 -314 390 -228 259 167 228 111 -60 125 224 100 291 627 -386 6 -479 240 245 890 385 -558 -1334 -730 -1050 -509 -97 -248 -814 -363 -245 27 345 -160 16 -250 -181 503 832 790 1282 766 585 869 595 457 127 755 759 1358 1274 1047 -85 -359 -147 155 1034 514 13 -31 -235 51 -254 -475 -421 -813 -26 -1320 -1027 -1606 -2528 -1555 -1054 -834 -180 -33 396 155 113 453 308 707 24 383 155 679 -758 -598 -507 -579 -20 233 -1075 -1299 -576 -567 747 498 772 -71 857 257 744 834 658 265 448 -665 -645 -62 355 366 617 384 777 1862 543 197 225 -401 11 226 180 -614 -19 62 -532 -721 -119 -725 -392 SS 20240828T123942.3Z 9006.527573 266 1 4.57 2 62.70 102.79 14.27 193.35 0.00 1 0.00 1 0 17 1.280e-02 6.474e-03 4.996e-03 1.803e-03 2.883480e-01 9.249304e-04 3.476691e-03 -6.000000e+00 7.459932e-03 230.69 -2.00 3.54 -2.00 317.02 0.00e+00 3.704272e-04 1.261910e-04 1.274994e-04 -6.000000e+00 3.354040e-04 288.07 -2.00 20.00 -2.00 316.20 0.00e+00 2.169 0.000 302.00 328.00 3 2.3934e+00 2.4431e-03 2.6454e-02 -6.0000e+00 1.8620e-02 1.0758e-02 2.7441e-03 1.5155e-02 -6.0000e+00 2.0181e-02 -2.3537e-03 1.6101e-03 7.3407e-03 -6.0000e+00 1.2034e-02 -2.3249e-03 7.7175e-04 2.0018e-03 -6.0000e+00 5.0545e-03 3.9326e-03 -3.6213e-04 5.2524e-05 2.3815e-05 -6.0000e+00 3.6166e-04 -1.2743e-02 0.0000e+00 12 9 1 12 1 1 99.76 23.65 0.24 -0.01274 -0.01546 18 40 1 5 0 240.180 26.51 20.01 23.65 30.63 4.3 1013.15 -601 -2814 -244 -4668 -2616 -4854 -396 -4027 605 -4418 -2413 -3709 -244 -1400 1094 -31 -1117 1139 254 1911 -511 1079 1317 2148 -421 2071 43 211 -713 1060 97 1821 1831 -2185 -2695 -3007 -1820 -1806 -85 -995 -92 -947 -19 -978 330 -113 -422 -185 -517 588 1407 1338 696 1191 524 1436 401 840 -3 714 1082 1656 1536 1508 -77 -248 328 -442 1019 142 198 97 -119 100 -297 -464 -395 -1155 21 -1051 -947 -1430 -2332 -1297 -830 -476 -213 138 17 267 224 4 -155 690 218 89 536 724 -433 -695 -260 -818 173 59 -823 -1196 -214 -713 578 445 548 362 550 454 168 571 519 197 91 -249 -834 78 144 136 653 347 476 1152 558 -28 207 -278 -146 -33 51 -511 76 135 -267 -103 -142 -438 -186 -75 -386 -33 -612 -305 -568 -48 -567 90 -715 -384 -632 -42 -281 244 -8 -293 305 72 549 -141 317 368 631 -134 663 14 64 -206 303 30 605 656 -822 -965 -1085 -720 -783 -44 -550 -55 -557 -11 -596 198 -68 -250 -115 -318 365 865 884 490 827 377 1050 301 623 -2 521 819 1346 1282 1329 -68 -203 266 -359 837 126 190 96 -117 94 -274 -384 -316 -907 17 -942 -902 -1429 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