File name: Pandora155s1_BostonMA_20241002_L2Fit_fout2c2d20231025p1-8.txt File generation date: 20241003T043649.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Jeff Gedes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 155 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora155_OF_v6d20190702.txt Instrument calibration file used: Pandora155s1_CF_v2d20231025.txt Level 1 file used: Pandora155s1_BostonMA_20241002_L1_smca1c2d20231025p1-8.txt Full location name: Boston University Short location name: BostonMA Country of location: USA Location latitude [deg]: 42.3497 Location longitude [deg]: -71.1040 Location altitude [m]: 40 Local noon date: 20241002 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 232 374 Nominal wavelengths inside fitting window [nm]: 305.1059 305.2467 305.3875 305.5283 305.6692 305.8100 305.9507 306.0915 306.2323 306.3730 306.5138 306.6545 306.7952 306.9359 307.0766 307.2173 307.3580 307.4987 307.6393 307.7800 307.9206 308.0612 308.2018 308.3424 308.4830 308.6236 308.7641 308.9047 309.0452 309.1857 309.3263 309.4668 309.6073 309.7477 309.8882 310.0287 310.1691 310.3096 310.4500 310.5904 310.7308 310.8712 311.0116 311.1519 311.2923 311.4326 311.5730 311.7133 311.8536 311.9939 312.1342 312.2745 312.4148 312.5550 312.6953 312.8355 312.9757 313.1159 313.2561 313.3963 313.5365 313.6767 313.8168 313.9569 314.0971 314.2372 314.3773 314.5174 314.6575 314.7976 314.9376 315.0777 315.2177 315.3577 315.4978 315.6378 315.7778 315.9177 316.0577 316.1977 316.3376 316.4776 316.6175 316.7574 316.8973 317.0372 317.1771 317.3169 317.4568 317.5966 317.7365 317.8763 318.0161 318.1559 318.2957 318.4355 318.5752 318.7150 318.8547 318.9945 319.1342 319.2739 319.4136 319.5533 319.6930 319.8326 319.9723 320.1119 320.2515 320.3912 320.5308 320.6704 320.8099 320.9495 321.0891 321.2286 321.3682 321.5077 321.6472 321.7867 321.9262 322.0657 322.2051 322.3446 322.4840 322.6235 322.7629 322.9023 323.0417 323.1811 323.3204 323.4598 323.5992 323.7385 323.8778 324.0171 324.1565 324.2957 324.4350 324.5743 324.7136 324.8528 324.9920 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241002T121000.9Z 9041.506955 75 1 51.16 2 75.20 109.61 73.31 110.82 0.00 1 0.00 1 0 25 2.384e-01 1.571e-02 1.715e-01 8.882e-03 4.955353e-01 4.608688e-03 5.879219e-03 -6.000000e+00 1.379111e-01 227.12 -2.00 3.54 -2.00 320.36 0.00e+00 2.009374e-03 1.693481e-03 1.622398e-03 -6.000000e+00 6.158988e-03 284.51 -2.00 20.00 -2.00 319.68 0.00e+00 3.836 0.001 302.00 328.00 3 4.3574e+00 1.4058e-02 4.6554e-02 -6.0000e+00 3.4190e-01 1.3267e-01 1.7376e-02 2.7445e-02 -6.0000e+00 3.7211e-01 -7.2786e-02 1.4556e-02 1.3697e-02 -6.0000e+00 2.2117e-01 2.2959e-02 7.3284e-03 3.8610e-03 -6.0000e+00 9.2761e-02 8.0873e-05 -6.6290e-04 2.6677e-04 5.2573e-05 -6.0000e+00 6.8153e-03 -5.4502e-03 0.0000e+00 12 9 8 11 8 0 99.24 23.06 0.12 -0.00545 -0.01043 16 3 1 5 0 3196.990 26.11 20.01 23.06 21.31 4.6 942.75 -7679 -100601 -65799 -32629 15369 -106363 900000 -138704 -11715 -61727 292 -85821 10534 -44638 -815 -8260 54297 41621 -6057 29568 -11235 34894 -42792 42825 -10829 40467 -30665 9394 -28363 23241 -9725 2984 15192 -9797 14326 -16498 6828 -7694 -586 3061 11661 -8280 10979 903 7115 7556 112 3244 1084 3635 4865 9401 2521 8744 -2374 6492 -391 10916 -1636 3021 474 6772 -762 4086 2464 1035 2758 -1154 1839 647 4529 -1455 3218 1133 3775 -5219 -1578 -2242 864 -4002 -212 -1150 -4719 -1401 -2066 -557 -724 1430 -1015 -1103 -1261 692 -1196 427 -1287 526 1301 -213 -134 -134 -770 -1995 62 -1456 230 -3135 -312 -1570 1172 691 445 481 1552 575 317 103 -270 814 -1257 291 -974 1323 341 732 390 1037 1004 1952 717 123 578 -869 106 -975 856 -1376 191 652 380 -1167 41 -252 -221 -87 -3086 -1472 -516 145 -3109 900000 -6631 -190 -1671 5 -3468 206 -1788 -25 -316 1268 1191 -284 1014 -588 1158 -3113 1484 -684 1592 -2445 481 -2088 1090 -726 225 1129 -958 1055 -1679 616 -920 -79 463 1781 -1635 1856 171 1282 1372 22 627 220 759 1099 2224 690 2402 -761 1966 -129 3180 -528 928 156 2308 -312 1727 1068 435 1107 -495 848 342 2495 -876 1814 615 1820 -2481 -677 -980 407 -2297 -134 -820 -3745 -1138 -1807 -510 -696 1373 -988 -1024 -1087 542 -912 329 -1117 510 1423 -255 -168 -165 -918 -2185 63 -1555 259 -3855 -392 -2128 1611 1045 725 802 2500 882 475 148 -396 1193 -1998 472 -1592 2049 536 1101 562 1421 1338 2699 1110 201 1012 -1611 202 -1987 1820 -3120 436 1501 871 -2604 86 -504 -436 SS 20241002T130849.4Z 9041.547794 100 1 2.01 2 65.40 121.23 63.98 122.61 0.00 1 0.00 1 0 25 2.053e-02 8.216e-03 1.300e-02 4.119e-03 3.160746e-01 2.082791e-03 3.810321e-03 -6.000000e+00 1.180046e-02 227.11 -2.00 3.54 -2.00 317.21 0.00e+00 9.959800e-04 3.023372e-04 9.069127e-05 -6.000000e+00 5.296215e-04 284.50 -2.00 20.00 -2.00 316.46 0.00e+00 2.386 0.000 302.00 328.00 3 2.7779e+00 5.4844e-03 2.8817e-02 -6.0000e+00 2.9239e-02 3.1175e-02 6.1855e-03 1.6352e-02 -6.0000e+00 3.1794e-02 1.3137e-03 3.6985e-03 8.0059e-03 -6.0000e+00 1.8974e-02 -7.3609e-03 1.8158e-03 2.3673e-03 -6.0000e+00 8.0007e-03 2.0660e-03 5.3045e-04 1.1962e-04 2.6645e-05 -6.0000e+00 5.7916e-04 -1.2642e-02 0.0000e+00 12 9 1 12 9 1 -109.53 23.28 0.37 -0.01264 -0.00866 3 19 1 5 0 501.360 26.32 20.01 23.28 22.60 4.6 952.52 -10254 -299 -4569 -4295 -2630 1325 367 -2286 -3404 -7298 1172 -7721 6349 -6572 1165 -4299 3444 1141 3829 -438 857 -1341 -1505 -1138 -884 2829 -3440 3090 -3197 2695 -242 1096 1350 -644 -3726 -1458 -2698 -1782 1509 6 730 -631 -30 -167 1519 -716 -300 -938 831 63 1576 703 459 1128 1287 939 1423 640 180 156 315 2197 1826 2876 385 50 57 -305 92 30 -397 -675 -344 554 179 -999 787 -1582 -391 -1041 -656 -1404 -2569 -1943 -985 -684 -129 179 -57 -517 195 447 -517 863 239 533 -237 861 290 -955 -362 -556 765 263 -975 -1325 -544 -949 698 382 986 -74 976 -59 464 375 341 540 -281 -280 -747 212 -51 476 364 570 524 1507 938 267 124 76 78 -413 161 -362 -75 15 -264 -576 345 -987 -130 -1170 -34 -541 -471 -258 124 37 -269 -446 -975 154 -1122 924 -1273 228 -976 765 273 931 -115 225 -361 -399 -319 -261 830 -1059 841 -886 756 -72 355 472 -220 -1309 -506 -1005 -743 697 3 407 -358 -17 -98 877 -423 -174 -540 487 37 969 451 313 777 912 684 1045 469 130 113 239 1707 1498 2468 323 40 45 -243 77 27 -380 -649 -325 510 158 -826 608 -1229 -324 -921 -630 -1447 -2762 -2126 -1111 -798 -157 216 -69 -611 218 482 -541 891 260 607 -288 1109 382 -1271 -457 -666 894 314 -1239 -1731 -721 -1293 995 557 1503 -112 1436 -84 635 504 462 749 -400 -419 -1107 313 -73 665 497 759 690 1970 1296 389 186 115 120 -657 264 -609 -127 25 -451 -959 558 -1593 -205 SS 20241002T130911.9Z 9041.548055 102 1 2.63 2 65.34 121.31 63.92 122.69 0.00 1 0.00 1 0 17 1.685e-02 6.934e-03 3.357e-03 1.136e-03 3.157626e-01 5.742218e-04 3.811649e-03 -6.000000e+00 9.679487e-03 227.11 -2.00 3.54 -2.00 317.15 0.00e+00 4.594444e-04 8.129446e-05 7.833913e-05 -6.000000e+00 4.348287e-04 284.50 -2.00 20.00 -2.00 316.38 0.00e+00 2.381 0.000 302.00 328.00 3 7.7310e-01 1.5089e-03 2.8760e-02 -6.0000e+00 2.3982e-02 1.7493e-02 1.7028e-03 1.6303e-02 -6.0000e+00 2.6086e-02 -2.9763e-03 1.0124e-03 7.9942e-03 -6.0000e+00 1.5567e-02 -2.2084e-03 4.9197e-04 2.2434e-03 -6.0000e+00 6.5578e-03 1.5571e-02 -2.5582e-04 3.2909e-05 2.6154e-05 -6.0000e+00 4.7546e-04 -7.0415e-03 0.0000e+00 12 9 1 12 1 1 86.59 23.28 0.31 -0.00704 -0.00896 41 156 1 5 0 62.480 26.32 20.01 23.28 22.60 4.6 952.52 -134 -4681 -1291 -7597 -4825 -7898 -2463 -4579 -1344 -5788 -5429 -4233 -2230 -1518 180 193 304 1716 364 2224 -799 1409 372 1024 453 1261 -399 -875 -621 285 1376 918 1699 -2653 -2403 -2649 -1666 -1276 234 -695 -663 -199 66 -207 589 130 -129 481 -301 941 1025 1584 1404 1615 842 1436 974 319 208 750 1164 1500 1717 1257 -239 -334 -121 -416 1315 76 -189 34 -67 202 -563 -572 -819 -936 -445 -1384 -1387 -1636 -2585 -1423 -987 -522 -326 184 295 160 401 211 297 664 237 91 514 532 -198 -660 -406 -716 199 172 -804 -1053 -581 -485 398 574 341 193 328 434 497 682 394 254 66 -508 -564 -1 233 190 741 311 874 1458 654 260 98 -272 19 8 -3 -414 136 20 -354 -354 -224 -492 -262 -15 -586 -158 -917 -516 -862 -276 -591 -185 -867 -817 -674 -367 -289 39 46 76 408 92 570 -214 370 102 298 140 399 -127 -263 -177 82 426 313 578 -949 -813 -909 -630 -532 115 -373 -386 -114 39 -122 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