File name: Pandora155s1_BostonMA_20241028_L2Fit_fout2c2d20231025p1-8.txt File generation date: 20241029T043356.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Jeff Gedes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 155 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora155_OF_v6d20190702.txt Instrument calibration file used: Pandora155s1_CF_v2d20231025.txt Level 1 file used: Pandora155s1_BostonMA_20241028_L1_smca1c2d20231025p1-8.txt Full location name: Boston University Short location name: BostonMA Country of location: USA Location latitude [deg]: 42.3497 Location longitude [deg]: -71.1040 Location altitude [m]: 40 Local noon date: 20241028 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 232 374 Nominal wavelengths inside fitting window [nm]: 305.1059 305.2467 305.3875 305.5283 305.6692 305.8100 305.9507 306.0915 306.2323 306.3730 306.5138 306.6545 306.7952 306.9359 307.0766 307.2173 307.3580 307.4987 307.6393 307.7800 307.9206 308.0612 308.2018 308.3424 308.4830 308.6236 308.7641 308.9047 309.0452 309.1857 309.3263 309.4668 309.6073 309.7477 309.8882 310.0287 310.1691 310.3096 310.4500 310.5904 310.7308 310.8712 311.0116 311.1519 311.2923 311.4326 311.5730 311.7133 311.8536 311.9939 312.1342 312.2745 312.4148 312.5550 312.6953 312.8355 312.9757 313.1159 313.2561 313.3963 313.5365 313.6767 313.8168 313.9569 314.0971 314.2372 314.3773 314.5174 314.6575 314.7976 314.9376 315.0777 315.2177 315.3577 315.4978 315.6378 315.7778 315.9177 316.0577 316.1977 316.3376 316.4776 316.6175 316.7574 316.8973 317.0372 317.1771 317.3169 317.4568 317.5966 317.7365 317.8763 318.0161 318.1559 318.2957 318.4355 318.5752 318.7150 318.8547 318.9945 319.1342 319.2739 319.4136 319.5533 319.6930 319.8326 319.9723 320.1119 320.2515 320.3912 320.5308 320.6704 320.8099 320.9495 321.0891 321.2286 321.3682 321.5077 321.6472 321.7867 321.9262 322.0657 322.2051 322.3446 322.4840 322.6235 322.7629 322.9023 323.0417 323.1811 323.3204 323.4598 323.5992 323.7385 323.8778 324.0171 324.1565 324.2957 324.4350 324.5743 324.7136 324.8528 324.9920 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241028T121003.5Z 9067.506985 145 1 25.69 2 81.18 117.27 44.40 143.39 0.00 1 0.00 1 0 25 6.357e-01 1.484e-02 3.164e-01 6.319e-03 8.101493e-01 3.529466e-03 8.840028e-03 -6.000000e+00 3.633947e-01 224.46 -2.00 3.54 -2.00 321.86 0.00e+00 3.115390e-03 2.043556e-03 1.767065e-03 -6.000000e+00 1.839623e-02 281.28 -2.00 20.00 -2.00 321.36 0.00e+00 6.169 0.004 302.00 328.00 3 1.0267e+00 1.3443e-02 7.5329e-02 -6.0000e+00 8.9688e-01 3.2592e-01 2.0005e-02 4.5511e-02 -6.0000e+00 9.7992e-01 -4.2436e-01 2.1039e-02 2.4902e-02 -6.0000e+00 5.8310e-01 1.5900e-01 9.5578e-03 8.3444e-03 -6.0000e+00 2.4628e-01 1.8683e-04 -5.8997e-04 1.7644e-04 1.2059e-04 -6.0000e+00 1.8135e-02 1.2320e-03 0.0000e+00 12 9 9 12 1 1 98.26 22.06 0.54 0.00123 -0.00320 53 20 1 5 0 475.610 25.28 20.44 22.06 11.41 4.7 866.39 -154414 -185362 -165901 7594 -125024 -200388 -99870 -242019 900000 -265075 900000 -223641 900000 -150837 900000 -102262 -35929 -64086 -29886 89044 -49240 61321 -90671 284557 -38021 900000 -91622 154385 -59218 33697 -22884 26186 -34805 -15499 -23261 -36202 21785 -54339 25962 -12125 36963 -6325 43171 731 23873 -15118 33103 -1189 7094 12078 5788 12900 7068 18478 716 23941 8878 31098 -7032 17683 -1662 12088 7286 11218 12152 4848 7125 -532 13584 3825 10219 3413 8399 187 3750 -6075 1597 -2010 1729 490 -321 -559 -4634 -118 -2117 816 -1421 2313 -625 1832 -1003 376 -2240 884 -2568 -847 -315 196 -109 -1042 -547 -3448 -347 -2652 -920 -3510 -626 -906 375 -1081 404 739 85 340 -134 1003 -693 280 -791 429 -911 1798 246 1263 1151 879 274 1458 692 -153 752 -600 136 -456 343 -635 648 146 77 -286 24 -548 -652 -951 -1453 -1114 47 -770 -1682 -615 -3793 900000 -6232 900000 -4632 900000 -2617 900000 -1660 -376 -897 -350 548 -661 378 -1979 1752 -632 900000 -2462 951 -1276 332 -493 419 -1071 -408 -702 -1155 483 -2829 815 -597 1241 -351 1675 40 1056 -1015 1427 -77 453 811 470 1098 704 1789 88 2426 1063 2924 -933 1811 -218 1556 1138 1896 2129 912 1340 -116 2920 1034 2803 1024 2313 52 896 -1452 344 -483 470 163 -126 -252 -2376 -61 -1101 436 -808 1288 -353 1047 -552 195 -1194 497 -1592 -609 -264 187 -111 -1054 -508 -2934 -265 -2124 -775 -3202 -593 -939 432 -1445 593 1143 133 514 -195 1411 -1016 428 -1283 696 -1450 2654 355 1748 1541 1142 358 2055 1138 -290 1435 -1245 298 -1079 860 -1671 1712 390 202 -714 56 -1194 -1405 SS 20241028T121158.6Z 9067.508317 147 1 50.26 2 80.87 117.62 44.20 144.00 0.00 1 0.00 1 0 25 6.513e-01 1.108e-02 1.931e-01 4.249e-03 7.919103e-01 2.345778e-03 8.749732e-03 -6.000000e+00 3.701361e-01 224.46 -2.00 3.54 -2.00 321.87 0.00e+00 5.519286e-03 1.352351e-03 1.782519e-03 -6.000000e+00 1.659068e-02 281.28 -2.00 20.00 -2.00 321.36 0.00e+00 5.980 0.004 302.00 328.00 3 7.7137e-01 8.8476e-03 7.3057e-02 -6.0000e+00 9.1245e-01 2.7944e-01 1.3083e-02 4.4008e-02 -6.0000e+00 9.9534e-01 -3.7125e-01 1.3749e-02 2.4575e-02 -6.0000e+00 5.9402e-01 1.4404e-01 6.2646e-03 9.7797e-03 -6.0000e+00 2.5054e-01 2.9253e-04 -7.1522e-04 1.1829e-04 1.3422e-04 -6.0000e+00 1.8368e-02 9.4667e-04 0.0000e+00 12 8 8 10 0 0 81.99 22.05 0.45 0.00095 -0.00443 156 30 1 5 0 322.100 25.28 20.12 22.05 11.57 4.6 868.27 -263767 -134490 -233915 -175512 -237222 -188089 -235503 -215078 -159857 -191959 -106561 -169860 -130627 -175072 -97562 -81869 -45429 -48446 -7030 -27203 -33634 -66878 -27647 -48608 -31803 -50185 -38167 -4198 -35736 8244 -24638 23786 -23365 -10889 -15944 4045 -17331 19268 22140 13208 19008 2173 14031 22256 21873 -3825 7478 -2793 131265 2577 12540 -701 12674 4422 6590 11109 2582 8167 4810 4168 7876 8174 5033 13450 3805 7902 4486 6221 4666 6687 4272 3547 1607 1346 442 429 866 -1542 -512 -2144 1706 -2952 -1145 -1632 178 334 694 745 103 666 -15 -608 -2493 -365 -2235 -810 -934 98 -373 -127 -992 -530 -302 -1168 -2213 -2421 -1136 -945 153 -282 560 267 56 -319 397 157 213 31 312 114 -128 781 423 1221 210 616 394 1768 186 254 359 -29 87 -143 -131 -290 146 21 -3 -329 125 -348 -262 -3775 -669 -2996 -1309 -2770 -1481 -2927 -2673 -1258 -2227 -574 -2111 -1461 -3693 -1334 -1153 -508 -622 -64 -316 -418 -1164 -344 -806 -474 -936 -633 -49 -592 102 -531 384 -697 -298 -443 94 -560 519 706 542 819 119 715 1070 1078 -252 459 -183 2665 190 949 -68 1189 490 755 1264 325 954 562 487 938 1096 806 2229 727 1444 865 1261 1090 1746 1236 1057 472 366 109 96 188 -367 -142 -727 655 -1354 -563 -857 98 194 419 457 63 384 -8 -316 -1319 -205 -1483 -625 -846 100 -376 -126 -993 -471 -249 -991 -2029 -2348 -1161 -1050 173 -366 801 404 85 -473 559 217 299 46 485 180 -197 1135 594 1645 276 851 543 2403 296 461 717 -61 198 -350 -341 -788 402 57 -8 -852 299 -787 -584 SS 20241028T121405.0Z 9067.509780 149 1 50.46 2 80.53 118.01 43.99 144.67 0.00 1 0.00 1 0 25 5.481e-01 1.012e-02 2.271e-01 4.379e-03 7.665055e-01 2.386409e-03 8.593402e-03 -6.000000e+00 3.114619e-01 224.46 -2.00 3.54 -2.00 321.76 0.00e+00 7.080458e-03 1.329892e-03 2.019792e-03 -6.000000e+00 1.396081e-02 281.28 -2.00 20.00 -2.00 321.24 0.00e+00 5.786 0.004 302.00 328.00 3 1.0755e+00 8.6946e-03 7.0391e-02 -6.0000e+00 7.6781e-01 2.6721e-01 1.2824e-02 4.1979e-02 -6.0000e+00 8.3756e-01 -3.1478e-01 1.3461e-02 2.4521e-02 -6.0000e+00 4.9986e-01 1.1241e-01 6.1772e-03 1.0882e-02 -6.0000e+00 2.1082e-01 2.6170e-04 -6.0007e-04 1.2187e-04 1.3767e-04 -6.0000e+00 1.5456e-02 9.9802e-04 0.0000e+00 12 8 8 10 0 0 99.58 22.07 0.40 0.00100 -0.00351 120 23 1 5 0 420.470 25.28 20.42 22.07 11.80 4.7 870.07 -166016 -180319 -14248 -180052 -170995 -209627 -217216 -100389 -100815 -159145 -212511 -125180 -136532 -15922 -123155 -45505 -86184 -60157 -58079 -68218 -53301 -67302 -45324 -78789 -21356 -70953 -33320 -64518 -24765 -51604 -6307 -9898 5937 -31472 11518 -23162 2236 -7689 1246 -253 2238 8528 6184 2022 -4974 13556 935 17394 4718 17704 5613 12370 13898 14155 10104 11084 7786 -1662 4392 1409 2070 32 8695 5207 9640 3132 5714 3982 4292 4566 4137 3554 1968 2993 -1186 -819 -2330 -1758 -3122 -5104 -1063 -436 -2300 -273 -417 716 358 256 1774 322 414 -673 19 -2009 -594 -1676 81 239 -205 -309 -703 -2075 -1173 -588 -1937 -1204 -1741 -657 -215 405 234 602 176 668 -91 174 108 -168 143 -285 232 411 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