File name: Pandora155s1_BostonMA_20241112_L2Fit_fwvt1c9d20240425p1-8.txt File generation date: 20241210T104347.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c9p1-8 Local principal investigator: Jeff Gedes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 155 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora155_OF_v6d20190702.txt Instrument calibration file used: Pandora155s1_CF_v9d20240425.txt Level 1 file used: Pandora155s1_BostonMA_20241112_L1_smca1c9d20240425p1-8.txt Full location name: Boston University Short location name: BostonMA Country of location: USA Location latitude [deg]: 42.3497 Location longitude [deg]: -71.1040 Location altitude [m]: 40 Local noon date: 20241112 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1653 1802 Nominal wavelengths inside fitting window [nm]: 492.1080 492.2290 492.3500 492.4710 492.5920 492.7130 492.8339 492.9548 493.0758 493.1966 493.3175 493.4384 493.5592 493.6801 493.8009 493.9217 494.0425 494.1632 494.2840 494.4047 494.5254 494.6461 494.7668 494.8874 495.0081 495.1287 495.2493 495.3699 495.4905 495.6111 495.7316 495.8521 495.9727 496.0932 496.2136 496.3341 496.4545 496.5750 496.6954 496.8158 496.9362 497.0565 497.1769 497.2972 497.4175 497.5378 497.6581 497.7784 497.8986 498.0188 498.1390 498.2592 498.3794 498.4996 498.6197 498.7399 498.8600 498.9801 499.1001 499.2202 499.3402 499.4603 499.5803 499.7003 499.8203 499.9402 500.0602 500.1801 500.3000 500.4199 500.5398 500.6596 500.7795 500.8993 501.0191 501.1389 501.2587 501.3784 501.4982 501.6179 501.7376 501.8573 501.9770 502.0966 502.2163 502.3359 502.4555 502.5751 502.6947 502.8142 502.9338 503.0533 503.1728 503.2923 503.4118 503.5312 503.6507 503.7701 503.8895 504.0089 504.1283 504.2476 504.3669 504.4863 504.6056 504.7249 504.8441 504.9634 505.0826 505.2018 505.3210 505.4402 505.5594 505.6785 505.7977 505.9168 506.0359 506.1550 506.2741 506.3931 506.5121 506.6312 506.7501 506.8691 506.9881 507.1070 507.2260 507.3449 507.4638 507.5827 507.7015 507.8204 507.9392 508.0580 508.1768 508.2956 508.4144 508.5331 508.6518 508.7705 508.8892 509.0079 509.1266 509.2452 509.3638 509.4824 509.6010 509.7196 509.8382 509.9567 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241112T120846.2Z 9082.506091 111 1 5.89 2 84.81 120.03 133.53 332.09 0.00 1 0.00 1 0 15 2.563e-03 2.552e-03 1.114e-04 1.112e-04 6.655603e+03 7.186263e+00 4.568799e+02 -6.000000e+00 1.412540e+02 279.41 -2.00 20.00 -2.00 505.31 0.00e+00 1.850053e-03 3.049127e-06 1.054503e-04 -6.000000e+00 7.146364e-05 279.41 -2.00 20.00 -2.00 500.61 0.00e+00 7.579830e-01 2.183176e-03 5.133700e-02 -6.000000e+00 5.070991e-02 223.11 -2.00 3.54 -2.00 502.18 0.00e+00 9.559 0.016 489.00 513.00 1 7.1786e-03 1.6708e-04 1.4710e-02 -6.0000e+00 3.8861e-03 -4.5984e-03 4.2631e-05 1.4059e-03 -6.0000e+00 1.0065e-03 4.5678e-01 9.2994e-04 1.0955e-05 6.6167e-05 -6.0000e+00 2.6431e-04 7.1626e-03 -1.1062e-04 10 0 0 10 0 0 -3.32 22.42 1.59 0.00716 0.01361 690 133 1 4 0 8.520 25.58 19.87 22.42 17.12 4.8 914.06 -530 -584 -337 -77 192 425 418 325 326 200 92 -75 -176 -140 -171 -63 -37 -11 64 46 140 200 208 266 290 254 116 -47 -190 -278 -171 -210 -148 -33 32 87 220 120 55 17 20 56 141 178 144 154 118 25 -173 -343 -507 -484 -471 -340 -238 -142 -35 111 292 362 443 398 347 273 219 134 14 -158 -215 -230 -128 -18 -67 -67 -151 -177 -194 -216 -289 -372 -386 -375 -369 -224 -229 -252 -209 -138 -75 124 140 136 115 126 456 165 -38 -226 -347 -468 -332 -255 -191 -188 -278 -223 -138 -136 -97 -34 -53 119 317 504 601 601 477 357 217 232 309 254 254 135 44 32 193 95 40 -88 -210 -220 -113 -148 -91 -15 -62 -23 181 305 304 367 324 102 -137 -301 -392 -339 -333 -284 -499 -563 -327 -77 191 431 431 337 337 204 93 -75 -173 -139 -171 -62 -37 -12 65 47 144 206 215 277 302 265 120 -48 -189 -277 -169 -209 -148 -34 33 90 224 124 57 18 21 56 144 184 151 161 122 26 -174 -345 -498 -466 -464 -331 -239 -143 -36 114 300 372 456 402 353 276 225 136 14 -156 -210 -228 -126 -18 -66 -67 -150 -174 -188 -212 -281 -362 -377 -361 -358 -219 -227 -251 -208 -137 -75 123 138 135 115 125 445 161 -36 -216 -326 -435 -310 -238 -186 -184 -279 -224 -137 -134 -95 -34 -52 119 320 510 612 616 482 362 219 235 309 251 250 134 44 32 193 95 40 -88 -208 -214 -109 -142 -87 -15 -61 -23 183 311 306 371 330 104 -140 -304 -398 -337 -327 -280 SQ 20241112T120852.4Z 9082.506162 111 2 5.91 2 84.79 120.05 133.54 332.12 0.00 1 0.00 1 0 22 2.572e-03 2.560e-03 1.111e-04 1.110e-04 6.616355e+03 7.162768e+00 4.542840e+02 -6.000000e+00 1.417433e+02 279.41 -2.00 20.00 -2.00 505.31 0.00e+00 1.847772e-03 3.042615e-06 1.054724e-04 -6.000000e+00 7.171096e-05 279.41 -2.00 20.00 -2.00 500.61 0.00e+00 7.537329e-01 2.177619e-03 5.112567e-02 -6.000000e+00 5.088414e-02 223.11 -2.00 3.54 -2.00 502.18 0.00e+00 9.536 0.016 489.00 513.00 1 7.5581e-03 1.6666e-04 1.4672e-02 -6.0000e+00 3.8994e-03 -4.4990e-03 4.2524e-05 1.4000e-03 -6.0000e+00 1.0100e-03 4.5825e-01 9.0289e-04 1.0935e-05 6.6033e-05 -6.0000e+00 2.6522e-04 6.2876e-03 -1.0313e-04 10 0 0 10 0 0 -2.85 22.42 1.60 0.00629 0.01255 690 133 1 4 0 8.520 25.58 20.01 22.42 17.12 4.8 914.06 -558 -578 -340 -69 219 424 442 336 326 191 70 -48 -169 -128 -182 -66 -39 12 52 62 165 220 179 275 290 237 104 -36 -194 -274 -149 -221 -155 -32 36 81 198 133 30 8 11 58 122 182 131 158 127 30 -172 -326 -493 -473 -461 -341 -258 -145 -42 90 286 362 438 407 342 270 210 122 18 -174 -219 -226 -113 -36 -72 -49 -124 -191 -225 -218 -288 -378 -403 -343 -359 -236 -238 -288 -201 -139 -69 77 146 125 116 119 459 178 -18 -238 -368 -499 -307 -255 -209 -208 -259 -229 -137 -144 -87 -21 -56 149 340 526 603 610 470 362 213 249 329 242 211 129 38 48 190 68 37 -73 -189 -229 -90 -128 -82 7 -65 -4 168 297 303 357 329 90 -124 -296 -419 -354 -320 -272 -526 -558 -330 -69 218 431 456 349 336 195 70 -48 -166 -128 -182 -64 -39 13 53 64 170 227 185 285 302 248 108 -37 -194 -273 -147 -221 -154 -33 37 83 201 135 31 9 12 58 125 188 137 165 132 30 -173 -328 -484 -456 -443 -332 -259 -146 -43 93 294 372 452 412 347 274 216 124 18 -172 -214 -224 -112 -35 -70 -48 -124 -188 -218 -214 -281 -368 -395 -330 -348 -231 -236 -287 -200 -138 -68 77 143 124 117 119 449 174 -17 -227 -345 -464 -287 -238 -203 -204 -260 -230 -136 -142 -86 -21 -55 149 342 533 614 626 475 368 214 253 328 239 208 128 38 48 190 68 37 -73 -187 -223 -86 -122 -79 7 -63 -4 170 303 305 361 335 92 -127 -300 -425 -352 -315 -269 SQ 20241112T120858.3Z 9082.506231 111 3 5.88 2 84.78 120.07 133.55 332.15 0.00 1 0.00 1 0 22 2.566e-03 2.553e-03 1.109e-04 1.108e-04 6.594425e+03 7.157265e+00 4.535737e+02 -6.000000e+00 1.414519e+02 279.41 -2.00 20.00 -2.00 505.31 0.00e+00 1.859202e-03 3.036746e-06 1.060757e-04 -6.000000e+00 7.156373e-05 279.41 -2.00 20.00 -2.00 500.61 0.00e+00 7.605434e-01 2.173676e-03 5.087848e-02 -6.000000e+00 5.078065e-02 223.11 -2.00 3.54 -2.00 502.18 0.00e+00 9.515 0.016 489.00 513.00 1 6.8049e-03 1.6631e-04 1.4637e-02 -6.0000e+00 3.8915e-03 -4.6490e-03 4.2450e-05 1.3949e-03 -6.0000e+00 1.0079e-03 4.5973e-01 9.3156e-04 1.0911e-05 6.5887e-05 -6.0000e+00 2.6468e-04 7.2867e-03 -1.1093e-04 10 0 0 10 0 0 -2.37 22.42 1.59 0.00729 0.01375 690 133 1 4 0 8.520 25.58 20.01 22.42 17.12 4.8 914.06 -540 -573 -306 -68 189 431 435 316 321 196 74 -48 -163 -152 -180 -79 -47 30 61 45 149 232 203 266 315 237 107 -46 -219 -305 -175 -222 -151 -28 23 82 204 128 38 31 22 71 133 171 142 143 143 25 -150 -333 -512 -467 -488 -375 -246 -152 -36 88 289 352 433 415 349 278 204 147 -2 -142 -209 -244 -139 -47 -72 -64 -129 -183 -203 -208 -287 -369 -382 -334 -337 -242 -255 -262 -231 -132 -73 116 172 142 102 116 461 184 -52 -241 -356 -481 -314 -242 -223 -185 -265 -226 -124 -136 -106 -58 -55 145 321 497 592 611 473 334 216 242 327 261 241 131 29 58 211 76 16 -84 -173 -221 -107 -136 -82 -3 -67 -38 164 308 308 369 319 96 -134 -271 -404 -368 -316 -276 -509 -553 -297 -68 188 439 449 328 332 200 75 -48 -161 -152 -175 -77 -47 31 63 46 153 240 210 277 329 248 112 -47 -218 -305 -172 -222 -151 -29 24 84 208 129 39 32 22 72 137 177 149 150 149 25 -151 -336 -504 -450 -470 -367 -248 -153 -36 91 298 363 446 420 354 282 205 149 -2 -141 -204 -237 -137 -45 -71 -63 -129 -181 -198 -204 -280 -360 -365 -322 -328 -237 -253 -262 -230 -131 -72 113 169 142 103 116 451 180 -50 -226 -334 -448 -293 -227 -216 -182 -266 -227 -124 -134 -105 -57 -54 145 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