File name: Pandora204s1_BoulderCO-NCAR_20210907_L2Fit_fout2c2d20210826p1-8.txt File generation date: 20250127T104330.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: --- Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 204 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora204_OF_v2d20210322.txt Instrument calibration file used: Pandora204s1_CF_v2d20210826.txt Level 1 file used: Pandora204s1_BoulderCO-NCAR_20210907_L1_smca1c2d20210826p1-8.txt Full location name: National Center for Atmospheric Research Short location name: BoulderCO-NCAR Country of location: United States Location latitude [deg]: 40.0375 Location longitude [deg]: -105.2420 Location altitude [m]: 1616 Local noon date: 20210907 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 232 374 Nominal wavelengths inside fitting window [nm]: 305.0564 305.1973 305.3381 305.4790 305.6198 305.7606 305.9014 306.0422 306.1829 306.3237 306.4645 306.6052 306.7459 306.8866 307.0273 307.1680 307.3087 307.4494 307.5901 307.7307 307.8713 308.0120 308.1526 308.2932 308.4338 308.5743 308.7149 308.8555 308.9960 309.1365 309.2771 309.4176 309.5581 309.6985 309.8390 309.9795 310.1199 310.2604 310.4008 310.5412 310.6816 310.8220 310.9624 311.1028 311.2431 311.3835 311.5238 311.6641 311.8044 311.9447 312.0850 312.2253 312.3656 312.5058 312.6461 312.7863 312.9265 313.0667 313.2069 313.3471 313.4873 313.6274 313.7676 313.9077 314.0478 314.1879 314.3280 314.4681 314.6082 314.7483 314.8883 315.0284 315.1684 315.3084 315.4484 315.5884 315.7284 315.8684 316.0083 316.1483 316.2882 316.4281 316.5681 316.7080 316.8478 316.9877 317.1276 317.2674 317.4073 317.5471 317.6869 317.8267 317.9665 318.1063 318.2461 318.3859 318.5256 318.6654 318.8051 318.9448 319.0845 319.2242 319.3639 319.5035 319.6432 319.7828 319.9225 320.0621 320.2017 320.3413 320.4809 320.6205 320.7600 320.8996 321.0391 321.1786 321.3182 321.4577 321.5971 321.7366 321.8761 322.0156 322.1550 322.2944 322.4339 322.5733 322.7127 322.8520 322.9914 323.1308 323.2701 323.4095 323.5488 323.6881 323.8274 323.9667 324.1060 324.2453 324.3845 324.5238 324.6630 324.8022 324.9414 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210907T132646.7Z 7920.560263 64 1 48.83 2 80.92 89.98 86.95 83.41 0.00 1 0.00 1 0 25 3.999e-01 1.144e-02 3.166e-01 9.277e-03 6.469476e-01 5.000659e-03 6.870531e-03 -6.000000e+00 2.308793e-01 228.87 -2.00 3.45 -2.00 321.39 0.00e+00 4.998800e-03 1.970191e-03 6.659186e-04 -6.000000e+00 9.487590e-03 280.49 -2.00 20.00 -2.00 321.05 0.00e+00 6.016 0.004 302.00 328.00 3 7.1347e+00 1.5280e-02 6.0147e-02 -6.0000e+00 5.7902e-01 1.1732e-01 2.1230e-02 3.4299e-02 -6.0000e+00 6.3102e-01 -2.0281e-01 2.4551e-02 1.8942e-02 -6.0000e+00 3.7011e-01 8.1431e-02 1.2175e-02 6.2760e-03 -6.0000e+00 1.5402e-01 1.4965e-06 -6.9037e-04 2.7890e-04 7.7181e-05 -6.0000e+00 1.0952e-02 1.8969e-03 -3.1412e-05 12 8 8 10 0 0 -3.18 18.22 0.55 0.00190 -0.00329 25 5 1 5 0 1953.000 21.17 15.00 18.22 21.75 4.9 884.03 -90683 -188454 900000 -81899 -61591 900000 -169032 131348 -152364 38947 -135464 96904 -123266 56019 900000 -23610 1813 -66643 2207 -16848 21980 -62095 -27446 -66958 96277 -62077 4492 -55888 -53803 -35664 16064 -4460 -37985 22774 -35638 13037 -13648 10583 -6789 10618 22465 5844 2410 998 18351 3041 4000 10223 10623 1215 15992 12143 8890 10482 12542 422 11170 6670 -376 6 3498 6891 -1849 4561 4380 6225 -1607 1269 3894 3455 579 3855 3524 459 1635 -3836 -4849 -6742 2235 -1109 -434 -2607 -449 -816 -2215 -239 550 1300 -1399 1247 -9 -3258 -2049 -1624 -2565 -1077 -199 -657 951 -931 78 -240 355 762 -603 -1125 -189 -246 842 958 501 143 181 -16 -955 219 60 -585 31 -1124 750 583 956 364 1487 -1223 213 565 -555 115 177 -271 0 -30 -224 57 10 897 91 205 -203 -704 -526 -820 -3124 900000 -741 -557 900000 -2501 1188 -2380 352 -2004 876 -2331 507 900000 -330 22 -1808 33 -319 289 -1889 -609 -2367 871 -2347 89 -1975 -1858 -1114 357 -147 -2030 711 -1933 429 -639 461 -430 672 1422 432 194 84 1328 264 353 878 953 128 1615 1427 1186 1493 1852 73 1784 1111 -65 1 598 1257 -419 1093 1112 1525 -418 330 1089 1117 213 1435 1304 166 533 -1188 -1414 -2027 687 -419 -191 -1340 -248 -481 -1414 -160 384 931 -1029 863 -6 -2057 -1224 -992 -1768 -849 -181 -686 1068 -1072 83 -232 312 670 -577 -1149 -201 -281 1042 1326 772 217 298 -25 -1452 316 87 -894 50 -1914 1248 937 1475 546 2122 -1728 287 786 -880 205 346 -566 0 -63 -514 138 25 2239 229 496 -466 -1523 -1189 SS 20210907T133735.1Z 7920.567767 69 1 49.39 2 78.85 91.72 84.99 85.10 0.00 1 0.00 1 0 17 2.290e-01 6.968e-03 1.225e-01 3.398e-03 5.548508e-01 1.794213e-03 6.078351e-03 -6.000000e+00 1.315490e-01 228.87 -2.00 3.45 -2.00 320.86 0.00e+00 4.151957e-03 6.255467e-04 4.404983e-04 -6.000000e+00 5.282384e-03 280.49 -2.00 20.00 -2.00 320.51 0.00e+00 4.995 0.002 302.00 328.00 3 6.5404e+00 5.2731e-03 5.0335e-02 -6.0000e+00 3.3015e-01 3.8257e-03 6.7452e-03 2.8970e-02 -6.0000e+00 3.5957e-01 -5.0227e-02 7.3246e-03 1.5504e-02 -6.0000e+00 2.1123e-01 1.7068e-02 3.7551e-03 4.9562e-03 -6.0000e+00 8.7670e-02 6.7486e-06 -5.1545e-04 1.0246e-04 5.8015e-05 -6.0000e+00 6.2499e-03 9.3840e-04 -2.3173e-05 11 8 0 10 0 0 22.11 18.22 0.40 0.00094 -0.00293 71 15 1 5 0 695.450 21.17 15.00 18.22 22.07 4.9 887.12 -4830 -133684 -50359 -78626 -63730 -52791 -66432 -78289 -77958 -32394 -97387 -36790 -78937 -18959 -33171 -1345 -15107 -3017 8780 -5962 -4835 -12258 -81 -3567 2666 -14855 -5610 -16809 -4 -9485 2860 -5698 -5048 -2135 -3970 -2811 -11039 8059 -5647 3214 -4286 -57 -2147 2605 -104 2194 2854 1620 -339 200 2257 1778 3657 2103 2080 1214 1853 -704 1697 223 1630 2913 3170 3626 1700 2226 -481 1492 630 1234 140 714 1276 -573 -618 -1411 -1366 -3327 -170 -2407 -386 -1410 -1775 -901 -1097 -182 292 1009 605 919 -328 195 -1238 -267 -970 48 390 1050 74 166 -261 -845 69 -945 -1625 -1653 -261 -350 510 598 1007 308 327 155 -734 -293 -473 152 -477 -82 -147 736 508 604 395 -361 232 716 -2 -319 -193 -332 -90 -362 68 -240 647 588 187 206 -300 -423 -408 -22 -2363 -417 -847 -546 -429 -605 -908 -1012 -312 -1721 -396 -1613 -272 -687 -24 -350 -68 192 -160 -132 -362 -2 -107 81 -566 -198 -650 0 -359 111 -286 -290 -127 -234 -161 -753 539 -488 302 -488 -7 -271 324 -13 286 378 223 -49 31 371 327 721 455 475 290 452 -176 405 54 400 775 950 1205 602 762 -164 507 237 529 67 356 629 -274 -272 -563 -504 -1249 -68 -1157 -211 -886 -1222 -652 -850 -150 252 893 538 787 -265 146 -890 -192 -775 44 377 1144 89 199 -295 -869 70 -974 -1685 -1820 -298 -426 667 865 1590 515 543 247 -1107 -419 -678 227 -763 -136 -247 1187 793 910 571 -506 311 983 -3 -548 -360 -658 -186 -788 148 -549 1503 1393 446 475 -706 -941 -880 SS 20210907T134324.6Z 7920.571813 72 1 49.24 2 77.73 92.67 83.93 86.02 0.00 1 0.00 1 0 17 1.443e-01 6.706e-03 7.071e-02 2.286e-03 5.158922e-01 1.185175e-03 5.664389e-03 -6.000000e+00 8.286115e-02 228.87 -2.00 3.45 -2.00 320.58 0.00e+00 2.222512e-03 3.865889e-04 3.604228e-04 -6.000000e+00 3.327292e-03 280.49 -2.00 20.00 -2.00 320.24 0.00e+00 4.575 0.002 302.00 328.00 3 6.3160e+00 3.4124e-03 4.6199e-02 -6.0000e+00 2.0795e-01 -1.9416e-02 4.2464e-03 2.6619e-02 -6.0000e+00 2.2649e-01 -1.7985e-02 4.4439e-03 1.4079e-02 -6.0000e+00 1.3305e-01 4.5523e-03 2.3168e-03 4.4405e-03 -6.0000e+00 5.5223e-02 1.2337e-05 -3.6262e-04 6.8218e-05 4.9751e-05 -6.0000e+00 3.9367e-03 7.9354e-04 -2.6226e-05 11 8 0 10 0 0 -7.29 18.22 0.26 0.00079 -0.00193 105 23 1 5 0 468.860 21.17 15.00 18.22 22.31 4.9 888.96 -3452 -49240 -26947 -45646 -62058 -25065 -64309 -9522 -64079 12163 -73972 12593 -49088 4620 -24775 904 -17975 -2990 7017 -1819 7420 -5192 8850 -12743 2097 -11527 -9220 -11300 3571 1986 -3970 68 -2756 3909 -4336 2053 -8748 3659 -4937 1910 -3279 1082 -616 711 3585 -886 2839 -1632 2878 -579 3949 -618 3095 919 1238 740 679 -309 -929 -21 200 2758 1811 4271 341 1720 14 2 1297 419 66 415 528 -54 -102 -1840 -524 -3271 -1256 -2490 -1407 -1579 -2276 -1144 -1046 73 257 1222 1107 1420 782 1054 -659 -439 -520 28 654 1096 457 -301 -220 -1518 -38 -538 -1333 -1376 -483 -479 491 843 557 373 195 208 -717 212 -255 -84 -292 -166 -146 663 645 181 533 -935 41 466 141 -404 -80 -355 -274 -46 -136 18 561 541 89 131 -315 -189 -453 -22 -561 -267 -525 -773 -218 -856 -87 -1082 110 -1528 129 -1065 76 -642 22 -563 -89 204 -61 234 -185 288 -546 84 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