File name: Pandora204s1_BoulderCO-NCAR_20220825_L2Fit_fout2c3d20210826p1-8.txt File generation date: 20250127T140404.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: --- Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 204 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora204_OF_v2d20210322.txt Instrument calibration file used: Pandora204s1_CF_v3d20210826.txt Level 1 file used: Pandora204s1_BoulderCO-NCAR_20220825_L1_smca1c3d20210826p1-8.txt Full location name: National Center for Atmospheric Research Short location name: BoulderCO-NCAR Country of location: United States Location latitude [deg]: 40.0375 Location longitude [deg]: -105.2420 Location altitude [m]: 1616 Local noon date: 20220825 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: New Fieldcal for early data (starting from 20210826) First and last pixel inside fitting window: 232 374 Nominal wavelengths inside fitting window [nm]: 305.0399 305.1807 305.3215 305.4624 305.6032 305.7440 305.8848 306.0256 306.1663 306.3071 306.4478 306.5886 306.7293 306.8700 307.0107 307.1514 307.2921 307.4327 307.5734 307.7140 307.8546 307.9953 308.1359 308.2765 308.4171 308.5576 308.6982 308.8387 308.9793 309.1198 309.2603 309.4008 309.5413 309.6818 309.8223 309.9627 310.1032 310.2436 310.3840 310.5244 310.6648 310.8052 310.9456 311.0860 311.2263 311.3667 311.5070 311.6473 311.7876 311.9279 312.0682 312.2085 312.3487 312.4890 312.6292 312.7695 312.9097 313.0499 313.1901 313.3302 313.4704 313.6106 313.7507 313.8909 314.0310 314.1711 314.3112 314.4513 314.5914 314.7314 314.8715 315.0115 315.1515 315.2916 315.4316 315.5716 315.7115 315.8515 315.9915 316.1314 316.2714 316.4113 316.5512 316.6911 316.8310 316.9709 317.1107 317.2506 317.3904 317.5303 317.6701 317.8099 317.9497 318.0895 318.2292 318.3690 318.5088 318.6485 318.7882 318.9279 319.0676 319.2073 319.3470 319.4867 319.6263 319.7660 319.9056 320.0452 320.1848 320.3244 320.4640 320.6036 320.7432 320.8827 321.0223 321.1618 321.3013 321.4408 321.5803 321.7198 321.8592 321.9987 322.1382 322.2776 322.4170 322.5564 322.6958 322.8352 322.9746 323.1139 323.2533 323.3926 323.5320 323.6713 323.8106 323.9499 324.0891 324.2284 324.3677 324.5069 324.6462 324.7854 324.9246 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220825T130103.1Z 8272.542397 108 1 48.85 2 83.56 81.49 63.51 83.30 0.00 1 0.00 1 0 17 6.119e-01 2.364e-02 3.571e-01 1.137e-02 8.536591e-01 6.728025e-03 9.245154e-03 -6.000000e+00 3.604999e-01 229.86 -2.00 3.45 -2.00 322.22 0.00e+00 3.358788e-03 4.010828e-03 3.742620e-03 -6.000000e+00 1.773158e-02 281.62 -2.00 20.00 -2.00 321.75 0.00e+00 8.089 0.009 302.00 328.00 3 1.7282e+00 2.7145e-02 8.3386e-02 -6.0000e+00 9.0766e-01 5.9226e-01 3.9165e-02 5.1827e-02 -6.0000e+00 9.9145e-01 -9.3407e-01 3.8508e-02 2.8355e-02 -6.0000e+00 5.7997e-01 3.8020e-01 1.7412e-02 9.2004e-03 -6.0000e+00 2.4357e-01 5.2458e-05 -4.8239e-04 3.2525e-04 1.5212e-04 -6.0000e+00 1.6880e-02 -5.2822e-05 0.0000e+00 12 8 8 10 0 0 74.23 18.36 0.43 -0.00005 -0.00368 52 11 1 5 0 939.250 21.27 15.00 18.36 20.74 8.7 812.78 -172814 900000 -92733 149930 -72661 -216875 900000 -167482 900000 -226243 900000 -156908 900000 -72619 900000 4839 16743 900000 -104916 900000 -65068 900000 -107694 900000 -73688 900000 62378 -45828 -95047 -43198 199813 59740 185605 -23800 900000 -17454 900000 -6938 176048 21272 114310 51601 23736 42848 4698 126640 17036 118600 -2733 64804 2467 86358 13619 32380 30647 47014 35453 -3914 31533 -11125 43546 -3730 64131 10471 39533 2903 26173 8328 24503 15439 15893 15215 1267 22840 2443 14699 -3743 7910 -6514 2891 -5540 3602 -1868 -6669 3997 -2016 11249 -1240 9311 -3711 4451 -5327 -11 -6916 -3742 -5003 -3651 381 -1950 1771 -4686 522 -6822 1064 -3143 -1548 -4588 -604 -2057 -490 1096 -78 2253 -1046 415 -2578 -59 -1933 414 -12 1168 1537 1863 2382 1811 2016 -1636 2001 -1062 1803 -731 1403 -864 417 115 -257 107 395 927 -373 462 -1926 -1014 -2804 900000 -1026 1658 -804 -4958 900000 -2779 900000 -7174 900000 -2975 900000 -975 900000 54 185 900000 -3636 900000 -1645 900000 -3999 900000 -2212 900000 690 -1014 -3304 -956 2210 762 2053 -827 900000 -510 900000 -225 1947 756 1945 1631 1031 1557 249 2155 821 2321 -177 2304 183 3139 1055 2430 2494 3380 2941 -444 2566 -1239 3028 -424 4560 1374 4227 447 3185 1265 3506 2812 3211 3243 306 4160 492 2320 -660 1272 -1379 678 -1695 1101 -675 -2702 1550 -885 4549 -586 3965 -1742 1803 -2239 -4 -3017 -1811 -2919 -2492 292 -1720 1544 -4127 391 -4895 690 -2284 -1181 -3813 -522 -2011 -544 1372 -108 3156 -1499 563 -3483 -78 -2741 609 -18 1752 2187 2528 3127 2315 2498 -2036 2507 -1584 3050 -1431 2931 -1970 1007 282 -673 286 1066 2488 -974 1180 -4669 -2315 SS 20220825T131248.9Z 8272.550566 111 1 49.08 2 81.33 83.35 61.34 85.04 0.00 1 0.00 1 0 17 5.296e-01 8.659e-03 2.204e-01 3.355e-03 7.087929e-01 1.831205e-03 7.951843e-03 -6.000000e+00 3.018411e-01 229.86 -2.00 3.45 -2.00 321.61 0.00e+00 4.166917e-03 9.656781e-04 3.641465e-03 -6.000000e+00 1.311310e-02 281.62 -2.00 20.00 -2.00 321.10 0.00e+00 6.272 0.004 302.00 328.00 3 1.4805e+00 6.6474e-03 6.5987e-02 -6.0000e+00 7.5437e-01 1.5882e-02 9.7397e-03 4.3063e-02 -6.0000e+00 8.1750e-01 -1.0842e-01 1.0464e-02 2.4687e-02 -6.0000e+00 4.8578e-01 4.4368e-02 4.8469e-03 8.5910e-03 -6.0000e+00 2.0658e-01 3.3777e-04 -3.2181e-04 9.3724e-05 1.3565e-04 -6.0000e+00 1.3784e-02 -3.4727e-04 0.0000e+00 11 8 0 10 0 0 83.56 18.35 0.25 -0.00035 -0.00277 158 34 1 5 0 310.440 21.27 15.00 18.35 21.97 8.6 820.38 -134938 -155374 -164573 -213433 -185366 -192267 -115379 -167094 -135910 -121445 -153078 196131 -103679 -26123 -128109 5295 -65871 -9758 -68882 -17008 -32467 -30109 -30468 -57035 71449 -49915 -15965 -39383 -20251 -46297 -22518 -15108 -9811 -8473 -17631 -4621 -27309 8829 -6234 20988 -1292 10255 2744 6601 1197 8975 3920 2536 8431 -1858 8817 2465 5833 2381 5895 4848 4948 -377 1014 -195 1573 5317 3227 6590 2346 4382 461 1180 -22 2720 2633 2701 1073 755 340 -2798 -591 -7280 -1614 -3485 266 -768 -1385 -1743 -764 -219 546 1138 982 1463 -472 784 -1522 -1770 -2030 -416 -347 608 280 43 -153 -1723 -1234 -1335 -1028 -1615 -262 -615 571 768 1618 1055 538 46 -985 -525 -860 -161 -318 502 60 979 557 1025 392 -711 -545 -135 -245 -453 107 -498 -213 -385 -35 -104 454 590 577 -15 -102 -255 -699 -482 -832 -1077 -2285 -1378 -1487 -446 -1242 -849 -722 -1320 642 -802 -137 -2210 30 -882 -84 -1188 -187 -435 -394 -417 -1120 467 -1069 -252 -773 -325 -1046 -489 -377 -254 -240 -534 -131 -968 260 -265 830 -73 565 174 418 82 585 278 191 634 -154 739 251 637 296 760 663 702 -57 146 -28 227 815 581 1320 531 964 104 273 -6 796 865 936 377 252 105 -795 -152 -2021 -474 -1252 109 -369 -692 -931 -432 -132 345 740 642 923 -285 469 -894 -1067 -1278 -302 -294 591 303 48 -160 -1645 -1055 -1129 -933 -1569 -264 -668 672 1019 2391 1688 878 73 -1509 -766 -1257 -245 -513 843 100 1562 858 1523 564 -999 -734 -186 -384 -813 212 -1065 -447 -862 -84 -265 1174 1549 1522 -39 -246 -576 -1624 SS 20220825T134124.6Z 8272.570423 121 1 18.15 2 75.88 87.87 56.05 89.40 0.00 1 0.00 1 0 17 8.795e-02 7.440e-03 3.087e-02 1.675e-03 4.802705e-01 8.553896e-04 5.485133e-03 -6.000000e+00 5.013594e-02 229.86 -2.00 3.45 -2.00 319.83 0.00e+00 1.652995e-03 2.621565e-04 1.082238e-03 -6.000000e+00 2.177946e-03 281.62 -2.00 20.00 -2.00 319.19 0.00e+00 4.011 0.001 302.00 328.00 3 2.1398e+00 2.4741e-03 4.1618e-02 -6.0000e+00 1.2530e-01 -2.7403e-02 2.9672e-03 2.5147e-02 -6.0000e+00 1.3578e-01 -5.4970e-03 2.5186e-03 1.2847e-02 -6.0000e+00 8.0684e-02 1.4459e-04 1.3122e-03 3.9625e-03 -6.0000e+00 3.4318e-02 1.2896e-03 -1.6673e-04 4.6626e-05 4.3890e-05 -6.0000e+00 2.2891e-03 -1.5118e-03 0.0000e+00 12 9 1 12 1 1 35.99 18.38 0.25 -0.00151 -0.00276 65 39 1 5 0 272.290 21.27 15.00 18.38 25.52 8.6 845.75 -33287 -34257 -19658 -12002 -27060 -30556 -35780 -27294 -32364 -6932 -34193 -23421 -24481 -7975 -9523 -5084 -4925 -3640 -1055 -3054 -1650 -1814 -1664 -4933 -2456 -3765 -2712 -6960 -5730 -4918 -4335 -319 678 75 -3371 -5125 -6118 -2185 -2382 39 -803 906 1521 1140 1556 866 27 -744 -422 -298 1172 353 2150 886 1713 1214 340 564 43 -339 262 1575 1992 3015 1318 1075 -120 -1116 486 1011 986 748 931 870 196 -826 -1499 -3115 -2253 -2119 -1800 -1319 -2223 -1538 -931 -149 744 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