File name: Pandora204s1_BoulderCO-NCAR_20230225_L2Fit_fout2c3d20230101p1-8.txt File generation date: 20250127T152933.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: --- Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 204 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora204_OF_v2d20210322.txt Instrument calibration file used: Pandora204s1_CF_v3d20230101.txt Level 1 file used: Pandora204s1_BoulderCO-NCAR_20230225_L1_smca1c3d20230101p1-8.txt Full location name: National Center for Atmospheric Research Short location name: BoulderCO-NCAR Country of location: United States Location latitude [deg]: 40.0375 Location longitude [deg]: -105.2420 Location altitude [m]: 1616 Local noon date: 20230225 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: official CF from Session80 First and last pixel inside fitting window: 232 374 Nominal wavelengths inside fitting window [nm]: 305.0197 305.1605 305.3013 305.4422 305.5830 305.7238 305.8646 306.0054 306.1462 306.2869 306.4277 306.5684 306.7091 306.8498 306.9905 307.1312 307.2719 307.4126 307.5532 307.6939 307.8345 307.9752 308.1158 308.2564 308.3970 308.5375 308.6781 308.8186 308.9592 309.0997 309.2402 309.3807 309.5212 309.6617 309.8022 309.9427 310.0831 310.2236 310.3640 310.5044 310.6448 310.7852 310.9256 311.0659 311.2063 311.3466 311.4870 311.6273 311.7676 311.9079 312.0482 312.1885 312.3287 312.4690 312.6092 312.7495 312.8897 313.0299 313.1701 313.3103 313.4504 313.5906 313.7308 313.8709 314.0110 314.1511 314.2912 314.4313 314.5714 314.7115 314.8515 314.9916 315.1316 315.2716 315.4116 315.5516 315.6916 315.8316 315.9716 316.1115 316.2515 316.3914 316.5313 316.6712 316.8111 316.9510 317.0908 317.2307 317.3706 317.5104 317.6502 317.7900 317.9298 318.0696 318.2094 318.3492 318.4889 318.6286 318.7684 318.9081 319.0478 319.1875 319.3272 319.4668 319.6065 319.7462 319.8858 320.0254 320.1650 320.3046 320.4442 320.5838 320.7234 320.8629 321.0024 321.1420 321.2815 321.4210 321.5605 321.7000 321.8395 321.9789 322.1184 322.2578 322.3972 322.5366 322.6760 322.8154 322.9548 323.0942 323.2335 323.3729 323.5122 323.6515 323.7908 323.9301 324.0694 324.2087 324.3479 324.4872 324.6264 324.7656 324.9048 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230225T141941.1Z 8456.597004 59 1 49.25 2 83.54 107.56 111.61 42.09 0.00 1 0.00 1 0 17 6.552e-01 1.380e-02 3.376e-01 5.803e-03 9.205542e-01 3.263886e-03 9.520209e-03 -6.000000e+00 3.694731e-01 224.66 -2.00 3.45 -2.00 322.19 0.00e+00 9.679248e-03 1.677520e-03 2.464089e-03 -6.000000e+00 1.577759e-02 266.98 -2.00 20.00 -2.00 321.83 0.00e+00 8.091 0.009 302.00 328.00 3 5.6936e-01 1.1484e-02 8.5576e-02 -6.0000e+00 9.1956e-01 4.4979e-01 1.8889e-02 6.2432e-02 -6.0000e+00 1.0030e+00 -6.3261e-01 2.2635e-02 2.9989e-02 -6.0000e+00 5.8950e-01 2.5949e-01 1.0378e-02 1.5413e-02 -6.0000e+00 2.4991e-01 1.6202e-04 -1.2688e-04 1.5866e-04 1.7641e-04 -6.0000e+00 1.7301e-02 1.1390e-02 0.0000e+00 12 8 8 10 0 0 17.16 18.26 0.33 0.01139 0.01044 148 32 1 5 0 332.720 21.17 15.00 18.26 1.20 9.8 742.04 -150864 -111636 -280489 -181241 -192492 -154686 -284140 900000 -220484 900000 -43724 -183637 -197688 -14766 -111746 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1587 459 1228 1384 1944 1674 2353 785 1527 1010 1372 1727 1240 1835 647 944 -274 541 -1216 -109 -467 391 114 -867 35 -594 715 717 1638 349 1276 -216 -17 -1245 -1898 -1189 -1768 -711 -50 1190 40 -561 -2022 -723 -826 -834 -1857 -1498 -1196 -1230 596 700 -373 -228 -502 -2078 -1376 -1830 311 119 819 884 2515 2368 1621 1753 -574 114 538 809 399 778 158 -476 -422 -1131 389 211 2087 1046 1712 -760 -1893 -3643 SS 20230225T143036.2Z 8456.604586 62 1 49.18 2 81.56 109.40 110.21 44.31 0.00 1 0.00 1 0 25 5.629e-01 9.515e-03 1.556e-01 2.149e-03 7.756627e-01 1.165403e-03 8.405194e-03 -6.000000e+00 3.167998e-01 224.66 -2.00 3.45 -2.00 321.68 0.00e+00 5.586421e-03 5.387165e-04 2.217480e-03 -6.000000e+00 1.319084e-02 266.98 -2.00 20.00 -2.00 321.30 0.00e+00 6.432 0.005 302.00 328.00 3 5.5721e-01 3.7933e-03 6.6330e-02 -6.0000e+00 7.8598e-01 1.2557e-01 5.9159e-03 4.1918e-02 -6.0000e+00 8.5708e-01 -1.8946e-01 7.1433e-03 2.7711e-02 -6.0000e+00 5.0541e-01 7.7283e-02 3.3856e-03 1.3388e-02 -6.0000e+00 2.1412e-01 7.0512e-04 7.0739e-05 5.9328e-05 1.5481e-04 -6.0000e+00 1.4728e-02 1.1654e-02 0.0000e+00 12 8 8 10 0 0 25.13 18.27 0.23 0.01165 0.01219 323 70 1 5 0 152.250 21.17 14.99 18.27 3.22 9.7 757.34 -228906 -185280 -200992 -217660 -65405 -222068 900000 -230380 -64829 -190469 -93133 -205077 -65722 -115849 -50271 -69255 -54752 -10703 -68346 1561 -59486 9174 -63995 3409 -58484 -20434 -55861 -14004 -38529 -44948 5764 -23441 22461 -11843 6384 -33411 -1101 -19352 10590 -3116 5601 5674 3243 6666 -2988 12189 920 13989 -652 9882 3232 10768 4231 9252 7221 3170 5535 2103 2559 -159 3068 -20 7676 6782 6488 2391 1803 1141 1030 3160 1436 3988 1119 1908 -1568 -179 -3900 -4439 -3259 -2210 -1573 -801 -983 -2304 -216 -766 1289 336 2096 645 1406 -556 -1743 -2377 -1943 -1209 -338 1272 751 593 -674 -865 -2062 -561 -1522 -1545 -1055 -770 432 461 1169 553 566 -476 -646 -1212 -348 -219 445 372 344 1250 1313 925 262 -138 -1158 407 -362 -30 -159 -232 -574 -248 -171 -56 370 617 547 -24 -74 -740 -434 -1744 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-2.00 319.80 0.00e+00 4.100 0.001 302.00 328.00 3 3.8645e-01 7.6358e-04 4.2747e-02 -6.0000e+00 1.4632e-01 2.2055e-02 9.3766e-04 2.6606e-02 -6.0000e+00 1.5950e-01 -2.2486e-02 9.2080e-04 1.4797e-02 -6.0000e+00 9.4367e-02 4.1835e-03 4.8156e-04 5.8502e-03 -6.0000e+00 4.0128e-02 6.6252e-03 1.7238e-04 1.4735e-05 5.7973e-05 -6.0000e+00 2.7402e-03 1.0976e-02 0.0000e+00 11 8 0 10 0 0 79.18 18.28 0.21 0.01098 0.01227 1025 223 1 5 0 47.710 21.17 15.00 18.28 9.38 9.8 805.17 -40721 -32763 -25623 -26840 -35934 -47150 -40288 -33632 -29594 -31304 -26673 -30562 -19473 -14129 -9716 -6463 -2844 -4442 -1547 -1406 -2660 -3229 -4093 -4064 -3720 -3496 -5838 -6636 -8553 -5036 -5180 -2187 -1350 -1833 -5598 -6059 -5796 -3005 -1153 -391 -418 -341 380 77 765 308 505 388 -210 165 879 1231 1752 1806 1516 1432 891 200 -161 -280 615 1565 2631 3226 1745 470 -294 -1364 54 813 981 1104 737 737 -191 -928 -2175 -3142 -2541 -1959 -1413 -1104 -2082 -1682 -1004 -319 703 949 1483 1261 938 103 -880 -1130 -719 -694 351 1206 897 266 -237 -1136 -1187 -377 -1006 -961 -761 -496 117 715 944 819 541 46 -614 -657 -537 -210 179 326 157 635 751 326 353 -388 -816 45 -220 -207 -172 -375 -513 -238 -104 44 261 728 519 139 -14 -486 -482 -422 -371 -294 -308 -409 -572 -485 -432 -417 -489 -411 -526 -365 -317 -260 -200 -95 -164 -55 -53 -105 -128 -168 -181 -179 -178 -312 -347 -438 -257 -302 -146 -103 -153 -467 -489 -502 -298 -138 -56 -68 -59 69 14 144 59 98 77 -43 35 202 314 485 540 481 471 304 69 -54 -92 206 562 1052 1325 769 203 -132 -622 24 414 557 660 442 423 -102 -485 -1049 -1493 -1290 -1065 -890 -788 -1646 -1399 -883 -298 688 959 1497 1237 862 88 -712 -908 -624 -687 366 1417 1159 349 -296 -1292 -1322 -414 -1111 -1129 -934 -643 162 1086 1466 1343 888 73 -977 -986 -796 -323 290 521 253 1063 1212 511 528 -562 -1130 62 -336 -353 -297 -689 -977 -475 -220 93 561 1587 1139 298 -30 -998 -952 SS 20230225T150618.3Z 8456.629379 75 1 49.03 2 75.24 115.68 105.24 51.14 0.00 1 0.00 1 0 25 8.046e-02 6.998e-03 9.329e-03 4.476e-04 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