File name: Pandora204s1_BoulderCO-NCAR_20231001_L2Fit_fout2c3d20230101p1-8.txt File generation date: 20250127T172746.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: --- Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 204 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora204_OF_v2d20210322.txt Instrument calibration file used: Pandora204s1_CF_v3d20230101.txt Level 1 file used: Pandora204s1_BoulderCO-NCAR_20231001_L1_smca1c3d20230101p1-8.txt Full location name: National Center for Atmospheric Research Short location name: BoulderCO-NCAR Country of location: United States Location latitude [deg]: 40.0375 Location longitude [deg]: -105.2420 Location altitude [m]: 1616 Local noon date: 20231001 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: official CF from Session80 First and last pixel inside fitting window: 232 374 Nominal wavelengths inside fitting window [nm]: 305.0197 305.1605 305.3013 305.4422 305.5830 305.7238 305.8646 306.0054 306.1462 306.2869 306.4277 306.5684 306.7091 306.8498 306.9905 307.1312 307.2719 307.4126 307.5532 307.6939 307.8345 307.9752 308.1158 308.2564 308.3970 308.5375 308.6781 308.8186 308.9592 309.0997 309.2402 309.3807 309.5212 309.6617 309.8022 309.9427 310.0831 310.2236 310.3640 310.5044 310.6448 310.7852 310.9256 311.0659 311.2063 311.3466 311.4870 311.6273 311.7676 311.9079 312.0482 312.1885 312.3287 312.4690 312.6092 312.7495 312.8897 313.0299 313.1701 313.3103 313.4504 313.5906 313.7308 313.8709 314.0110 314.1511 314.2912 314.4313 314.5714 314.7115 314.8515 314.9916 315.1316 315.2716 315.4116 315.5516 315.6916 315.8316 315.9716 316.1115 316.2515 316.3914 316.5313 316.6712 316.8111 316.9510 317.0908 317.2307 317.3706 317.5104 317.6502 317.7900 317.9298 318.0696 318.2094 318.3492 318.4889 318.6286 318.7684 318.9081 319.0478 319.1875 319.3272 319.4668 319.6065 319.7462 319.8858 320.0254 320.1650 320.3046 320.4442 320.5838 320.7234 320.8629 321.0024 321.1420 321.2815 321.4210 321.5605 321.7000 321.8395 321.9789 322.1184 322.2578 322.3972 322.5366 322.6760 322.8154 322.9548 323.0942 323.2335 323.3729 323.5122 323.6515 323.7908 323.9301 324.0694 324.2087 324.3479 324.4872 324.6264 324.7656 324.9048 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231001T133717.6Z 8674.567565 243 1 33.56 2 83.22 100.02 69.60 271.96 0.00 1 0.00 1 0 17 6.838e-01 2.870e-02 3.375e-01 1.708e-02 7.433572e-01 9.790277e-03 9.197454e-03 -6.000000e+00 3.990633e-01 226.62 -2.00 3.45 -2.00 321.78 0.00e+00 6.127549e-03 5.030028e-03 8.235860e-03 -6.000000e+00 2.032689e-02 277.69 -2.00 20.00 -2.00 321.30 0.00e+00 7.754 0.008 302.00 328.00 3 2.7272e+00 3.4964e-02 8.3400e-02 -6.0000e+00 9.9496e-01 5.6516e-01 4.6240e-02 5.8574e-02 -6.0000e+00 1.0884e+00 -7.8699e-01 4.3253e-02 3.0004e-02 -6.0000e+00 6.4092e-01 3.2418e-01 2.0544e-02 9.2206e-03 -6.0000e+00 2.7592e-01 2.7073e-05 3.3692e-04 5.0148e-04 2.2170e-04 -6.0000e+00 1.9128e-02 9.6126e-03 0.0000e+00 12 9 9 12 1 1 84.50 18.40 0.38 0.00961 0.01214 10 3 1 5 0 3049.910 21.27 15.00 18.40 22.17 13.0 817.46 900000 900000 -182164 900000 -69144 900000 139790 900000 -197275 176926 900000 -87476 900000 -127488 900000 -109308 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1576 3106 3942 4581 1664 5234 2783 4369 -1653 5032 958 1556 2116 2746 2701 2172 1648 1290 5068 1613 4032 1619 3180 2118 -95 -133 -790 -2507 -638 -2560 132 2895 -824 1855 -3223 -1457 479 2133 -2739 1288 629 -4794 -2068 -4706 -757 -3879 -2237 -2160 2953 -511 -607 -3079 -3470 -1787 -5812 1577 -1034 410 -293 2704 -1030 2757 -655 -480 -2799 776 -2833 -1846 2800 -851 4255 132 3629 1382 3949 872 2948 1469 -1647 309 695 2459 -2475 -1016 -857 1424 1580 3427 -1579 2675 -4074 -508 -4603 SS 20231001T134844.0Z 8674.575509 246 1 49.58 2 81.07 101.92 71.70 273.74 0.00 1 0.00 1 0 17 4.004e-01 1.227e-02 1.888e-01 5.855e-03 6.256430e-01 3.177415e-03 7.168241e-03 -6.000000e+00 2.295599e-01 226.62 -2.00 3.45 -2.00 321.26 0.00e+00 2.231414e-03 1.469259e-03 3.496310e-03 -6.000000e+00 1.024110e-02 277.69 -2.00 20.00 -2.00 320.76 0.00e+00 6.111 0.004 302.00 328.00 3 2.8604e+00 1.0571e-02 6.1751e-02 -6.0000e+00 5.7081e-01 4.8577e-02 1.4546e-02 3.8447e-02 -6.0000e+00 6.2140e-01 -9.8705e-02 1.5182e-02 2.1124e-02 -6.0000e+00 3.6772e-01 4.1155e-02 7.2911e-03 6.7343e-03 -6.0000e+00 1.5735e-01 1.0482e-04 1.6183e-04 1.7144e-04 1.0268e-04 -6.0000e+00 1.0768e-02 9.2872e-03 0.0000e+00 12 9 8 11 8 0 89.52 18.40 0.09 0.00929 0.01050 36 8 1 5 0 1376.860 21.27 15.00 18.40 22.43 13.0 819.39 -173841 900000 -188057 900000 -159239 900000 -182869 900000 -157276 -121800 -109738 -27569 1847 -26072 900000 -72458 900000 -63202 63246 -26850 50814 -44255 29126 -20409 2095 36736 -46885 13381 -38292 29590 -15952 29138 -6450 28877 1452 -15358 8090 4299 20124 -16583 17849 -17333 5143 -2673 18619 303 8122 -263 12495 248 6334 8515 749 5620 -1176 13061 -785 5641 -459 11152 6632 9400 3577 3332 3380 1026 4461 -1878 7828 -278 4294 -664 2610 -310 2468 -4146 -4103 -3669 -3033 -1282 -3121 -642 -4069 -667 -2833 1211 -237 2466 1618 850 1191 -670 -371 -3249 -1022 -2869 1713 231 919 -624 304 -1863 -1983 -830 -1934 -691 -2202 -245 -217 1248 890 1722 257 310 -1163 -225 -827 -46 202 212 658 333 1095 160 1131 -274 -217 126 13 191 -312 -178 -622 -181 -472 279 -218 743 679 488 -448 -351 -891 -2206 900000 -3453 900000 -2111 900000 -3059 900000 -2693 -1673 -1416 -190 12 -270 900000 -1639 900000 -1626 592 -578 580 -1149 414 -482 44 610 -1659 275 -1203 539 -497 724 -253 905 57 -676 310 199 978 -1346 1199 -1736 442 -255 1479 29 744 -27 1180 28 738 1089 113 882 -210 2130 -152 1031 -87 1853 1173 1761 802 846 920 281 1153 -525 2165 -96 1583 -271 1036 -121 868 -1401 -1278 -1130 -1014 -496 -1439 -330 -2388 -402 -1856 817 -171 1796 1196 617 810 -434 -228 -2070 -700 -2295 1509 235 1022 -717 329 -1877 -1821 -746 -1884 -708 -2395 -279 -266 1672 1321 2697 412 483 -1745 -319 -1176 -68 312 343 1067 527 1663 238 1611 -383 -292 172 20 322 -575 -349 -1274 -388 -1077 666 -536 1840 1692 1187 -1045 -776 -1910 SS 20231001T141643.4Z 8674.594947 256 1 49.27 2 75.88 106.70 76.79 278.02 0.00 1 0.00 1 0 17 5.727e-02 7.067e-03 9.058e-03 5.644e-04 4.393068e-01 2.871046e-04 5.046206e-03 -6.000000e+00 3.228584e-02 226.62 -2.00 3.45 -2.00 319.80 0.00e+00 1.540310e-03 8.467202e-05 8.184152e-04 -6.000000e+00 1.396156e-03 277.69 -2.00 20.00 -2.00 319.21 0.00e+00 4.013 0.001 302.00 328.00 3 7.3549e-01 8.2344e-04 3.9967e-02 -6.0000e+00 8.0184e-02 -7.0960e-03 9.7970e-04 2.2595e-02 -6.0000e+00 8.7113e-02 -2.0043e-03 8.2918e-04 1.1739e-02 -6.0000e+00 5.1779e-02 -3.2747e-03 4.3391e-04 3.8429e-03 -6.0000e+00 2.2133e-02 5.5554e-03 4.2352e-05 1.6194e-05 4.1961e-05 -6.0000e+00 1.4888e-03 8.5142e-03 0.0000e+00 11 8 0 10 0 0 97.82 18.40 0.23 0.00851 0.00883 731 159 1 5 0 67.390 21.27 15.00 18.40 23.62 13.1 828.65 -15224 -19669 -16475 -14522 -20791 -23955 -25044 -15418 -16163 -13646 -16130 -15710 -12340 -8910 -3817 -2979 -1620 -2274 -1057 -1838 292 -2348 -492 -2789 -1322 -1711 -2518 -3741 -4285 -4975 -2101 -1198 93 -780 -4090 -5017 -5381 -3298 -1505 198 -719 113 200 101 780 633 605 -7 -469 -381 819 723 1212 1278 1287 1073 963 235 -10 -158 446 1332 2412 2982 1486 617 -539 -1441 48 616 1015 1176 728 834 85 -919 -1748 -2982 -2189 -2117 -1536 -1380 -2042 -1755 -1028 -249 588 977 1384 1197 886 172 -754 -864 -688 -528 315 1131 789 197 -305 -1281 -1288 -588 -1126 -1163 -770 -553 115 826 1036 920 659 191 -436 -638 -641 -281 72 156 -37 542 679 376 441 -224 -699 51 -62 -182 -93 -327 -455 -178 -64 20 179 663 431 111 -104 -503 -508 -241 -381 -332 -282 -387 -435 -486 -309 -374 -335 -414 -421 -377 -323 -160 -133 -78 -119 -59 -108 17 -144 -30 -188 -95 -131 -199 -288 -315 -371 -169 -110 10 -87 -455 -539 -624 -439 -240 37 -155 26 48 25 191 158 151 -2 -120 -100 229 224 404 458 486 419 388 96 -4 -62 178 569 1137 1547 820 329 -274 -729 26 344 631 771 482 531 51 -540 -938 -1555 -1196 -1331 -1024 -1038 -1690 -1528 -947 -244 606 1043 1482 1250 867 156 -640 -716 -609 -526 354 1321 1013 257 -378 -1458 -1446 -655 -1364 -1397 -965 -730 161 1251 1702 1480 1053 313 -667 -919 -910 -413 112 259 -64 897 1087 583 653 -320 -953 69 -91 -295 -163 -564 -811 -330 -125 41 384 1446 950 241 -215 -993 -967 SS 20231001T142226.2Z 8674.598915 259 1 49.29 2 74.84 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