File name: Pandora204s1_BoulderCO-NCAR_20231104_L2Fit_fout2c2d20210826p1-8.txt File generation date: 20240212T181404.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Ivan Ortega Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 204 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora204_OF_v3d20210322.txt Instrument calibration file used: Pandora204s1_CF_v2d20210826.txt Level 1 file used: Pandora204s1_BoulderCO-NCAR_20231104_L1_smca1c2d20210826p1-8.txt Full location name: National Center for Atmospheric Research Short location name: BoulderCO-NCAR Country of location: United States Location latitude [deg]: 40.0375 Location longitude [deg]: -105.2420 Location altitude [m]: 1616 Local noon date: 20231104 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 232 374 Nominal wavelengths inside fitting window [nm]: 305.0564 305.1973 305.3381 305.4790 305.6198 305.7606 305.9014 306.0422 306.1829 306.3237 306.4645 306.6052 306.7459 306.8866 307.0273 307.1680 307.3087 307.4494 307.5901 307.7307 307.8713 308.0120 308.1526 308.2932 308.4338 308.5743 308.7149 308.8555 308.9960 309.1365 309.2771 309.4176 309.5581 309.6985 309.8390 309.9795 310.1199 310.2604 310.4008 310.5412 310.6816 310.8220 310.9624 311.1028 311.2431 311.3835 311.5238 311.6641 311.8044 311.9447 312.0850 312.2253 312.3656 312.5058 312.6461 312.7863 312.9265 313.0667 313.2069 313.3471 313.4873 313.6274 313.7676 313.9077 314.0478 314.1879 314.3280 314.4681 314.6082 314.7483 314.8883 315.0284 315.1684 315.3084 315.4484 315.5884 315.7284 315.8684 316.0083 316.1483 316.2882 316.4281 316.5681 316.7080 316.8478 316.9877 317.1276 317.2674 317.4073 317.5471 317.6869 317.8267 317.9665 318.1063 318.2461 318.3859 318.5256 318.6654 318.8051 318.9448 319.0845 319.2242 319.3639 319.5035 319.6432 319.7828 319.9225 320.0621 320.2017 320.3413 320.4809 320.6205 320.7600 320.8996 321.0391 321.1786 321.3182 321.4577 321.5971 321.7366 321.8761 322.0156 322.1550 322.2944 322.4339 322.5733 322.7127 322.8520 322.9914 323.1308 323.2701 323.4095 323.5488 323.6881 323.8274 323.9667 324.1060 324.2453 324.3845 324.5238 324.6630 324.8022 324.9414 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231104T141438.5Z 8708.593502 266 1 49.29 2 83.58 116.34 26.46 240.69 0.00 1 0.00 1 0 17 7.693e-01 1.138e-02 2.913e-01 5.144e-03 8.521915e-01 2.854020e-03 8.848210e-03 -6.000000e+00 4.346628e-01 223.54 -2.00 3.45 -2.00 322.11 0.00e+00 5.351888e-03 1.303677e-03 1.292509e-03 -6.000000e+00 1.775090e-02 273.13 -2.00 20.00 -2.00 321.75 0.00e+00 8.123 0.009 302.00 328.00 3 4.1269e+00 9.4489e-03 8.0459e-02 -6.0000e+00 1.0779e+00 2.4608e-01 1.5845e-02 4.6590e-02 -6.0000e+00 1.1769e+00 -3.8498e-01 1.9786e-02 2.8350e-02 -6.0000e+00 6.9416e-01 1.5844e-01 9.2480e-03 1.0321e-02 -6.0000e+00 2.9261e-01 5.0011e-06 -7.6529e-04 1.4694e-04 1.3347e-04 -6.0000e+00 2.0948e-02 -2.3378e-02 7.1625e-05 12 8 8 10 0 0 20.88 18.38 0.30 -0.02338 -0.02913 172 38 1 5 0 286.510 21.27 15.00 18.38 9.33 12.9 740.23 -271398 -41989 -261246 -209470 -129586 -250516 -263245 -291126 -141074 -242374 -225352 -234238 -193261 -140165 172364 -74653 -108528 -103064 -72309 -109720 -25133 -130944 -69891 -73598 -57525 -76359 -52841 -71209 -60403 -39187 -69326 -32546 -41528 3277 -35069 -31658 -38707 -24478 -10696 10384 35405 -1337 2768 13992 -11056 1072 5407 -3023 5592 19579 17798 21953 15592 8272 13834 19457 7567 5508 12438 -227 5454 14344 10364 12048 9875 11177 8786 1082 8745 7119 5333 7168 3679 1310 4518 -142 843 -3773 -3356 -1482 -1224 308 -1951 -259 -1178 100 1836 327 1690 669 684 -1188 -2181 -3867 -1676 -2240 426 945 -68 70 -47 -1980 -1054 -877 -1847 -1747 -1737 -1126 -634 132 513 47 267 -610 -856 -878 54 -318 -11 20 512 1681 1809 861 668 -248 43 681 57 -9 201 -62 -114 -2 -134 -319 353 621 500 -325 60 -714 -686 -1981 -211 -2383 -1146 -650 -1828 -2281 -3718 -708 -2321 -1953 -2564 -1851 -1195 865 -562 -1237 -1269 -798 -1701 -189 -2568 -842 -997 -721 -1114 -689 -1107 -849 -491 -1328 -549 -928 58 -816 -693 -971 -625 -293 279 856 -51 109 511 -529 47 237 -153 281 938 982 1332 1131 654 1116 1562 709 527 1076 -22 499 1319 1153 1536 1424 1626 1319 184 1528 1467 1255 1750 926 318 965 -28 155 -748 -753 -397 -394 106 -770 -108 -528 47 896 168 857 333 320 -533 -964 -1815 -876 -1400 308 794 -65 69 -44 -1701 -798 -640 -1440 -1450 -1522 -1059 -659 157 693 69 411 -942 -1275 -1259 76 -473 -17 33 818 2529 2592 1207 909 -331 55 906 87 -17 406 -138 -269 -6 -338 -856 964 1715 1381 -872 161 -1789 -1628 SS 20231104T142602.0Z 8708.601412 269 1 49.21 2 81.65 118.30 28.37 244.33 0.00 1 0.00 1 0 17 4.498e-01 7.236e-03 1.698e-01 2.097e-03 7.112628e-01 1.124500e-03 7.611444e-03 -6.000000e+00 2.541109e-01 223.54 -2.00 3.45 -2.00 321.54 0.00e+00 5.495232e-03 4.634138e-04 8.298757e-04 -6.000000e+00 1.037735e-02 273.13 -2.00 20.00 -2.00 321.20 0.00e+00 6.487 0.005 302.00 328.00 3 4.0997e+00 3.4857e-03 6.4642e-02 -6.0000e+00 6.3018e-01 6.0558e-02 5.2271e-03 3.7747e-02 -6.0000e+00 6.8806e-01 -1.0738e-01 6.4370e-03 2.1978e-02 -6.0000e+00 4.0582e-01 4.4432e-02 3.1360e-03 7.6671e-03 -6.0000e+00 1.7106e-01 2.0832e-05 -7.4638e-04 6.0979e-05 9.4047e-05 -6.0000e+00 1.2247e-02 -2.3366e-02 5.6214e-05 11 8 0 10 0 0 99.46 18.38 0.19 -0.02337 -0.02897 419 91 1 5 0 117.430 21.27 15.00 18.38 10.25 12.8 746.01 -197255 83140 -182672 11398 -213379 -113545 -205350 -64793 -121754 -112740 -123347 -105076 -87671 -107265 10421 -52353 -18263 -55627 -4747 -33523 -811 -31470 -39909 -13036 -33200 -16549 -30368 -18970 -47423 -13580 -41494 -7735 -12869 4842 -592 -3415 -5208 -6885 445 -5616 11414 -7696 7394 -3610 4813 -1603 5834 4496 2448 5118 5357 5160 2889 7242 1836 5545 931 615 -1436 -749 222 3511 4028 4251 3421 2662 3181 404 2165 928 2240 1172 1325 135 -458 -1140 -2847 -2700 -2512 -959 -1695 -241 -2460 -938 -1112 69 370 586 1669 935 1218 -641 -398 -1255 -963 -1477 535 1012 744 129 -269 -1124 -934 318 -1672 -1153 -1331 -490 -100 849 538 433 262 156 -668 -324 -251 -432 156 -266 330 633 1049 405 357 -355 -364 605 -30 -15 -276 -106 -350 83 -271 -144 156 746 302 -10 -41 -470 -366 -1467 170 -1630 23 -2255 -464 -2214 -212 -724 -671 -871 -703 -636 -1276 50 -594 -173 -796 -49 -499 -9 -480 -626 -184 -571 -280 -559 -339 -1035 -250 -1117 -185 -386 135 -17 -101 -168 -265 18 -293 578 -517 456 -260 326 -120 420 344 203 447 521 570 337 888 255 777 141 94 -219 -111 33 560 734 887 784 617 725 98 562 282 752 421 475 47 -145 -327 -769 -733 -756 -340 -719 -117 -1355 -544 -688 42 237 388 1099 647 788 -395 -235 -761 -649 -1167 453 985 807 145 -288 -1093 -814 267 -1522 -1112 -1354 -530 -117 1117 798 694 430 251 -1028 -474 -365 -654 248 -445 547 1007 1593 599 509 -492 -487 822 -46 -26 -542 -222 -781 184 -644 -361 402 1935 789 -27 -97 -1120 -833 SS 20231104T145800.4Z 8708.623616 279 1 49.59 2 76.42 124.07 34.00 252.84 0.00 1 0.00 1 0 25 7.649e-02 5.899e-03 1.254e-02 5.725e-04 4.842565e-01 2.908024e-04 5.502912e-03 -6.000000e+00 4.321722e-02 223.53 -2.00 3.45 -2.00 320.10 0.00e+00 2.325147e-03 8.494943e-05 2.855958e-04 -6.000000e+00 1.764890e-03 273.12 -2.00 20.00 -2.00 319.79 0.00e+00 4.161 0.001 302.00 328.00 3 4.1497e+00 8.1538e-04 4.1876e-02 -6.0000e+00 1.0718e-01 5.9244e-03 9.7933e-04 2.4358e-02 -6.0000e+00 1.1702e-01 -5.8720e-03 9.5206e-04 1.2891e-02 -6.0000e+00 6.9019e-02 -2.1219e-03 5.0846e-04 4.0738e-03 -6.0000e+00 2.9093e-02 1.5384e-04 -5.4857e-04 1.6812e-05 4.6798e-05 -6.0000e+00 2.0830e-03 -2.3689e-02 4.6807e-05 10 0 0 10 0 0 99.79 18.38 0.21 -0.02369 -0.02781 1107 241 1 5 0 44.500 21.27 15.00 18.38 15.26 12.9 783.15 -17874 -24808 -20911 -23315 -23242 -33767 -28642 -27872 -21840 -22654 -24560 -17738 -17416 -11451 -8161 -3405 -3078 -1342 -1481 130 -2179 -1081 -1457 -2435 -3381 -4607 -3826 -6947 -5834 -4985 -3019 -1813 745 -2414 -4240 -4361 -4652 -2299 -1107 -1132 -1182 -437 -599 -272 563 200 383 618 -194 267 1145 1138 1576 1808 1313 1179 673 -260 -275 -10 1041 1469 2544 2617 865 528 292 -604 931 639 486 885 253 631 -266 -771 -1305 -2225 -1542 -1679 -1310 -1241 -2144 -1603 -828 -508 466 683 1218 970 960 396 -474 -468 -380 -370 319 1252 346 65 -179 -847 -598 21 -1279 -1252 -838 -618 229 743 713 448 445 23 -337 -241 -237 -218 38 -190 -181 548 670 294 315 -325 -535 705 86 -123 -121 -380 -321 -58 -67 -86 287 593 253 7 6 -471 -381 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