File name: Pandora204s1_BoulderCO-NCAR_20231119_L2Fit_fout2c2d20210826p1-8.txt File generation date: 20231120T073404.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Ivan Ortega Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 204 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora204_OF_v3d20210322.txt Instrument calibration file used: Pandora204s1_CF_v2d20210826.txt Level 1 file used: Pandora204s1_BoulderCO-NCAR_20231119_L1_smca1c2d20210826p1-8.txt Full location name: National Center for Atmospheric Research Short location name: BoulderCO-NCAR Country of location: United States Location latitude [deg]: 40.0375 Location longitude [deg]: -105.2420 Location altitude [m]: 1616 Local noon date: 20231119 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 232 374 Nominal wavelengths inside fitting window [nm]: 305.0564 305.1973 305.3381 305.4790 305.6198 305.7606 305.9014 306.0422 306.1829 306.3237 306.4645 306.6052 306.7459 306.8866 307.0273 307.1680 307.3087 307.4494 307.5901 307.7307 307.8713 308.0120 308.1526 308.2932 308.4338 308.5743 308.7149 308.8555 308.9960 309.1365 309.2771 309.4176 309.5581 309.6985 309.8390 309.9795 310.1199 310.2604 310.4008 310.5412 310.6816 310.8220 310.9624 311.1028 311.2431 311.3835 311.5238 311.6641 311.8044 311.9447 312.0850 312.2253 312.3656 312.5058 312.6461 312.7863 312.9265 313.0667 313.2069 313.3471 313.4873 313.6274 313.7676 313.9077 314.0478 314.1879 314.3280 314.4681 314.6082 314.7483 314.8883 315.0284 315.1684 315.3084 315.4484 315.5884 315.7284 315.8684 316.0083 316.1483 316.2882 316.4281 316.5681 316.7080 316.8478 316.9877 317.1276 317.2674 317.4073 317.5471 317.6869 317.8267 317.9665 318.1063 318.2461 318.3859 318.5256 318.6654 318.8051 318.9448 319.0845 319.2242 319.3639 319.5035 319.6432 319.7828 319.9225 320.0621 320.2017 320.3413 320.4809 320.6205 320.7600 320.8996 321.0391 321.1786 321.3182 321.4577 321.5971 321.7366 321.8761 322.0156 322.1550 322.2944 322.4339 322.5733 322.7127 322.8520 322.9914 323.1308 323.2701 323.4095 323.5488 323.6881 323.8274 323.9667 324.1060 324.2453 324.3845 324.5238 324.6630 324.8022 324.9414 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231119T143318.4Z 8723.606463 61 1 49.08 2 83.68 122.11 147.41 63.59 0.00 1 0.00 1 0 17 5.625e-01 1.927e-02 3.987e-01 1.243e-02 9.088525e-01 7.106552e-03 9.432658e-03 -6.000000e+00 3.216058e-01 222.59 -2.00 3.45 -2.00 322.22 0.00e+00 5.401977e-03 3.278340e-03 1.403244e-03 -6.000000e+00 1.384062e-02 271.18 -2.00 20.00 -2.00 321.87 0.00e+00 8.225 0.010 302.00 328.00 3 5.4859e+00 2.3763e-02 8.2536e-02 -6.0000e+00 7.9773e-01 6.0588e-01 3.6121e-02 4.8263e-02 -6.0000e+00 8.7300e-01 -9.3243e-01 4.1869e-02 2.8584e-02 -6.0000e+00 5.1022e-01 3.9789e-01 1.9987e-02 1.0400e-02 -6.0000e+00 2.1766e-01 1.0704e-06 -1.0482e-03 3.5967e-04 1.4319e-04 -6.0000e+00 1.5934e-02 -2.5042e-02 1.1094e-04 12 8 8 10 0 0 98.09 18.41 0.32 -0.02504 -0.03292 41 9 1 5 0 1196.850 21.27 15.00 18.41 10.69 12.9 754.67 900000 -159408 -235301 900000 -146369 900000 -243656 900000 -98682 900000 -182823 -217858 -142748 60189 900000 -115696 -58517 -119649 28732 77504 16055 -37582 -86293 -891 48416 93442 -75510 -7647 -85348 900000 -52642 152346 -1347 47736 21521 10089 44337 -26806 -3031 1216 79612 -2462 29652 -9624 53747 -1185 10179 -1843 15317 29250 24621 18874 27793 72142 20060 26158 28629 27469 21497 24728 34613 46211 5517 19531 29688 17153 28322 2737 10995 11808 15371 4611 12651 9346 14899 9753 -11412 5261 -2806 2501 -2174 4676 -3036 2579 -3864 1762 297 3061 101 -187 4140 169 -2093 -7906 -1471 -3904 969 -1424 303 -1068 -2090 -793 -1434 -1652 -3404 -1688 -2566 -183 -1197 -797 -915 757 -1404 -602 -1203 -728 -1959 182 -156 -64 585 2358 2615 1395 1700 1037 844 1584 600 352 -502 1068 -427 434 -213 165 -75 1189 307 363 -234 -1320 -2165 900000 -1943 -6230 900000 -1771 900000 -5516 900000 -1194 900000 -2870 -5254 -2158 728 900000 -2790 -950 -3767 348 938 194 -582 -2089 -11 586 1131 -1887 -98 -2232 900000 -1319 1844 -31 747 422 209 693 -920 -99 45 1612 -114 1070 -509 1596 -59 470 -99 753 1371 1336 1213 1816 3417 1628 2088 2284 2195 1749 1874 2403 3112 616 2209 3361 2229 3345 427 1744 2130 2970 1036 2612 1872 2575 1582 -2103 850 -553 564 -614 1441 -1129 975 -1642 751 135 1395 47 -86 1719 69 -856 -3573 -712 -2298 644 -1130 266 -988 -1871 -632 -1024 -1134 -2498 -1298 -2098 -158 -1159 -884 -1165 1048 -2069 -881 -1715 -1004 -2732 258 -235 -99 895 3371 3554 1866 2205 1320 1047 2031 886 608 -988 2257 -976 1053 -557 452 -210 3335 869 988 -599 -3161 -4937 SS 20231119T144457.5Z 8723.614554 64 1 18.33 2 81.81 124.14 145.46 66.68 0.00 1 0.00 1 0 17 5.438e-01 1.141e-02 2.900e-01 7.469e-03 7.765907e-01 4.066531e-03 8.257023e-03 -6.000000e+00 3.087560e-01 222.59 -2.00 3.45 -2.00 321.57 0.00e+00 5.012910e-03 1.698033e-03 9.261200e-04 -6.000000e+00 1.421145e-02 271.18 -2.00 20.00 -2.00 321.24 0.00e+00 6.602 0.005 302.00 328.00 3 5.9571e+00 1.2634e-02 6.7154e-02 -6.0000e+00 7.6774e-01 1.3939e-01 1.9333e-02 4.1003e-02 -6.0000e+00 8.3993e-01 -2.3304e-01 2.3763e-02 2.4209e-02 -6.0000e+00 4.9193e-01 1.0066e-01 1.1523e-02 8.5403e-03 -6.0000e+00 2.0907e-01 2.7667e-06 -6.1546e-04 2.1037e-04 1.0245e-04 -6.0000e+00 1.5203e-02 -2.5500e-02 9.8279e-05 12 9 9 12 9 1 97.68 18.41 0.14 -0.02550 -0.03012 17 10 1 5 0 1017.730 21.27 15.00 18.41 11.09 12.8 756.86 -290212 900000 -226319 157230 -190309 51880 -201041 900000 -177935 900000 900000 -228090 900000 -19351 900000 -122456 26315 -49573 -35804 -67906 -19595 -40355 -61428 -40594 -96087 -32664 -70123 13756 -59633 -11534 -66569 744 -36195 22115 8883 13991 32951 1167 6344 6982 6752 9229 17664 12626 -1942 4677 8696 8842 14643 20663 12298 21762 3477 4831 681 7923 -4020 9586 -2416 1828 209 3968 8048 6035 6000 2563 3819 -1178 6231 3102 5910 1927 4960 1879 -366 1839 -2413 -1801 -20 -1409 -2518 810 -2499 -1292 -2455 -1817 1585 837 432 -835 1105 -709 -499 -1567 -1264 -1612 47 -87 450 779 -594 -273 -908 -803 -1478 -1643 -861 -539 -193 592 200 645 712 -479 -745 -692 -461 57 -151 -205 201 777 1230 1529 1122 -411 -589 1016 -73 -195 36 -317 -340 35 -16 -111 158 773 819 -154 -511 -695 -615 -4474 900000 -2656 1144 -1536 377 -1802 900000 -1608 900000 900000 -4210 900000 -141 900000 -2323 191 -641 -449 -1205 -233 -579 -1090 -644 -2695 -553 -1700 157 -1317 -179 -2014 15 -1208 486 219 322 681 37 230 299 330 481 904 703 -126 294 546 582 972 1405 1003 1835 383 576 90 1030 -604 1273 -350 249 29 585 1307 1144 1243 556 817 -273 1475 866 1792 640 1598 593 -108 481 -612 -460 -6 -475 -1013 365 -1288 -703 -1431 -1115 992 544 283 -539 664 -408 -278 -905 -810 -1204 40 -85 484 857 -633 -264 -799 -687 -1340 -1581 -861 -574 -223 761 287 992 1122 -753 -1131 -1012 -670 86 -238 -334 325 1205 1828 2205 1577 -569 -794 1386 -112 -337 68 -645 -725 77 -37 -275 399 1964 2082 -385 -1214 -1560 -1325 SS 20231119T151829.1Z 8723.637837 74 1 49.63 2 76.70 130.27 139.64 74.37 0.00 1 0.00 1 0 25 1.463e-01 6.772e-03 7.460e-02 2.734e-03 5.335663e-01 1.399297e-03 6.017044e-03 -6.000000e+00 8.236963e-02 222.59 -2.00 3.45 -2.00 320.43 0.00e+00 3.149576e-03 4.500410e-04 3.627770e-04 -6.000000e+00 3.375713e-03 271.18 -2.00 20.00 -2.00 320.12 0.00e+00 4.246 0.001 302.00 328.00 3 6.9653e+00 3.9861e-03 4.3863e-02 -6.0000e+00 2.0385e-01 2.7067e-02 4.9470e-03 2.6856e-02 -6.0000e+00 2.2270e-01 -2.9006e-02 5.1319e-03 1.4444e-02 -6.0000e+00 1.3144e-01 9.8309e-03 2.6959e-03 4.6541e-03 -6.0000e+00 5.5531e-02 8.0437e-06 -5.5470e-04 7.9356e-05 5.5037e-05 -6.0000e+00 3.9822e-03 -2.5403e-02 4.8261e-05 11 8 0 10 0 0 98.48 18.41 0.20 -0.02540 -0.02957 61 13 1 5 0 813.380 21.27 14.99 18.41 11.99 12.9 763.24 -53032 -14166 -52805 -31333 -84650 -16303 -68145 -51633 -40815 -40164 -7132 -38887 -29883 -22695 -17167 809 -5632 1439 -8893 -295 -6428 -5038 47 4071 -15807 -57 -8498 -6380 -10800 -5777 -5941 4949 1473 -1913 -4975 -4587 -7272 -6177 804 -1839 1509 292 502 -1101 1975 2211 1239 307 -1234 989 395 2707 1589 1756 572 2262 301 -78 12 832 1164 994 2330 2891 1501 977 562 -232 1107 1027 1573 762 117 1069 57 -1232 -2677 -2336 -1654 -1809 -1616 -830 -2620 -1655 -1380 -369 482 630 1152 664 1046 179 -228 -819 -131 -554 341 1709 295 251 -192 -912 -599 36 -1602 -1535 -1131 -456 173 821 758 613 418 71 -375 -524 69 -437 -143 -143 -276 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